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Characterization of 3D Printed Poly(3-Hydroxybutyric-Co-3-Hydroxyvalerate) by Fused Granular Fabrication through Thermal and Mechanical Analyses
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作者 Lok-Ching Wu Cheng-Hao Lee +2 位作者 Yanming Wang Yaohui Liu Chi-Wai Kan 《Journal of Materials Science and Chemical Engineering》 2023年第12期54-63,共10页
Poly[R-3-hydroxybutyrate-co-(R-3-hydroxyvalerate)] (PHBVs) copolymers are promising biopolymers, which could substitute petroleum-based plastics for various applications. PHB and PHBV pellets were processed on a custo... Poly[R-3-hydroxybutyrate-co-(R-3-hydroxyvalerate)] (PHBVs) copolymers are promising biopolymers, which could substitute petroleum-based plastics for various applications. PHB and PHBV pellets were processed on a customized 3D printer via Fused Granular Manufacturing (FGM) approach modified with a Mahor screw extruder. To anticipate the behaviour of PHBVs when transformed using conventional thermo-mechanical shaping processes, thermal and mechanical analyses were carried out in order to better understand the effect of annealing temperature on their crystallization behaviour and mechanical properties of PHB polymer and PHBV copolymer. The objectives of the present work were to propose an experimental strategy to study the melting and crystallization events, crystalline structure changes, and mechanical performances of both PHB homopolymer and PHBV copolymer according to identical thermal annealing treatments. A monitoring of 3D printed PHB and PHBV structures was achieved by coupling Differential Scanning Calorimetry (DSC) and tensile tests. . 展开更多
关键词 Additive Manufacturing 3D Printing Biodegradable Plastic Fused Gran-ular Manufacturing poly[R-3-hydroxybutyrate-Co-(R-3-Hydroxyvalerate)]
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Miscibility, Crystallization, and Rheological Behavior of Solution Casting Poly(3-hydroxybutyrate)/poly(ethylene succinate) Blends Probed by Differential Scanning Calorimetry, Rheology, and Optical Microscope Techniques
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作者 孙伟华 乔晓平 +1 位作者 曹启坤 刘结平 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第1期107-112,I0002,共7页
The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybuty- rate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and opti... The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybuty- rate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and optical microscopy. The blends showed two glass transition temperatures and a depression of melting temperature of PHB with compositions in phase diagram, which indicated that the blend was partially miscible. The morphology observation supported this result. It was found that the PHB and PES can crystallize simultaneously or upon stepwise depending on the crystallization temperatures and compositions. The spherulite growth rate of PHB increased with increasing of PES content. The influence of compositions on the spherulitic growth rate for the partially miscible polymer blends was discussed. 展开更多
关键词 MISCIBILITY poly3-hydroxybutyrate)/poly(ethylene succinate) blend Phase behavior CRYSTALLIZATION
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Biosynthesis of poly-3-hydroxybutyrate with a high molecular weight by methanotroph from methane and methanol 被引量:6
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作者 Yingxin Zhang Jiaying Xin +2 位作者 Linlin Chen Hao Song Chungu Xia 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第1期103-109,共7页
Poly-3-hydroxybutyrate (PHB) can be produced by various species of bacteria. Among the possible carbon sources, both methane and methanol could be a suitable substrate for the production of PHB. Methane is cheap and... Poly-3-hydroxybutyrate (PHB) can be produced by various species of bacteria. Among the possible carbon sources, both methane and methanol could be a suitable substrate for the production of PHB. Methane is cheap and plentiful not only as natural gas, but also as biogas. Methanol can also maintain methanotrophic activity in some conditions. The methanotrophic strain Methylosinus trichosporium IMV3011 can accumulate PHB with methane and methanol in a brief nonsterile process. Liquid methanol (0.1%) was added to improve the oxidization of methane. The studies were carried out using shake flasks. Cultivation was performed in two stages: a continuous growth phase and a PHB accumulation phase under the conditions short of essential nutrients (ammonium, nitrate, phosphorus, copper, iron (Ⅲ), magnesium or ethylenediamine tetraacetate (EDTA)) in batch culture. It was found that the most suitable growth time for the cell is 144 h. Then an optimized culture condition for second stage was determined, in which the PHB concentration could be much increased to 0.6 g/L. In order to increase PHB content, citric acid was added as an inhibitor of tricarboxylic acid cycle (TCA). It was found that citric acid is favorable for the PHB accumulation, and the PHB yield was increased to 40% (w/w) from the initial yield of 12% (w/w) after nutrient deficiency cultivation. The PHB produced is of very high quality with molecular weight up to 1.5 × 10^6Da. 展开更多
关键词 poly-3-hydroxybutyrate METHANOTROPHS METHANE METHANOL cultivation biosynthesis high molecular weight
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Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) supports adhesion and migration of mesenchymal stem cells and tenocytes 被引量:3
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作者 Alex J Lomas George GQ Chen +1 位作者 Alicia J El Haj Nicholas R Forsyth 《World Journal of Stem Cells》 SCIE CAS 2012年第9期94-100,共7页
AIM: To establish the potential of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) as a material for tendon repair. METHODS: The biocompatibility of PHBHHx with both rat tenocytes (rT) and human mesenchymal ste... AIM: To establish the potential of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) as a material for tendon repair. METHODS: The biocompatibility of PHBHHx with both rat tenocytes (rT) and human mesenchymal stem cells (hMSC) was explored by monitoring adhesive characteristics on films of varying weight/volume ratios coupled to a culture atmosphere of either 21% O2 (air) or 2% O2 (physiological normoxia). The diameter and stiffness of PHBHHx films was established using optical coherence tomography and mechanical testing, respectively. RESULTS: Film thickness correlated directly with weight/volume PHBHHx (r2 = 0.9473) ranging from 0.1 mm (0.8% weight/volume) to 0.19 mm (2.4% weight/volume). Film stiffness on the other hand displayed a biphasic response which increased rapidly at values > 1.6% weight/volume. Optimal cell attachment of rT required films of ≥ 1.6% and ≥ 2.0% weight/volume PHBHHx in 2% O2 and 21% O2 respectively. A qualitative adhesion increase was noted for hMSC in films ≥ 1.2% weight/volume, becoming significant at 2% weight/volume in 2% O2. An increase in cell adhesion was also noted with ≥ 2% weight/volume PHBHHx in 21% O2. Cell migration into films was not observed. CONCLUSION: This evaluation demonstrates that PHBHHx is a suitable polymer for future cell/polymer replacement strategies in tendon repair. 展开更多
关键词 MESENCHYMAL stem cell TENOCYTES polyHYDROXYALKANOATES Hypoxia poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)
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Production of Poly(3-Hydroxybutyrate)by Fed-Batch Culture of Alcaligenes Eutrophus at Phosphorus Limitation in 50 L fermenter
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作者 李红旗 沈忠耀 +2 位作者 ParkByungGeon ChangYongKeun ChangHoNam 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第4期368-371,共4页
Poly(3-hydroxybutyrate) (PHB) is an intracellular carbon and energy storage material accumulated by many kinds of microorganism under unfavorable growth conditions. For the production of PHB, Alcaligenes eutrophus has... Poly(3-hydroxybutyrate) (PHB) is an intracellular carbon and energy storage material accumulated by many kinds of microorganism under unfavorable growth conditions. For the production of PHB, Alcaligenes eutrophus has been widely used because it is easy to grow, and its physiological and biochemical changes during the PHB synthesis is understood in details. A very high concentration and productivity of PHB could be obtained by fed-batch culture of Alcaligenes eutrophus with phosphate limitation in 50 L fermenter. 展开更多
关键词 poly(3-hydroxybutyrate) Alcaligenes eutrophus scale-up FERMENTATION
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BIOSYNTHESIS AND THERMAL PROPERTIES OF POLY(3-HYDROXYBUTYRATE-co-3-HYDROXYVALERATE)WITH LARGE VARIETY OF HYDROXYVALERATE CONTENTS BY BACILLUS CEREUS
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作者 严群 Chung HimYu Peter Hoi Fu Yu 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2007年第4期341-345,共5页
Biosynthesis and thermal properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with different HV (hydrovalerate) content produced by a Bacillus cereus strain were investigated. A large variety of HV ... Biosynthesis and thermal properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with different HV (hydrovalerate) content produced by a Bacillus cereus strain were investigated. A large variety of HV contents (up to about 90 mol%) of PHBV could be produced by this strain. Combined nitrogen sources containing both yeast extract and ammonium sulphate were better for cell growth and polyhydroxyalkanoates (PHA) production than either yeast extract or ammonium sulphate alone. Propionic acid is more favorable for the production of HV content than that of valeric acid. Finally, thermal properties of PHBV produced by this strain are found close to the results of other groups. 展开更多
关键词 Bacillus cereus poly3-hydroxybutyrate-co-3-hydroxyvalerate) BIOSYNTHESIS Thermal properties
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Silk fibroins modify the atmospheric low temperature plasma-treated poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) film for the application of cardiovascular tissue engineering
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作者 Huaxiao Yang Min Sun +2 位作者 Ping Zhou Luanfeng Pan Chungen Wu 《Journal of Biomedical Science and Engineering》 2010年第12期1146-1155,共10页
Tissue engineered scaffold is one of the hopeful therapies for the patients with organ or tissue damages. The key element for a tissue engineered scaffold material is high biocompatibility. Herein the poly (3-hydroxyb... Tissue engineered scaffold is one of the hopeful therapies for the patients with organ or tissue damages. The key element for a tissue engineered scaffold material is high biocompatibility. Herein the poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) film was irradiated by the low temperature atmospheric plasma and then coated by the silk fibroins (SF). After plasma treatment, the surface of PHBHHx film became rougher and more hydrophilic than that of original film. The experiment of PHBHHx flushed by phosphate buffer solution (PBS) proves that the coated SF shows stronger immobilization on the plasma-treated film than that on the untreated film. The cell viability assay demonstrates that SF-coated PHBHHx films treated by the plasma significantly supports the proliferation and growth of the human smooth muscle cells (HSMCs). Furthermore, the scanning electron microscopy and hemotoylin and eosin (HE) staining show that HSMCs formed a cell sub-monolayer and secreted a large amount of extracellular matrix (ECM) on the films after one week's culture. The silk fibroins modify the plasma-treated PHBHHx film, providing a material potentially applicable in the cardiovascular tissue engi-neering. 展开更多
关键词 BIOCOMPATIBLE Cardiovascular Tissue Engineering Low Temperature Plasma poly (3-hydroxybutyrate-Co-3-Hydroxyhexanoate) (PHBHHx) Silk Fibroin
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Complete Valorization of Olive Mill Wastewater through an Integrated Process for Poly-3-hydroxybutyrate Production
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作者 Vito Emanuele Carofiglio Roberta Romano +6 位作者 Maurizio Servili Antonio Goffredo Pietro Alifano Gianluca Veneziani Christian Demitri Domenico Centrone Paolo Stufano 《Journal of Life Sciences》 2015年第10期481-493,共13页
An economical and environmental sustainability of bioplastic production is dependent on the use of low cost and waste C-sources as raw materials. OMW (Olive Mill Wastewater) with its high organic load represents a d... An economical and environmental sustainability of bioplastic production is dependent on the use of low cost and waste C-sources as raw materials. OMW (Olive Mill Wastewater) with its high organic load represents a dangerous polluting waste. Herein the authors present an integrated process for the simultaneous recovery of polyphenols, high value natural antioxidants, production of PHAs (polyhydroxyalkanotes), thermoplastic bio-polymers, in particular of PHB (poly-3-hydroxybutyrate) starting from OMW. The combination of membrane filtration and bacterial digestion of OMW resulted in very high yields of polyphenols (3 2.5 g/L) and PHB (31.4 mg/L.h) if compared with the state of the art. These results make the technical approach described here effective for reducing the polluting effect of OMW and maximizing the valuable product yield. Moreover the process is readily suitable for an industrial scale PHB production from OMW. 展开更多
关键词 poly-3-hydroxybutyrate olive mill wastewater polyPHENOL Azotobacter vinelandii UWD membrane filtration.
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STUDY ON BIODEGRADABILITY OF POLY (3-HYDROXYBUTYRATE-co-3-HYDROXYVALERATE)/ORGANOPHILIC MONTMORILLONITE NANOCOMPOSITES
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作者 WANGShufang SONGCunjiang +5 位作者 CHENGuangxin LIUJing YANGChao ZHANGXihui GUOTianying ZHANGBanghua 《Chinese Journal of Reactive Polymers》 2004年第1期65-73,共9页
Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)/Organophilic montmorillonite (PHBV/OMMT) nanocomposites were prepared and the biodegradability of the PHBV/OMMT nanocomposites was studied by a cultivation degrading metho... Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)/Organophilic montmorillonite (PHBV/OMMT) nanocomposites were prepared and the biodegradability of the PHBV/OMMT nanocomposites was studied by a cultivation degrading method in soil suspension. The relationship between structure and biodegradability of PHBV/OMMT nanocomposites was investigated. The results showed that the biodegradability of PHBV/OMMT nanocomposites decreased with increasing amount of OMMT and it was related to the number of PHBV degrading microorganisms in degradation environment, the anti-microbial property of OMMT and the degree of crystallinity of the nanocomposites. 展开更多
关键词 poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Organophilic montmorillonite Biodegradability.
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THERMAL PROPERTY, MISCIBILITY AND CRYSTALLIZATION BEHAVIOR OF POLY(3-HYDROXYBUTYRATE-co-3-YDROXYHEXANOATE) AND POLY(BUTYLENE SUCCINATE-ADIPATE) (PHBHHX/PBSA) BLENDS
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作者 WANG Shufang GUO Tianying +3 位作者 TAO Jian ZHENG Chenggang ZHANG Banghua SONG Cunjiang 《Chinese Journal of Reactive Polymers》 2005年第1期1-7,共7页
Blends of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) and poly(butylene succinate-adipate) (PBSA), both biodegradable semicrystalline polyesters, were prepared with the ratio of PHBHHx/PBSA ranging from 80/... Blends of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) and poly(butylene succinate-adipate) (PBSA), both biodegradable semicrystalline polyesters, were prepared with the ratio of PHBHHx/PBSA ranging from 80/20 to 20/80 by melt mixing method. Differential scanning calorimetry (DSC), thermogravimetry analysis (TGA), dynamic mechanical thermal analysis (DMA), polarizing optical microscopy (POM) and wide angle X-ray diffractometer (WAXD) were used to study the miscibility and crystallization behavior of PHBHHx/PBSA blends. Experimental results indicate that PHBHHx is immiscible with PBSA as shown by the almost unchanged glass transition temperature and the biphasic melt. 展开更多
关键词 poly3-hydroxybutyrate-co-hydroxyhexanoate)/poly(butylenes succinate-adipate) blends Thermal property MISCIBILITY Crystallization.
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Preparation of Poly(3-hydroxybutyrate) Porous Films by Microemulsion Templates Method
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作者 CAI Zhi jiang,CHENG Guo xiangSchool of Materials Science and Engineering of Tianjin University,Tianjin 300072,China 《Chinese Journal of Biomedical Engineering(English Edition)》 2002年第4期166-170,共5页
Porous poly(3 hydroxybutyrate)(PHB) membranes were prepared by microemulsion templates. The influence of microemulsion templates on pore size and porosity of the PHB membranes were studied. Preliminary studies showed... Porous poly(3 hydroxybutyrate)(PHB) membranes were prepared by microemulsion templates. The influence of microemulsion templates on pore size and porosity of the PHB membranes were studied. Preliminary studies showed that the pore size made by microemulsion templates were smaller and were estimated in the range of 100~500 nanometer. In this research, the ultraviolet/visible light spectrometer was applied in the investigation of H 2O/Span85 Tween60/chloroform reserve microemulsion. Surfactant content(P) and water content(R) were optimized. Furthermore, the effects of variation of P and R on the pore size and porosity of PHB films were discussed. 展开更多
关键词 poly(3 hydroxybutyrate) MICROEMULSION Templates
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聚(3-羟基丁酸酯-4-羟基丁酸酯)/聚乳酸纤维的制备及其性能
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作者 陈宇 周长年 +7 位作者 朱金唐 彭杰 崔华帅 崔宁 史贤宁 李杰 黄庆 吴鹏飞 《毛纺科技》 CAS 北大核心 2024年第4期1-7,共7页
聚(3-羟基丁酸酯-4-羟基丁酸酯)(P34HB)是极具前景的生物基可降解材料,但结晶慢且加工黏度大等因素使其难以直接熔纺制备纤维。左旋聚乳酸(PLLA)与P34HB化学结构相似,加工温度接近,与P34HB具有协同增强作用。采用熔融纺丝法制备P34HB含... 聚(3-羟基丁酸酯-4-羟基丁酸酯)(P34HB)是极具前景的生物基可降解材料,但结晶慢且加工黏度大等因素使其难以直接熔纺制备纤维。左旋聚乳酸(PLLA)与P34HB化学结构相似,加工温度接近,与P34HB具有协同增强作用。采用熔融纺丝法制备P34HB含量为30%的P34HB/PLLA纤维,研究纤维的力学性能、热稳定性能以及结晶性能。结果发现,2000 m/min的卷绕速率下制备的P34HB/PLLA预牵伸纤维(POY)经1.40、1.75倍牵伸和定形后得到的全牵伸纤维(FDY-1和FDY-2)的断裂强度分别为1.66、2.29 cN/dtex,断裂伸长率分别为33.3%、28.8%;差示扫描量热仪(DSC)测试结果显示,POY、FDY-1、FDY-2结晶度分别为62.51%、62.05%、61.36%;XRD衍射仪测试结果也表明POY的结晶度与FDY结晶度相近,这表明在POY成形过程中,纤维中的结晶已经接近完成,P34HB提高了PLLA结晶效率。 展开更多
关键词 聚(3-羟基丁酸酯-4-羟基丁酸酯) 聚乳酸 纤维 热稳定性 力学性能 结晶性能
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基于Caspase-3/PARP通路探究龟鹿二仙胶及拆方对IL-1β诱导的退变软骨细胞凋亡及细胞外基质的影响
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作者 吴伟欣 郑珍萍 +3 位作者 顾富城 杨美鑫 王和鸣 李楠 《现代中西医结合杂志》 CAS 2024年第1期8-16,共9页
目的 基于半胱氨酸蛋白酶3/多聚腺苷二磷酸核糖聚合酶(Caspase-3/PARP)通路探究龟鹿二仙胶及拆方对白细胞介素-1β(IL-1β)诱导的退变软骨细胞凋亡及细胞外基质(ECM)的影响。方法 采用SD大鼠制备空白血清、龟鹿二仙胶含药血清、龟甲胶... 目的 基于半胱氨酸蛋白酶3/多聚腺苷二磷酸核糖聚合酶(Caspase-3/PARP)通路探究龟鹿二仙胶及拆方对白细胞介素-1β(IL-1β)诱导的退变软骨细胞凋亡及细胞外基质(ECM)的影响。方法 采用SD大鼠制备空白血清、龟鹿二仙胶含药血清、龟甲胶含药血清及鹿角胶含药血清,采用酶消法体外培养C57BL/6小鼠软骨细胞。将软骨细胞分为5组,空白组加入空白血清培养,模型组加入IL-1β和空白血清培养,龟鹿组加入IL-1β和龟鹿二仙胶含药血清培养,龟板组加入IL-1β和龟甲胶含药血清培养,鹿角组加入IL-1β和鹿角胶含药血清培养,干预24 h后,采用CCK-8法检测软骨细胞活性,采用TUNEL法检测软骨细胞凋亡情况,采用免疫荧光染色法检测Caspase-3、PARP-1表达情况,分别采用Western blot和qRT-PCR法检测细胞中Caspase-3、PARP-1、基质金属蛋白酶-13(MMP-13)、聚集蛋白聚糖(Aggrecan)蛋白及mRNA表达情况。结果 与空白组比较,模型组软骨细胞活性明显降低(P<0.05),软骨细胞凋亡率明显升高(P<0.05);细胞中Caspase-3、PARP-1平均荧光强度和Caspase-3、PARP-1、MMP-13蛋白及mRNA相对表达量均明显升高(P均<0.05),细胞中Aggrecan蛋白及mRNA相对表达量均明显降低(P均<0.05)。与模型组比较,龟鹿组、龟板组及鹿角组软骨细胞活性均明显升高(P均<0.05),软骨细胞凋亡率均明显降低(P均<0.05);细胞中Caspase-3、PARP-1平均荧光强度和Caspase-3、PARP-1、MMP-13蛋白及mRNA相对表达量均明显降低(P均<0.05),细胞中Aggrecan蛋白及mRNA相对表达量均明显升高(P均<0.05)。与龟板组、鹿角组比较,龟鹿组软骨细胞活性更高(P均<0.05),软骨细胞凋亡率更低(P均<0.05);细胞中Caspase-3、PARP-1平均荧光强度和Caspase-3、PARP-1、MMP-13蛋白及mRNA相对表达量均更低(P均<0.05),细胞中Aggrecan蛋白及mRNA相对表达量均更高(P均<0.05)。与龟板组比较,鹿角组软骨细胞活性,软骨细胞凋亡率,细胞中Caspase-3、PARP-1平均荧光强度,细胞中Caspase-3、PARP-1、MMP-13、Aggrecan蛋白及mRNA相对表达量高均更高(P均<0.05)。结论 龟板胶可抑制软骨细胞凋亡及ECM降解,鹿角胶可促进软骨细胞增殖和ECM合成代谢,龟鹿二仙胶作用效果优于龟板胶及鹿角胶,作用机制可能与激活Caspase-3/PARP信号通路有关。 展开更多
关键词 龟鹿二仙胶 软骨细胞 凋亡 细胞外基质 半胱氨酸蛋白酶3 多聚腺苷二磷酸核糖聚合酶
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SYNTHESIS OF NOVEL BLOCK COPOLYMERS OF POLY(3-HYDROXYBUTYRIC ACID)WITH POLY(ETHYLENE GLYCOL)THROUGH ANIONIC POLYMERISATION
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作者 Xin-tao Shuai Zbigniew Jedlinski +1 位作者 Qiang Luo Nozirow Farhod Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China Institute of Polymer Chemistry, Polish Academy of Sciences, 41-800 Zabrze, Poland Institute of Synthetic Fibre, Chinese Academy of Textile Sciences, Beijing 100025, China 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2000年第1期19-23,共5页
A novel kind of copolymer with ABA-type block structure was synthesized by anionic ring-opening polymerization of beta-butyrolactone (beta-BL) in the presence of a PEG-based dicarboxylates as macroinitiators which wer... A novel kind of copolymer with ABA-type block structure was synthesized by anionic ring-opening polymerization of beta-butyrolactone (beta-BL) in the presence of a PEG-based dicarboxylates as macroinitiators which were prepared by the esterification of aliphatic cyclic anhydride and poly(ethylene glycol) (PEG) oligomers (M-n = 2000, 4000 and 6000) and conversion of potassium dicarboxylates. The resultant copolymers as well as the intermediates were characterized by IR, H-1-NMR and GPC. 展开更多
关键词 block copolymer poly(ethylene glycol) poly(3-hydroxybutyric acid)
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Agro-Industrial Waste Materials as Substrates for the Production of Poly(3-Hydroxybutyric Acid)
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作者 Artun Sukan Ipsita Roy Tajalli Keshavarz 《Journal of Biomaterials and Nanobiotechnology》 2014年第4期229-240,共12页
Accumulation of recalcitrant plastics in the environment has become a world-wide problem in today’s societies. Rapid depletion of natural resources for synthetic plastics along with environmental concerns has directe... Accumulation of recalcitrant plastics in the environment has become a world-wide problem in today’s societies. Rapid depletion of natural resources for synthetic plastics along with environmental concerns has directed research towards finding alternatives to petroleum-based polymers. Poly(3-hydroxybutyric acid) P(3HB), as one of these alternatives, have attracted much attention in recent years due to their varied mechanical properties, biocompatibility and biodegradability. The aim of this study was to identify an agro-industrial waste resource economically suitable for large-scale production of P(3HB), to optimize the production using Response Surface Methodology in small-scale and subsequently, to test the production in a continuously stirred tank reactor. Among a range of agro-industrial waste, orange peel was selected as the most suitable for P(3HB) production. P(3HB) concentration of 1.24 g P(3HB)/L culture broth with 41% P(3HB)/dcw yield was obtained using orange peel as the sole carbon source in optimized medium with a modified strain of Bacillus subtilis (B. subtilis OK2). 展开更多
关键词 Agro-Industrial WASTES CCD STR Orangepeel Optimisation poly(3-Hyrdroxybutyric Acid)
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Novel sandwich structured glass fiber Cloth/Poly(ethylene oxide)-MXene composite electrolyte
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作者 Yu-Qin Mao Guang-He Dong +3 位作者 Wei-Bin Zhu Yuan-Qing Li Pei Huang Shao-Yun Fu 《Nano Materials Science》 EI CAS CSCD 2024年第1期60-67,共8页
Recently,poly(ethylene oxide)(PEO)-based solid polymer electrolytes have been attracting great attention,and efforts are currently underway to develop PEO-based composite electrolytes for next generation high performa... Recently,poly(ethylene oxide)(PEO)-based solid polymer electrolytes have been attracting great attention,and efforts are currently underway to develop PEO-based composite electrolytes for next generation high performance all-solid-state lithium metal batteries.In this article,a novel sandwich structured solid-state PEO composite electrolyte is developed for high performance all-solid-state lithium metal batteries.The PEO-based composite electrolyte is fabricated by hot-pressing PEO,LiTFSI and Ti_(3)C_(2)T_(x) MXene nanosheets into glass fiber cloth(GFC).The as-prepared GFC@PEO-MXene electrolyte shows high mechanical properties,good electrochemical stability,and high lithium-ion migration number,which indicates an obvious synergistic effect from the microscale GFC and the nanoscale MXene.Such as,the GFC@PEO-1 wt%MXene electrolyte shows a high tensile strength of 43.43 MPa and an impressive Young's modulus of 496 MPa,which are increased by 1205%and 6048%over those of PEO.Meanwhile,the ionic conductivity of GFC@PEO-1 wt%MXene at 60℃ reaches 5.01×10^(-2) S m^(-1),which is increased by around 200%compared with that of GFC@PEO electrolyte.In addition,the Li/Li symmetric battery based on GFC@PEO-1 wt%MXene electrolyte shows an excellent cycling stability over 800 h(0.3 mA cm^(-2),0.3 mAh cm^(-2)),which is obviously longer than that based on PEO and GFC@PEO electrolytes due to the better compatibility of GFC@PEO-1 wt%MXene electrolyte with Li anode.Furthermore,the solid-state Li/LiFePO_(4) battery with GFC@PEO-1 wt%MXene as electrolyte demonstrates a high capacity of 110.2–166.1 mAh g^(-1) in a wide temperature range of 25–60C,and an excellent capacity retention rate.The developed sandwich structured GFC@PEO-1 wt%MXene electrolyte with the excellent overall performance is promising for next generation high performance all-solid-state lithium metal batteries. 展开更多
关键词 Solid polymer electrolyte Ti_(3)C_(2)T_(x)MXene poly(ethylene oxide) Glass fiber cloth All-solid-state Li metal Battery
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Use of a Simple Fabrication Process to Produce a Biosensor: The 3-Hydroxybutyrate Dehydrogenase Case
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作者 I. Ribau and E. Fortunato 《Journal of Pharmacy and Pharmacology》 2018年第2期140-148,共9页
This study was aimed to construct a biodegradable but reliable 3-β-hydroxybutymte biosensor. In this context a versatile paper based biosensor, quickly, easily and cheaply fabricated is reported. The procedure of fab... This study was aimed to construct a biodegradable but reliable 3-β-hydroxybutymte biosensor. In this context a versatile paper based biosensor, quickly, easily and cheaply fabricated is reported. The procedure of fabrication is based on the assumption that the introduction of the enzyme in the carbon ink will allow enzyme stabilization and facilitate the study of the catalysis of enzymes and the detection of substrates. To prove this concept we use the enzyme 3-hydroxybutyrate dehydrogenase, in aqueous solution. This enzyme was chosen because it catalyzes the 3-β-hydroxybutyrate, which results from ketoacidosis. The quantification this substance in the diabetics' blood is very important as it can increase the reliability of the diagnosis of glycaemia. To prove the multi-use of this biosensor we not only study the redox process in steady state and during the catalytic process, but also detected and quantify the 3-β-hydroxybutyrate. Our results showed that it was possible to study the redox process that occurred during the catalysis and to confirm the amino acid residues that participate in it. It was also observed that glucose and ascorbic acid can interfere in the detection and quantification of the 3-β-hydroxybutyrate, what should be in mind when the quantification of the 3-β-hydroxybutyrate is made in blood samples. 展开更多
关键词 DIABETICS paper biosensor screen-printing 3-hydroxybutyrate dehydrogenase.
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Effect of Nanostructures Addition and Enhancement of Poly (Vinylidene Difluoride) (PVDF) Energy Harvesting
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作者 Omar Peña-Oliveras Brenda Javier-Boodhan +1 位作者 Anthony La Santa Juan Gonzalez-Sanchez 《Materials Sciences and Applications》 2024年第7期228-244,共17页
With concerns in energy crisis and global warming, researchers are actively investigating alternative energy renewable solutions. Among the various methods, piezoelectric transduction stands out due to its impressive ... With concerns in energy crisis and global warming, researchers are actively investigating alternative energy renewable solutions. Among the various methods, piezoelectric transduction stands out due to its impressive electromechanical coupling factor and coefficient. As a result, piezoelectric energy harvesting has garnered significant attention from the scientific community. In this study, we explored methods to enhance the piezoelectric properties of polyvinylidene fluoride (PVDF) through two distinct approaches. The first approach involved applying external high voltages at various stages during the mixture reaction. The goal was to determine whether this voltage application could alter or enhance PVDF’s piezoelectric conformation by improving the alignment of polarized dipoles. In the second part of our study, we investigated the effects of incorporating various nanostructures (including Iron Oxide, Magnesium Oxide, and Zinc Oxide) into PVDF. To analyze changes in PVDF’s crystalline structure, we utilized Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Diffraction (XRD) techniques. Additionally, we measured the electric polarization of samples using a Precision LC Meter and examined the morphology of nanofibers through Scanning Electron Microscopy (SEM). 展开更多
关键词 poly (Vinylidene Fluoride) (PVDF) Energy Harvesting ELECTROSPINNING Nanoparticles ZnO MgO FE3O4
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Al(OH)_3、ISA206及Poly(I:C)免疫佐剂对灭活口蹄疫140S抗原免疫效果的影响 被引量:3
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作者 周春雪 魏巍 +3 位作者 李冬 韩成昊 李艳丽 刘在新 《免疫学杂志》 CAS CSCD 北大核心 2013年第11期927-932,共6页
目的选取Al(OH)3、ISA206及Poly(I:C)3种佐剂,分别与灭活口蹄疫病毒(FMDV)配制成疫苗,并通过小鼠实验比较和评价3种佐剂的免疫效力。方法以口蹄疫O型病毒为毒种,经细胞培养传代,获得较高滴度的病毒培养物,并经化学方法灭活制成140S口蹄... 目的选取Al(OH)3、ISA206及Poly(I:C)3种佐剂,分别与灭活口蹄疫病毒(FMDV)配制成疫苗,并通过小鼠实验比较和评价3种佐剂的免疫效力。方法以口蹄疫O型病毒为毒种,经细胞培养传代,获得较高滴度的病毒培养物,并经化学方法灭活制成140S口蹄疫完整病毒粒子抗原。在蔗糖密度梯度定量后分别与Al(OH)3、ISA206及Poly(I:C)3种佐剂配合制作口蹄疫灭活疫苗。疫苗经肌肉注射免疫Balb/c小鼠,通过检测抗体效价评价机体产生的体液免疫反应。通过检测体外刺激免疫小鼠脾淋巴细胞后产生的细胞因子以及淋巴细胞增殖实验评价机体产生的细胞免疫反应。结果 ISA206口蹄疫灭活苗和Poly(I:C)口蹄疫灭活苗诱导小鼠产生的抗体效价较高;通过体外刺激实验发现,ISA206口蹄疫灭活苗免疫组小鼠脾淋巴细胞在抗原刺激后,产生的IFN-γ和IL-4含量最高;通过淋巴细胞增殖实验发现,ISA206口蹄疫灭活苗免疫组小鼠脾淋巴细胞的增殖能力最强(P<0.05)。结论ISA206佐剂在配合灭活口蹄疫140S完整病毒粒子进行免疫时所表现的免疫效力最高。 展开更多
关键词 poly(I C) AL(OH)3 ISA206 口蹄疫
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Poly3D软件及其在地学中的应用 被引量:4
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作者 龚发雄 单业华 +2 位作者 李自安 林舸 刘士林 《大地构造与成矿学》 EI CAS CSCD 北大核心 2008年第1期50-56,共7页
免费的Poly3D边界元软件基于位移不连续性方法,它不仅能够模拟断层或裂缝的静态生长,而且所采用的多边形单元可以很好地表示出复杂多边的不连续界面。该软件在地学中的应用较为广泛,诸如裂缝形成、由断层互相作用造成的应力扰动和滑移... 免费的Poly3D边界元软件基于位移不连续性方法,它不仅能够模拟断层或裂缝的静态生长,而且所采用的多边形单元可以很好地表示出复杂多边的不连续界面。该软件在地学中的应用较为广泛,诸如裂缝形成、由断层互相作用造成的应力扰动和滑移量分布、地下断层形态的确定、低于地震识别精度的断层的预测、地震触发等等。 展开更多
关键词 poly3D 位移不连续 单元 角位错 断层 滑移量
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