Calculation of Interaction Parameters from Immiscible Phase Diagram of Alkali Metal or Alkali Earth Metal-Halide System by Means of Subregular Solution Model

In this paper, the interaction parameters in the subregular solution model, λ1 and λ2, are regarded as a linear function of temperature, T. Therefore, the molar excess Gibbs energy of A-B binary system may be reexpressed as follows:Gm^E=xAxB[(λ11+λ12T)+(λ21+λ22T)xB]The calculation of the model parameters, λ11, λ12, λ21and λ22, was carried out numerically from the phase diagrams for 11 alkali metal-alkali halide or alkali earth metal-halide systems. In addition, artificial neural network trained by known data has been used to predict the values of these model parameters. The predicted results are in good agreement with the .calculated ones. The applicability of the subregular solution model to the alkali metal-alkali halide or alkali earth metal-halide systems were tested by comparing the available experimental composition along the boundary of miscibility gap with the calculated ones which were obtained by using genetic algorithm. The good agreement between the calculated and experimental results across the entire liquidus is valid evidence in support of the model.

COMPUTERIZED PREDICTION OF INTERACTION PARAMETERSAND PHASE DIAGRAMS OF CONTINUOUS SOLID SOLUTION OFBINARY ALLOY SYSTEMS

The artificial neural network method has been applied to the relationship between the atomic parameters and intemction packeters of binary alloy Phases, and the principle of thermodynamics in combination with artificial neural network method has been used for the computerized phase diagrams of continuous solid solution of bigamy alloy systems. The computerized phase diagrams well agree with the real phase diagmms.

A Relation of the Noncommutative Parameters in Generalized Noncommutative Phase Space

We introduce the deformed boson operators which satisfy a deformed boson algebra in some special types of generalized noncommutative phase space. Based on the deformed boson algebra, we construct coherent state representations. We calculate the variances of the coordinate operators on the coherent states and investigate the corresponding Heisenberg uncertainty relations. It is found that there are some restriction relations of the noncommutative parameters in these special types of noncommutative phase space.

Tri-frequency spectrum method and results for resolving the parameters of Earth's liquid core free nutation

The parameters of Earth free core nutation (FCN) are two relatively significant geophysical parameters. Sasao et al. (1980) and Wahr and Bergen (1986) provided the theoretical estimation values of FCN parameters. Gwinn, Herring and Shapiro (1987) first obtained the observational values of FCN parameters by very long base Interference (VLBI) at Cambridge University. In the same year, Neuberg and Zurn in former West Germany and Hinderer in France began to retrieve FCN parameters by the observation of gravity tides and introduced the stacking method. The other scholars who researched into the same geophysical problems by applying the data of gravity tides basically followed the stacking method. The results they reached were similar to the observational result of FCN parameters given by Neuberg et al. in 1987. But the observational results of FCN parameters gained from gravity tides were not identical with those from VLBI, mainly because of the large difference of quality of FCN. So there was not an affirmative observational result of FCN parameters since then. In this paper, The authors firstly introduce the tri-frequency spectrum method with clearly geometrical and geophysical meaning for the resolution of FCN parameters , and the observational results of FCN parameters obtained from tide data at three superconducting gravity stations were accordant with those from VLBI, which will be relatively important to arriving at a certain observational result of FCN parameters.