Reanalysis of the photoassociation spectrum of the weakly binding （6S1/2 ＋ 6P3/2） lg 133Cs2 levels, reported in the previous study [J. Mol. Spectro. 255 （2009） 106], is performed by using a Lu-Fano graph coupled ...Reanalysis of the photoassociation spectrum of the weakly binding （6S1/2 ＋ 6P3/2） lg 133Cs2 levels, reported in the previous study [J. Mol. Spectro. 255 （2009） 106], is performed by using a Lu-Fano graph coupled to the improved LeRoy- Bernstein formula including two additional modified terms. A more accurate coefficient （c3） is obtained for the leading long-range potential （-c3/R3） of a diatomic molecule.展开更多
We investigate the high resolution photoassociation spectra of ^（85）Rb_2 molecules in 0~＋_u long range state below the（5S_（1/2）＋ 5P_（1/2）） asymptote. The ^（85）Rb atomic samples are trapped in a dark magnet...We investigate the high resolution photoassociation spectra of ^（85）Rb_2 molecules in 0~＋_u long range state below the（5S_（1/2）＋ 5P_（1/2）） asymptote. The ^（85）Rb atomic samples are trapped in a dark magneto–optical trap（MOT） and prepared in the dark state. With the help of trap loss technique, we obtain considerable photoassociation spectroscopy with rovibrational resolution, some of which have never been observed before. The observed spectrum is fitted by a rigid rotation model, and the rotational constants of ultracold ^（85）Rb_2 molecule in long range 0~＋_u are obtained for different vibrational states. By applying the Le Roy–Bernstein method, we assign the vibrational quantum numbers and derive C_3 coefficient, which is used to obtain the potential energy curve.展开更多
基金supported by the National Basic Research Program of China(Grant No.2012CB921603)the 863 Program(Grant No.2011AA010801)+3 种基金the National Natural Science Foundation of China(Grant Nos.61008012,10934004,11074204,and 11174236)the International Science and Technology Cooperation Program of China(Grant No.2011DFA12490)the New Teacher Fund of the Ministry of Education of China(Grant No.20101401120004)the Natural Science Foundation of Shanxi Province,China(Grant No.2013021005-1)
文摘Reanalysis of the photoassociation spectrum of the weakly binding （6S1/2 ＋ 6P3/2） lg 133Cs2 levels, reported in the previous study [J. Mol. Spectro. 255 （2009） 106], is performed by using a Lu-Fano graph coupled to the improved LeRoy- Bernstein formula including two additional modified terms. A more accurate coefficient （c3） is obtained for the leading long-range potential （-c3/R3） of a diatomic molecule.
基金supported by the National Natural Science Foundation of China(Grant Nos.61675120,11434007,and 61378015)the National Natural Science Foundation of China for Excellent Research Team(Grant No.61121064)+1 种基金the Shanxi Scholarship Council of Chinathe PCSIRT(Grant No.IRT 13076)
文摘We investigate the high resolution photoassociation spectra of ^（85）Rb_2 molecules in 0~＋_u long range state below the（5S_（1/2）＋ 5P_（1/2）） asymptote. The ^（85）Rb atomic samples are trapped in a dark magneto–optical trap（MOT） and prepared in the dark state. With the help of trap loss technique, we obtain considerable photoassociation spectroscopy with rovibrational resolution, some of which have never been observed before. The observed spectrum is fitted by a rigid rotation model, and the rotational constants of ultracold ^（85）Rb_2 molecule in long range 0~＋_u are obtained for different vibrational states. By applying the Le Roy–Bernstein method, we assign the vibrational quantum numbers and derive C_3 coefficient, which is used to obtain the potential energy curve.
