Photodetecting and light-emitting devices based on two-dimensional materials

Two-dimensional （2D） materials, e.g., graphene, transition metal dichalcogenides （TMDs）, and black phosphorus （BP）, have demonstrated fascinating electrical and optical characteristics and exhibited great potential in optoelectronic applications. High-performance and multifunctional devices were achieved by employing diverse designs, such as hybrid systems with nanostructured materials, bulk semiconductors and organics, forming 2D heterostructures. In this review, we mainly discuss the recent progress of 2D materials in high-responsive photodetectors, light-emitting devices and single photon emitters. Hybrid systems and van der Waals heterostructure-based devices are emphasized, which exhibit great potential in state-of-the-art applications.

Low insertion loss silicon-based spatial light modulator with high reflective materials outside Fabry–Perot cavity

The extinction ratio and insertion loss of spatial light modulator are subject to the material problem, thus limiting its applications. One reflection-type silicon-based spatial light modulator with high reflective materials outside the Fabry-Perot cavity is demonstrated in this paper. The reflectivity values of the outside-cavity materials with different film layer numbers are simulated. The reflectivity values of 6-pair Ta2O5/SiO2 films at 1550 nm are experimentally verified to be as high as 99.9%. The surfaces of 6-pair Ta2O5/SiO2 films are smooth: their root-mean-square roughness values are as small as 0.53 nm. The insertion loss of the device at 1550 nm is only 1.2 dB. The high extinction ratio of the device at 1550 nm and 11 V is achieved to be 29.7 dB. The spatial light modulator has a high extinction ratio and low insertion loss for applications.

A study on light-aging resistance of instrument panel materials and bumper materials on the automobile

The light-aging test method commonly used in the automotive industry is utilized to carry out light- aging research on automotive instrument panel （IP） materials and bumper materials. On one hand, the impacts of common light-aging test methods on aging degree of automotive component materials are reviewed; on the other hand, the light-aging resistances of different component materials are compared. The results show that, for light-aging behavior of IP materials, the aging degree of the third test method is not severer than that of the second method, but it is severer than that of the first method. The light-aging resistance of IP material A is al- most the same as that of IP material B. With reference to light-aging behavior of bumper materials, the aging de- gree of three common test methods indicates that the aging degree of the sixth test method is not severer than that of the fourth method, but it is severer than that of the fifth method. The light-aging resistance of bumper material D is superior to that of bumper material C.

Study on preparation and application performance of blue sky rare earth light storage and emission material

Under reduction atmosphere, a blue sky rare earth silicate light storage and emission material was prepared by high temperature solid phase synthesis. The best constituent ratio of this material was determined through orthogonal experiment, and its excitation and emission spectra and X-ray diffraction patterns were measured. And a comparative study was conducted on its application properties.

The New Technology of Composite Materials Repairing by Light Wave

The repairing of damaged composite materials becomes a hot research subject in the late 1990s.In this paper a new technology of repairing composite materials is given on the basis of our previous research.The light wave of 675nm transmitted by optical fiber is used as repairing light source,special repairable adhesive which can be stimulated by the light is adopted.By comparing the stiffness of the composite material before and after being damaged,it can be concluded that the mechanical property will not be changed with the feasible repairing technology.

Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials:A Review

As an environmentally friendly and high-density energy carrier,hydrogen has been recognized as one of the ideal alternatives for fossil fuels.One of the major challenges faced by“hydrogen economy”is the development of efficient,low-cost,safe and selective hydrogen generation from chemical storage materials.In this review,we summarize the recent advances in hydrogen production via hydrolysis and alcoholysis of light-metal-based materials,such as borohydrides,Mg-based and Al-based materials,and the highly efficient regeneration of borohydrides.Unfortunately,most of these hydrolysable materials are still plagued by sluggish kinetics and low hydrogen yield.While a number of strategies including catalysis,alloying,solution modification,and ball milling have been developed to overcome these drawbacks,the high costs required for the“one-pass”utilization of hydrolysis/alcoholysis systems have ultimately made these techniques almost impossible for practical large-scale applications.Therefore,it is imperative to develop low-cost material systems based on abundant resources and effective recycling technologies of spent fuels for efficient transport,production and storage of hydrogen in a fuel cell-based hydrogen economy.

Multidimensional(0D-3D)functional nanocarbon:Promising material to strengthen the photocatalytic activity of graphitic carbon nitride

As a prospective visible-light-responsive photochemical material,graphitic carbon nitride(g-C_(3)N_(4))has become a burgeoning research hot topics and aroused a wide interest as a metal-free semiconductor in the area of energy utilization and conversion,environmental protection due to its unique properties,such as facile synthesis,high physicochemical stability,excellent electronic band structure,and sustainability.However,the shortcomings of high recombination rate of charge carriers,relatively low electrical conductivity and visible light absorption impede its practical application.Various strategies,such as surface photosensitization,heteroatom deposition,semiconductor hybridization,etc.,have been applied to overcome the barriers.Among all the strategies,functional nanocarbon materials with various dimensions(0D~3D)attract much attention as modifiers of g-C_(3)N_(4)due to their unique electronic properties,optical properties,and easy functionalization.More importantly,the properties of these functional nanocarbon materials can be tuned by various dimensions and thus there will be a way to overcome the defects of g-C_(3)N_(4)by choosing different dimensional carbon materials.Distinguishing from some present reviews,this review starts with the fundamental physicochemical characteristics of g-C_(3)N_(4)materials,followed by analyzing the advantages of functional nanocarbon materials modifying gC_(3)N_(4).Then,we present a systematic introduction to various dimensional carbon materials.The design philosophy of carbon/g-C_(3)N_(4)composites and the advanced studies are exemplified in detail.Finally,a nichetargeting summary and outlook on the major challenges,opportunities for future research in high-powered carbon/g-C_(3)N_(4)composites was proposed.

Preparation of Ultra-light Xonotlite Thermal Insulation Material Using Carbide Slag

Using carbide slag as the calcareous materials, xonotlite thermal insulation material was successfully prepared via dynamic hydrothermal synthesis. The experimental results show that the xonotlite thermal insulation material is made up of large numbers of ＂chestnut bur shape＂ particles. Optimum conditions of calcination temperature of carbide slag, synthesis reaction temperature and time, stirring rate, CaO/SiO2 mol ratio, water/solid weight ratio, amount of fiberglass, molding pressures, dryness temperatures and the presence of dispersant （glycol and polyvinyl alcohol） favor the preparation of xonotlite thermal insulation material. The evaluation of xonotlite thermal insulation material reveals that the product is ultra-light and excellent in physical performances. Such a little amount of impurities in carbide slag has no effect on the phase, morphology, stability at high temperature and physical performances of products.

Preparation and characterization of the TiO_2-V_2O_5 photocatalyst with visible-light activity

Visible-light responsive TiO2-V2O5 catalyst was prepared using a binary sol-gel and in-situ intercalation method. The TiO2 sol and V2O5 sol were mixed to disperse the V2O5 species in the TiO2 phase at molecular level. The binary sol was then intercalated into interspaces of polyaniline （PANI） by means of in-situ polymerization of aniline. Conglomeration of the TiO2-V2O5 dusters during the calcination process was avoided because of the wrap of polyaniline. The surface mor- phology, the crystal phases, the structure, and the absorption spectra of （PANI）,/TiO2-V2O5 and the composite catalyst were studied using SEM, XRD, FT-IR, and UV-Vis. The photoactivity of the prepared catalyst under UV and visible light irradiation were evaluated by decolorization of methylene blue （MB） solution. The results showed that the composite catalyst displayed a homogeneous anatase phase, and the vanadium pentoxide species was highly dispersed in the TiO2 phase. The composite catalyst responded to visible light because of the narrowed band gap. In this study, the catalyst with the sol volume ratio of TiO2： V2O5 = 10：1 presented the best photocatalytic activity.

Preparation of Light-weight Spinel Refractories by Foaming-gel Process

Light-weight magnesium -aluminate spinel materi- als were prepared by foaming-gel process with polyalumi- nium chloride （PAC） as gel. Effect of solid loading in initial slurry on microstructure, porosity, pore size distri- bution, thermal conductivity and mechanical properties was investigated. The results show that the bulk density of the light-weight magnesium -aluminate spinel mate- rials is in the range of O. 7 1.2 g cm-3 ; pore size distribution curves show single-peak characteristics and the mean pore size is in the range of 30. 83 - 61.37 μm ; with the increase of solid loading, the linear shrinkage of the green body during firing and the permanent change in dimensions on heating at l 600 ℃ for 3 h de- crease, but the bulk density increases, the mechanical properties increase obviously; the maximum compressive strength and bending strength reach 35. 25 MPa and 9. 92 MPa, respectively, while the bulk density is 1. 16 g · cm ; and the thermal conductivity at 1 000 ℃ tea- ches 0. 371 W · m-1 . K-1 while the bulk density is O. 7 -3 g · cm

Experimental Study on the Use of Trass as a Supplementary Cementitious Material in Pervious Concrete

Abstract： The purpose of this paper is to evaluate the suitability of using trass as a supplementary cementing material in pervious concrete. OPC （Ordinary Portland Cement） was replaced in the concrete mix by 15%, 25% and 35% weight percentages and the results were compared with reference mixtures with 100% Portland cement. The variables in this study were trass content, aggregate size and water to cement ratio. Sixteen eases of concrete mixtures were tested to study physical and mechanical properties of hardened concrete, including porosity, permeability, compressive strength, splitting-tensile strength and flexural strength at various ages. Results indicated that mechanical properties of the pervious concrete marginally decreased with the increased content of trass when compared to the reference mixtures. However, at later ages the differences were insignificant.

Developing High Strength Pervious Concrete Mixtures with Local Materials

This study focuses on developing pervious concrete mixtures that have higher compressive strengths than conventional pervious concrete. This study also focuses on producing high strength pervious concrete that is also made with locally available materials. The study focused on four aspects of pervious concrete to produce high compressive strengths. These parameters were the effect of the coarse aggregate (type and size), the compaction of the test specimens, the effect of the w/c along with superplasticizers, and lastly the effect of silica fume. This study was completed parametrically in order to isolate each variable in order to see its individual affect. Once an optimum performance was obtained from one variable the best performing mixture was used for the next variable testing. This method allowed for the highest performing mixture to be obtained from each of the investigated variables. The results showed that high strength pervious concrete made with local aggregates, without polymers, and without fibers can be produced in the range of 15.44 MPa - 21.63 MPa. A porosity range 19.1% - 32.9% with a percolation rate range of 5.8 mm/s - 1.9 mm/s was also achieved, with a porosity of 19.4% and percolation rate of 2.6 mm/s for the highest performing mixture.

Time Dependent Surface Heat Transfer in Light Weight Aggregate Cement Based Materials

Surface temperature changes of building materials affect the calculation of heat flow and thus the energy use in heating and cooling. The surface heat transfer coefficient , limiting the heat flow between material surface and ambient air is normally taken as a constant. In this study we propose a time-dependent function . We estimate from unidirectional heat flow experiments with transient and steady-state conditions. Using temperature measurements and the conservation of energy at the surface including convective and irradiative boundary conditions, the value of was obtained both using Finite Difference and Taylor Polynomials methods. Numerical solutions of temperature distribution as function of time were improved with the obtained -functions compared to with constant . There were no clear difference between on different materials, and the final values observed were in the order of magnitude expected from the literature.

Light–matter interaction of 2D materials:Physics and device applications

In the last decade, the rise of two-dimensional （2D） materials has attracted a tremendous amount of interest for the entire field of photonics and opto-electronics. The mechanism of light-matter interaction in 2D materials challenges the knowledge of materials physics, which drives the rapid development of materials synthesis and device applications. 2D materials coupled with plasmonic effects show impressive optical characteristics, involving efficient charge transfer, plas- monic hot electrons doping, enhanced light-emitting, and ultrasensitive photodetection. Here, we briefly review the recent remarkable progress of 2D materials, mainly on graphene and transition metal dichalcogenides, focusing on their tunable optical properties and improved opto-electronic devices with plasmonic effects. The mechanism of plasmon enhanced light-matter interaction in 2D materials is elaborated in detail, and the state-of-the-art of device applications is compre- hensively described. In the future, the field of 2D materials holds great promise as an important platform for materials science and opto-electronic engineering, enabling an emerging interdisciplinary research field spanning from clean energy to information technology.

Removal of ammonia nitrogen from inorganic wastewater by AgBr/C_(3)N_(5)heterojunction under visible light irradiation

AgBr/C_(3)N_(5)composite was prepared by in-situ precipitation of AgBr on the surface of nitrogen-rich carbon nitride(C_(3)N_(5)).The crystal phase,chemical composition,elemental composition,spectral absorption and photoelectron-hole separation of the composite were characterized by X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),ultraviolet-visible diffuse reflectance spectroscopy(UV-vis DRS)and photoluminescence spectroscopy(PL).The construction of AgBr and C_(3)N_(5)heterojunction could broaden the spectral response range,realize the efficient separation of photoelectrons and holes,and thus improve the photocatalytic performance.The photocatalytic performance of the composite material was studied by simulating inorganic ammonia nitrogen wastewater with NH_(4)Cl solution.The dosage of the composite material was 0.10 g,the initial mass concentration of NH_(4)Cl solution was 100 mg/L,and the initial pH was 10.0.The removal rate of ammonia nitrogen by the composite material reached 90.27%after 60 min of simulated visible light irradiation.After 5 cycles,the removal rate of ammonia nitrogen only declined by 0.12%.The composite material showed good photocatalytic performance and stability.The Z-scheme mechanism effectively retained the reduction and oxidation activities of photoelectrons and holes,which could change O_(2)and H2O to active groups such as superoxide radicals(·O_(2)-)and hydroxyl radicals(·OH),respectively,achieving efficient removal of inorganic ammonia nitrogen.

Preparation of Novel Mesoporous Photocatalyst Bi₄O₅Br₂/SBA-15 with Enhanced Visible-Light Catalytic Activity

Photocatalysis is one of the most promising methods owing to its great potential to relieve environmental issue. To construct efficient photocatalyst with low energy consumption, mild catalytic conditions, and stable chemical properties are highly desired. In this work, a novel, highly active and environmental friendly mesoporous photocatalyst Bi4O5Br2/SBA-15 was synthesized by hydrothermal method, and its characteristics and visible-light catalytic activity were investigated. The synthesized photocatalyst consisted of Langmuir type IV hysteresis loops, which was confirmed to be a composite material with mesoporous structure. It exhibited a high visible-light absorption intensity and a low recombination rate of photo-generated electrons and holes. When the mass ratio of Bi/SiO2 was 30/100 during the synthesis, the obtained photocatalyst (Bi30/SBA-15) reflected the fastest Rhodamine B (RhB) removal rate and achieved 100% decolorization of RhB by both adsorption and degradation process. This high decolorization efficiency can also be maintained and realized by recycling the used composite in practice. The enhanced visible-light photocatalytic activity of novel Bi4O5Br2/SBA-15 photocatalyst can be ascribed to the existing active sites both inside and outside SBA-15 which enhanced the separation of photo-generated electrons and holes.

Evaluating Acid Resistance Effect of Fluoride-Releasing Dental Materials Using Quantitative Light-Induced Fluorescence-Digital in Vitro

As erosion has become one of the serious oral health problems, some fluoride-releasing dental materials have been developed to protect enamel from demineralization. The purpose of this study was to evaluate the antidemineralization effect of PRG Barrier Coat® and FujiVII® (fluoride-releasing dental materials). Four square windows measuring 1 mm2 were prepared on the labial enamel surface of each bovine tooth using masking tape and nail varnish. The first and second windows were half covered by fluoride-releasing material and control material, respectively, whereas the third and fourth windows were left untreated. All windows were immersed into 0.1 M lactic acid and 6wt% CM-cellulose (pH 4.5) at 38℃ for 21 days. Subsequently, the first and second windows were covered with nail varnish after removal of the materials, and the third and fourth windows were immersed into ultrapure water at 38℃ for 28 days after being half covered with fluoride-releasing and control materials, respectively. The following procedure was performed separately during evaluations of the fluoride-releasing materials, PRG Barrier Coat, and FujiVII®, using eight and six bovine teeth, respectively. The first, second, third, and fourth windows were classified into DM-PRG;Demineralized-PRG or DM-FujiVII;Demineralized-FujiVII, DM-TCM;Demineralized-traditional cement or DM-TGIC;De-mineralized-traditional glass ionomer cement, RM-PRG;Remineralized-PRG or RM-FujiVII;Re-mineralized-FujiVII, and RM-TCM;Remineralized- traditional cement or RM-TGIC;Remineral-ized-traditional glass ionomer cement, respectively. After nail varnish was removed, △Q values (mean ± SD) of the windows were measured using QLF-D and were compared between DM-PRG and DM-TCM, RM-PRG and RM-TCM, DM-FujiVII and DM-TGIC, and RM-FujiVII and RM-TGIC groups. △Q values of RM-PRG (-60 ± 44) and RM-FujiVII (-5.0 ± 10) were significantly higher than that of RM-TCM (-315 ± 193) and RM-TGIC (-56 ± 43), respectively. The fluoride releasing materials provided remineralization effects to bovine enamel.

Rational Design of Star-shaped Molecules with Benzene Core and Naphthalimide Derivatives End Groups as Organic Light-emitting Materials

A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminescent materials for organic light-emitting diodes（OLEDs）. The frontier molecular orbitals（FMOs） analysis has turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer（ICT）. The calculated results show that the optical and electronic properties of star-shaped molecules are affected by the substituent groups in N-position of 1,8-naphthalimide ring. Our results suggest that star-shaped molecules with n-butyl（1）,benzene（2）,thiophene（3）,thiophene S？,S？-dioxide（4）,benzo[c][1,2,5]thiadiazole（5）,and 2,7a-dihydrobenzo[d]thiazole（6） fragments are expected to be promising candidates for luminescent and electron transport materials for OLEDs. This study should be helpful in further theoretical investigations on such kind of systems and also to the experimental study for charge transport and/or luminescent materials for OLEDs.

AutoCAD渲染功能在工业设计中的应用

AutoCAD具有强大二维、三维设计和造型功能,而且已广泛地用在工程设计领域,但AutoCAD的渲染功能却往往被人忽略,其实它的渲染功能也非常强大,广泛地适用于建筑、工业设计、广告设计等行业。本文就AutoCAD2004版本的渲染功能进行了比较详尽的探讨。