A new algorithm of retrieving a petroleum substances absorption coefficient in sea water based on a remote sensing image

Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o（λ）], consists of the absorption coefficient of pure water [ACPW, a_w（λ）], plankton [ACP, a_（ph）（λ）], colored scraps [ACCS, a_（d,g）（λ）], and petroleum substance [ACPS, a_（oil）（λ）]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d（λ）] and colored dissolved organic matter [ACCDOM, a_g（λ）]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_（d,g,oil）（λ）]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm（QAA）, with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_（bp）（555）] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g（440）, the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.

Multi-wavelength measurements of aerosol optical absorption coefficients using a photoacoustic spectrometer

The atmospheric aerosol absorption capacity is a critical parameter determining its direct and indirect effects on cli- mate. Accurate measurement is highly desired for the study of the radiative budget of the Earth. A multi-wavelength （405 rim, 532 nm, 780 nm） aerosol absorption meter based on photoacoustic spectroscopy （PAS） invovling a single cylin- drical acoustic resonator is developed for measuring the aerosol optical absorption coefficients （OACs）. A sensitivity of 1.3 Mm-l （at 532 nm） is demonstrated. The aerosol absorption meter is successfully tested through measuring the OACs of atmospheric nigrosin and ambient aerosols in the suburbs of Hefei city. The absorption cross section and absorption Angstrom exponent （AAE） for ambient aerosol are determined for characterizing the component of the ambient aerosol.

The proportions and variations of the light absorption coefficients of major ocean color components in the East China Sea

The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented, showing these features in typical summer and winter seasons. The absorption coefficient aCDOM, aNAp and aphy of colored dissolved organic matter, non-algal particle, and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf. According to the aeDOM distribution at 440 nm, the Changjiang River plume shows an abnormal southeastward transport. An extremely high aNaP value patch at 440 nm is present in the middle coast. The chlorophyll-a-specific phytoplankton pigment absorption （a^hy） is much higher in winter than in summer, which may cause serious underestimated results when applying the averaged aphy into remote-sensing algorithms for chlorophyll concentration retrieval. The importance of phytoplankton size was evident in outer shelf waters. The absorption of aCDOM （440） is a dominant component accounting for over half of the total seawater absorption in summer. The aNAP（440） accounts for 64% of the absorption of the ECS coastal area in winter.

A preliminary study of the variation of phytoplankton absorption coefficients in the northern South China Sea

The temporal and spatial variabilities of phytoplankton absorption coefficients （a ph （λ）） and their relationships with physical processes in the northern South China Sea were examined, based on in situ data collected from two cruise surveys during May 14 to 25, 2001 and November 2 to 21, 2002. Significant changes in the surface water in a ph values and B/R ratios （a ph （440）/a ph （675）） were observed in May, which were caused by a phytoplankton bloom on the inner shelf stimulated by a large river plume due to heavy precipitation. This is consistent with the observed one order of magnitude elevation of chlorophyll a and a shift from a pico/nano dominated phytoplankton community to one dominated by micro-algae. Enhanced vertical mixing due to strengthened northeast monsoon in November has been observed to result in higher surface a ph （675） （0.002–0.006 m-1 higher） and less pronounced subsurface maximum on the outer shelf/slope in November as compared with that in May. Measurements of a ph and B/R ratios from three transects in November revealed a highest surface a ph （675） immediately outside the mouth of the Zhujiang （Pearl） River Estuary, whereas lower a ph （675） and higher B/R ratios were featured in the outer shelf/slope waters, demonstrating the respective influence of the Zhujiang River plume and the oligotrophic water of the South China Sea. The difference in spectral shapes of phytoplankton absorption （measured by B/R ratios and bathochromic shifts） on these three transects infers that picoprocaryotes are the major component of the phytoplankton community on the outer shelf/slope rather than on the inner shelf. A regional tuning of the phytoplankton absorption spectral model （Carder et al., 1999） was attempted, demonstrating a greater spatial variation than temporal variation in the lead parameter a 0 （λ）. It was thus implicated that region-based parameterization of ocean color remote sensing algorithms in the northern South China Sea was mandatory.

A research on statistical retrieval algorithms and spectral characteristics of the total absorption coefficients in the Yellow Sea and the East China Sea

This paper suggests a group of statistical algorithms for calculating the total absorption coefficients based on in situ data of apparent optical property and inherent optical property collected with strict quality assurance according to NASA ocean bio-optic protocols in the Yellow Sea and the East China Sea in spring 2003. The band-ratios ofRrs412/Rrs555, Rrs49o/Rrs555 are used in the algorithms to derive the total absorption coefficients （at） at 412, 440, 488, 510, 532 and 555nm bands, respectively. The average relative errors between inversed and measured values are less than 25.8%, with the correlative coefficients （R2） being 0.75-0.85. Error sensitivity analysis shows that the maximum retrieval error is less than 24.0% at ＋5% error in Rrs＇s. So the statistical algorithms of this paper are practicable. In this paper, the relations between the total absorption coefficients at 412, 488, 510, 532, 555 nm and that of 440nm are also studied. The results show that the relations between the total absorption coefficients of 400-600 nm and that of 440 nm are correlated well and all of their correlative coefficients R2 are greater than 0.99. Furthermore, a regression analysis is also done for the slope of the linear relations and wavelengths, and the R2 is also 0.99. Thus it is possible to retrieve other bands＇ total absorption coefficients with only one band absorption value, which significantly reduce the number of unknown parameters in studying other ocean color related problems.

Back Surface Recombination Velocity Dependent of Absorption Coefficient as Applied to Determine Base Optimum Thickness of an n+/p/p+ Silicon Solar Cell

The monochromatic absorption coefficient of silicon, inducing the light penetration depth into the base of the solar cell, is used to determine the optimum thickness necessary for the production of a large photocurrent. The absorption-generation-diffusion and recombination (bulk and surface) phenomena are taken into account in the excess minority carrier continuity equation. The solution of this equation gives the photocurrent according to absorption and electronic parameters. Then from the obtained short circuit photocurrent expression, excess minority carrier back surface recombination velocity is determined, function of the monochromatic absorption coefficient at a given wavelength. This latter plotted versus base thickness yields the optimum thickness of an n+-p-p+ solar cell, for each wavelength, which is in the range close to the energy band gap of the silicon material. This study provides a tool for improvement solar cell manufacture processes, through the mathematical relationship obtained from the thickness limit according to the absorption coefficient that allows base width optimization.

Influence of Density on Sound Absorption Coefficient of Fibre Board

For acoustic applications such as theaters, cinema halls, auditoriums the data on acoustic properties i.e. sound absorption coefficient and sound transmission loss are required to evaluate the acoustic behavior of panel products and to facilitate the necessary design computations. Fibre boards are widely used in private and commercial buildings, but not much data are available on acoustic efficiency of fibre boards. The study was carried using acoustic pulse tester based on standing wave method for evaluating sound absorption coefficient. Wood fibre boards of different densities ranging from 200 to 800 kg/m3 were taken and their sound absorption coefficients at frequencies ranging from 125 Hz to 4000 Hz were evaluated in third octave band. Noise reduction coefficient of the samples was also computed. From the study, it is observed that low density fibre board possess high sound absorption coefficient and noise reduction coefficient when compared with high density fibre boards. It was seen that sound absorption coefficient increases with decrease in density and vice versa.

Remote sensing retrieval of total absorption coefficient in the Bohai Sea

Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex. In this paper, we used 77 groups of field data of AOPs （apparent optical properties） and IOPs （inherent optical properties） collected in June, August, and September of 2005 in the Bohai Sea, to retrieve the spectral total absorption coefficient a（2） with the quasi-analytical algorithm （QAA）. For QAA implementation, different bands in the region 680-730 nm （in 5 nm intervals） were selected and compared, to determine the optimal band domain of the reference wavelength. On this basis, we proposed a new algorithm （QAA-Com）, a combination of QAA-685 and QAA-715, according to turbidity characterized by a（440）. The percentage difference of model retrievals in the visible domain was between 4.5%-45.1%, in average of 18.8% for a（2）. The QAA model was then applied to Medium Resolution Imaging Spectrometer （MERIS） radiometric products, which were temporally and spatially matched with in-situ optical measurements. Differences between MERIS retrievals and in-situ values were in the range 9.2%-27.8% for a（2） in the visible domain. Major errors in satellite retrieval are attributable to uncertainties of QAA model parameters and in-situ measurements, as well as imperfect atmospheric correction of MERIS data by the European Space Agency （ESA）. During a storm surge in April 2009, time series of MERIS images together with the QAA model were used to analyze spatial and temporal variability of the total absorption coefficient pattern in the Bohai Sea. It is necessary to collect more independent field data to improve this algorithm.

Estimation of mass transfer coefficient in ozone absorption by linear least square fitting and Simplex search methods

For physical ozone absorption without reaction,two parametric estimation methods,i.e.the common linear least square fitting and non-linear Simplex search methods,were applied,respectively,to determine the ozone mass transfer coefficient during absorption and both methods give almost the same mass transfer coefficient.While for chemical absorption with ozone decomposition reaction,the common linear least square fitting method is not applicable for the evaluation of ozone mass transfer coefficient due to the difficulty of model linearization for describing ozone concentration dissolved in water.The nonlinear Simplex method obtains the mass transfer coefficient by minimizing the sum of the differences between the simulated and experimental ozone concentration during the whole absorption process,without the limitation of linear relationship between the dissolved ozone concentration and absorption time during the initial stage of absorption.Comparison of the ozone concentration profiles between the simulation and experimental data demonstrates that Simplex method may determine ozone mass transfer coefficient during absorption in an accurate and high efficiency way with wide applicability.

Recovery of carbon monoxide from flue gases by reactive absorption in ionic liquid imidazolium chlorocuprate(I): Mass transfer coefficients

Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile solvents such as aromatic hydrocarbons. The present work evaluates the CO mass transfer rates from the gas phase to the ionic liquid solutions in the absence of chemical reaction. To that end, carbon dioxide was employed as an inert model gas and absorption experiments were performed to assess the influence of different process variables in a batch reactor with fiat gas-liquid interface. The experimental mass transfer coefficients showed significant var- iation with temperature, （3.4-10.9） × 10^-7 m·s^-1 between 293 and 313 K; stirring speed, （10.2- 33.1）× 10^-7 m.s 1 between 100 and 300 r·min^-1; and concentration of copper（1）, （6.6-10.2） × 10^-7 m·s^-1 between 0.25 and 2 mol· L^- 1. In addition, the mass transfer coefficients were eventually found to follow a poten- tial proportionality of the type kL ∝μ^-0.5 and the dimensionless correlation that makes the estimation of the mass transfer coefficients possible in the studied range of process variables was obtained： Sh=10^-2.64 Re^1.07 , Sc^0.75,These results constitute the first step in the kinetic analysis of the reaction between CO and imidazolium chlorocuprate（I） ionic liquid that determines the design of the separation units.

Light absorption coefficients of ionic liquids under electric field

Ionic liquids have attracted a lot of research attention for their applications in novel optoelectronic structures and devices as an optical means of regulating electricity. Although the electro-optic effect of ionic liquids is mentioned in some literature, quantitative testing and analysis are hardly found in light absorption coefficients of ionic liquids under an electric field. In the present study, an experimental apparatus is designed to measure the absorption coefficients of ionic liquids under different electric fields. Five groups of imidazole ionic liquids are experimentally investigated and an inversion is performed to determine the spectral absorption coefficients of the imidazole ionic liquids under the electric fields. Different intensities with multiple interface refractions and reflections are also considered, and the various measurement errors are analyzed through uncertainties propagation analysis. Spectral absorptions of ionic liquids from 300 nm to 2500 nm are obtained and the absorption coefficients are retrieved. It is found that the absorption behavior of ionic liquids changes in some frequency bands under an applied electric field. The experimental results show that the absorption coefficient of the ionic liquid increases with the voltage increasing at 1520 nm and 1920 nm. The change rate is affected by the types of anions and cations in the ionic liquid and the diffusion rate of the ions therein. This study provides illustrations for the ionic liquid-based electro-optical regulation in terms of physical property parameters and the testing technique.

Semi-empirical schemes for the x-ray mass absorption coefficients used in XRF analysis

X-ray mass absorption coefficients play an important role in the accu racy of any XRF intensity calculation. It is necessary to determine the proper schemes for providing satisfying values μ/ρ. In this work we examined and compared various schemes. A program based on the existing schemes to provide more accurate and convenient μ/ρ values was then introduced. The results from the program appears to be tolerable.

Band structure and absorption coefficient in GaN/AlGaN quantum wires

The band structures of rectangular GaN/AlGaN quantum wires are modeled by using a parabolic effective-mass theory. The absorption coefficients are calculated in a contact-density matrix approach based on the band structure. The results obtained indicate that the peak absorption coefficients augment with the increase of the injected carrier density, and the optical gain caused by interband transition is polarization anisotropic. For the photon energy near 1.55 eV, we can obtain relatively large peak gain. The calculations support the previous results published in the recent literature.

The effect of an optical pump on the absorption coefficient of magnesium-doped near-stoichiometric lithium niobate in terahertz range

The absorption coefficient of magnesium-doped near-stoichiometric lithium niobate crystal is measured by terahertz time-domain spectroscopy in a frequency range of 0.2 THz^0.9 THz at room temperature. The absorption coefficient is modulated by external optical pump fields. Experimental results show that the absorption coefficient of near-SLN：Mg crystal is approximately in a range of 22 cm- 1_35 cm- 1 in a frequency range of 0.2 THz-0.9 THz and tunable up to nearly 15%. Further theoretical analysis reveals that the variation of absorption coefficient is related to the number of light-induced carriers, domain reversal process, and OH- absorption in this crystal.

Nonlinear Refractive Index and Absorption Coefficient of Single-Shell Semiconductor Carbon Nanotube

The nonlinear refractive index and absorption coefficient of single\|shell semiconductor carbon nanotubes(CN s ) are calculated based on the two\|band approximation and Genkin\|Mednis approach. The results of nonlinear refractive index and absorption coefficient reach the order of 10 -8 and 10 -4 cm 2\5W -1 separately, which indicates that CN s have wonderful nonlinear optical properties. Taking into account the temperature effect and overlapping of σ and π orbits, the effect of relaxation term and chiral angle is discussed. The results show that the smaller the relaxation term, the larger the nonlinear absorption coefficient and refractive index. At the same time, CN s with different chiral angles have different results due to their different energy gap.

Studies on absorption coefficients of dual-energy γ-rays and measur-ing error correction for multiphase fraction determination

In this article, principle and mathematical method of determining the phase fractions of multiphase flows by using a dual-energy γ -ray system have been described. The dual-energy γ -ray device is composed of radioactive isotopes of 241Am and 137Cs with γ -ray energies of 59.5 and 662 keV, respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The modified arithmetic is beneficial to removing the extra Compton scattering from the measured value. The result shows that the dual-energy γ -ray technique can be used in three-phase flow with average accuracy greater than 95%, which enables us to determine phase fractions almost independent of the flow regime. Improvement has been achieved on measurement accuracy of phase fractions.

Study on absorption coefficients of dual-energy γ-rays in determining phase fractions of multiphase flows

This paper discusses the principle and mathematical method to measure the phase fractions of multiphase flows by using a dual-energy gamma-ray system. The dual-energy gamma-ray device is composed of radioactive isotopes of 241Am and 137Cs with emission energies of 59.5 keV and 662 keV respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The statistical error has been analyzed on the basis of the accurate absorption coefficient which enables determination phrase fractions almost independent of the flow regime. Improvement has been achieved on the measurement accuracy of phase fractions.

Origin of anomalous enhancement of the absorption coefficient in a PN junction

The absorption coefficient is usually considered as a constant for certain materials at the given wavelength.However,recent experiments demonstrated that the absorption coefficient could be enhanced a lot by the PN junction.The absorption coefficient varies with the thickness of the intrinsic layer in a PIN structure.Here,we interpret the anomalous absorption coefficient from the competition between recombination and drift for non-equilibrium carriers.Based on the Fokker-Planck theory,a non-equilibrium statistical model that describes the relationship between absorption coefficient and material thickness has been proposed.It could predict the experimental data well.Our results can give new ideas to design photoelectric devices.

Determination of Integrated Molar Absorption Coefficients for Gaseous Phenol Infrared Bands and Influence of Water Vapor on Their Values

The integrated molar absorption coefficients for ν(OH) (3655 cm-1), δ(OH) (Q branch at 1176 cm-1 or whole bands), [ν(CCring) + δ(OH)] (Q branch at 1344 cm-1 or whole bands) and γ(CH) (752 cm-1) were determined at 342 K, by recording infrared spectra of pure gaseous phenol at different partial pressure (from 0 to 33 Pa). The integrated molar absorption coefficients (ε) values were obtained with a good reproducibility and the relative uncertainty on the given values is below 2%. The influence of water on the integrated molar absorption coefficients of phenol has been investigated in a large range of nwater/nphenol values (from 0.5 to 6.1 and from 44 to 94) using distinct setups. The infrared spectra of a gas mixture containing a constant amount of phenol and different amount of water were recorded (closed cell) whereas in dynamic condition (under flow) the water partial pressure was kept constant at 1.3 kPa and the phenol partial pressure was increased from 0 to 30 Pa. It is here demonstrated that, at 342 or 355 K, the presence of water does not affect the epsilon values of δ(OH) and [ν(CCring) + δ(OH)] bands.

High Temperature Effect on Absorption Coefficient of M-MPPs and Sandwich Structures Coupled with MPPs

This paper addresses the effect of high temperature on absorption performance of sandwich material coupled with microperforated panels (MPPs) in multiple configurations using a finite element model (FEM) over a frequency range from 10 to 3000 Hz. The structure is backed with a rigid wall which can either be Aluminium or Al-Alloy used in aeronautic or automobile. The wave propagation in porous media is addressed using Johnson Champoux Allard model (JCA). The FEM model developed using COMSOL Multiphysics software makes it possible to predict the acoustic absorption coefficient in multilayer microperforated panels (M-MPPs) and sandwich structure. It is shown that, when structures made by MPPs or sandwich materials are submitted to high temperature, the absorption performance of the structure is strongly modified in terms of amplitude and width of the bandgap. For application in sever environment (noise reduction in engines aircrafts), Temperature is one of the parameters that will most influence the absorption performance of the structure. However, for application in the temperature domain smaller than 50?C (automotive applications for example), the effect of temperature is not significant on absorption performance of the structure.