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Uniform deposition of ultra-thin TiO_(2) film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration 被引量:2
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作者 Ming Liu Ying Li +4 位作者 Rui Wang Guoqiang Shao Pengpeng Lv Jun Li Qingshan Zhu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期99-107,共9页
The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl_(4) concentration on the initial deposition of TiO_(2) on mica by atmospheric pre... The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl_(4) concentration on the initial deposition of TiO_(2) on mica by atmospheric pressure chemical vapor deposition(APCVD) was investigated. The precursor concentration significantly affected the deposition and morphology of TiO_(2) grains assembling the film. The deposition time for fully covering the surface of mica decreased from 120 to 10 s as the TiCl_(4) concentration increased from 0.38%to 2.44%. The grain size increased with the TiCl_(4) concentration. The AFM and TEM analysis demonstrated that the aggregation of TiO_(2) clusters at the initial stage finally result to the agglomeration of fine TiO_(2) grains at high TiCl_(4) concentrations. Following the results, it was suggested that the nucleation density and size was easy to be adjusted when the TiCl_(4) concentration is below 0.90%. 展开更多
关键词 Chemical vapor deposition TiO_(2)thin film Nucleation reaction Precursor concentration Pearlescent pigment
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彩色PVC管材的生产
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作者 刘孔文 骆健宁 +2 位作者 周俊豫 冯茹虹 扈廷勇 《聚氯乙烯》 CAS 2023年第7期14-19,共6页
介绍了彩色PVC管材的生产现状。从原材料质量检测与控制、生产管理控制、储存管理等方面分析了彩色管材生产的影响因素,并提出了相应的生产控制建议。
关键词 pvc管材 彩色 颜料 色泽
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PVC-双硫腙复膜树脂分离富集——火焰原子吸收法测定痕量金 被引量:3
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作者 白祖海 周方钦 +1 位作者 周含英 江放明 《湘潭大学自然科学学报》 CAS CSCD 2004年第4期71-73,共3页
研究了PVC -双硫腙复膜树脂的合成及其分离富集金的最隹条件 .在pH为 1 .5的盐酸介质中 ,金能定量吸附在PVC -双硫腙复膜树脂上 ,采用 0 .5mol/L硫脲 -0 .1mol/LHCl溶液洗脱 ,火焰原子吸收光谱测定 ,回收率均在 95 .4%~1 0 6 .7% ,RSD ... 研究了PVC -双硫腙复膜树脂的合成及其分离富集金的最隹条件 .在pH为 1 .5的盐酸介质中 ,金能定量吸附在PVC -双硫腙复膜树脂上 ,采用 0 .5mol/L硫脲 -0 .1mol/LHCl溶液洗脱 ,火焰原子吸收光谱测定 ,回收率均在 95 .4%~1 0 6 .7% ,RSD <4.5 % . 展开更多
关键词 pvc双硫腙 分离富集 原子吸收
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白色硬质PVC制品的增白技术 被引量:2
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作者 严海标 王茂坤 《现代塑料加工应用》 CAS 1998年第3期37-39,共3页
采用电脑测色仪研究了金红石钛白粉着色硬质PVC制品的特性和增白技术。
关键词 聚氯乙烯 着色 增白 金红石 钛白粉 颜料
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浓硫酸清净技术在PVC生产中的应用 被引量:5
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作者 李晋文 张丽俊 徐瑞芳 《中国氯碱》 CAS 2011年第4期12-13,共2页
介绍了浓硫酸清净新技术在电石法PVC生产中的运行情况,并和次氯酸钠清净技术作了比较,指出该技术更加符合节能减排发展思路。
关键词 浓硫酸清净 次氯酸钠清净 pvc 应用
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亚光铁红环氧酯防锈底漆的制备及其PVC与光泽的探讨
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作者 付岩 杨国生 赵春英 《表面技术》 EI CAS CSCD 2007年第2期68-69,77,共3页
介绍了亚光铁红环氧酯防锈底漆的制备过程,探讨了亚光铁红环氧酯防锈漆PVC与光泽的关系,在不改变底漆其它性能的条件下,通过改变配方中原材料的用量,来调整颜料体积浓度(PVC)值,试验得到底漆的PVC值在42%左右,符合亚光铁红环氧酯防锈... 介绍了亚光铁红环氧酯防锈底漆的制备过程,探讨了亚光铁红环氧酯防锈漆PVC与光泽的关系,在不改变底漆其它性能的条件下,通过改变配方中原材料的用量,来调整颜料体积浓度(PVC)值,试验得到底漆的PVC值在42%左右,符合亚光铁红环氧酯防锈底漆行业标准40%-55%的范围,能达到理想的亚光效果。 展开更多
关键词 pvc 亚光 铁红环氧酯防锈底漆
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水性建筑涂料耐洗刷性能影响因素探讨
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作者 隋延秋 杨文颐 +4 位作者 张丹武 耿薇薇 刘璐 贾艳征 冯春研 《中国建材科技》 CAS 2024年第1期1-4,共4页
水性建筑涂料是建材领域的重要产品,耐洗刷性能是影响其功能性使用的关键技术指标。本文从内因和外因两方面介绍影响水性建筑涂料耐洗刷性能的主要因素,包括乳液聚合物结构、颜填料含量、成膜条件、制膜方式、基材表面、毛刷硬度等,并... 水性建筑涂料是建材领域的重要产品,耐洗刷性能是影响其功能性使用的关键技术指标。本文从内因和外因两方面介绍影响水性建筑涂料耐洗刷性能的主要因素,包括乳液聚合物结构、颜填料含量、成膜条件、制膜方式、基材表面、毛刷硬度等,并对比分析国内外主要的建筑涂料耐洗刷性能检测标准。 展开更多
关键词 耐洗刷性能 建筑涂料 乳液聚合物 颜填料体积浓度
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探讨让PVC中小树脂厂走出困境的途径
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作者 赵劲松 《聚氯乙烯》 CAS 2011年第9期9-12,共4页
介绍了笔者研制出的性价比较高的神奇纳米碳酸钙、低铅稳定剂和改性钛白粉,以这3种加工助剂为基础投建加工助剂厂,并与树脂厂、加工厂合办,其PVC-U制品的原料成本比单办加工厂的原料成本降低800~850元/t。
关键词 聚氯乙烯 加工 碳酸钙 稳定剂 钛白粉
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Effects of irradiance on pigment signatures of harmful algae during growth process 被引量:3
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作者 LIU Shuxia YU Zhigang YAO Peng ZHENG Yan LI Dong 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2011年第6期46-57,共12页
Three harmful algal bloom (HAB) species, Phaeocystis globosa, Thalassiosira rotula, and Prorocentrum donghaiense were isolated from the coast of China and cultured in batches at three light intensities (40, 70 and ... Three harmful algal bloom (HAB) species, Phaeocystis globosa, Thalassiosira rotula, and Prorocentrum donghaiense were isolated from the coast of China and cultured in batches at three light intensities (40, 70 and 150 μmol photons · m -2 · s -1 ). The variation patterns of cell numbers and growth rates with light intensity during growth process were different among species. In P. globosa and T. rotula, maximum growth rates were found at 150 μmol photons · m -2 · s -1 and ranged from 0.60 divisions per day in T. rotula, to 1.17 divisions per day in P. globosa. The highest growth rate of P. donghaiense, however, was found at 70 μmol photons · m -2 · s -1 (0.36 divisions per day). In general, all the three HAB species showed adaptation to increasing light intensity by decreasing cellular concentrations of chlorophyll a (Chl a), but the variation patterns during the growth process were species-specific. The cellular concentrations of Chl a in P. donghaiense and T. rotula increased gradually with incubation time, but the opposite trend was found in P. globosa. Most of the pigment ratios and pigment indices of these three species were nearly constant during the growth process and showed small changes at different light intensities illustrating the applicability of chemotaxonomy during the initial and developing stages of HAB events, which is very important to study the ecological issues related to HAB species. Ratios of photoprotective carotenoids, such as diadinoxanthin, diatoxanthin and β, β-carotene to total chlorophylls a (Tchl a) showed the trend of increasing with the increase of light intensity during growth process. The species-specific and pigment-specific variations in pigment ratios/indices at different light intensities during growth process probably reflected the differences in the pigment composition as well as the adaption capabilities of different species to the changes of physical conditions. 展开更多
关键词 harmful algal bloom light intensity growth rate pigment ratio pigment index cellular concentration
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高强度PVC纤维湿法纺丝工艺及其性能研究 被引量:1
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作者 冯凯 刘蓉 +3 位作者 王颖杰 魏发云 胡佳丽 张伟 《纺织科学与工程学报》 CAS 2022年第4期82-85,共4页
将聚氯乙烯(PVC)树脂溶解于四氢呋喃(THF)与二甲基甲酰胺(DMF)的混合溶剂中得到纺丝原液,通过湿法纺丝技术成功制备了PVC纤维。通过流变研究了纺丝温度对纤维可纺性的影响,并研究了凝固浴浓度和牵伸倍率对纤维结构与性能的影响。结果表... 将聚氯乙烯(PVC)树脂溶解于四氢呋喃(THF)与二甲基甲酰胺(DMF)的混合溶剂中得到纺丝原液,通过湿法纺丝技术成功制备了PVC纤维。通过流变研究了纺丝温度对纤维可纺性的影响,并研究了凝固浴浓度和牵伸倍率对纤维结构与性能的影响。结果表明,当纺丝温度为60℃,凝固浴为50%二甲基亚砜(DMSO)的水溶液,通过湿法纺丝牵伸4倍得到的PVC纤维力学性能最好。 展开更多
关键词 湿法纺丝 聚氯乙烯纤维 纺丝液温度 凝固浴浓度 牵伸倍率
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Different modes of foveal regeneration after closure of full-thickness macular holes by(re)vitrectomy and autologous platelet concentrate 被引量:3
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作者 Andreas Bringmann Claudia Jochmann +3 位作者 Jan Darius Unterlauft Renate Wiedemann Matus Rehak Peter Wiedemann 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2020年第1期36-48,共13页
AIM: To describe using spectral-domain optical coherence tomography the regeneration of the foveal morphology after pars plana(re)vitrectomy surgery and gas tamponade combined with injection of autologous platelet con... AIM: To describe using spectral-domain optical coherence tomography the regeneration of the foveal morphology after pars plana(re)vitrectomy surgery and gas tamponade combined with injection of autologous platelet concentrate to treat full-thickness macular holes, and to describe different anatomical outcome. METHODS: A retrospective case series of 8 eyes of 8 patients was described. RESULTS: In all cases investigated, the plateletassisted closure of macular holes was associated with a rapid resolution of cystic cavities in the foveal walls. In two patients, there was a regular regeneration of the foveal morphology after hole closure;the regenerated central fovea had a regular structure with a foveola and photoreceptors. In three other patients, there was an irregular regeneration of the fovea;a foveola was not formed, photoreceptor cells were absent from the foveal center, and the center was composed of Müller and retinal pigment epithelial(RPE) cells. The foveal regeneration after hole closure may proceed with or without a temporary detachment of the foveal center from the RPE, and with or without a direct contact between the central outer nuclear layer(ONL) and the RPE. Contacts between the ONL and RPE were observed only in patients with an irregular foveal regeneration after hole closure.CONCLUSION: The data show that there are different modes of foveal regeneration after closure of macular holes with(re)vitrectomy and platelet concentrate. It is suggested that the regular regeneration of the foveal morphology proceeds by Müller cell-mediated tissue movements without cell proliferation, whereas the irregular foveal regeneration proceeds in part by proliferation of Müller and RPE cells. 展开更多
关键词 macular hole platelet concentrate FOVEA Müller glia retinal pigment epithelium
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Gaussian decomposition and component pigment spectral analysis of phytoplankton absorption spectra 被引量:1
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作者 YE Huping ZHANG Bing +5 位作者 LIAO Xiaohan LI Tongji SHEN Qian ZHANG Fangfang ZHU Jianhua LI Junsheng 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2019年第5期1542-1554,共13页
The absorption spectrum of phytoplankton is an important bio-optical parameter for ocean color hyperspectral remote sensing;its magnitude and shape can be aff ected considerably by pigment composition and concentratio... The absorption spectrum of phytoplankton is an important bio-optical parameter for ocean color hyperspectral remote sensing;its magnitude and shape can be aff ected considerably by pigment composition and concentration. We conducted Gaussian decomposition to the absorption spectra of phytoplankton pigment and studied the spectral components of the phytoplankton, in which the package effect was investigated using pigment concentration data and phytoplankton absorption spectra. The decomposition results were compared with the corresponding concentrations of the five main pigment groups (chlorophylls a , b , and c , photo-synthetic carotenoids (PSC), and photo-protective carotenoids (PPC)). The results indicate that the majority of residual errors in the Gaussian decomposition are <0.001 m^-1 , and R 2 of the power regression between characteristic bands and HPLC pigment concentrations (except for chlorophyll b) was 0.65 or greater for surface water samples at autumn cruise. In addition, we determined a strong predictive capability for chlorophylls a , c , PPC, and PSC. We also tested the estimation of pigment concentrations from the empirical specific absorption coeffi cient of pigment composition. The empirical decomposition showed that the Ficek model was the closest to the original spectra with the smallest residual errors.The pigment decomposition results and HPLC measurements of pigment concentration are in a high consistency as the scatter plots are distributed largely near the 1:1 line in spite of prominent seasonal variations. The Wozniak model showed a better fit than the Ficek model for Ch1 a , and the median relative error was small. The pigment component information estimated from the phytoplankton absorption spectra can help better remote sensing of hyperspectral ocean color that related to the changes in phytoplankton communities and varieties. 展开更多
关键词 PHYTOPLANKTON ABSORPTION spectrum pigment concentration GAUSSIAN DECOMPOSITION
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我国电石法PVC行业面对《关于汞的水俣公约》时限挑战须采取的积极措施及建议 被引量:9
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作者 曹战国 肖国营 曹贺鸣 《聚氯乙烯》 CAS 2018年第10期1-11,共11页
介绍了《关于汞的水俣公约》的相关要求及我国的具体实施计划,调查了我国电石法PVC行业汞触媒的单耗及履约情况,分析了我国电石法PVC低汞触媒单耗高的原因及解决措施,指出了我国电石法PVC企业控制汞消耗及汞污染需要进一步解决的问题。
关键词 《关于汞的水俣公约》 pvc 低汞触媒 乙炔脱水 氯化氢脱水 次氯酸钠清净 浓硫酸清净
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Purification of specularite by centrifugation instead of flotation to produce iron oxide red pigment 被引量:1
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作者 Xi Zhang Shun-wei Zhu +3 位作者 Yu-jiang Li Yong-li Li Qiang Guo Tao Qi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2021年第1期56-65,共10页
This study used specularite, a high-gradient magnetic separation concentrate, as a raw material in reverse flotation.An iron concentrate with a grade of 65.1 wt% and a recovery rate of 75.31% were obtained.A centrifug... This study used specularite, a high-gradient magnetic separation concentrate, as a raw material in reverse flotation.An iron concentrate with a grade of 65.1 wt% and a recovery rate of 75.31% were obtained.A centrifugal concentrator served as the deep purification equipment for the preparation of iron oxide red pigments, and its optimal rotating drum speed, feed concentration, and other conditions were determined.Under optimal conditions, a high-purity iron oxide concentrate with a grade of 69.38 wt% and a recovery rate of 80.89% were obtained and used as a raw material for preparing iron oxide red pigment.Calcining with sulfuric acid produced iron red pigments with different hues.Simultaneously, middlings with a grade of 60.20 wt% and a recovery rate of 17.51% were obtained and could be used in blast furnace ironmaking.High-value utilization of specularite beneficiation products was thus achieved. 展开更多
关键词 SPECULARITE REconcentration centrifugal concentrator iron oxide red pigment
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等离子体处理对PVC封边条性能影响 被引量:5
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作者 谢志昆 《广东化工》 CAS 2017年第11期80-81,共2页
PVC封边条的表面性质直接影响PVC与板材的剥离强度、与水性油墨的附着力等性能,进而影响产品的质量稳定性。本文研究了利用等离子体处理PVC表面,提高其表面的亲水性能,从而提高PVC封边条的表面张力、与板材剥离强度、与水性油墨的附着力... PVC封边条的表面性质直接影响PVC与板材的剥离强度、与水性油墨的附着力等性能,进而影响产品的质量稳定性。本文研究了利用等离子体处理PVC表面,提高其表面的亲水性能,从而提高PVC封边条的表面张力、与板材剥离强度、与水性油墨的附着力等,处理后的PVC封边条明显优于未处理的结果,能够满足实际的使用要求。 展开更多
关键词 等离子体 pvc 剥离强度 封边条 颜料
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水性油墨在PVC封边条印刷中耐光色牢度研究 被引量:4
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作者 谢志昆 《广东化工》 CAS 2016年第24期64-65,共2页
文章研究了水性油墨在PVC封边条印刷中的耐光色牢度性能。研究结果表明,添加了铁黄和铁红颜料的水性油墨PVC封边条比添加了有机黄和品红颜料的封边条具有更好的耐光色牢度,这主要与铁黄和铁红具有更好的耐太阳光降解性能和在水性油墨中... 文章研究了水性油墨在PVC封边条印刷中的耐光色牢度性能。研究结果表明,添加了铁黄和铁红颜料的水性油墨PVC封边条比添加了有机黄和品红颜料的封边条具有更好的耐光色牢度,这主要与铁黄和铁红具有更好的耐太阳光降解性能和在水性油墨中更好的分散性能有关。 展开更多
关键词 水性油墨 pvc 耐光色牢度 封边条 颜料
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PVC共挤彩色型材表面变色分析 被引量:3
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作者 冯伟刚 《聚氯乙烯》 CAS 2014年第12期22-27,共6页
介绍了颜色与颜料的概念、分类等,分析了PVC/PVC共挤彩色型材与ASA/PVC共挤彩色型材表面变色的原因。结果表明:1PVC/PVC共挤彩色型材的表面变色主要是PVC树脂降解加速颜料褪色和颜料本身褪色共同作用的结果;2ASA/PVC共挤彩色型材的表面... 介绍了颜色与颜料的概念、分类等,分析了PVC/PVC共挤彩色型材与ASA/PVC共挤彩色型材表面变色的原因。结果表明:1PVC/PVC共挤彩色型材的表面变色主要是PVC树脂降解加速颜料褪色和颜料本身褪色共同作用的结果;2ASA/PVC共挤彩色型材的表面变色主要是颜料本身褪色,ASA树脂基本没有变化。 展开更多
关键词 pvc 型材 变色 ASA 颜料
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悬浮PVC聚合体系中分散剂过量的判定
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作者 鲍春伟 侯斌 +2 位作者 梁斌 车万里 张勇 《聚氯乙烯》 CAS 2010年第4期33-35,共3页
指出了PVC悬浮聚合时分散剂浓度过高时易析出凝胶,提出了一种用四氢呋喃来溶解离心母液滤出物来判定分散剂过量的方法。
关键词 pvc 聚合体系 分散剂 饱和吸附量 临界胶束浓度 凝胶 凝胶温度
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PVC-U制品用钛白粉的选择与控制 被引量:3
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作者 聂少姬 扈廷勇 《聚氯乙烯》 CAS 2015年第2期28-31,共4页
分析市场上国家标准钛白粉、复合钛白粉和掺杂钛白粉的性能,提出应根据TiO2含量、白度和色调、光稳定性和耐候性、晶型和重金属含量等性能指标选择PVC-U制品适用的钛白粉,并给出了相关性能指标的检测方法。
关键词 pvc-U制品 钛白粉 选择 控制
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高PVC乳胶涂料配方设计 被引量:1
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作者 张朝平 《中国涂料》 CAS 2005年第10期35-37,共3页
探讨了高颜料体积浓度(PVC)乳胶涂料中原材料的选择方法,分析了各组分对产品性能的影响,总结了提高产品配方临界颜料体积浓度(LCPVC)的途径。
关键词 乳胶涂料 LCpvc pvc 乳液 颜填料
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