Ferroelectric materials have enormous potential applications in advanced techniques. However, there are still many problems in its practical application. Dielectric and mechanical (internal friction) measurements are ...Ferroelectric materials have enormous potential applications in advanced techniques. However, there are still many problems in its practical application. Dielectric and mechanical (internal friction) measurements are very sensitive to phase transitions, relaxation process of point defects, domain walls and their mobility, which have severe effect on ferroelectric properties. These make them become very good means to investigate substantial information on structural features and to explore the fundamental principles in ferroelectric materials and their applications. In this paper, the dielectric and internal friction measurement were used to investigate the behaviors for point defects and phase transition in ferroelectric ceramics such as Bi_ 4-x La_ x Ti_ 3 O_ 12 , Bi_ 4 Ti_ 3-y Nb_ y O_ 12 , SrBi_ 2 Ti_ 2 O_ 9 , PbZr_ x Ti_ 1-x O_ 3 ,_ PMN-PT. They were used to clarify the mechanism for some ferroelectric behaviors.展开更多
Manganese silicide MnSi_(2-x) thin films have been prepared on n-type siliconsubstrates through solid phase reaction. The heterostructures were analyzed by X-ray diffraction,Rutherford backscattering spectroscopy, Fou...Manganese silicide MnSi_(2-x) thin films have been prepared on n-type siliconsubstrates through solid phase reaction. The heterostructures were analyzed by X-ray diffraction,Rutherford backscattering spectroscopy, Fourier transform infrared transmittance spectroscopy andthe four-point probe technique. The results show that two manganese silicides have been formedsequentially via the reaction of thin layer Mn with Si substrate at different irradiation annealingstages, i.e., MnSi at 450 deg C and MnSi_(1.73) at 550 deg C. MnSi_(1.73) phase exhibits preferredgrowth after irradiation with infrared. In situ four-point probe measurements of sheet resistanceduring infrared irradiation annealing show that nucleation of MnSi and phase transformation of MnSito MaSi_(1.73) occur at 410 deg C and 530 deg C, respectively; the MnSi phase shows metallicbehavior, while MnSi_(1.73) exhibits semiconducting behavior. Characteristic phonon bands ofMnSi_(2-x) silicides, which can be used for phase identification along with conventional XRDtechniques, have been observed by FTIR spectroscopy.展开更多
The nonlinear properties of rotating machinery vibration signals are presented. The relationship between faults and quadratic phase coupling is discussed. The mechanism that gives rise to quadratic phase coupling is a...The nonlinear properties of rotating machinery vibration signals are presented. The relationship between faults and quadratic phase coupling is discussed. The mechanism that gives rise to quadratic phase coupling is analyzed, and the coupling models are summarized. As a result, higher order spectra analysis is introduced into fault diagnosis of rotors. A brief review of the properties of higher order spectra is presented. Furthermore, the bicoherence spectrum is employed to extract the features that signify the machinery condition. Experiments show that bicoherence spectrum patterns of different faults are quite different, so it is proposed to identify the faults in rotors.展开更多
By using a microscopic sdIBM-2+2q.p. approach which is the phenomenological core plus two-quasi-particle model and the experimental single-particle energies, the levels of the ground-band, β-band, γ-band, and partia...By using a microscopic sdIBM-2+2q.p. approach which is the phenomenological core plus two-quasi-particle model and the experimental single-particle energies, the levels of the ground-band, β-band, γ-band, and partial two-quasi-particle states on 64~68 Ge isotopes are successfully reproduced. Based on the phenomenological model and microscopic approach, it has been deduced that no s-boson in the nucleus is breaking up and aligning; and that when one d-boson does, the minimum aligned energy can be calculated. This paper explicitly indicates that, with the increase of neutron number, an evolution process of PPT objectes, i.e. from the two-quasi-proton states (on64Ge nucleus) to the two-quasi-neutron states (on 68Ge nucleus) may take place in even Ge isotopes.展开更多
In this paper, we demonstrate the residual phase noise of a few microwave frequency dividers which usually limit the performance of frequency synthesizers. In order to compare these dividers under different operation ...In this paper, we demonstrate the residual phase noise of a few microwave frequency dividers which usually limit the performance of frequency synthesizers. In order to compare these dividers under different operation frequencies, we calculate additional time jitters of these dividers by using the measured phase noise. The time jitters are various from -0.1 fs to 43 fs in a bandwidth from 1 Hz to 100 Hz in dependent of models and operation frequencies. The HMC series frequency dividers exhibit outstanding performance for high operation frequencies, and the time jitters can be sub-fs. The time jitters of SP8401, MC10EP139, and MC100LVEL34 are comparable or even below that of HMC series for low operation frequencies.展开更多
The absorption–dispersion properties of a microwave-driven five-level atom embedded in an isotropic photonic bandgap(PBG) have been studied. Due to the singular density of modes(DOM) in the isotropic PBG and the dyna...The absorption–dispersion properties of a microwave-driven five-level atom embedded in an isotropic photonic bandgap(PBG) have been studied. Due to the singular density of modes(DOM) in the isotropic PBG and the dynamically coherence induced by the coupling fields, modified reservoir-induced transparency and quantum interference-induced transparency emerge simultaneously. Their interaction leads to ultra-narrow spectral structure. As a result of closed-loop configuration, these features can be manipulated by the amplitudes and relative phase of the coherently driven fields. The position and width of PBG also have an influence on the spectra. The theoretical studies can provide us with more efficient methods to control the atomic absorption–dispersion properties, which have applications in optical switching and slow light.展开更多
A drawn high density polyethylene(HDPE)has been measured by Raman spectroscopy and differential scanning calorimetry (DSC). The crystalline structure of drawn HDPE is analysed by the Raman internal modes in terms ...A drawn high density polyethylene(HDPE)has been measured by Raman spectroscopy and differential scanning calorimetry (DSC). The crystalline structure of drawn HDPE is analysed by the Raman internal modes in terms of mass fractions of the crystalline orthorhombic phase, the liquid- like amorphous phase and the disordered anisotropic phase. The mass fractions depend on draw temperature T;and draw ratio R;. The fraction of disordered anisotropic amorphous phase changes very little with, the T;and increases with increasing R;. Sum of the mass fractions of crystalline orthorhombic phase and the disordered anisotropic phase increases linearly as the same slope as the crystallinity W;determined from DSC measurements with increasing T;or R;and it is higher than the W;for all the samples. The results show that the mass fraction of disordered anisotropic phase is partially devoted by the taut tie molecules (TTM s) in the amorphous state. The dependence of the disordered anisotropic phase on T;and R;supports the mechanism of plastic deformation of fibre structure.展开更多
针对热障涂层制备过程中的厚度评估问题,通过数值模拟手段研究了光脉冲激励下制备在镍基高温合金上不同厚度的Ni Cr Al Y涂层表面热波瞬态响应规律;在此基础上分析了表面热波相位特征随涂层厚度的变化规律,结果表明特定频率范围的热波...针对热障涂层制备过程中的厚度评估问题,通过数值模拟手段研究了光脉冲激励下制备在镍基高温合金上不同厚度的Ni Cr Al Y涂层表面热波瞬态响应规律;在此基础上分析了表面热波相位特征随涂层厚度的变化规律,结果表明特定频率范围的热波相位特征与涂层厚度具有近似线性对应关系,但不同涂层厚度之间的相位差绝对值较小,不利于厚度定量评价;为提高不同厚度涂层之间的热波相位差,提出采用小波分解第二层细节系数对涂层表面热波进行重构,重构热波相位差比原始热波提高了约500倍,有利于提高涂层厚度评价的准确率;最后采用试验手段验证了模拟结果的准确性。展开更多
FT infrared spectrometer was used to obtain a series of infrared spectra at various temperatures of pentaerythritol(PE)、pentaglycerine(PG)、neopentylglycol(NPG) and their binary mixtures.The shifts of -OH absorption ...FT infrared spectrometer was used to obtain a series of infrared spectra at various temperatures of pentaerythritol(PE)、pentaglycerine(PG)、neopentylglycol(NPG) and their binary mixtures.The shifts of -OH absorption peak reveal the solid solid phase transition mechanisms and the connection of wave number shifts with temperature and enthalpies of phase transition.The solid solid phase transitions of the three polyols and their binary mixtures are known to transform from a low symmetric layered crystal structure to a highly symmetric face centered cubic structure.Experimental results support a mechanism which involves reversible breaking of nearest neighbor hydrogen resonance bonds in the molecular crystals at the transformation temperature.Infrared spectra show reversible increase in the wave number of the absorption peak of -OH groups with reversible breaking of the hydrogen bonds.This is in agreement with the experimental results of X ray diffraction and thermal analysis.展开更多
文摘Ferroelectric materials have enormous potential applications in advanced techniques. However, there are still many problems in its practical application. Dielectric and mechanical (internal friction) measurements are very sensitive to phase transitions, relaxation process of point defects, domain walls and their mobility, which have severe effect on ferroelectric properties. These make them become very good means to investigate substantial information on structural features and to explore the fundamental principles in ferroelectric materials and their applications. In this paper, the dielectric and internal friction measurement were used to investigate the behaviors for point defects and phase transition in ferroelectric ceramics such as Bi_ 4-x La_ x Ti_ 3 O_ 12 , Bi_ 4 Ti_ 3-y Nb_ y O_ 12 , SrBi_ 2 Ti_ 2 O_ 9 , PbZr_ x Ti_ 1-x O_ 3 ,_ PMN-PT. They were used to clarify the mechanism for some ferroelectric behaviors.
基金supported in part by the National Natural Science Foundation of China(Nos.52376114,92041001)the Natural Science Foundation of Jiangsu Province(No.BK20200069)the National Science and Technology Major Projects(Nos.J2019-Ⅲ-0015-0059,2017-Ⅲ-0005-0029).
基金This work has been supported jointly by the National Natural Science Foundation ofChina (Crant No. 69806005)the Natural Scie
文摘Manganese silicide MnSi_(2-x) thin films have been prepared on n-type siliconsubstrates through solid phase reaction. The heterostructures were analyzed by X-ray diffraction,Rutherford backscattering spectroscopy, Fourier transform infrared transmittance spectroscopy andthe four-point probe technique. The results show that two manganese silicides have been formedsequentially via the reaction of thin layer Mn with Si substrate at different irradiation annealingstages, i.e., MnSi at 450 deg C and MnSi_(1.73) at 550 deg C. MnSi_(1.73) phase exhibits preferredgrowth after irradiation with infrared. In situ four-point probe measurements of sheet resistanceduring infrared irradiation annealing show that nucleation of MnSi and phase transformation of MnSito MaSi_(1.73) occur at 410 deg C and 530 deg C, respectively; the MnSi phase shows metallicbehavior, while MnSi_(1.73) exhibits semiconducting behavior. Characteristic phonon bands ofMnSi_(2-x) silicides, which can be used for phase identification along with conventional XRDtechniques, have been observed by FTIR spectroscopy.
文摘The nonlinear properties of rotating machinery vibration signals are presented. The relationship between faults and quadratic phase coupling is discussed. The mechanism that gives rise to quadratic phase coupling is analyzed, and the coupling models are summarized. As a result, higher order spectra analysis is introduced into fault diagnosis of rotors. A brief review of the properties of higher order spectra is presented. Furthermore, the bicoherence spectrum is employed to extract the features that signify the machinery condition. Experiments show that bicoherence spectrum patterns of different faults are quite different, so it is proposed to identify the faults in rotors.
基金Supported by the Science Foundation of the Science-Technology Department of Guizhou Province China (Grant No. Qian-ji-he-ji-zi [2002] 3025)
文摘By using a microscopic sdIBM-2+2q.p. approach which is the phenomenological core plus two-quasi-particle model and the experimental single-particle energies, the levels of the ground-band, β-band, γ-band, and partial two-quasi-particle states on 64~68 Ge isotopes are successfully reproduced. Based on the phenomenological model and microscopic approach, it has been deduced that no s-boson in the nucleus is breaking up and aligning; and that when one d-boson does, the minimum aligned energy can be calculated. This paper explicitly indicates that, with the increase of neutron number, an evolution process of PPT objectes, i.e. from the two-quasi-proton states (on64Ge nucleus) to the two-quasi-neutron states (on 68Ge nucleus) may take place in even Ge isotopes.
基金supported by the National Natural Science Foundation of China under Grant No.91336101 and No.61127901the West Light Foundation of the Chinese Academy of Sciences under Grant No.2013ZD02
文摘In this paper, we demonstrate the residual phase noise of a few microwave frequency dividers which usually limit the performance of frequency synthesizers. In order to compare these dividers under different operation frequencies, we calculate additional time jitters of these dividers by using the measured phase noise. The time jitters are various from -0.1 fs to 43 fs in a bandwidth from 1 Hz to 100 Hz in dependent of models and operation frequencies. The HMC series frequency dividers exhibit outstanding performance for high operation frequencies, and the time jitters can be sub-fs. The time jitters of SP8401, MC10EP139, and MC100LVEL34 are comparable or even below that of HMC series for low operation frequencies.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11447232 and 11204367)
文摘The absorption–dispersion properties of a microwave-driven five-level atom embedded in an isotropic photonic bandgap(PBG) have been studied. Due to the singular density of modes(DOM) in the isotropic PBG and the dynamically coherence induced by the coupling fields, modified reservoir-induced transparency and quantum interference-induced transparency emerge simultaneously. Their interaction leads to ultra-narrow spectral structure. As a result of closed-loop configuration, these features can be manipulated by the amplitudes and relative phase of the coherently driven fields. The position and width of PBG also have an influence on the spectra. The theoretical studies can provide us with more efficient methods to control the atomic absorption–dispersion properties, which have applications in optical switching and slow light.
文摘A drawn high density polyethylene(HDPE)has been measured by Raman spectroscopy and differential scanning calorimetry (DSC). The crystalline structure of drawn HDPE is analysed by the Raman internal modes in terms of mass fractions of the crystalline orthorhombic phase, the liquid- like amorphous phase and the disordered anisotropic phase. The mass fractions depend on draw temperature T;and draw ratio R;. The fraction of disordered anisotropic amorphous phase changes very little with, the T;and increases with increasing R;. Sum of the mass fractions of crystalline orthorhombic phase and the disordered anisotropic phase increases linearly as the same slope as the crystallinity W;determined from DSC measurements with increasing T;or R;and it is higher than the W;for all the samples. The results show that the mass fraction of disordered anisotropic phase is partially devoted by the taut tie molecules (TTM s) in the amorphous state. The dependence of the disordered anisotropic phase on T;and R;supports the mechanism of plastic deformation of fibre structure.
基金Supported by Key Scientific Research Project of Hunan Provincial Department of Education (No. 22A0484)National Natural Science Foundation of China (No. 12104150)。
基金supported by the National Natural Science Foundation of China(No.41204091)New Teachers’ Fund for Doctor Stations,the Ministry of Education(No.20105122120001)Science and Technology Support Program from Science and Technology Department of Sichuan Province(No.2011GZ0244)
文摘针对热障涂层制备过程中的厚度评估问题,通过数值模拟手段研究了光脉冲激励下制备在镍基高温合金上不同厚度的Ni Cr Al Y涂层表面热波瞬态响应规律;在此基础上分析了表面热波相位特征随涂层厚度的变化规律,结果表明特定频率范围的热波相位特征与涂层厚度具有近似线性对应关系,但不同涂层厚度之间的相位差绝对值较小,不利于厚度定量评价;为提高不同厚度涂层之间的热波相位差,提出采用小波分解第二层细节系数对涂层表面热波进行重构,重构热波相位差比原始热波提高了约500倍,有利于提高涂层厚度评价的准确率;最后采用试验手段验证了模拟结果的准确性。
文摘FT infrared spectrometer was used to obtain a series of infrared spectra at various temperatures of pentaerythritol(PE)、pentaglycerine(PG)、neopentylglycol(NPG) and their binary mixtures.The shifts of -OH absorption peak reveal the solid solid phase transition mechanisms and the connection of wave number shifts with temperature and enthalpies of phase transition.The solid solid phase transitions of the three polyols and their binary mixtures are known to transform from a low symmetric layered crystal structure to a highly symmetric face centered cubic structure.Experimental results support a mechanism which involves reversible breaking of nearest neighbor hydrogen resonance bonds in the molecular crystals at the transformation temperature.Infrared spectra show reversible increase in the wave number of the absorption peak of -OH groups with reversible breaking of the hydrogen bonds.This is in agreement with the experimental results of X ray diffraction and thermal analysis.