The title copolymer(PDEBO) was synthesized. The thermal characteristics of the polymer were determined by means of DSC and TGA, revealing that the polymer has a good thermal stability. The X-ray diffraction measuremen...The title copolymer(PDEBO) was synthesized. The thermal characteristics of the polymer were determined by means of DSC and TGA, revealing that the polymer has a good thermal stability. The X-ray diffraction measurements of the thin films showed that the polymer is disorder. Electroluminescence(EL) in the green region of the spectrum with a maximum at 500 nm was observed from the polymer films sandwiched between indium-tin-oxide and an Al electrode.展开更多
Using diamine as anchoring group, the self-assembled monolayers（SAMs） based on oligo（phenyleneethynylene）s（OPEs） and cruciform OPEs with an extended tetrathiafulvalene（TTF）（OPE3 and OPE3-TTF）were successfull...Using diamine as anchoring group, the self-assembled monolayers（SAMs） based on oligo（phenyleneethynylene）s（OPEs） and cruciform OPEs with an extended tetrathiafulvalene（TTF）（OPE3 and OPE3-TTF）were successfully formed on the Au substrate. The Uniformity and stability of SAMs were confirmed through cyclic voltammetry（CV） and electrochemical reductive desorption. The investigation of transport properties of SAMs was achieved by conducting-probe atomic force microscopy（CP-AFM） with both Au and Pt tips. The results indicated that the conductance of OPE3-TTF was 17 and 46 times that of OPE3 for Au and Pt tips, respectively. Theoretical calculations are qualitatively consistent with the experimental results, suggesting that the diamine as anchoring group has a great potential in molecular electronics.展开更多
基金Supported by the National Natural Science Foundation of China(No.2 99740 2 5 ) and Zhejiang Provincial Nature Science Foundation(No.5 9910 0 ) State Key L aboratory of Silicon MaterialsL aboratory of Organnic Solids,Institute of Chemistry,Chinese Acade
文摘The title copolymer(PDEBO) was synthesized. The thermal characteristics of the polymer were determined by means of DSC and TGA, revealing that the polymer has a good thermal stability. The X-ray diffraction measurements of the thin films showed that the polymer is disorder. Electroluminescence(EL) in the green region of the spectrum with a maximum at 500 nm was observed from the polymer films sandwiched between indium-tin-oxide and an Al electrode.
基金financially supported by the National Natural Science Foundation of China (Nos. 61571415, 61622406, 51502283)the National Key Research and Development Program of China (Nos. 2017YFA0207500, 2016YFB0700700)the "Hundred Talents Program" of Chinese Academy of Sciences (CAS)
文摘Using diamine as anchoring group, the self-assembled monolayers（SAMs） based on oligo（phenyleneethynylene）s（OPEs） and cruciform OPEs with an extended tetrathiafulvalene（TTF）（OPE3 and OPE3-TTF）were successfully formed on the Au substrate. The Uniformity and stability of SAMs were confirmed through cyclic voltammetry（CV） and electrochemical reductive desorption. The investigation of transport properties of SAMs was achieved by conducting-probe atomic force microscopy（CP-AFM） with both Au and Pt tips. The results indicated that the conductance of OPE3-TTF was 17 and 46 times that of OPE3 for Au and Pt tips, respectively. Theoretical calculations are qualitatively consistent with the experimental results, suggesting that the diamine as anchoring group has a great potential in molecular electronics.
