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Effects of Peracetic Acid(PAA) Combined with Calcium Treatments on Storage Quality of Loquat Fruit 被引量:4
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作者 宋虎卫 郑永华 +2 位作者 袁卫明 张瑞越 杨立明 《Agricultural Science & Technology》 CAS 2013年第10期1476-1481,共6页
[Objective] The paper was to evaluate effects of peracetic acid (PAA) combined with calcium treatments on storage quality of Ioquat fruits, so as to pro- vide practical techniques to solve the problems of postharves... [Objective] The paper was to evaluate effects of peracetic acid (PAA) combined with calcium treatments on storage quality of Ioquat fruits, so as to pro- vide practical techniques to solve the problems of postharvest rot and quality deteri- oration for Ioquat fruits. [Method] With Ioquat fruits of Qingzhong variety as materi- als, 0.2%, 0.4% and 0.8% PAA combined with 0.8% CaCI2 was used to soak Ioquat fruits for 4 min, 0.8% CaCl2 and water treatments were set as two controls; the fruits were dried and packaged by 0.02 mm PE bags, then stored under non-chilling low temperature of (7±1) ℃. The indicators related to storage quality of Ioquat fruits were randomly tested once every 3 d, and their variation situations were analyzed. [Result] Compared with two control treatments and 0.2% PAA, 0.8% PAA combined with calcium treatments, the treatment of 0.4% PAA combined with 0.8% CaCl2 could significantly inhibit rot index, weight loss rate, firmness and cell membrane permeability of Ioquat fruits during storage period, which could also effectively delay the reduction of titratable acid, vitamin C, soluble solid content and juice yield, and maintain respiration intensity of fruits at a low level; the appearance and flavor qual- ity of fruits were good after stored for 25 d. [Conclusion] 0.4% PAA combined with 0.8% CaCl2 treatment is an efficient, safe and economical practice technology in an- ti-corrosion and quality preservation for postharvest Ioquat fruits . 展开更多
关键词 Loquat (Eriobotrya japonica) Peracetic acid paa Calcium treatment Storage quality
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Study on the Synthesis of Phenylacetic Acid by Carbonylation of Benzyl Chloride under Normal Pressure 被引量:1
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作者 ZuminQiu YunbingHe +1 位作者 DianmoZheng FufangLiu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2005年第1期40-46,共7页
The influences of some factors on the yield of phenylacetic acid in thecarbonylation of benzyl chloride were studied in this paper. These factors included the variety andcontent of catalyst, and that of solvent, way o... The influences of some factors on the yield of phenylacetic acid in thecarbonylation of benzyl chloride were studied in this paper. These factors included the variety andcontent of catalyst, and that of solvent, way of material feeding, reaction temperature, sodiumhydrate concentration, triphenylphosphine content, presence of surfactant, the ratio of organicphase volume to aqueous phase volume etc. The optimum reaction conditions were found to be: with aone-time pour of 0.15 g Pd(PPh_3)_2Cl_2, 0.24 g PPh_3, 75 ml NaOH of 3.5 mol/L, 20 ml benzylchloride and 55 ml n-butyl alcohol, and the reaction was carried out at 50℃ for about 3 hours. Theas-obtained yield of phenylacetic acid was as high as 97.6%. In addition, the influences of thepresence of phenylacetic acid and air in the reaction system were also studied. The results showedthat the presence of air in the system and the entrainment of phenylacetic acid in the circulatingorganic phase had great influence on the reaction rate, the stability and performance of catalystand the yield of phenylacetic acid. 展开更多
关键词 synthesis phenylacetic acid CARBONYLATION phenyl chloride dichloro-bistriphenylphosphine palladium
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Synthesis, Crystal Structure and Luminescence Property of a Cd(Ⅱ) Complex Assembled by 4-Carboxymethoxy Phenylacetic Acid 被引量:1
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作者 郭静轲 冀珺 温一航 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第5期774-778,共5页
A new structure with the molecular formula [CdL]n was formed by CdSO4 with 4-carboxymethoxy phenylacetic acid (H2L) through the hydrothermal method. The complex was characterized by elemental analysis and infrared s... A new structure with the molecular formula [CdL]n was formed by CdSO4 with 4-carboxymethoxy phenylacetic acid (H2L) through the hydrothermal method. The complex was characterized by elemental analysis and infrared spectroscopy. The structure of the complex was determined by single-crystal X-ray diffraction, which is of monoclinic system, space group P21/c with a = 10.3887(2), b = 7.10710(10), c = 14.7212(2) , β = 120.6940(10)°, V = 934.65(3) 3, Dc = 2.278 g·cm-3, Z = 4, F(000) = 624, S = 1.022, the final R = 0.0187 and wR = 0.0487 for 2000 observer reflections (Ⅰ 〉 2σ(Ⅰ)). The center metal ion Cd(Ⅱ) in the complex is six-coordinated in a distorted octahedral geometry, and is connected with L ligands to form a 3D fishing net structure, which is a novel (3,6) network topology. The luminescence of the complex has been investigated, and the result reveals that it displays luminescent property in the voilet region. 展开更多
关键词 4-carboxymethoxy phenylacetic acid cadmium complex crystal structure luminescent property
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Syntheses and Crystal Structures of Three Ag(Ⅰ) Complexes with Chloro-phenylacetic Acid and Nitrogen Heterocyclic Ligand 被引量:4
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作者 郝晓敏 谷长生 +3 位作者 纪丽丽 胡世伟 李泳 宋文东 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2015年第9期1362-1370,共9页
Three new coordination polymers {[Ag2(2,4-DCPA)(4,4"-bipy)2(NO3)].(H20)}, (1), [Ag(2,4-DCPA)(bpp)], (2) and {[Ag(4-DCPA)(bpp)]'(H20)}, (3), were synthesized by evaporation methods using 2,4-d... Three new coordination polymers {[Ag2(2,4-DCPA)(4,4"-bipy)2(NO3)].(H20)}, (1), [Ag(2,4-DCPA)(bpp)], (2) and {[Ag(4-DCPA)(bpp)]'(H20)}, (3), were synthesized by evaporation methods using 2,4-dichlorophenylacetic acid (2,4-DCPA), 4-chlorophenylacetic acid (4-DCPA), 4,4"-dipyridyl (4,4"-bipy), 1,3-bis(4-pyridyl)propane(bpp) and AgNO3. Compound 1 crystallizes in monoclinic, space group P21/c with a = 10.035(2), b = 17.796(3), c = 16.448(2) A, fl = 104.086(2)°, V= 2705.9(2) A3, Dc = 1.893 g/cm-3, C28H23C12NsO6Ag2, Mr = 812.15, F(000) = 1608,μ(MoKot) = 1.615 mm-1, Z = 4, R = 0.0310, wR = 0.0832 for 4357 observed reflections (I 〉 20(/)), and R = 0.0362, wR = 0.0873 for all data. Compound 2 crystallizes in monoclinic, space group P21/c with a = 9.840(2), b = 24.971(5), c = 9.3301(2)°, fl = 117.504(2)°, V= 2033.5(7) A3, Dc = 1.666 g/cm3, C2tH19C12N202Ag, Mr = 510.15, F(000) = 1024,/I(MoKa) = 1.273 mml, Z= 4, R = 0.0315 and wR = 0.0680 for 2853 observed reflections (1 〉 20(/)) and R = 0.0454, wR = 0.0736 for all data. Compound 3 crystallizes in monoclinic, space group P21/n with a = 15.472(4), b = 9.000(2), c = 16.262(4) A, fl = 112.049(4)°, V = 2099.0(8) A3, Dc = 1.562 g/cm-3, C2H22C1N203Ag, Mr = 493.73, F(000) = 1000, μ(MoKa) = 1.111 mm-1, Z = 4, R = 0.0296, wR = 0.0821 for 3059 observed reflections (I 〉 2δ-(I)), and R = 0.0398, wR = 0.0986 for all data. The complexes were characterized by elemental analysis, FT-IR, thermogravimetrie analysis (TGA) and X-ray single-crystal structure analysis. Fluorescence properties of complex 3 and PXRD of 1 and 2 have been studied. As a result, in complex 1, the Ag(I) ion is surrounded by two nitrogen atoms from two bipy ligands to form an infinite chain, and adjacent Ag-bipy chains produce "'rungs" of a ladder by silver ions contact. And in complexes 2 and 3, the two-dimensional ,β-sheet like layers are obtained by Ag……Ag interactions. 展开更多
关键词 silver complex chloro-phenylacetic acid crystal structure
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Inhibitory Effects of Phenylacetic Acid on Proliferation of Human Pancreatic Carcinoma BXPC-3 Cells by the Regulation of Adenosine Deaminases Acting on RNA
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作者 JIANG Yao REN Hui +5 位作者 ZHANG Guang ZHANG Ling TIAN Xiao-feng JIA Hui-jie HAN Li-ying TIAN Yu 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2010年第6期964-968,共5页
The effect and mechanism of phenylacetic acid on the proliferation of pancreatic carcinoma cells were investigated in cultured pancreatic carcinoma BXPC-3 cells by means of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenylt... The effect and mechanism of phenylacetic acid on the proliferation of pancreatic carcinoma cells were investigated in cultured pancreatic carcinoma BXPC-3 cells by means of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay and flow cytometry assay.The results show that the treatment of pancreatic carcinoma cells with phenylacetic acid significantly inhibited the cell proliferation in time-dependent and dose-dependent manners.The proliferation of BXPC-3 cells was inhibited at the stage of S phase,the cells at the end stage of S phase were accumulated abundantly,and thus DNA synthesis could not be accomplished entirely.In addition,the expression of adenosine deaminases acting on RNA(ADARs) mRNA in BXPC-3 cells and pancreatic carcinoma specimen were detected by RT-PCR.Having been treated with phenylacetic acid,ADAR2 mRNA in BXPC-3 cells was significantly decreased,the differences were of statistical significance(P0.01).Taken together,these results suggest that phenylacetic acid may likely regulate the proliferation of pancreatic carcinoma cells through the regulation of ADAR2 mRNA expression. 展开更多
关键词 Pancreatic carcinoma phenylacetic acid ADAR2 RNA editing
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ADSORPTION OF PHENYLACETIC ACID ON MACROPOROUS POLYMERIC ADSORBENTS
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作者 PANBingcai CHEN Jinlong +2 位作者 XIONG Ying SUN Yue ZHANG Quanxing 《Chinese Journal of Reactive Polymers》 2002年第1期61-68,共8页
Several macroporous polymeric adsorbents (NDA-999, XAD-8, X-5 and XAD-2) were employed in the study to adsorb phenylacetic acid from aqueous solution. Effect of salt and ambient temperature on adsorption was studied u... Several macroporous polymeric adsorbents (NDA-999, XAD-8, X-5 and XAD-2) were employed in the study to adsorb phenylacetic acid from aqueous solution. Effect of salt and ambient temperature on adsorption was studied using NDA-999 adsorbent and the adsorption process conforms to Freundlich抯 model reasonably. Adsorption dynamics were conducted in batch experiments in order to make clear the mechanism of adsorption process. It is proved that the squared driving force mass transfer model can be adopted to elucidate the process. The treatment process of industrial wastewater containing high strength of phenylacetic acid was proposed for cleaner production of phenylacetic acid. 展开更多
关键词 Macroporous polymeric adsorbents phenylacetic acid ADSORPTION wastewater treatment
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Bacteroides fragilis Supernatant Extracts Enriched in Phenylacetic Acid Induce a Cytotoxic Effect in Mammalian Cells
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作者 Laís S.Falcao Eduardo N.F.Antunes +9 位作者 Eliane O.Ferreira Heidi Pauer Maria Teresa V.Romanos Rossiane C.Vommaro Sérgio H.Seabra Daniela S.Alviano Celuta S.Alviano Antonio Jorge R.da Silva Leandro A.Lobo Regina Maria C.P.Domingues 《Advances in Microbiology》 2015年第10期730-736,共7页
Bacteroides species are nearly half of the fecal flora community and some are host symbionts crucial to host nutrition and systemic immunity. Among Bacteroides species B. fragilis strains are considered to be the oppo... Bacteroides species are nearly half of the fecal flora community and some are host symbionts crucial to host nutrition and systemic immunity. Among Bacteroides species B. fragilis strains are considered to be the opportunistic ones, being the most isolated anaerobic bacteria in clinical samples. Cell-free supernatants of 65 B. fragilis strains were assayed and they were capable of inducing vacuolating phenotype on Vero cells lineage. The supernatant of the Bacteroides fragilis ATCC 23745 strain was elicited to have the strongest vacuolating effect on Vero cells monolayers and peritoneal macrophages. Some drastic cell alterations were observed, such as a general disorganization of cytoplasm and chromatin condensation, evidencing cell death. By transmission electron microscopy it was confirmed that the vacuoles observed were, in fact, swollen mitochondria. An immunocytochemical assay, TUNEL, was used to confirm this hypothesis and showed that Vero cells and peritoneal macrophages were dying by apoptotic process after exposition of B. fragilis cell-free supernatant. Physical analysis of the apoptotic factor has revealed properties similar to short-chain fatty acids. After gas chromatography and mass spectrometry analysis, phenylacetic acid (PA) was characterized as the major compound present in the most purified active fraction. We believe that the PA is responsible for the pro-apoptotic effect elicited by the supernatant of B. fragilis cultures. 展开更多
关键词 Bacteroides fragilis Vacuolization APOPTOSIS Vero cells Lineage Peritoneal Macrophages phenylacetic acid
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铁离子配位聚丙烯酸基芬顿催化纤维的制备及其性能
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作者 徐乃库 王敬宏 《天津工业大学学报》 CAS 北大核心 2024年第2期16-21,共6页
为改善聚丙烯酸(PAA)纤维的性能,在湿法纺丝过程中基于铁离子配位反应成功制备了可拉伸PAA初生纤维,利用后拉伸以及热定型工艺优化纤维性能,并探究其作为Fenton催化剂在染料废水处理领域的应用。结果表明:相较硫酸铁盐,氯化铁盐配位的PA... 为改善聚丙烯酸(PAA)纤维的性能,在湿法纺丝过程中基于铁离子配位反应成功制备了可拉伸PAA初生纤维,利用后拉伸以及热定型工艺优化纤维性能,并探究其作为Fenton催化剂在染料废水处理领域的应用。结果表明:相较硫酸铁盐,氯化铁盐配位的PAA纤维具有更为优异的力学性能和尺寸稳定性;后拉伸和热定型工艺可显著提高PAA纤维的力学性能和催化活性,并抑制铁离子的流失,拉伸20倍且在130℃定型的纤维断裂强度为1.42 cN/dtex,与未拉伸纤维相比提高了914.3%,且可在3 min内脱色90%以上的亚甲基蓝(MB),循环使用40次未出现脱色率衰减现象。 展开更多
关键词 聚丙烯酸(paa) 湿法纺丝 芬顿催化纤维 染料废水处理
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PASP、PAA与PBTCA阻垢性能的对比实验研究 被引量:16
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作者 覃海华 李彩亭 +4 位作者 刘海 张巍 曾光明 高宏亮 李焕利 《中国环境科学》 EI CAS CSCD 北大核心 2010年第11期1466-1472,共7页
采用静态阻垢法研究了聚天冬氨酸(PASP)、聚丙烯酸(PAA)和2-膦酸基丁烷-1,2,4-三羧酸(PBTCA)对碳酸钙和硫酸钙的阻垢性能,并用旋转挂片法研究了3种阻垢剂作用下湿法石灰脱硫浆液系统的结垢规律.研究发现:随着阻垢剂浓度的增加,3种阻垢... 采用静态阻垢法研究了聚天冬氨酸(PASP)、聚丙烯酸(PAA)和2-膦酸基丁烷-1,2,4-三羧酸(PBTCA)对碳酸钙和硫酸钙的阻垢性能,并用旋转挂片法研究了3种阻垢剂作用下湿法石灰脱硫浆液系统的结垢规律.研究发现:随着阻垢剂浓度的增加,3种阻垢剂都表现出溶限效应;相同实验条件下,3种阻垢剂对碳酸钙的静态阻垢性能表现为PBTCA>PAA>PASP;对中性和碱性环境,pH对阻垢剂阻硫酸钙垢的性能影响较小;随着温度的升高和反应时间的延长,3种阻垢剂阻硫酸钙的阻垢率先增大后减小;对湿法石灰脱硫浆液系统,3种阻垢剂作用下,单位面积挂片上的结垢量均是随着阻垢剂质量浓度的增大先增大后减小,在浓度达到30mg/L时,挂片上的结垢量都很小. 展开更多
关键词 聚天冬氨酸(PASP) 聚丙烯酸(paa) 2-膦酸基丁烷-1 2 4-三羧酸(PBTCA) 阻垢性能
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PAA/HB去除白钨矿选矿废水COD的研究 被引量:7
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作者 何玉凤 王华 +3 位作者 张侠 晏得珍 李慧茹 王荣民 《工业水处理》 CAS CSCD 北大核心 2011年第10期61-63,共3页
采用酸碱联用水处理工艺对选矿废水中的水玻璃进行混凝反应,消除了废水中悬浮物和重金属对选硫和选钨指标的影响。其次,利用聚丙烯酸/硫酸酸化膨润土(PAA/HB)复合物对混凝后选矿废水中的COD去除进行了研究。结果表明,经酸碱联用混凝沉... 采用酸碱联用水处理工艺对选矿废水中的水玻璃进行混凝反应,消除了废水中悬浮物和重金属对选硫和选钨指标的影响。其次,利用聚丙烯酸/硫酸酸化膨润土(PAA/HB)复合物对混凝后选矿废水中的COD去除进行了研究。结果表明,经酸碱联用混凝沉淀后的澄清选矿废水1 L,在20℃下,吸附剂用量为1.0 g,pH=5.0,100 r/min振荡2 min时,处理效果最好,COD去除率最高达78.9%。处理后的废水可全部回用到磨矿、选硫及重选作业,真正实现了"零排放",达到了清洁生产的目的。 展开更多
关键词 选矿废水 循环利用 酸碱联用 paa/HB复合物
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Peracetic acid(PAA)-based pretreatment effectively improves medium-chain fatty acids(MCFAs)production from sewage sludge 被引量:1
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作者 Yufen Wang Haixiao Guo +5 位作者 Xuecheng Li Xueming Chen Lai Peng Tingting Zhu Peizhe Sun Yiwen Liu 《Environmental Science and Ecotechnology》 SCIE 2024年第4期154-166,共13页
Peracetic acid(PAA),known for its environmentally friendly properties as a oxidant and bactericide,is gaining prominence in decontamination and disinfection applications.The primary product of PAA oxidation is acetate... Peracetic acid(PAA),known for its environmentally friendly properties as a oxidant and bactericide,is gaining prominence in decontamination and disinfection applications.The primary product of PAA oxidation is acetate that can serve as an electron acceptor(EA)for the biosynthesis of medium-chain fatty acids(MCFAs)via chain elongation(CE)reactions.Hence,PAA-based pretreatment is supposed to be beneficial for MCFAs production from anaerobic sludge fermentation,as it could enhance organic matter availability,suppress competing microorganisms and furnish EA by providing acetate.However,such a hypothesis has rarely been proved.Here we reveal that PAA-based pretreatment leads to significant exfoliation of extracellular polymeric substances(EPS)from sludge flocs and disruption of proteinic secondary structures,through inducing highly active free radicals and singlet oxygen.The production of MCFAs increases substantially to 11,265.6 mg COD L^(-1),while the undesired byproducts,specifically long-chain alcohols(LCAs),decrease to 723.5 mg COD L^(-1).Microbial activity tests further demonstrate that PAA pretreatment stimulates the CE process,attributed to the up-regulation of functional genes involved in fatty acid biosynthesis pathway.These comprehensive findings provide insights into the effectiveness and mechanisms behind enhanced MCFAs production through PAA-based technology,advancing our understanding of sustainable resource recovery from sewage sludge. 展开更多
关键词 Sewage sludge Medium-chain fatty acids(MCFAs) Extracellular polymeric substances(EPS) Peracetic acid(paa) Metabolic activity
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温度对α-Al_2O_3-H_2O-PAA悬浮液稳定性的影响 被引量:2
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作者 李登好 朱晓文 郭露村 《材料科学与工程学报》 CAS CSCD 北大核心 2006年第2期227-229,共3页
研究了温度对-αAl2O3-H2O-聚丙烯酸悬浮液分散稳定性的影响。研究表明:温度升高,粉体充分分散时所需的PAA添加量增大。浆料体系中分散剂添加量低于给定温度下的最佳添加量时,温度升高,浆料粘度增加,稳定性下降。但在适量聚丙烯酸(polya... 研究了温度对-αAl2O3-H2O-聚丙烯酸悬浮液分散稳定性的影响。研究表明:温度升高,粉体充分分散时所需的PAA添加量增大。浆料体系中分散剂添加量低于给定温度下的最佳添加量时,温度升高,浆料粘度增加,稳定性下降。但在适量聚丙烯酸(polyacrylic acid,PAA)分散剂存在的前提下,提高温度,可以显著降低高固含量浆料的粘度。 展开更多
关键词 Α-AL2O3 聚丙烯酸 浆料 温度 稳定性
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PVA/PAA/Fe3+超分子水凝胶的制备及其性能 被引量:2
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作者 付维贵 毛云云 +3 位作者 薛莹莹 杨雪松 梅淑贞 孙宝山 《天津工业大学学报》 CAS 北大核心 2019年第3期28-34,共7页
为提高水凝胶的力学性能并扩展其应用,采用生物相容性良好的聚乙烯醇(PVA)、聚丙烯酸(PAA)为基质材料,以氢键和配位键为物理交联点,制备具有高力学性能的PVA/PAA/Fe^3+水凝胶;通过调节溶液中盐酸浓度、Fe^3+浓度和水凝胶浸泡时间研究其... 为提高水凝胶的力学性能并扩展其应用,采用生物相容性良好的聚乙烯醇(PVA)、聚丙烯酸(PAA)为基质材料,以氢键和配位键为物理交联点,制备具有高力学性能的PVA/PAA/Fe^3+水凝胶;通过调节溶液中盐酸浓度、Fe^3+浓度和水凝胶浸泡时间研究其对水凝胶力学性能的影响,通过溶液的pH值探讨水凝胶的稳定性,通过循环加载-卸载实验评估水凝胶的自恢复性能。研究结果表明:红外光谱表征水凝胶网络结构氢键及配位键已形成;当溶液盐酸浓度为0.2 mol/L、Fe^3+浓度为0.09 mol/L、浸泡时间为20 h时,水凝胶力学强度最优,其拉伸强度为12.69 MPa,韧性为41.64 MJ/m3;将水凝胶做一次循环加载-卸载实验之后,静置240min,其应力、应变恢复率分别达到90%、87.8%。 展开更多
关键词 聚乙烯醇(PVA) 聚丙烯酸(paa) 超分子水凝胶 金属配位键 氢键 力学性能
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紫外联合过氧乙酸工艺降解废水中磺胺甲恶唑
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作者 王婷 刘义青 +1 位作者 田琳 付永胜 《净水技术》 CAS 2024年第11期85-91,140,共8页
文章研究了紫外联合过氧乙酸(UV/PAA)对水中磺胺甲恶唑(SMX)的降解,探讨了pH、PAA用量、SMX初始浓度以及常见水体成分对SMX降解的影响,分析了SMX在该体系中的降解机理,探讨了SMX可能的降解途径。结果表明:UV/PAA体系对SMX的降解符合准... 文章研究了紫外联合过氧乙酸(UV/PAA)对水中磺胺甲恶唑(SMX)的降解,探讨了pH、PAA用量、SMX初始浓度以及常见水体成分对SMX降解的影响,分析了SMX在该体系中的降解机理,探讨了SMX可能的降解途径。结果表明:UV/PAA体系对SMX的降解符合准一级反应动力学模型,其对SMX的降解优于单独UV和单独PAA对SMX的降解。该体系在酸性条件下对SMX的降解率明显高于中性和碱性条件;提高PAA浓度,SMX的降解效率随之逐渐增大,但提高SMX初始浓度,SMX的降解效率却随之逐渐降低。NO3-、HCO3-的存在可以明显促进SMX的降解;而天然有机物的存在对SMX的降解有显著的抑制作用。在UV/PAA体系中,共检出5种SMX降解产物,由此提出了4种可能的SMX转化途径,包括羟基化、断键反应、氨基氧化和偶联反应。 展开更多
关键词 紫外光 过氧乙酸 磺胺甲恶唑 有机自由基 羟基自由基
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不同条件制备聚丙烯酸水凝胶的结构与性能
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作者 张金玉 曲德智 王舒羽 《广西科技大学学报》 CAS 2024年第2期103-110,共8页
采用乳液聚合方法将引发剂过硫酸铵(APS)和乳化剂十二烷基硫酸钠(SDS)制备出聚丙烯酸树脂乳液,再加入不同条件交联剂固化成聚丙烯酸(PAA)水凝胶,并探究使用紫外固化和热固化2种不同固化方式及不同固化时间对PAA水凝胶性能的影响。通过... 采用乳液聚合方法将引发剂过硫酸铵(APS)和乳化剂十二烷基硫酸钠(SDS)制备出聚丙烯酸树脂乳液,再加入不同条件交联剂固化成聚丙烯酸(PAA)水凝胶,并探究使用紫外固化和热固化2种不同固化方式及不同固化时间对PAA水凝胶性能的影响。通过氮气等温吸脱附曲线测试(Brunauer-Emmet-Teller,BET)、扫描电子显微镜(scanning electron microscope,SEM)、热失重分析(thermogravimetric analysis,TGA)、溶胀度、力学测试等方法,对水凝胶的性能进行表征分析。结果表明,形成的PAA水凝胶主要为片状颗粒材料,在紫外固化20 min条件下,其孔径主要分布在2~4 nm;且在热固化条件下,当交联剂质量浓度为0.06、0.07 g/mL时PAA水凝胶溶胀度可达到667%,在交联剂质量浓度为0.09 g/mL时拉伸强度可达到60 k Pa。综上所述,对比紫外固化和热固化2种方法以及不同条件交联剂下制备的PAA水凝胶的差异,对理解和优化PAA水凝胶的制备具有一定的指导意义。 展开更多
关键词 聚丙烯酸水凝胶 制备条件 紫外固化 热固化
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以TEA和PAA为分散剂的水基流延SDC
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作者 李喜宝 王海燕 《电池》 CAS CSCD 北大核心 2010年第5期266-268,共3页
分别以三乙醇胺(TEA)和聚丙烯酸(PAA)为分散剂,用水基流延法制备Sm2O3掺杂的CeO2(Ce0.8Sm0.2O1.9,SDC)陶瓷,研究了pH值对SDCζ电位的影响,分析了SDC生坯的物理性能。TEA和PAA分散的SDC,最大ζ电位绝对值分别为62 mV和49 mV,TEA分散的生... 分别以三乙醇胺(TEA)和聚丙烯酸(PAA)为分散剂,用水基流延法制备Sm2O3掺杂的CeO2(Ce0.8Sm0.2O1.9,SDC)陶瓷,研究了pH值对SDCζ电位的影响,分析了SDC生坯的物理性能。TEA和PAA分散的SDC,最大ζ电位绝对值分别为62 mV和49 mV,TEA分散的生坯在基板上铺展得更好,外观更均一,显微结构更均匀、致密,TEA和PAA分散的生坯,相对密度分别为51.7%和46.2%,极限抗拉强度分别为1.25 MPa和1.06 MPa。TEA是SDC陶瓷较好的水基流延分散剂。 展开更多
关键词 Sm2O3掺杂的CeO2(SDC) 水基流延 三乙醇胺(TEA) 聚丙烯酸(paa) 分散剂
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聚丙烯酸对蒸汽发生器二次侧泥渣颗粒的分散效果
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作者 刘佳露 王骏 +8 位作者 但体纯 杨顺龙 赖宏宇 邓清泉 吴申奥 操容 肖调兵 陈银强 桂春 《腐蚀与防护》 CAS CSCD 北大核心 2024年第9期80-84,共5页
压水堆核电站蒸汽发生器(SG)二次侧泥渣颗粒主要成分为铁氧化物,采用静态沉降试验考察了分散剂聚丙烯酸(PAA)对Fe_(3)O_(4)和Fe_(2)O_(3)铁氧化物颗粒的分散效果。结果表明:PAA明显减缓了Fe_(3)O_(4)和Fe_(2)O_(3)颗粒的沉降速率,其对... 压水堆核电站蒸汽发生器(SG)二次侧泥渣颗粒主要成分为铁氧化物,采用静态沉降试验考察了分散剂聚丙烯酸(PAA)对Fe_(3)O_(4)和Fe_(2)O_(3)铁氧化物颗粒的分散效果。结果表明:PAA明显减缓了Fe_(3)O_(4)和Fe_(2)O_(3)颗粒的沉降速率,其对前者的分散效果更优;PAA对颗粒的分散效果随着颗粒粒径的减小而增强,PAA对粒径在12μm以下的Fe_(3)O_(4)颗粒具有明显的分散效果;PAA对铁氧化物颗粒保持较好分散效果的有效质量浓度范围较宽,在μg/L至mg/L级别;PAA对粒径小于28μm的SG真实泥渣具有明显的分散效果,PAA的加入使得泥渣颗粒的悬浮率从34.05%提高至56.93%。 展开更多
关键词 聚丙烯酸(paa) 铁氧化物颗粒 静态沉降试验 分散效果 压水堆核电站
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添加剂PAAS对锌镍电池负极性能的影响 被引量:2
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作者 倪霞 杨占红 +1 位作者 王升威 申松胜 《电池》 CAS CSCD 北大核心 2010年第5期262-265,共4页
分析了负极中添加聚丙烯酸钠(PAAS)对密封锌镍电池充放电性能及内阻的影响。PAAS可分散浆料并提高电极的润湿性,负极浆料的固含量可提高11%。添加PAAS制备的锌镍电池,放电平台电压高达1.670 V,循环寿命延长。当PAAS添加量为0.3%~0.5%... 分析了负极中添加聚丙烯酸钠(PAAS)对密封锌镍电池充放电性能及内阻的影响。PAAS可分散浆料并提高电极的润湿性,负极浆料的固含量可提高11%。添加PAAS制备的锌镍电池,放电平台电压高达1.670 V,循环寿命延长。当PAAS添加量为0.3%~0.5%时,电池以1.0C在1.400~2.100 V循环,第110次循环的容量保持率高于90%。 展开更多
关键词 锌镍电池 润湿性 聚丙烯酸钠(paaS)
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PAA-Na改性膨润土在酸碱盐溶液中的渗透性 被引量:2
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作者 康祺祯 李静静 +2 位作者 李育超 姚士元 陈云敏 《浙江大学学报(工学版)》 EI CAS CSCD 北大核心 2021年第10期1877-1884,1921,共9页
针对高盐或强酸碱溶液中以膨润土为主材的防污屏障的阻控效果因膨润土膨胀性和抗渗性的降低而劣化的问题,采用聚丙烯酸钠(PAA-Na)对国产钠化钙基膨润土进行改性,提高膨胀性和防渗性.通过自由膨胀试验和改进滤失试验,研究不同浓度的NaCl... 针对高盐或强酸碱溶液中以膨润土为主材的防污屏障的阻控效果因膨润土膨胀性和抗渗性的降低而劣化的问题,采用聚丙烯酸钠(PAA-Na)对国产钠化钙基膨润土进行改性,提高膨胀性和防渗性.通过自由膨胀试验和改进滤失试验,研究不同浓度的NaCl溶液和酸碱溶液对聚丙烯酸钠改性膨润土PB2、PB5、PB10、PBHV5和美国怀俄明天然钠基膨润土的膨胀特性、渗透特性的影响规律.结果表明,在酸碱盐溶液中PB10的膨胀特性和渗透性优于怀俄明膨润土,PBHV5与怀俄明膨润土相近.pH=2的强酸条件和pH=12的强碱条件会降低PBHV5和PB10的膨胀性和抗渗性,pH=3~11的酸碱溶液对两者的影响很小.在酸碱溶液和低浓度(≤20 mmol/L)盐溶液中,由于晶层结构层剥离,3种膨润土渗透系数随着膨胀指数和孔隙比的增大而增大;在中高浓度(>20 mmol/L)盐溶液中,膨润土膨胀性降低,渗流通道增多,产生了渗透系数随膨胀指数和孔隙比的减小而增大的现象.在所研究的聚合物掺量(2%~10%)下,膨润土抗渗性和化学相容性随着聚合物掺量的增大而提高,若目标取得优于美国怀俄明天然钠基膨润土的特性,聚合物掺量须不低于5%. 展开更多
关键词 改性膨润土 聚丙烯酸钠(paa-Na) 渗透系数 膨胀指数 酸碱盐溶液 化学相容性
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A new multifunctional polymer:Synthesis and characterization of mPEG-b-PAA-grafted chitosan copolymer 被引量:4
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作者 刘承斌 王小见 +2 位作者 刘荣华 吴育林 罗胜联 《Journal of Central South University》 SCIE EI CAS 2010年第5期936-942,共7页
A new multifunctional mPEG-b-PAA-grafted chitosan copolymer possessing amino and carboxyl groups,mPEG-b-PAA-g-CHI(compound 6) ,was designed for a potential application in gene/drug delivery and synthesized by the meth... A new multifunctional mPEG-b-PAA-grafted chitosan copolymer possessing amino and carboxyl groups,mPEG-b-PAA-g-CHI(compound 6) ,was designed for a potential application in gene/drug delivery and synthesized by the methods of reversible addition-fragmentation chain transfer(RAFT) polymerization of acrylic acid(AA) and grafting reaction of a biodegradable chitosan(CHI) derivative.Completion of the reactions and characterization of the resulting compounds were demonstrated by 1 H NMR,FTIR and gel permeation chtomatography(GPC) studies.The results show that the molar ratio of amino groups to carboxyl groups in the copolymer(compound 6) is 0.41-0.59. 展开更多
关键词 CHITOSAN polyacrylic acid paa polyethylene glycol (PEG) multifunction polymer synthesis characterization
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