In this paper, TitaiJum dioxide (TiO2) rutile single crystal was irradiated by infrared femtosecond laser pulses with repetition rate of 250 kHz. For a P-polarized femtosecond laser, the periodic nanograting structu...In this paper, TitaiJum dioxide (TiO2) rutile single crystal was irradiated by infrared femtosecond laser pulses with repetition rate of 250 kHz. For a P-polarized femtosecond laser, the periodic nanograting structure on the ablation crater surface was formed . The periodicity is much less than the laser wavelength. The direction of nanograting alignment depends on the polarization laser beam. Micro-Raman spectra show that the intensity of Eg Raman vibrating mode of rutile phase increases and that of Alg Raman vibrating mode decreases apparently within the ablation crater. With the increase of irradiation time and laser average power, the Raman vibrating modes of anatase phase emerged. Rutile phase of TiO2 single crystal is partly transformed into anatase phase.展开更多
In the present paper,we report a reproducible,cost effective,fast response method for detection of malathion and its effects on leukocytes in different human blood groups.Spectroscopic methods(UV-Vis spectrometry)an...In the present paper,we report a reproducible,cost effective,fast response method for detection of malathion and its effects on leukocytes in different human blood groups.Spectroscopic methods(UV-Vis spectrometry)and Fourier transform infrared coupled with solid phase extraction were applied for analyzing malathion content in human blood plasma.The spiking levels of malathion in the range of 0.1-1.7μg/mL were extracted from blood plasma samples using SPE.The present active functional groups(C=0;P-O-C;-OH;P=S)were also characterized.The recovery rate of malathion was 80%±4.5%.The calculated correlation coefficient was 0.9799,indicating the linearity of the results.The limit of detection(LOD)and limit of quantification(LOQ)were(0.1-1.7)μg/mL and(0.3-1.5)μg/mL,respectively.Malathion〈1.0μg/mL showed no significant change while higher levels of malathion exposure(1.5μg/mL and 3.0|ig/mL)reduced the number of white blood cells.In conclusion,the spectroscopic results may be useful to understand the mechanism of other pesticides such as methyl parathion and parathion.展开更多
基金Project supported by Shanghai Leading Academic Discipline Project, China (Grant No T0104), the Shanghai Nano-technology Promotion Center and Science & Technology of Shanghai Municipality, China (Grant No 0652nm005), Science Foundation of Shanghai Municipal Commission Education and Science and Technology Commission of Shanghai Municipal, China (Grant No 06PJ14042).
文摘In this paper, TitaiJum dioxide (TiO2) rutile single crystal was irradiated by infrared femtosecond laser pulses with repetition rate of 250 kHz. For a P-polarized femtosecond laser, the periodic nanograting structure on the ablation crater surface was formed . The periodicity is much less than the laser wavelength. The direction of nanograting alignment depends on the polarization laser beam. Micro-Raman spectra show that the intensity of Eg Raman vibrating mode of rutile phase increases and that of Alg Raman vibrating mode decreases apparently within the ablation crater. With the increase of irradiation time and laser average power, the Raman vibrating modes of anatase phase emerged. Rutile phase of TiO2 single crystal is partly transformed into anatase phase.
文摘In the present paper,we report a reproducible,cost effective,fast response method for detection of malathion and its effects on leukocytes in different human blood groups.Spectroscopic methods(UV-Vis spectrometry)and Fourier transform infrared coupled with solid phase extraction were applied for analyzing malathion content in human blood plasma.The spiking levels of malathion in the range of 0.1-1.7μg/mL were extracted from blood plasma samples using SPE.The present active functional groups(C=0;P-O-C;-OH;P=S)were also characterized.The recovery rate of malathion was 80%±4.5%.The calculated correlation coefficient was 0.9799,indicating the linearity of the results.The limit of detection(LOD)and limit of quantification(LOQ)were(0.1-1.7)μg/mL and(0.3-1.5)μg/mL,respectively.Malathion〈1.0μg/mL showed no significant change while higher levels of malathion exposure(1.5μg/mL and 3.0|ig/mL)reduced the number of white blood cells.In conclusion,the spectroscopic results may be useful to understand the mechanism of other pesticides such as methyl parathion and parathion.