The polarographic adsorptive complex wave of rare earths (RE) with 1-phenyl-3-methyl-4-benzoylpyrazoione-5 (PMBP) was studied in HAc-NaAc medium at pH=3.80. In the singlesweep polarography, the reduction potential of ...The polarographic adsorptive complex wave of rare earths (RE) with 1-phenyl-3-methyl-4-benzoylpyrazoione-5 (PMBP) was studied in HAc-NaAc medium at pH=3.80. In the singlesweep polarography, the reduction potential of complex wave (-1.16V) is more negative than that of the free ligand. (-1.12V), and the wave was proven to be an adsorptive complex wave by cyclic voltammetry method. This experiment proved that only the complexes of heavy RE ions can be adsorbed on the electrode under the same conditions. So it is a good method to determine heavy rare earths in the presence of light rare earths.展开更多
The micro-amount of nickel in MnO2, electrolytical and natural both, was determined by differential pulse polarography. NH4OH-NH4Cl was used as supporting electrolyte. It was found that the peak potential of Ni(II) re...The micro-amount of nickel in MnO2, electrolytical and natural both, was determined by differential pulse polarography. NH4OH-NH4Cl was used as supporting electrolyte. It was found that the peak potential of Ni(II) reduction wave is -1.0V (vs. Ag-AgCl electrode). The presence of great amount of Mn(II) does not interfere in the trace nickel determination. the peak current relationship with the Ni2+ concentration presents a quite fine straight line. The differential pulse polarography is proved that it is a simple, reliable and acceptable method for determination of trace Ni in various species of MnO2.展开更多
文摘The polarographic adsorptive complex wave of rare earths (RE) with 1-phenyl-3-methyl-4-benzoylpyrazoione-5 (PMBP) was studied in HAc-NaAc medium at pH=3.80. In the singlesweep polarography, the reduction potential of complex wave (-1.16V) is more negative than that of the free ligand. (-1.12V), and the wave was proven to be an adsorptive complex wave by cyclic voltammetry method. This experiment proved that only the complexes of heavy RE ions can be adsorbed on the electrode under the same conditions. So it is a good method to determine heavy rare earths in the presence of light rare earths.
文摘The micro-amount of nickel in MnO2, electrolytical and natural both, was determined by differential pulse polarography. NH4OH-NH4Cl was used as supporting electrolyte. It was found that the peak potential of Ni(II) reduction wave is -1.0V (vs. Ag-AgCl electrode). The presence of great amount of Mn(II) does not interfere in the trace nickel determination. the peak current relationship with the Ni2+ concentration presents a quite fine straight line. The differential pulse polarography is proved that it is a simple, reliable and acceptable method for determination of trace Ni in various species of MnO2.
