The effects of phenyl content and group distribution on the refractive index of phenyl silicone oil were investigated by synthesis and characterization of silicone oils of different molecular structures.A group contri...The effects of phenyl content and group distribution on the refractive index of phenyl silicone oil were investigated by synthesis and characterization of silicone oils of different molecular structures.A group contribution function model was established to predict the refractive index. The results showed that refractive index of phenyl silicone oil increased as its phenyl content increased. A linear equation had been established to describe the quantitative relationship between the refractive index and phenyl content.Refractive index values from the group contribution function model showed good consistency with experimental results.展开更多
基金National Natural Science Foundation of China(No.11304048)Special Fund Project for Technology Development of Guangdong Province,China(No.2016B070701023)Funds of Applied Science and Technology Research in Guangdong Province,China(Nos.2017A070701024,2017A070702020)
文摘The effects of phenyl content and group distribution on the refractive index of phenyl silicone oil were investigated by synthesis and characterization of silicone oils of different molecular structures.A group contribution function model was established to predict the refractive index. The results showed that refractive index of phenyl silicone oil increased as its phenyl content increased. A linear equation had been established to describe the quantitative relationship between the refractive index and phenyl content.Refractive index values from the group contribution function model showed good consistency with experimental results.