Phase-locked single-mode terahertz quantum cascade lasers array

We demonstrated a scheme of phase-locked terahertz quantum cascade lasers(THz QCLs)array,with a single-mode pulse power of 108 mW at 13 K.The device utilizes a Talbot cavity to achieve phase locking among five ridge lasers with first-order buried distributed feedback(DFB)grating,resulting in nearly five times amplification of the single-mode power.Due to the optimum length of Talbot cavity depends on wavelength,the combination of Talbot cavity with the DFB grating leads to better power amplification than the combination with multimode Fabry-Perot(F-P)cavities.The Talbot cavity facet reflects light back to the ridge array direction and achieves self-imaging in the array,enabling phase-locked operation of ridges.We set the spacing between adjacent elements to be 220μm,much larger than the free-space wavelength,ensuring the operation of the fundamental supermode throughout the laser's dynamic range and obtaining a high-brightness far-field distribution.This scheme provides a new approach for enhancing the single-mode power of THz QCLs.

Coherent Beam Combining of Two Slab Laser Amplifiers and Second-Harmonic Phase Locking Based on a Multi-Dithering Technique

Coherent beam combining(CBC)is an efficient way to scale the brightness of laser arrays.We demonstrate the active phase locking CBC of two slab laser amplifiers based on the multi-dithering technique.The experimental investigation on the 102 W coherent beam combining of two slab amplifiers shows that the whole system in a closed loop performs well over a long time observation.The contrast of the coherent combined beam profile is about 87%and the combining efficiency is nearly 85%.In addition,the CBC of two green lasers is realized based on the second-harmonic generation of the phase locking pump lasers.To the best of our knowledge,this is the first report about second-harmonic active phase locking,which indicates further potential applications of CBC.

A NOVEL PHASE CONTROL TECHNIQUE FOR INJECTION LOCKED OSCILLATORS

A novel technique to obtain injection locked oscillators phase tuning beyond 180° is demonstrated. The idea is to cascade injection locked oscillators together for phase change accumulation. A two stage injection locked oscillators can theoretically provide a maximum of 360?phase change within the locking range. This is particularly useful for phased array antenna applications.

A Static Phase Offset Reduction Technique for Multiplying Delay-Locked Loop

Static phase offset (SPO) in conventional multiplying delay-locked loops (MDLLs) dramatically degrades the deterministic jitter performance. To overcome the issue, this paper presents a new SPO reduction technique for MDLLs. The technique is based on the observation that the SPO of MDLL is mainly caused by the non-idealities on charge pump (e.g. sink and source current mismatch), and control line (e.g. gate leakage of loop filter and voltage controlled delay line (VCDL) control circuit). With a high gain stage inserting between phase detector/phase frequency detector (PD/PFD) and charge pump, the equivalent SPO has been decreased by a factor equal to the gain of the gain stage. The effectiveness of the proposed technique is validated by a Simulink model of MDLL. The equivalent SPO is measured by the power level of reference spur.

PREPARATION OF WATERBORNE ULTRAFINE PARTICLES OF EPOXY RESIN BY PHASE INVERSION TECHNIQUE

Waterborne ultrafine particles of epoxy resin were prepared by phase inversion technique. The results of SEM revealed that the particles diameter was in the range of 50 to 100 nm and the effects on amount of water required at phase inversion point were also discussed.

Hollow fiber-based liquid phase microextraction followed by analytical instrumental techniques for quantitative analysis of heavy metal ions and pharmaceuticals

Hollow-fiber liquid-phase microextraction(HF-LPME)and electromembrane extraction(EME)are miniaturized extraction techniques,and have been coupled with various analytical instruments for trace analysis of heavy metals,drugs and other organic compounds,in recent years.HF-LPME and EME provide high selectivity,efficient sample cleanup and enrichment,and reduce the consumption of organic sol-vents to a few micro-liters per sample.HF-LPME and EME are compatible with different analytical in-struments for chromatography,electrophoresis,atomic spectroscopy,mass spectrometry,and electrochemical detection.HF-LPME and EME have gained significant popularity during the recent years.This review focuses on hollow fiber based techniques(especially HF-LPME and EME)of heavy metals and pharmaceuticals(published 2017 to May 2019),and their combinations with atomic spectroscopy,UV-VIS spectrophotometry,high performance liquid chromatography,gas chromatography,capillary elec-trophoresis,and voltammetry.

Dynamic phase transition behavior of a LiMn_(0.5)Fe_(0.5)PO_(4) olivine cathode material for lithium-ion batteries revealed through in-situ X-ray techniques

LiMn_(0.5)Fe_(0.5)PO_(4) has attracted great interest due to its good electrochemical performance and higher operating voltages.This has led to a greater than 30 percent higher energy density than for commercial Li Fe PO4 olivine cathodes.Understanding the phase transition behaviors and kinetics of this material will help researchers to design and develop next generation cathodes for Li-ion batteries.In this study,we investigated non-equilibrium phase transition behaviors in a LiMn_(0.5)Fe_(0.5)PO_(4) cathode material during charge–discharge processes by varying current rates(C-rates)using synchrotron in-situ X-ray techniques.These methods included wide angle X-ray scattering(in-situ WAXS)and X-ray absorption spectroscopy(in-situ XAS).The WAXS spectra indicate that the phase transition of LiMn_(0.5)Fe_(0.5)PO_(4) material at slow C-rates is induced by a two-phase reaction.In contrast,at a high C-rate(5 C),the formation of an intermediate phase upon discharge is clearly observed.Concurrently,the oxidation numbers of the redox reactions of Fe^(2+)/Fe^(3+)and Mn^(2+)/Mn^(3+)were evaluated using in-situ XAS.This combination of synchrotron in-situ X-ray techniques gives clear insights into the non-equilibrium phase transition behavior of a LiMn_(0.5)Fe_(0.5)PO_(4) cathode material.This new understanding will be useful for further developments of this highly promising cathode material for practical commercialization.

PLL DEMODULATION TECHNIQUE FOR M-RAY POSITION PHASE SHIFT KEYING

The paper presents a kind of transmission system which employs M-ary Position Phase Shift Keying(MPPSK) to send data and Phase Locked Loop(PLL) based techniques for data retrieve.With a single PLL, MPPSK demodulation is achieved, as well as carrier recovery and symbol synchronization.Firstly, MPPSK modulation method is briefly introduced.2PPSK's PSD expression is given with its optimization result.Orthogonal Phase Detector(PD) and static threshold are used for the purpose of wider phase range and simplicity in demodulation.The data rate is alterable, which is 4.65 kbps for 2PPSK and 9.3 kbps for 4PPSK in the paper.Then some indicative comparisons in Signal to Noise Ratio Symbol Error Rate(SNR-SER) are made among 2PPSK, 3PPSK and 4PPSK, of which 4PPSK has proved to be optimal in ten slots each symbol conditions.And finally, it is demonstrated by system simulations that lower than 10-4 Symbol Error Rate(SER) performance can be obtained at 13 dB symbol SNR.

Ultrahigh spatiotemporal resolution beam signal reconstruction with bunch phase compensation

Various electromagnetic signals are excited by the beam in the acceleration and beam-diagnostic elements of a particle accelerator.It is important to obtain time-domain waveforms of these signals with high temporal resolution for research,such as the study of beam–cavity interactions and bunch-by-bunch parameter measurements.Therefore,a signal reconstruction algorithm with ultrahigh spatiotemporal resolution and bunch phase compensation based on equivalent sampling is proposed in this paper.Compared with traditional equivalent sampling,the use of phase compensation and setting the bunch signal zero-crossing point as the time reference can construct a more accurate reconstructed signal.The basic principles of the method,simulation,and experimental comparison are also introduced.Based on the beam test platform of the Shanghai Synchrotron Radiation Facility(SSRF)and the method of experimental verification,the factors that affect the reconstructed signal quality are analyzed and discussed,including the depth of the sampled data,quantization noise of analog-to-digital converter,beam transverse oscillation,and longitudinal oscillation.The results of the beam experiments show that under the user operation conditions of the SSRF,a beam excitation signal with an amplitude uncertainty of 2%can be reconstructed.

Optical nonlinearity measurement of 4-(N-methyl,N-hydroxyethl)amino,4'-nitroazobenzene using a transmittance technique with a phase object(T-PO) with top-hat beams at 600-nm wavelength

The transmittance technique with a phase object（T-PO）,for measuring optical nonlinear coefficients is proposed with a top-hat beam.The sensitivity of the T-PO with a top-hat beam is a factor of 4 greater than that with a Gaussian beam.The validity of this method is verified by measuring the nonlinearity of a well-characterized liquid,CS 2 at 532-nm wavelength.The ease of use of this method has been proved by measuring a new compound 4-（N-methyl,N-hydroxyethyl）amino,4＇-nitroazobenzene（ANAB） at 600-nm wavelength,indicating that this method can be extended to the measurement of optical nonlinearities in a wide-band spectrum.

Method for differential phase delay resolution of phase referencing VLBI technique and its experimental verification

The phase referencing Very Long Baseline Interferometry(VLBI)technique is a newly developed tool to measure the angular position of a deep space exploration probe in the plane-of-the-sky.Through alternating observations between the probe and a nearby reference radio source,their accurate relative angular separation can be obtained from the radio images generated by this technique.To meet the requirements of the current orbit determination software,differential delay should be firstly derived from those radio images.A method to resolve the differential phase delay from the phase referencing VLBI technique is proposed in this paper,and as well the mathematical model for differential phase ambiguity resolution is established.This method is verified with practical measurement data from the Chang’E-3 mission.The differential phase delay between the Chang’E-3 lander and rover was derived from the phase referencing VLBI measurements,and was then imported into the Shanghai astronomical observatory Orbit Determination Program(SODP)to calculate the position of the rover relative to the lander on the lunar surface.The results are consistent with those acquired directly from radio images,indicating that the differential phase ambiguity has been correctly resolved.The proposed method can be used to promote applications of the phase referencing VLBI technique in future lunar or deep space explorations,and more accurate orbit determination becomes promising.

Efficient Solvent- and Catalyst-Free Syntheses of Imine Derivatives Applying the Pressure Reduction Technique: Remarkable Change of the Reaction Rate with the Phase Transition

Because imines could be used as convenient starting materials in various fields, the development of an easy synthetic method of imine was strongly desired. In response to this demand, we thought that it would be an effective synthesis method if an aldehyde and an amine could be reacted to give an imine in good yield under solvent- and catalyst-free conditions. In fact, we tried the reaction of benzaldehyde with various amines under solvent- and catalyst-free conditions followed by removal of water that was produced in the reaction system by a vacuum pump, and desired imines could be obtained in good yields. Observation of this reaction using a nuclear magnetic resonance spectrometer revealed that the reaction rate was extremely fast at the initial stage but slowed over time. However, the reaction of benzaldehyde with aniline differed greatly, and the reaction rate dramatically improved in 47 - 48 minutes after the start of the reaction. At this time, we found that the reaction system underwent a phase transition from the liquid phase to the solid phase.

Creation of reversed phase high-performance liquid chromatographic technique to assay platelet-activating factor

Objective: To establish a new assay for platelet-activating factor (PAF), to compare it with bio-assay; and to discuss its significance in some elderly people diseases such as cerebral infarction and coronary heart disease. Methods: To measure PAF levels in 100 controls, 23 elderly patients with cerebral infarction and 65 cases with coronary heart disease by reversed phase high-performance liquid chromatographic technique (rHPLC). Results:rHPLC is more convenient, sensitive,specific, and less confusing, compared with bio-assay. The level of plasma PAF in patients with cerebral infarction was higher than that in the controls (P<0.01), and in patients with coronary heart disease. Conclusion: Detection of PAF with rHPLC is more reliable and more accurate. The new assay has important significance in PAF research.

A Low Phase Noise, Low Power and Wide Tuning Range VCO with Filtering Technique in ISM Band

In this paper, a novel voltage controlled oscillator (VCO) with low phase noise, low power consumption and wide tuning range in the industrial, scientific and medical (ISM) band is proposed for communication systems applications. For improving the phase noise, filtering technique is used and VCO is designed with TSMC CMOS 0.18 μm technology and the power supply is 1.5 V. The simulation results with advanced design system (ADS) shows that phase noise in 1 MHz offset frequency from the carrier is -122 dBc/Hz and tuning range is 2 to 2.8 GHz. The power consumption of the core is 2.49 mW.

Liquid phase separating mechanism and preparation techniques of immiscible alloys

Immiscible alloys have attracted growing interest for their valuable physical and mechanical properties. However, their production is difficult because of metallurgical problems in which there is a serious tendency for gravity separation in the region of the miscibility gap. So far the study on the liquid separation mechanism is still one of the important projects in the spatial materials science and the spatial fluid science. The studied results about the liquid phase separating mechanism of immiscible alloys are presented, at the same time the preparation techniques of homogeneous immiscible alloys are summarized, and the existing problems and the related researching areas in the future are also pointed out.

Propagation of phase-locked truncated Gaussian beam array in turbulent atmosphere

Truncation manipulation is a simple but effective way to improve the intensity distribution properties of the phase-locked Gaussian beam array at the receiving plane. In this paper, the analytical expression for the propagation of the phase-locked truncated Gaussian beam array in a turbulent atmosphere is obtained based on the extended Huygens--Fresnel principle. Power in the diffraction-limited bucket is introduced as the beam quality factor to evaluate the influence of different truncation parameters. The dependence of optimal truncation ratio on the number of beamlets, the intensity of turbulence, propagation distance and laser wavelength is calculated and discussed. It is revealed that the optimal truncation ratio is larger for the laser array that contains more lasers, and the optimal truncation ratio will shift to a larger value with an increase in propagation distance and decrease in intensity of atmosphere turbulence. The optimal truncation ratio is independent of laser wavelength.

On the Mechanism of the Locking of the El Nino Event Onset Phase to Boreal Spring

The mechanism of the locking of the E1 Nino event onset phase to boreal spring （from April to June） in an intermediate coupled ocean-atmosphere model is investigated. The results show that the seasonal variation of the zonal wind anomaly over the equatorial Pacific associated with the seasonal variation of the ITCZ is the mechanism of the locking in the model. From January to March of the E1 Nino year, the western wind anomaly over the western equatorial Pacific can excite the downwelling Kelvin wave that propagates eastward to the eastern and middle Pacific by April to June. From April to December of the year before the E1 Nifio year, the eastern wind anomaly over the equatorial Pacific forces the downwelling Rossby waves that modulate the ENSO cycle. The modulation and the reflection at the western boundary modulate the time of the transition from the cool to the warm phase to September of the year before the E1 Nifio year and cause the strongest downwelling Kelvin wave from the reflected Rossby waves at the western boundary to arrive in the middle and eastern equatorial Pacific by April to June of the E1 Nino year. The superposition of these two kinds of downwelling Kelvin waves causes the El Nino event to tend to occur from April to June.

Seasonal Phase-Locking of Peak Events in the Eastern Indian Ocean

The sea surface temperature （SST） anomaly of the eastern Indian Ocean （EIO） exhibits cold anomalies in the boreal summer or fall during E1 Nino development years and warm anomalies in winter or spring following the E1 Nino events. There also tend to be warm anomalies in the boreal summer or fall during La Nina development years and cold anomalies in winter or spring following the La Nina events. The seasonal phase-locking of SST change in the EIO associated with E1 Nino/Southern Oscillation is linked to the variability of convection over the maritime continent, which induces an atmospheric Rossby wave over the EIO. Local air-sea interaction exerts different effects on SST anomalies, depending on the relationship between the Rossby wave and the mean flow related to the seasonal migration of the buffer zone, which shifts across the equator between summer and winter. The summer cold events start with cooling in the Timor Sea, together with increasing easterly flow along the equator. Negative SST anomalies develop near Sumatra, through the interaction between the atmospheric Rossby wave and the underneath sea surface. These SST anomalies are also contributed to by the increased upwelling of the mixed layer and the equatorward temperature advection in the boreal fall. As the buffer zone shifts across the equator towards boreal winter, the anomalous easterly flow tends to weaken the mean flow near the equator, and the EIO SST increases due to the reduction of latent heat flux from the sea surface. As a result, wintertime SST anomalies appear with a uniform and nearly basin-wide pattern beneath the easterly anomalies. These SST anomalies are also caused by the increase in solar radiation associated with the anticyclonic atmospheric Rossby wave over the EIO. Similarly, the physical processes of the summer warm events, which are followed by wintertime cold SST anomalies, can be explained by the changes in atmospheric and oceanic fields with opposite signs to those anomalies described above.