The kinetic study on the hydrolysis reaction of bis（4-nitrophenyl） phosphate （BNPP） catalyzed by Tb-BDBPH system（2：1） was carried out in 50% ethanol solution （pH 7.0-10.0） at 35℃ with I=0.10NaNO3. The second...The kinetic study on the hydrolysis reaction of bis（4-nitrophenyl） phosphate （BNPP） catalyzed by Tb-BDBPH system（2：1） was carried out in 50% ethanol solution （pH 7.0-10.0） at 35℃ with I=0.10NaNO3. The second-order rate constant kBNPP, 2.3×10.3 （mol^-1L S^-1）, was determined. The dinuclear monohydroxo species, L-2Tb-OH, is kinetically mainly active species. The hydrolysis rate of BNPP by the complex is increased almost 2.6 million-fold compared with the background hydroxide rate at the same condition.展开更多
文摘The kinetic study on the hydrolysis reaction of bis（4-nitrophenyl） phosphate （BNPP） catalyzed by Tb-BDBPH system（2：1） was carried out in 50% ethanol solution （pH 7.0-10.0） at 35℃ with I=0.10NaNO3. The second-order rate constant kBNPP, 2.3×10.3 （mol^-1L S^-1）, was determined. The dinuclear monohydroxo species, L-2Tb-OH, is kinetically mainly active species. The hydrolysis rate of BNPP by the complex is increased almost 2.6 million-fold compared with the background hydroxide rate at the same condition.
