Effect of organophosphorus pesticide pollution on soil animals

This paper studied the change in soil animal community in contaminated and irrigated area by organophosphorus pesticide waste water and its mechanism was discussed. The results showed that the species and quantities of soil animals decreased with organophosphorus pesticide pollution degree increasing. The species of soil animals decreased with average and rare population mainly decreasing, while the amount change was associated with that of the dominant population of Acarina, Collembola and Nematoda. Toxicity experiment demonstrated that the respiration intensity of soil animal was restrained obviously by pesticide pollution. After observation of SEM, the effect of pesticide pollution on the earthworm (\%Pheretima robusta)\% stomach intestinal mucosa damage has been observed, which showed the pesticide contamination may damage the earthworms bodies. Ulcerous focus and perforation on stomach mucosa were usually seen. The stomach microvilli appeared atrophic and disordered especially in the bodies of these earthworms growing in seriously polluted soil, bad atrophic phenomena were seen not only on the stomach mucosa microvilli but also on the cilia of the intestinal mucosa which appeared swollen as a spheroid. Under TEM, RER and Golgi compound dilatation, chondrisome swell and ridge disappearance were observed on cells of stomach epithelium mucosa of \%P.robusta\% collected from heavy polluted area. By calculation, the safety concentration of earthworm in methamidophos pesticide is 0\^2517 ml/L.

Spatial variability of organochlorine pesticides (DDTs and HCHs) in surface soils from the alluvial region of Beijing,China

The spatial variability in the concentrations of 1,2,3,4,5,6-hexachlorocyclohexane （HCH） and 1,1,1-trichloro-2,2-bis-（p-chloro- phenyl） ethane （DDT） in surface soils was studied on the basis of the analysis of 131 soil samples collected from the surface layer （0-20 cm depth） of the alluvial region of Beijing, China. The concentrations of total HCHs （including α-,β-, γ-, and δ-isomers） and total DDTs （including p,p＇-DDT, p,p＇-DDD, p,p＇-DDE, and o,p＇-DDT） in the surface soils tested were in the range from nondetectable to 31.72 μg/kg dry soil, with a mean value of 0.91, and from nondetectable to 5910.83 μg/kg dry soil, with a mean value of 32.13, respectively. It was observed that concentrations of HCHs in all soil samples and concentrations of DDTs in 112 soil samples were much lower than the first grade （50 μg/kg） permitted in ＂Environment quality standard for soils in China （GB 15618-1995）＂. This suggests that the pollution due to organochlorine pesticides was generally not significant in the farmland soils in the Beijing alluvial region. In this study, the spatial distribution and trend of HCHs and DDTs were analyzed using Geostatistical Analyst and GS＋（513）. Spatial distribution indicated how these pesticides had been applied in the past. Trend analysis showed that the concentrations of HCHs, DDTs, and their related metabolites followed an obvious distribution trend in the surface soils from the alluvial region of Beijing.

Comprehensive Treatment Technology of Pesticidecontaminated Soil

Access approach of pesticide into soil and its migration and transformation process in soil are analyzed in the paper. Furthermore, it is put forward that soil pollution can be prevented by enhancing farmers＇ consciousness of safe and reasonable application of pesticide, strengthening production and management of pesticide, adopting comprehensive prevention and control measures, and developing treatment technology of pesticide-contaminated soil.

Use of micellar liquid chromatography for rapid monitoring of fungicides post harvest applied to citrus wastewater

A method based on micellar liquid chromatography has been developed to simultaneously monitor four pesticides largely post-harvest applied to citrus：thiabendazole,pyrimethanil,o-phenylphenol and imazalil.Water samples were filtered and directly injected without other treatment,thus avoiding extraction steps.The composition of the mobile phase was optimized using a chemometrical approach to achieve and excellent resolution to 0.07 mol/L SDS/5%,V/V 1-pentanol buffered at p H 3.Mobile phase run through a C18 column at 1 m L/min at room temperature.The detection was performing by UV–Visible absorbance using a wavelength program：0–10 min,305 nm（for thiabendazole）;10–12;265 nm（for pyrimethanil）and 12–18,220 nm（o-phenylphenol and imazalil）.The developed method was validated following the guidelines of the US Environmental Protection Agency in terms of：quantitation range,（0.5–4 to 15μg/m L）,linearity（r2〉0.9995）,sensitivity（LOD,0.18–1.4μg/m L）,precision（〈9.2%）,trueness（93.9%–103.7%）,and ruggedness（〈9.9%）.It was found that the fungicides remain up to eight days in surface water at outdoor conditions.The method was used to screen the presence of the analytes in several waste water samples,and was proved to be useful in routine analysis.

Disruption of iron homeostasis and resultant health effects upon exposure to various environmental pollutants:A critical review

Environmental pollution has become one of the greatest problems in the world, and the concerns about environmental pollutants released by human activities from agriculture and industrial production have been continuously increasing. Although intense efforts have been made to understand the health effects of environmental pollutants, most studies have only focused on direct toxic effects and failed to simultaneously evaluate the long-term adaptive, compensatory and secondary impacts on health. Burgeoning evidence suggests that environmental pollutants may directly or indirectly give rise to disordered element homeostasis, such as for iron. It is crucially important to maintain concerted cellular and systemic iron metabolism. Otherwise, disordered iron metabolism would lead to cytotoxicity and increased risk for various diseases, including cancers. Thus, study on the effects of environmental pollutants upon iron homeostasis is urgently needed. In this review, we recapitulate the available findings on the direct or indirect impacts of environmental pollutants, including persistent organic pollutants（POPs）, heavy metals and pesticides, on iron homeostasis and associated adverse health problems. In view of the unanswered questions, more efforts are warranted to investigate the disruptive effects of environmental pollutants on iron homeostasis and consequent toxicities.

Minimization of methabenzthiazuron residues in leaching water using amended soils and photocatalytic treatment with TiO_2 and ZnO

In the present work, potential groundwater pollution by methabenzthiazuron （MTBU） and the effect of three different amendments （composted sheep manure, composted pine bark and spent coffee grounds） on its mobility were investigated under laboratory conditions. The efficiency of ZnO and TiO2 suspensions in the photocatalytic degradation of MTBU in leaching water was also investigated. The relative and cumulative breakthrough curves were obtained from disturbed soil columns. The presence and/or addition of organic matter drastically reduced the movement of the herbicide. On other hand, photocatalytic experiments showed that the addition of ZnO and TiO2 strongly enhances the degradation rate of this herbicide compared with the results of photolytic experiments under artificial light. ZnO appeared to be more effective in MTBU oxidation than TiO2. The results obtained point to the interest of using organic wastes and heterogeneous photocatalysis for reducing the pollution of groundwater by pesticide drainage.