To find a reasonable way to prepare the designed CPP32 inhibitors. Method Ugifour-component condensation reaction was used to synthesize peptide mimic CPP32 inhibitors; ResultsA key isocyanide component (aspartate-der...To find a reasonable way to prepare the designed CPP32 inhibitors. Method Ugifour-component condensation reaction was used to synthesize peptide mimic CPP32 inhibitors; ResultsA key isocyanide component (aspartate-derived isocyanide 3) and one of the designed CPP32inhibitors 4 (as a template) were synthesized; Conclusion The CPP32 inhibitor 4 was synthesized bythe newly developed procedure, which is an Ugi four-component condensation reaction based onaspartate-derived isocyanide 3. This method can be used to build up the CPP32 inhibitor library.展开更多
The reaction mechanisms of Catalytic Pyrolysis Process and theethylene and propylene forma-tion reaction are analyzed, and ethylene and propylene are produced through both the free radical reac-tion and carbenium ion ...The reaction mechanisms of Catalytic Pyrolysis Process and theethylene and propylene forma-tion reaction are analyzed, and ethylene and propylene are produced through both the free radical reac-tion and carbenium ion reaction. The factors affecting the yields of ethylene and propylene are discussed.The results showed that greater yields of ethylene and propylene can be obtained on ZSM-5 catalystsrather than USY and REY catalysts, and the modified ZSM-5 could improve the ethylene yield. A highertemperature is favorable for enhancement of the free radical reaction as opposed to carbenium ion reaction,and change in temperature can adjust the ratio of ethylene and propylene production. A higher steamamount could produce more ethylene and propylene and less coke, and lowering the catalyst/oil ratio isfavorable for producing ethylene.展开更多
Catalytic pyrolysis process(CPP)producing ethylene and propylene from paraffin base atmospheric residue was developed by RIPP and its first in the world unit was put into commercial operation successfully.The results ...Catalytic pyrolysis process(CPP)producing ethylene and propylene from paraffin base atmospheric residue was developed by RIPP and its first in the world unit was put into commercial operation successfully.The results of performance test showed that the yield of ethylene and propylene reached 14.84% and 22.21% ,respectively,at a reaction temperature of610℃by using Daqing atmospheric residue as the feedstock under an operation mode of producing ethylene and propylene at the same time,and the aromatic content of cracked naphtha reached 82.46% .The successful operation of this unit has opened a novel route for producing light olefins and aromatics from heavy oil,which is also a good example symbolizing the integration of refining technology with petrochemical process.展开更多
On August 28,2009 the 0.5 Mt/a catalytic pyrolysis process (CPP) project for ethylene production owned by China Blue Star Shenyang Chemical Group,touted as a national demonstration project of new feedstock for ethylen...On August 28,2009 the 0.5 Mt/a catalytic pyrolysis process (CPP) project for ethylene production owned by China Blue Star Shenyang Chemical Group,touted as a national demonstration project of new feedstock for ethylene industry,was put on stream in Shenyang.The CPP project in which the investment totals 2.9 billion RMB adopts the technology for manufacture of ethylene via deep catalytic cracking of heavy oil that was jointly developed by the Blue Star Shenyang Chemical Group and RIPP aiming to produce ethylene and propylene from heavy residuum.This is the展开更多
The recently experienced hype concerning the so-called “4<sup>th</sup> Industrial Revolution” of production systems has prompted several papers of various subtopics regarding Cyber-Phdysical Production S...The recently experienced hype concerning the so-called “4<sup>th</sup> Industrial Revolution” of production systems has prompted several papers of various subtopics regarding Cyber-Phdysical Production Systems (CPPS). However, important aspects such as the modelling of CPPS to understand the theory regarding the performance of highly non-ergodic and non-deterministic flexible manufacturing systems in terms of Exit Rate (ER), Manufacturing Lead Time (MLT), and On-Time Delivery (OTD) have not yet been examined systematically and even less modeled analytically. To develop the topic, in this paper, the prerequisites for modelling such systems are defined in order to be able to derive an explicit and dedicated production mathematics-based understanding of CPPS and its dynamics: switching from explorative simulation to rational modelling of the manufacturing “physics” led to an own and specific manufacturing theory. The findings have led to enouncing, among others, the Theorem of Non-Ergodicity as well as the Batch Cycle Time Deviation Function giving important insights to model digital twin-based CPPS for complying with the mandatory OTD.展开更多
针对信息物理生产系统(Cyber-Physical Production System,CPPS)面临的安全一体化设计与工程难题,本文对安全一体化设计实现过程进行了研究,对功能安全和信息安全在设计过程中的协同设计要点进行了分析,构建了包含安全兼容性设计、安全...针对信息物理生产系统(Cyber-Physical Production System,CPPS)面临的安全一体化设计与工程难题,本文对安全一体化设计实现过程进行了研究,对功能安全和信息安全在设计过程中的协同设计要点进行了分析,构建了包含安全兼容性设计、安全一体化验证和安全一体化增强三个方面的安全一体化协同设计实现技术体系。展开更多
文摘To find a reasonable way to prepare the designed CPP32 inhibitors. Method Ugifour-component condensation reaction was used to synthesize peptide mimic CPP32 inhibitors; ResultsA key isocyanide component (aspartate-derived isocyanide 3) and one of the designed CPP32inhibitors 4 (as a template) were synthesized; Conclusion The CPP32 inhibitor 4 was synthesized bythe newly developed procedure, which is an Ugi four-component condensation reaction based onaspartate-derived isocyanide 3. This method can be used to build up the CPP32 inhibitor library.
文摘The reaction mechanisms of Catalytic Pyrolysis Process and theethylene and propylene forma-tion reaction are analyzed, and ethylene and propylene are produced through both the free radical reac-tion and carbenium ion reaction. The factors affecting the yields of ethylene and propylene are discussed.The results showed that greater yields of ethylene and propylene can be obtained on ZSM-5 catalystsrather than USY and REY catalysts, and the modified ZSM-5 could improve the ethylene yield. A highertemperature is favorable for enhancement of the free radical reaction as opposed to carbenium ion reaction,and change in temperature can adjust the ratio of ethylene and propylene production. A higher steamamount could produce more ethylene and propylene and less coke, and lowering the catalyst/oil ratio isfavorable for producing ethylene.
文摘Catalytic pyrolysis process(CPP)producing ethylene and propylene from paraffin base atmospheric residue was developed by RIPP and its first in the world unit was put into commercial operation successfully.The results of performance test showed that the yield of ethylene and propylene reached 14.84% and 22.21% ,respectively,at a reaction temperature of610℃by using Daqing atmospheric residue as the feedstock under an operation mode of producing ethylene and propylene at the same time,and the aromatic content of cracked naphtha reached 82.46% .The successful operation of this unit has opened a novel route for producing light olefins and aromatics from heavy oil,which is also a good example symbolizing the integration of refining technology with petrochemical process.
文摘On August 28,2009 the 0.5 Mt/a catalytic pyrolysis process (CPP) project for ethylene production owned by China Blue Star Shenyang Chemical Group,touted as a national demonstration project of new feedstock for ethylene industry,was put on stream in Shenyang.The CPP project in which the investment totals 2.9 billion RMB adopts the technology for manufacture of ethylene via deep catalytic cracking of heavy oil that was jointly developed by the Blue Star Shenyang Chemical Group and RIPP aiming to produce ethylene and propylene from heavy residuum.This is the
文摘The recently experienced hype concerning the so-called “4<sup>th</sup> Industrial Revolution” of production systems has prompted several papers of various subtopics regarding Cyber-Phdysical Production Systems (CPPS). However, important aspects such as the modelling of CPPS to understand the theory regarding the performance of highly non-ergodic and non-deterministic flexible manufacturing systems in terms of Exit Rate (ER), Manufacturing Lead Time (MLT), and On-Time Delivery (OTD) have not yet been examined systematically and even less modeled analytically. To develop the topic, in this paper, the prerequisites for modelling such systems are defined in order to be able to derive an explicit and dedicated production mathematics-based understanding of CPPS and its dynamics: switching from explorative simulation to rational modelling of the manufacturing “physics” led to an own and specific manufacturing theory. The findings have led to enouncing, among others, the Theorem of Non-Ergodicity as well as the Batch Cycle Time Deviation Function giving important insights to model digital twin-based CPPS for complying with the mandatory OTD.
文摘针对信息物理生产系统(Cyber-Physical Production System,CPPS)面临的安全一体化设计与工程难题,本文对安全一体化设计实现过程进行了研究,对功能安全和信息安全在设计过程中的协同设计要点进行了分析,构建了包含安全兼容性设计、安全一体化验证和安全一体化增强三个方面的安全一体化协同设计实现技术体系。
