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Preparation and Characterization of Activated Carbons from Palm Nut Shells: Effects of Calcination Temperature on Porosity and Chemical Properties
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作者 Charly Mve Mfoumou Berthy Lionel Mbouiti +2 位作者 Spenseur Bouassa Mougnala Pradel Tonda-Mikiela Guy Raymond Feuya Tchouya 《Open Journal of Inorganic Chemistry》 2024年第2期19-32,共14页
Activated carbons (ACs) calcined at 400˚C, 500˚C, and 600˚C (AC-400, AC-500, and AC-600) were prepared using palm nut shells from Gabon as raw material and zinc chloride (ZnCl2) as a chemical activating agent. Prepare... Activated carbons (ACs) calcined at 400˚C, 500˚C, and 600˚C (AC-400, AC-500, and AC-600) were prepared using palm nut shells from Gabon as raw material and zinc chloride (ZnCl2) as a chemical activating agent. Prepared ACs were characterized by physisorption of nitrogen (N2), determination of diode and methylene blue numbers for studies of porosity and by quantification and determination of surface functional groups and pH at point of zero charge (pHpzc) respectively, for studies of chemical properties of prepared ACs. Then, effects of calcination temperature (Tcal) on porosity and chemical properties of prepared ACs were studied. The results obtained showed that when the calcination temperature increases from 500˚C to 600˚C, the porosity and chemical properties of prepared ACs are modified. Indeed, the methylene blue and iodine numbers determined for activated carbons AC-400 (460 and 7.94 mg·g−1, respectively) and AC-500 (680 and 8.90 mg·g−1, respectively) are higher than those obtained for AC-600 (360 and 5.75 mg·g−1, respectively). Compared to the AC-500 adsorbent, specific surface areas (SBET) and microporous volume losses for AC-600 were estimated to 44.7% and 45.8%, respectively. Moreover, in our experimental conditions, the effect of Tcal on the quantities of acidic and basic functional groups on the surface of the ACs appears negligible. In addition, results of the pHpzc of prepared ACs showed that as Tcal increases, the pH of the adsorbents increases and tends towards neutrality. Indeed, a stronger acidity was determined on AC-400 (pHpzc = 5.60) compared to those on AC-500 and AC-600 (pHpzc = 6.85 and 6.70, respectively). Also according to the results of porosity and chemical characterizations, adsorption being a surface phenomenon, 500˚C appears to be the optimal calcination temperature for the preparation of activated carbons from palm nut shells in our experimental conditions. 展开更多
关键词 Palm Nut Shells Activated Carbon Calcination Temperature Porosity and chemical properties
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Physical and Chemical Properties of Horns Sheaths Particles for the Manufacture of Composite Materials
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作者 Tawe Laynde Zakari Yaou +2 位作者 Karga Tapsia Lionel Konai Noel Danwe Raidandi 《Journal of Materials Science and Chemical Engineering》 2024年第5期1-9,共9页
Salvaged cow horns from slaughterhouses have been transformed into fine particles for a physical characterization that has led us to determine the humidity rate (2.34% ± 0.054%), the actual density situated betwe... Salvaged cow horns from slaughterhouses have been transformed into fine particles for a physical characterization that has led us to determine the humidity rate (2.34% ± 0.054%), the actual density situated between 0.586 g/cm<sup>3</sup> and 0.732 g/cm<sup>3</sup>, the swelling rate (12%), and one chemical characterization that permitted us to determine the rate of dry matters (97.05%), of mineral matters (2.5%), of protein matters (94.52%). From these weak values, it can easily be seen that cow horn case doesn’t absorb much water and improve the mechanical characteristics of the composite;the high rate of protein shows that keratin which is the structural molecule favors its gripping as reinforcing element in the manufacturing of composite materials. 展开更多
关键词 HORNS Fibers Polymer Loads Physical properties chemical Composition
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Physico-Chemical and Nutritional Properties of a Food Broth Based on Nere (Parkia biglobosa)
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作者 Lassana Bamba Gervais Melaine M’Boh +5 位作者 N’Gbésso Amos Ekissi Kipré Laurent Séri Gnogbo Alexis Bahi Koffi Pierre Valery Niaba Allico Joseph Djaman Grah Avit Maxwell Beugre 《Food and Nutrition Sciences》 CAS 2024年第5期377-389,共13页
Purpose: Diet and eating habits are major risk factors for the health and the development of disease, such as, for example, metabolic disorder leading to cardiovascular pathology and cancer, decreased immunity exposin... Purpose: Diet and eating habits are major risk factors for the health and the development of disease, such as, for example, metabolic disorder leading to cardiovascular pathology and cancer, decreased immunity exposing to infections. This study of the physico-chemical and nutritional properties of a soumara-based food broth was carried out with the aim of promoting the consumption of organic broth made from nere seeds (soumara). That is to alleviate certain metabolic diseases, which is a matter of food safety, and also to limit the risk for the health about the consumption of some cooking stocks on the market. Methods: Several natural ingredients such as nere seeds (soumara), ginger, black pepper, parsley and garlic were used to create a nere-based stock. All these ingredients were freeze-dried and the powder obtained was used to make the broth, regarding their physical and chemical properties. Results: The broth had a good protein content of 17.41 ± 0.367 g/100g, a lipid content of 16.80 ± 0.08 g/100g and a fiber content of 8.66 ± 0.04 g/100g. In terms of nutritional values, the broth showed good levels of calcium 184.21 ± 0.09 mg/100g, potassium 50.04 ± 1.45 mg/100g and iron and zinc. In terms of antioxidant activity, the broth also showed good antioxidant activity. Conclusion: Regarding the properties of our food broth, whose composition is based on natural ingredients, could be recommended for consumption and, its properties, could play an important role in preventing and combating certain metabolic diseases. 展开更多
关键词 Food Broth Nere Physico-chemical properties NUTRITION Food Safety
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GIS-Based Assessment of Soil Chemical and Physical Properties as a Basis for Land Reclamation in Toshka Area, Aswan, EGYPT
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作者 Ahmed A. M. Awad Mostafa M. A. Al-Soghir 《Open Journal of Geology》 2023年第7期697-719,共23页
The accurate assessment of soil properties is a crucial factor for composing and implementing reclamation plans. The main objective of this study was to evaluate soil chemical and physical properties and calculate the... The accurate assessment of soil properties is a crucial factor for composing and implementing reclamation plans. The main objective of this study was to evaluate soil chemical and physical properties and calculate the chemical and fertility index for assisting land reclamation in Toshka area. The Toshka area is located between latitudes 31°32'N and 31°36'N and longitudes 32°40'E and 32°60'E. GIS was used to select 16 sites. The results revealed the soil has undesirable characteristics. The soil pH ranged from slightly alkaline to moderately alkaline. Furthermore, it was characterized as saline (with a ECe of 4.65 - 11.45 dS⋅m<sup>−1</sup>) and moderately calcareous soil (with CaCO<sub>3</sub> at 11.85% - 17.20%). The soil had a low soil organic matter content which did not exceed 0.18%. The soil was dominated by a sandy loam texture (62.50%) followed by a sandy clay loam texture (18.75%). The bulk density, total soil porosity and saturated hydraulic conductivity values varied with 1.38 - 1.55 Mg⋅cm<sup>−3</sup>, 41.85% - 48.45% and 1.20 - 3.34 cm⋅h<sup>−1</sup>, respectively. The chemical index ranged from low to moderate quality. The correlations between the parameters osculated between negative and positive. Therefore, the soil may be reclaimed if the soil properties are improved and crop selection is optimized for this soil. 展开更多
关键词 Land Reclamation Soil chemical and Physical properties chemical Quality Index Fertility Quality Index
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Biodiesel Production from Rhynchophorus ferrugineus Larvae Oil: Physichochemical Properties and Acid Composition of Oil as Affected by Oil Extraction Protocol
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作者 Arnaude Folepe Azemo Esther Julius K. Tangka Nsah-ko Tchoumboue 《Journal of Sustainable Bioenergy Systems》 2023年第4期117-130,共14页
Biodiesel, a renewable energy source made from natural oils and fats, can be produced using white raffia larvae as a raw material. These larvae have a high lipid content and a short life cycle, making them suitable fo... Biodiesel, a renewable energy source made from natural oils and fats, can be produced using white raffia larvae as a raw material. These larvae have a high lipid content and a short life cycle, making them suitable for this purpose. One crucial step in biodiesel production is oil extraction, and this study aimed to investigate how the extraction protocol affects the fuel properties of the oil. To study the impact of solvent type, solvent volume, and residence time on oil yield, 200 grams of Rhynchophorus ferrugineus were used in a Soxhlet extractor. The researchers examined the physicochemical properties and fatty acid composition of the crude grease using the European biodiesel standard (EN14214) and gas chromatography methods, respectively. The study found that hexane as a solvent produced the highest oil yield (64.44%) during a four-hour extraction period with a solvent ratio of 300 ml. Furthermore, the hexane-extracted oil had the highest iodine number (3.02 g/100 g) and cetane number (55.69). These values indicate favorable properties for biodiesel production. The Rhynchophorus ferrugineus larvae oil proved to be a rich source of monounsaturated fatty acids (76%), which were found to be significantly affected by the solvent type. Based on quality assessment, Rhynchophorus ferrugineus can be suitable for biodiesel production. In summary, under the given operational conditions, hexane is the most suitable solvent for Rhynchophorus ferrugineus oil extraction for biodiesel production. Further research in optimizing the extraction process can contribute to the efficient utilization of renewable energy sources like white raffia larvae for biodiesel production. 展开更多
关键词 BIODIESEL Extraction Process Fatty Acid Composition Physico-chemical properties Rhynchophorus ferrugineus Larvae
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Responses of microbial activities and soil physical-chemical properties to the successional process of biological soil crusts in the Gurbantunggut Desert,Xinjiang 被引量:29
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作者 BingChang ZHANG XiaoBing ZHOU YuanMing ZHANG 《Journal of Arid Land》 SCIE CSCD 2015年第1期101-109,共9页
Biological soil crusts (BSCs) are capable of modifying nutrient availability to favor the establishment of biogeochemical cycles. Microbial activities serve as critical roles for both carbon and nutrient transformat... Biological soil crusts (BSCs) are capable of modifying nutrient availability to favor the establishment of biogeochemical cycles. Microbial activities serve as critical roles for both carbon and nutrient transformation in BSCs. However, little is known about microbial activities and physical-chemical properties of BSCs in the Gurbantunggut Desert, Xinjiang, China. In the present research, a sampling line with 1-m wide and 20-m long was set up in each of five typical interdune areas selected randomly in the Gurbantunggut Desert. Within each sampling line, samples of bare sand sheet, algal crusts, lichen crusts and moss crusts were randomly collected at the depth of 0-2 cm. Varia- tions of microalgal biomass, microbial biomass, enzyme activities and soil physical-chemical properties in different succession of BSCs were analyzed. The relationships between microalgal biomass, microbial biomass, enzymatic activities and soil physical-chemical properties were explored by stepwise regression. Our results indicate that micro- algal biomass, microbial biomass and most of enzyme activities increased as the BSCs developed and their highest values occurred in lichen or moss crusts. Except for total K, the contents of most soil nutrients (organic C, total N, total P, available N, available P and available K) were the lowest in the bare sand sheet and significantly increased with the BSCs development, reaching their highest values in moss crusts. However, pH values significantly decreased as the BSCs developed. Significant and positive correlations were observed between chlorophyll a and microbial biomass C. Total P and N were positively associated with chlorophyll a and microbial biomass C, whereas there was a significant and negative correlation between microbial biomass and available P. The growth of cyanobacteria and microorganism contributed C and N in the soil, which offered substrates for enzyme activities thus increasing enzyme activities. Probably, improvement in enzyme activities increased soil fertility and promoted the growth of cyanobacteria, eukary- otic algae and heterotrophic microorganism, with the accelerating succession of BSCs. The present research found that microalgal-microbial biomass and enzyme activities played important roles on the contents of nutrients in the successional stages of BSCs and helped us to understand developmental mechanism in the succession of BSCs. 展开更多
关键词 chlorophyll a microbial biomass C soil enzyme physical-chemical properties biological soil crusts
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Effects of Different Application Amounts of Potassium Fulvate on Yield and Quality of Tomato and Soil Physical and Chemical Properties 被引量:2
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作者 高伟 李明悦 +4 位作者 杨军 高贤彪 冯海娟 张善平 郑春莲 《Agricultural Science & Technology》 CAS 2017年第12期2392-2395,2400,共5页
This study was conducted to study the optimum dosage of potassium ful- vate (PF) on greenhouse tomato, the effects of different amounts of PF on yield and quality of greenhouse tomato and soil physical and chemical ... This study was conducted to study the optimum dosage of potassium ful- vate (PF) on greenhouse tomato, the effects of different amounts of PF on yield and quality of greenhouse tomato and soil physical and chemical properties were investigated by a field plot experiment. The results showed that the bottom applica- tion of PF increased tomato yield, plant dry matter weight and root dry matter weight by 14.0%, 14.4 and 50.6%, respectively; Vc and soluble sugar content of tomato increased by 1&5% and 10.0%, respectively; and soil bulk density de- creased by 3.6%, and CEC increased by 5.0%. All the indexes increased with the increase of PF application amount, and reached the maximum value when the PF application rate was 4 500 kg/hm2. In consideration of the cost of fertilizer and all indexes, the optimum dosaqe of PF fertilizer was 4 500 kg/hm2. 展开更多
关键词 Greenhouse tomato Potassium fulvate (PF) YIELD QUALITY Soil physicaland chemical properties
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Changing Rules of Physical and Chemical Properties of Eucalyptus uraphylla spp. Forest at Different Ages in Southwest Yunnan Province 被引量:5
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作者 赵筱青 丁宁 闫平 《Agricultural Science & Technology》 CAS 2012年第6期1298-1302,共5页
[Objective] The aim was to study on changing rules of physical and chemical properties of Eucalyptus uraphylla spp. forest at different ages in Southwest of Yunnan Province. [Method] In the research, field survey and ... [Objective] The aim was to study on changing rules of physical and chemical properties of Eucalyptus uraphylla spp. forest at different ages in Southwest of Yunnan Province. [Method] In the research, field survey and laboratory analysis were adopted to study on physical and chemical properties of soils for the Eucalyptus uraphylla spp. at the first cutting ages in Lancang County. [Result] With the increasing of forest ages, for physical properties of soils, soil bulk density was increasing, and soil structure became poor; water contents in soils and capillary porosity were improving, but total soil porosity and non-capillary porosity were decreasing. For chemical properties, pH of soil dropped, but soil acidity improved; organic matter, total N, hydrolysable nitrogen, available phosphorus, and available potassium all declined; exchangeable Ca and Mg were improving due to fertilization and Ca and Mg lower consumption. The results showed that plays important roles in water absorption of soils and vegetation growth were improved with age increase by Eucalyptus uraphylla spp. forest, but ventilation and fertility declined accordingly. [Conclusion] The research indicated that dry branches and fallen leaves should be preserved and nutrient cycling should be protected during introduction and management of Eucalyptus uraphylla spp. to guarantee the nutrients in dry branches and leaves are back to soils, providing theoretical references for management of forest plantation and environment protection. 展开更多
关键词 Eucalyptus uraphylla spp. Physical and chemical properties Soil fertility Lancang County
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QSPR between Physical-Chemical Properties and Molecule Parameters of Alkanes
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作者 XU Qing-qing LI Liang-chao HU Li-ya 《Wuhan University Journal of Natural Sciences》 EI CAS 2005年第5期897-903,共7页
A set of molecule parameters, namely, N, N′, p, q, n, were used to express the structures of alkanes. A correlative model was established between certain physical-chemical properties and molecular parameters of alkan... A set of molecule parameters, namely, N, N′, p, q, n, were used to express the structures of alkanes. A correlative model was established between certain physical-chemical properties and molecular parameters of alkanes by regression method. Eight physical-chemical properties, such as evaporation heat (△vHm^20), density(D^20 ), capacity (C^20), surface tension (δ^20), boiling point (Tb), critical temperature(Tc), critical pressure(Pc) and critical volume(Vc), of fifty-six C3-C16 alkanes were calculated directly from the model in this paper. The calculated values are in good accordance with the literature ones reported for alkanes, and the correlation coefficients (R) equal or exceed 0.99 . The research results indicate that the principle of the method is simple and clear, the method is practical, the correlativity is excellent, and the predicted data are credible. 展开更多
关键词 ALKANE molecular parameters physical-chemical properties
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First principles study of electronic structure, chemical bonding and elastic properties of BiOCuS
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作者 潘留仙 夏庆林 +2 位作者 叶绍龙 丁宁 刘自然 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第5期1197-1202,共6页
The electronic structures, chemical bonding and elastic properties of the tetragonal phase BiOCuS were investigated by using density-functional theory (DFT) within generalized gradient approximation (GGA). The cal... The electronic structures, chemical bonding and elastic properties of the tetragonal phase BiOCuS were investigated by using density-functional theory (DFT) within generalized gradient approximation (GGA). The calculated energy band structures show that the tetragonal phase BiOCuS is an indirect semiconductor with the calculated band gap of about 0.503 eV. The density of states (DOS) and the partial density of states (PDOS) calculations show that the DOS near the Fermi level is mainly from the Cu-3d state. Population analysis suggests that the chemical bonding in BiOCuS has predominantly ionic character with mixed covalent-ionic character. Basic physical properties, such as lattice constant, bulk modulus, shear modulus, elastic constants, were calculated. The elastic modulus and Poisson ratio were also predicted. The results show that tetragonal phase BiOCuS is mechanically stable and behaves in a ductile manner. 展开更多
关键词 BiOCuS first principles electronic structures chemical bonding elastic properties
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Preparation of Manganese Oxide and Its Adsorption Properties
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作者 贺跃 王海峰 +4 位作者 YANG Pan WANG Song CHEN Xiaoliang YANG Chunyuan 王家伟 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期1031-1040,共10页
The in-situ oxidation of manganese sulfate solution with H2O_(2),sodium hypochlorite,potassium permanganate and oxygen as oxidants was investigated by means of SEM,EDS,XRD,BET and infrared analysis,and the effects of ... The in-situ oxidation of manganese sulfate solution with H2O_(2),sodium hypochlorite,potassium permanganate and oxygen as oxidants was investigated by means of SEM,EDS,XRD,BET and infrared analysis,and the effects of different oxidants on the morphology,phase composition,surface properties and specific surface area of manganese oxides were investigated.The experimental results show that the diameter of manganese oxide particles prepared with H_(2)O_(2)is the smallest,about 50 nm,and the specific surface area is the largest,63.8764 m^(2)/g.It has the advantages of abundant surface hydroxyl groups,no introduction of other impurities and large adsorption potential.It is most suitable to be used as an oxidant for oxidizing manganese sulfate solution to prepare manganese oxide by in-situ oxidation.Nano manganese oxide prepard by H_(2)O_(2)in-situ oxidation method is used as adsorbent to adsorb cobalt and nickel impurities in manganese sulfate.When the reaction pH is 6,the reaction time is 30min and the amount of adsorbent is 1.0 g,the adsorption rates of cobalt and nickel impurities in 100ml manganese sulfate solution are 97.59%and 97.67%,respectively.The residual amounts of cobalt and nickel meet the industrial process standard of first-class products(Co,Ni w/%≤0.005)of high-purity manganese sulfate(Hg/t4823-2015)for batteries.The study plays a guiding role in the preparation and regulation of manganese oxide,and provides a new method with high efficiency,purity and adsorbent availability for the preparation of high-purity manganese sulfate solution. 展开更多
关键词 manganese oxide in situ oxidation ADSORBENT regulation mechanism PHYSICAL chemical properties
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Field Spectra of Suaeda salsa in Response to Changes of Soil Chemical Properties
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作者 刘庆生 刘高焕 +2 位作者 黄翀 宁吉才 谢传节 《Agricultural Science & Technology》 CAS 2011年第6期883-886,936,共5页
[Objective] This study was to investigate the Suaeda salsa community characteristics,further getting the soil chemical properties.[Method] The paired-data of field spectra and corresponding soil physical-chemical prop... [Objective] This study was to investigate the Suaeda salsa community characteristics,further getting the soil chemical properties.[Method] The paired-data of field spectra and corresponding soil physical-chemical property of seventeen samples was used to reveal the relationship between soil chemical property and field spectra(visible and near infra-red spectra)of S.salsa.[Result] The second derivative spectrum of S.salsa at 1 121 nm could reflect the changes of soil organic matter and soil total nitrogen,and that at 1 208 nm could commendably indicate changes of soil total phosphorus and at 724 nm could indicate changes of soil pH.The first derivative spectrum of S.salsa at 353 nm can indicate changes of soil available potassium,and that at 950 nm could commendably reflect the changes of soil salt content.[Conclusion] Our results laid basis for monitoring chemical property of soil covered with S.salsa using remote sensing technology. 展开更多
关键词 SOILS chemical properties Field spectra Suaeda salsa
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First principles calculation of electronic structure, chemical bonding and elastic properties of ultra-incompressible Re_2P
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作者 王一夫 夏庆林 余燕 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第11期3400-3404,共5页
The electronic structures, chemical bonding and elastic properties of the Co2P-type structure phase ultra-incompressible Re2P (orthorhombic phase) were investigated by density-functional theory (DFT) within genera... The electronic structures, chemical bonding and elastic properties of the Co2P-type structure phase ultra-incompressible Re2P (orthorhombic phase) were investigated by density-functional theory (DFT) within generalized gradient approximation (GGA). The calculated energy band structures show that the orthorhombic structure phase Re2P is metallic material. The density of state (DOS) and the partial density of state (PDOS) calculations show that the DOS near the Fermi level is mainly from the Re-5d state. Population analysis suggests that the chemical bonding in Re2P has predominantly covalent character with mixed covalent-ionic character. Basic physical properties, such as lattice constant, bulk modulus, shear modulus, and elastic constants Cij, were calculated. The elastic modulus and Poisson ratio were also predicted. The results show that the Co2P-type structure phase Re2P is mechanically stable and behaves in a brittle manner. 展开更多
关键词 Re2P first principles electronic structures chemical bonding elastic properties
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Soil Physical and Chemical Properties of Five Subtropical Forests in Lingao of Hainan
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作者 薛杨 宿少锋 +1 位作者 王小燕 林之盼 《Agricultural Science & Technology》 CAS 2017年第8期1459-1464,共6页
With 5 types of typical forests as research object, the physical and chemical properties of different types of forests were analyzed by sample plot investigation method. The results showed that: the soil total porosi... With 5 types of typical forests as research object, the physical and chemical properties of different types of forests were analyzed by sample plot investigation method. The results showed that: the soil total porosity was the highest in the Casuarina equisetifolia forest (46.168%), but the lowest in the Encalyptus robusta forest (39.46%). The soil capillary porosity was the highest in the Acacia mangium forest (22.57%), but the lowest in the secondary forest (18.95%). The soil water content was the highest in the C. equisetifolia forest, with a mean value of 27.85%, but the lowest in the secondary forest, with a mean value of 4.34%. The soil pH values were in the range of 4.81-6.59, the soils in the A. mangium forest, C. equisetifolia forest and E. robusta forest were strongly acidic (pH 4.5-5.5), and the soils in the secondary forest and C. nucifera forest were weakly acidic. The soils had organic matter contents in the range of 0.34-28.68 g/kg, and showed an order of A. mangium forest〉C. equisetifolia forest〉E. robusta forest〉secondary forest〉C. nucifera forest, with a decreasing trend with the soil depth increasing. The soil total N contents were in the range of 0.10-1.63 g/kg, the A. mangium forest showed the highest soil total N contents, while the C. nucifera forest exhibited the lowest soil total N contents; the soil total P contents were in the range of 0.21-1.74 g/kg, and the E. robusta forest had the highest soil total P contents; and the soil total K contents were in the range of 0.16-2.15 g/kg, and the A. mangium forest exhibited the highest soil total K contents. The soil available P contents were in the range of 0.98-132.46 mg/kg; and the secondary forests had the highest soil available P contents; and the soil rapidly available K contents were in the range of 3.03-27.35 mg/kg, and the C. nucifera forest exhibited the highest soil rapidly available K contents. The soil ammonium N contents were in the range of 1.38-5.15 mg/kg, and the nitrate N contents were in the range were in the range of 0.56 -3.51 mg/kg. The A. mangium forest showed the highest soil nitrate N contents (with a mean value of 2.29 mg/kg) and ammonium N contents (with a mean value of 3.93 mg/kg). For the same forest type, with the increase of soil depth, the nitrate nitrogen and ammonium nitrogen content also showed a decreasing trend. 展开更多
关键词 Lingao County Coastal platform Different forest types Soil physical and chemical properties COMPARISON
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Chemical bonding and elastic properties of quaternary arsenide oxides YZnAsO and LaZnAsO investigated by first principles
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作者 施毅敏 叶绍龙 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第6期1378-1382,共5页
The structural parameters, chemical bonding and elastic properties of the tetragonal phase quaternary arsenide oxides YZnAsO and LaZnAsO were investigated by using density-functional theory (DFT) within generalized ... The structural parameters, chemical bonding and elastic properties of the tetragonal phase quaternary arsenide oxides YZnAsO and LaZnAsO were investigated by using density-functional theory (DFT) within generalized gradient approximation (GGA). The GGA calculated structural parameters are in agreement with the experimental results. Population analysis suggests that the chemical bonding in YZnAsO and LaZnAsO can be classified as a mixture of ionic and covalent characteristic. Single-crystal elastic constants were calculated and the polycrystalline elastic modules were estimated according to Voigt, Reuss and Hill's approximations (VRH). The result shows that both YZnAsO and LaZnAsO are relatively soft materials exhibiting ductile behavior. The calculated polycrystalline elastic anisotropy result shows that LaZnAsO is more anisotropy in compressibility and YZnAsO is more anisotropy in shear. 展开更多
关键词 YZnAsO LaZnAsO chemical bonding elastic properties density-functional theory generalized gradientapproximation Voigt Reuss and Hill's approximations
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Study of Potential Edaphic Chemical Factors in the Prevalence of Swollen Shoot Disease of Cocoa in the Marahoué Region (Côte d’Ivoire)
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作者 Ferdinand Gohi Bi Zro Martinez Arnauth Guei +3 位作者 Zoumana Konate Tchimou Elvis Paterne Dogniméton Soro Sidiky Bakayoko 《Open Journal of Soil Science》 2024年第10期660-673,共14页
This study looks at the prevalence of swollen shoot disease in cocoa plantations in the Marahoué region of Côte d’Ivoire, a key cocoa-producing area. Cocoa accounts for around a third of the country’s expo... This study looks at the prevalence of swollen shoot disease in cocoa plantations in the Marahoué region of Côte d’Ivoire, a key cocoa-producing area. Cocoa accounts for around a third of the country’s export earnings, but production is under threat from the swollen shoot virus, which is causing major yield reductions. The aim of the study is to establish a link between the chemical properties of the soil and the presence of the disease, in particular the levels of carbon, nitrogen, phosphorus, calcium and acidity (pH) in the soil. Specifically, soils from healthy plots were compared with soils from infested plots in six plantations in the Bouaflé and Kononfla sub-prefectures. The results show that soils from infested plots have lower phosphorus levels and near-neutral acidity in the 20 - 40 cm soil layer, while soils from healthy plots are slightly acidic and contain more calcium and phosphorus. These chemical differences seem to influence the prevalence of the virus. Low phosphorus levels appear to be a key factor in the vulnerability of cocoa trees to the disease. The study therefore suggests that any strategy to combat swollen shoot should include better soil management, incorporating factors such as soil depth and the availability of essential nutrients. In addition, an assessment of the micro-organisms present in the soil could provide further information on the interactions between the soil and the disease. 展开更多
关键词 Soil chemical properties Cocoa Swollen Shoot Marahoué Region
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Classification and Distribution of Common Aroma Components in Tobacco Leaf Based on Their Physical and Chemical Properties 被引量:4
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作者 詹军 周芳芳 +6 位作者 朱海滨 高侠飞 毛春堂 王柱石 严君 陈少鹏 张晓龙 《Agricultural Science & Technology》 CAS 2013年第9期1358-1364,共7页
[Objective] This study was aimed to find a new method for the classification of common aroma components in tobacco leaves. [Method] Sixty-four common aroma components in tobacco leaves were classified by cluster analy... [Objective] This study was aimed to find a new method for the classification of common aroma components in tobacco leaves. [Method] Sixty-four common aroma components in tobacco leaves were classified by cluster analysis based on their relative molecular weight. The contents and distribution of aroma components in another 71 C3F and 64 B2F tobacco leaf samples were analyzed by using the new method. [Result] The 64 common aroma components were divided into three categories trough the cluster analysis based on their molecular weight. CategoryⅠ consisted of 12 aroma components which had high molecular weight(281.308±21.536on average) and high boiling point(371.311±29.904 ℃ on average). Category Ⅱ included 27 components which had low molecular weight(103.722 ± 13.115 on average) and low boiling point(176.132±42.342 ℃ on average). Category Ⅲ included 25components which had middle molecular weight(175.393 ± 24.906 on average) and middle boiling point(250.562±45.431 ℃ on average). The content of high-molecularweight aroma components in middle leaves(547.344±224.391 μg/g) was much higher than that in upper leaves(477.549±182.066 μg/g). The content of low-molecularweight aroma component in middle leaves(17.468±3.459 μg/g) was also significantly higher than that in upper leaves(15.936±3.456 μg/g). The content of middle-molecular-weight aroma component in middle leaves(44.931 ±8.953 μg/g) was extremely significantly higher than that in upper leaves(37.997±6.042 μg/g). [Conclusion] This study proposed a new way to classify the aroma components in flue-cured tobacco leaves using the relative molecular weight as the index, which will provide theoretical reference for developing special tobacco leaves. 展开更多
关键词 Physical and chemical properties Flue-cured tobacco Aroma components Molecular weight Boiling point DENSITY CLASSIFICATION
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Effects of Green Manure Mixed Cropping Patterns on Physical and Chemical Properties of Soil and Economic Characters of Flue-cured Tobacco 被引量:4
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作者 陈治锋 邓小华 +2 位作者 周米良 田峰 张明发 《Agricultural Science & Technology》 CAS 2015年第8期1723-1727,共5页
[Objective] The aim was to clear the suitable green manure cropping pat- terns in Xiangxi tobacco-planting areas. [Method] 8 treatments were set to study the effects of the monoculture and mixed cropping of common vet... [Objective] The aim was to clear the suitable green manure cropping pat- terns in Xiangxi tobacco-planting areas. [Method] 8 treatments were set to study the effects of the monoculture and mixed cropping of common vetch (Vicia gigantea Bge.), perennial ryegrass (Lofium) and rapeseed (Brassica campestris L.) on physi- cal and chemical properties of soil and economic characters of flue-cured tobacco. [Result] (1) Green manure turnover can reduce soil bulk density by 1.08%-8.62%, and the effect of green manure mixed cropping pattern was the best. (2) Green manure turnover also can increase the soil nutrient, soil organic matter, total nitro- gen (N), total phosphorus (P), total potassium (K), alkali-hydrolyzale N, rapidly available P and rapidly available K by 1.44%-6.10%, 0.01-0.12 g/kg, 1.89%- 11.32%, 0.12%-3.56%, 1.06%-11.76%, 0.04%-18.93% and 0.98%-23.12%, respec- tively, and the effect of the monoculture of common vetch was the best.(3) The overall change of soil pH was not obvious.(4)Green manure turnover can increase the yield and output of flue-cured tobacco, and the effect of the monoculture of common vetch was the best. [Conclusion] The monoculture of common vetch can be generalized in the dry land of Xiangxi tobacco-planting areas. 展开更多
关键词 Green manure Mixed cropping Soil physical and chemical properties Economic characters of flue-cured tobacco
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Effect of fire severity on physical and biochemical soil properties in Zagros oak(Quercus brantii Lindl.)forests in Iran 被引量:16
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作者 M.Heydari A.Rostamy +1 位作者 F.Najafi D.C.Dey 《Journal of Forestry Research》 SCIE CAS CSCD 2017年第1期95-104,共10页
Fire affects the physical and chemical properties and soil biological activity of natural ecosystems. This study was conducted in the Miyan Tang region, Ilam Province in western Iran. The study site was 110 hectares, ... Fire affects the physical and chemical properties and soil biological activity of natural ecosystems. This study was conducted in the Miyan Tang region, Ilam Province in western Iran. The study site was 110 hectares, where we sampled soils in areas that were classified by fire severity: low (LS), high (HS) and medium severity (MS), and unburned (UB), which served as the control. In each severity class, 25 transect points were randomly selected for measurement. Around each transect plot center, 3 soil samples were selected randomly and soils collected from the 0 to 20 cm depth were combined into a composite sample that was used in laboratory analysis to represent conditions at that point. Plots in the UB and LS fire classes had similar soil conditions and had higher values of factors such as saturated moisture, organic carbon, carbon dioxide, and silt and clay content. In contrast, plots in the HS and MS fire severity classes were clustered in the positive direction along the first axis that represented gradients in soil acidity, electrical conductivity, cation exchange capacity, accessible phosphorus, accessible potassium, bulk density, and sand. Soil attributes were similar in areas of HS and MS fire severity classes, whereas soil conditions in the LS class and UB controls were most similar. Fire in the LS areas either did not significantly alter the physicalchemical soil properties and microbial basal respiration, or soils were able to recover quickly after being burned. 展开更多
关键词 Fire severity OAK Soil respiration Physical and chemical soil properties
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Effects of reclaimed water irrigation and nitrogen fertilization on the chemical properties and microbial community of soil 被引量:11
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作者 GUO Wei Mathias N Andersen +4 位作者 QI Xue-bin LI Ping LI Zhong-yang FAN Xiang-yang ZHOU Yuan 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2017年第3期679-690,共12页
The ecological effect of reclaimed water irrigation and fertilizer application on the soil environment is receiving more attention.Soil microbial activity and nitrogen(N)levels are important indicators of the effect... The ecological effect of reclaimed water irrigation and fertilizer application on the soil environment is receiving more attention.Soil microbial activity and nitrogen(N)levels are important indicators of the effect of reclaimed water irrigation on environment.This study evaluated soil physicochemical properties and microbial community structure in soils irrigated with reclaimed water and receiving varied amounts of N fertilizer.The results indicated that the reclaimed water irrigation increased soil electrical conductivity(EC)and soil water content(SWC).The N treatment has highly significant effect on the ACE,Chao,Shannon(H)and Coverage indices.Based on a 16S ribosomal RNA(16S rRNA)sequence analysis,the Proteobacteria,Gemmatimonadetes and Bacteroidetes were more abundant in soil irrigated with reclaimed water than in soil irrigated with clean water.Stronger clustering of microbial communities using either clean or reclaimed water for irrigation indicated that the type of irrigation water may have a greater influence on the structure of soil microbial community than N fertilizer treatment.Based on a canonical correspondence analysis(CCA)between the species of soil microbes and the chemical properties of the soil,which indicated that nitrate N(NO3-–-N)and total phosphorus(TP)had significant impact on abundance of Verrucomicrobia and Gemmatimonadetes,meanwhile the p H and organic matter(OM)had impact on abundance of Firmicutes and Actinobacteria significantly.It was beneficial to the improvement of soil bacterial activity and fertility under 120 mg kg^-1 N with reclaimed water irrigation. 展开更多
关键词 reclaimed water NITROGEN soil chemical properties 16S rRNA sequence soil microbe community
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