The vibrational spectrum of the CaAl2B2O7 was investigated. It was shown that the vibrations of the BO3 groups are present in the region of 1400600 cm-1, and the bands at 519 nm-1 may originate from the AlO6 vibration...The vibrational spectrum of the CaAl2B2O7 was investigated. It was shown that the vibrations of the BO3 groups are present in the region of 1400600 cm-1, and the bands at 519 nm-1 may originate from the AlO6 vibration. The luminescence properties of Eu3+ in CaAl2B2O7 were investigated. It was found that the Eu3+ ion in CaAl2B2O7 occupies two different sites. Investigation on the phonon sideband of Eu3+ indicates that BO3 groups are present in the surroundings of Eu3+ ions.展开更多
The glasses of 59 5H 3BO 3 40XF n 0 5Eu 2O 3 (X=Ca, Mg, Y, Pb, n =2 or 3) were prepared. The measurement of phonon sideband was performed. The higher energy range of phonon sideband spectra was fitted ...The glasses of 59 5H 3BO 3 40XF n 0 5Eu 2O 3 (X=Ca, Mg, Y, Pb, n =2 or 3) were prepared. The measurement of phonon sideband was performed. The higher energy range of phonon sideband spectra was fitted by Gaussian function, and the electron phonon coupling constant was calculated. The decreasing order of electron phonon coupling constant is from CaF 2, YF 3, MgF 2 to PbF 2, and the phonon sideband spectra are coincide with Raman scattering spectra.展开更多
文摘The vibrational spectrum of the CaAl2B2O7 was investigated. It was shown that the vibrations of the BO3 groups are present in the region of 1400600 cm-1, and the bands at 519 nm-1 may originate from the AlO6 vibration. The luminescence properties of Eu3+ in CaAl2B2O7 were investigated. It was found that the Eu3+ ion in CaAl2B2O7 occupies two different sites. Investigation on the phonon sideband of Eu3+ indicates that BO3 groups are present in the surroundings of Eu3+ ions.
文摘The glasses of 59 5H 3BO 3 40XF n 0 5Eu 2O 3 (X=Ca, Mg, Y, Pb, n =2 or 3) were prepared. The measurement of phonon sideband was performed. The higher energy range of phonon sideband spectra was fitted by Gaussian function, and the electron phonon coupling constant was calculated. The decreasing order of electron phonon coupling constant is from CaF 2, YF 3, MgF 2 to PbF 2, and the phonon sideband spectra are coincide with Raman scattering spectra.
