Vibration analysis of a new polymer quartz piezoelectric crystal sensor for detecting characteristic materials of volatility liquid

We present a new polymer quartz piezoelectric crystal sensor that takes a quartz piezoelectric crystal as the basal material and a nanometer nonmetallic polymer thin film as the surface coating based on the principle of quartz crystal microbalance(QCM). The new sensor can be used to detect the characteristic materials of a volatile liquid. A mechanical model of the new sensor was built, whose structure was a thin circle plate composing of polytef/quartz piezoelectric/polytef. The mechanical model had a diameter of 8 mm and a thickness of 170 μm. The vibration state of the model was simulated by software ANSYS after the physical parameters and the boundary condition of the new sensor were set. According to the results of experiments, we set up a frequency range from 9.995850 MHz to 9.997225 MHz, 17 kinds of frequencies and modes of vibration were obtained within this range. We found a special frequency fspof 9.996358 MHz. When the resonant frequency of the new sensor's mechanical model reached the special frequency, a special phenomenon occurred. In this case, the amplitude of the center point O on the mechanical model reached the maximum value. At the same time, the minimum absolute difference between the simulated frequency based on the ANSYS software and the experimental measured stable frequency was reached. The research showed that the design of the new polymer quartz piezoelectric crystal sensor perfectly conforms to the principle of QCM. A special frequency value fspwas found and subsequently became one of the most important parameters in the new sensor design.

Rayleigh-Type Wave in A Rotated Piezoelectric Crystal Imperfectly Bonded on a Dielectric Substrate

Propagation characteristics of Rayleigh-type wave in a piezoelectric layered system are theoretically investigated.The piezoelectric layer is considered as a cubic crystal with finite thickness rotated about Y-axis and is imperfectly bonded onto a semi-infinite dielectric substrate.The imperfect interface between the two constituents is assumed to be mechanically compliant and dielectrically weakly conducting.The exact dispersion relations for electrically open or shorted boundary conditions are obtained.The numerical results show that the phase velocity of Rayleigh-type wave is symmetric with respect to the cut orientation of 45°and can achieve the maximum propagation speed in this orientation.The mechanical imperfection plays an important role in the dispersion relations,further the normal imperfection can produce a significant reduction of phase velocity comparing with the tangential imperfection.Comparing with the mechanical imperfection the electrical imperfection makes a relatively small reduction of phase velocity of Rayleigh-type wave.The obtained results can provide some fundamentals for understanding of piezoelectric semiconductor and for design and application of piezoelectric surface acoustic wave devices.

Beam-focused SH wave transducer based on YSr_(3)(PO_(4))_(3)piezoelectric crystal for high temperature structural health monitoring

Guided-wave-based structural health monitoring(SHM)technology is of great importance for real-time inspection of high-temperature structures.The fundamental shear horizontal(SH_(0))wave is believed to be an ideal wave mode for developing SHM systems due to its nondispersive characteristics.However,currently very limited SH_(0)wave transducers can be used for SHM of high-temperature structures due to the limitation of materials.Herein,a novel YSr_(3)(PO_(4))_(3)(YSP)piezoelectric crystal in the space group I43d was grown.Experiments show that the face-shear piezoelectric coefficient d_(14)(d_(14)=d_(25)=d_(36))is 9.7 pC/N and varies little from 25 to 800℃.Then a beam-focused SH_(0)wave piezoelectric transducer is developed based on face-shear-mode YSP wafers.Both finite element simulations and experimental results indicate that the YSP-based transducer can excite pure SH_(0)wave and focus the wave energy along two opposite main directions.Especially,the obtained SH_(0)wave beam is highly concentrated with a small divergence angle of less than 30°,originating from the high working frequency range from 300 to 400 kHz.The excellent temperature stability of the as-grown YSP crystal makes the proposed SH_(0)wave piezoelectric transducer very suitable for SHM of high-temperature structures.

SAW diffraction field generated by source with finite aperture piezoelectric crystal surfaces

So far, the diffracted SAW field generated by an IDT with finite aperture on piezoelectric crystal surfaces is usually analyzed phenomenologically with the angular spectrum theory. A major approximation of this theory is to ignore the vector nature of the field by assuming that the wave field can be represented by a scalar as in optics. In this paper, a rigorous vector field theory of the surface excitation of elastic wave field in piezoelectric crystal developed by the authors is used to evaluate the SAW diffraction field adepately and precisely. As an example, numerical results for YZ-LiNbO3 are presented and compared with those obtained form the angular spectrum theory.

High sensitive piezoelectric quartz crystal liquid density sensor

We report for the first time a cleavage phenomenon in the resonant peak of a piezoelectric quartz crystal(PQC) in liquid phase.In the presence of a strong longitudinal wave effect,an additional resonant peak appears in the conductance-frequency curve.With gradually increasing liquid density,the additional peak moves from low to high frequency region then disappears.The frequency of the additional resonant peak is sensitive to the change in liquid density.The frequency shift of the additional peak is linear with the liquid density in a given range.For a 5 MHz PQC with a reflection distance of 16 mm for longitudinal wave,the sensitivity to liquid density is 2.61×10^6 Hz g^-1 cm^3.The overlap between the primary resonant peak and the additional resonant peak causes a decrease in the intensity of the former and an increase in the intensity of the latter.In a combined impedance analysis method,the changes in surface mass loading,density and viscosity of the liquid were monitored simultaneously by a PQC sensor.

Electro-mechanical coupling wave propagating in a locally resonant piezoelectric/elastic phononic crystal nanobeam with surface effects

The model of a "spring-mass" resonator periodically attached to a piezoelectric/elastic phononic crystal(PC) nanobeam with surface effects is proposed, and the corresponding calculation method of the band structures is formulized and displayed by introducing the Euler beam theory and the surface piezoelectricity theory to the plane wave expansion(PWE) method. In order to reveal the unique wave propagation characteristics of such a model, the band structures of locally resonant(LR) elastic PC Euler nanobeams with and without resonators, the band structures of LR piezoelectric PC Euler nanobeams with and without resonators, as well as the band structures of LR elastic/piezoelectric PC Euler nanobeams with resonators attached on PZT-4, with resonators attached on epoxy, and without resonators are compared. The results demonstrate that adding resonators indeed plays an active role in opening and widening band gaps. Moreover, the influence rules of different parameters on the band gaps of LR elastic/piezoelectric PC Euler nanobeams with resonators attached on epoxy are discussed, which will play an active role in the further realization of active control of wave propagations.

Temperature dependence of mode coupling effect in piezoelectric vibrator made of[001]c-poled Mn-doped 0.24PIN-0.46PMN-0.30PT ternary single crystals with high electromechanical coupling factor

The influence of temperature on mode coupling effect in piezoelectric vibrators remains unclear.In this work,we discuss the influence of temperature on two-dimensional(2D)mode coupling effect and electromechanical coupling coefficient of cylindrical[001]c-poled Mn-doped 0.24PIN-0.46PMN-0.30PT piezoelectric single-crystal vibrator with an arbitrary configuration ratio.The electromechanical coupling coefficient kt decreases with temperature increasing,whereas k33 is largely invariant in a temperature range of 25℃-55℃.With the increase of temperature,the shift in the‘mode dividing point’increases the scale of the poling direction of the piezoelectric vibrator.The temperature has little effect on coupling constantΓ.At a given temperature,the coupling constantΓof the cylindrical vibrator is slightly greater than that of the rectangular vibrator.When the temperature changes,the applicability index(M)values of the two piezoelectric vibrators are close to 1,indicating that the coupling theory can be applied to piezoelectric vibrators made of late-model piezoelectric single crystals.

Depolarization field in relaxor-based ferroelectric single crystals under one-cycle bipolar pulse drive

The [001]c-polarized(1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3(PMN-PT) single crystals are widely used in ultrasonic detection transducers and underwater acoustic sensors. However, the relatively small coercive field( 2 kV/cm) of such crystals restricts their application at high frequencies because the driving field will exceed the coercive field. The depolarization field can be considerably larger in an antiparallel direction than in a parallel direction with respect to polarization when the bipolar driving cycle starts. Thus, if the direction of the sine wave signal in the first half cycle is opposite to the polarization direction, then the depolarized domains can be repolarized in the second half of the sine cycle. However, if the direction of the sine wave signal in the first half of the cycle is along the polarization direction, then the change is negligible,and the domains switched in the second half of the sine cycle cannot be recovered. The design of electric driving method needs to allow the use of a large applied field to emit strong enough signals and produce good images. This phenomenon combined with the coercive field increases with the driving frequency, thereby making the PMN-PT single crystals usable for high-frequency applications. As such, the applied field can be considerably larger than the conventionally defined coercive field.

WAVE LOCALIZATION IN RANDOMLY DISORDERED PERIODIC PIEZOELECTRIC RODS WITH INITIAL STRESS

The elastic wave localization in disordered periodic piezoelectric rods with initial stress is studied using the transfer matrix and Lyapunov exponent method. The electric field is approximated as quasi-static. The effects of the initial stress on the band gap characteristics are investigated. The numerical calculations of localization factors and localization lengths are performed. It can be observed from the results that the band structures can be tuned by exerting the suitable initial stress. For different values of the piezoelectric rod length and the elastic constant, the band structures and the localization phenomena are very different. Larger disorder degree can lead to more obvious localization phenomenon.

New pattern recognition system in the e-nose for Chinese spirit identification

This paper presents a new pattern recognition system for Chinese spirit identification by using the polymer quartz piezoelectric crystal sensor based e-nose. The sensors are designed based on quartz crystal microbalance（QCM） principle,and they could capture different vibration frequency signal values for Chinese spirit identification. For each sensor in an8-channel sensor array, seven characteristic values of the original vibration frequency signal values, i.e., average value（A）,root-mean-square value（RMS）, shape factor value（S_f）, crest factor value（C_f）, impulse factor value（I_f）, clearance factor value（CL_f）, kurtosis factor value（K_v） are first extracted. Then the dimension of the characteristic values is reduced by the principle components analysis（PCA） method. Finally the back propagation（BP） neutral network algorithm is used to recognize Chinese spirits. The experimental results show that the recognition rate of six kinds of Chinese spirits is 93.33% and our proposed new pattern recognition system can identify Chinese spirits effectively.

Strain tunable quantum dot based non-classical photon sources

Semiconductor quantum dots are leading candidates for the on-demand generation of single photons and entangled photon pairs.High photon quality and indistinguishability of photons from different sources are critical for quantum information applications.The inability to grow perfectly identical quantum dots with ideal optical properties necessitates the application of post-growth tuning techniques via e.g.temperature,electric,magnetic or strain fields.In this review,we summarize the state-of-the-art and highlight the advantages of strain tunable non-classical photon sources based on epitaxial quantum dots.Using piezoelectric crystals like PMN-PT,the wavelength of single photons and entangled photon pairs emitted by InGaAs/GaAs quantum dots can be tuned reversibly.Combining with quantum light-emitting diodes simultaneously allows for electrical triggering and the tuning of wavelength or exciton fine structure.Emission from light hole exciton can be tuned,and quantum dot containing nanostructure such as nanowires have been piezo-integrated.To ensure the indistinguishability of photons from distant emitters,the wavelength drift caused by piezo creep can be compensated by frequency feedback,which is verified by two-photon interference with photons from two stabilized sources.Therefore,strain tuning proves to be a flexible and reliable tool for the development of scalable quantum dots-based non-classical photon sources.

Spectroscopic Characterization and Stereodynamics of Ferrocenylselenoethers Pt(Ⅱ),Pd(Ⅱ),Rh(Ⅲ)Complexes

A new method of determination of trace CN - in water was proposed. A thin film of Ag 2S was electrochemically deposited on both sides of a silver coated piezoelectric crystal. The Ag 2S Ag films can react with CN - selectively, which causes the frequency shifts of the piezoelectric crystal. The frequency shifts are proportional to the concentration of CN - in the range of 10 -6 ～10 -3 g/L. XPS experiments indicated the sensing film was Ag 2S Ag. A coordination complex Ag CN - was formed when Ag 2S Ag film contacted with solution containing CN - ion. A response mechanism was proposed based on the XPS data. Key wards piezoelectric crystal, microbalance, XPS, cyanide ion.

Finite difference time domain analysis of two-dimensional surface acoustic wave piezoelectric phononic crystals at radio frequency

The finite-difference time-domain （FDTD） method is proposed for analyzing the surface acoustic wave （SAW） propagation in two-dimensional （2D） piezoelectric phononic crystals （PCs） at radio frequency （RF）, and also experiments are established to demonstrate its analysis result of the PCs＇ band gaps. The FDTD method takes the piezoelectric effect of PCs into account, in which periodic boundary conditions are used to decrease memory/time consumption and the perfectly matched layer boundary conditions are adopted as the SAW absorbers to attenuate artificial reflections. Two SAW delay lines are established with/without piezoelectric PCs located between interdigital transducers. By removing several echoes with window gating function in time domain, delay lines transmission function is achieved. The PCs＇ transmission functions and band gaps are obtained by comparing them in these two delay lines. When Aluminum/128°YX-LiNbO3 is adopted as scatter and substrate material, the PCs＇ band gap is calculated by this FDTD method and COMSOL respectively. Results show that computational results of FDTD agree well with experimental results and are better than that of COMSOL.

In Situ Monitoring of the Generation of Monodisperse Silica Particles during the Hydrolysis of Tetraethyl Orthosilicate with Piezoelectric Quartz Crystal Impedance Analyzer

The piezoelectric quartz crystal (PQC) impedance analyzer was used to monitor in situ the generation of monodisperse silica particles during the hydrolysis of tetraethyl orthosilicate (TEOS) and their adsorption onto an Au electrode in alcohol solutions containing water (6-15 mol/L) and ammonia (0 2-2 0 mol/L). The equivalent circuit parameters, the resonance frequencies and the half peak width values of the conductance spectra of the PQC resonance were obtained. The resonant frequency decreased notably while the motional resistance changed very slightly (within 1 Ω) during the hydrolysis reaction, suggesting that the mass effect do^minated the adsorption of generated monodisperse silica particles on the gold electrode in this system. Changes in f 0 indicated that the ammonia concentration affected the hydrolytic reaction obviously, and the influence of water concentration on the reaction was small while the water was significantly excessive. Kinetics of monodisperse silica particle adsorption occurring at the electrode|solution interface was analyzed using a first order reaction scheme. In addition, the electrolyte induced precipitation of the monodisperse silica particles was monitored and discussed. The mean size, the number of adsorbed particles per area and the converge of monodisperse silica particles were obtained from scanning electron microscope (SEM) observations.

Creep rate sensitivities of materials by a depth-sensing indentation technique

The strain rate sensitivity to creep of single crystal Cu（110）, metal tantalum, and 128°Y-X LiNbO3 piezoelectric single crystal were measured at room temperature by MTS Nanoindenter XP. Among the three kinds of materials studied, Cu showed the highest degree of resistance to creep-induced deformation, which is followed by Ta, while the LiNbO3 single crystal deformed more readily than the others. The values of the steady-state strain rate sensitivities determined by the indentation methods are in the range of 0.002-0.006, 0.02-0.06 and 0.02-0.03 for Cu, Ta, and LiNbO3, respectively. The mechanisms for the indentation-induced creeping behavior and the factors that influenced the creeping are discussed.

Band gap structure analysis of phononic crystal rods with hybrid shunted piezoelectric patches

The band gap structures by arranging hybrid shunted piezoelectric materialswith resistance inductive （RL） circuit and negative impedance converter （NIC） closely and at in- tervals are presented. The theoretical model is built using transfer matrix method. Then the MATLAB computing language is utilized to simulate the band gap structures. Meanwhile, the effects of the resistance, inductance and capacitance on the local resonant gap are studied. By comparing different combinations of resistance, inductance and capacitance as well as different arrangement of circuits, a 13 kHz band gap is reached under the effect of arranging hybrid pe- riodic shunted piezoelectric patches at intervals and the stability of the system is also analyzed. It is proved that utilizing hybrid shunted piezoelectric patches would have a clear impact on the band gap structure of phononic crystal rods. Moreover, the band gap would be clearly enlarged by arranging hybrid piezoelectric patches at intervals.

Frequency characteristic of series piezoelectric sensor and application to the determination of water in organic solvents

Theoretical consideration was proposed for the frequency response of a series piezoelectric sensor to the properties of liquid and verified experimentally. This kind of sensor has sensitive and selective frequency response to the permittivity and specific conductivity of solution with excellent stability, and was applied to the determination of micro-content of water in organic solvents. The detection limit is 0.01 g/L in dioxane.