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Oxidation Modification of Polyacrylonitrile-Based Carbon Fiber and Its Electro-Chemical Performance as Marine Electrode for Electric Field Test 被引量:8
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作者 ZAI Xuerong LIU Ang +2 位作者 TIAN Yuhua CHAI Fanggang FU Yubin 《Journal of Ocean University of China》 SCIE CAS CSCD 2020年第2期361-368,共8页
A novel sensor for ocean electric field testing has been fabricated by polyacrylonitrile-based on carbon fibers with electro-chemical oxidation.The surface profile characteristics of the carbon fibers were characteriz... A novel sensor for ocean electric field testing has been fabricated by polyacrylonitrile-based on carbon fibers with electro-chemical oxidation.The surface profile characteristics of the carbon fibers were characterized by scanning electron microscope,Fourier transform infrared spectra and contact angle.Cyclic voltammetry and Tafel curves have been used to study its electro-chemical performances.Two identical electrodes in sea water as the electric field sensor will swiftly respond to applied electric field which causes positive and negative ions to move in opposite direction,resulting in a electric potential difference(ΔE).Test result indicates that the offset potential is typically below 1 m V with a drift of 60-170μVd^-1.Typical self noise level is 1.07 nV√Hz^(1/2)@1 Hz.The electric field response indicates that the modified electrode pair shows better response to AC sine signal of amplitude and frequency(5 mV and 1 mHz)respectively than its blank.The electric field response model of the modified electrodes is creatively presented according to its electric double layer capacitance and Faraday pseudo-capacitance.Many advantages of the carbon fiber electric field electrode will make it have potential application prospect. 展开更多
关键词 carbon fiber electrode electro-chemical oxidation modification electro-chemical performance electric field response electric field test
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Catalytic graphitization of polyacrylonitrile-based carbon fibers coated with Prussian blue
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作者 彭奇龄 周海晖 +2 位作者 黄振华 陈金华 旷亚非 《Journal of Central South University》 SCIE EI CAS 2010年第4期683-687,共5页
Prussian blue(PB) was used as catalyst to improve the extent of graphitization of polyacrylonitrile(PAN)-based carbon fibers.PB was deposited on carbon fibers by anodic electrodeposition and the thickness of PB coatin... Prussian blue(PB) was used as catalyst to improve the extent of graphitization of polyacrylonitrile(PAN)-based carbon fibers.PB was deposited on carbon fibers by anodic electrodeposition and the thickness of PB coating(PB content) was controlled by adjusting the electrodeposition time.PAN-based carbon fibers with PB coating were heat-treated and the extent of graphitization was measured by X-ray diffractometry and Raman spectroscopy.The results indicate that the extent of graphitization of PAN-based carbon fibers is enhanced in the presence of the coating.When the PB-coated carbon fibers were heat-treated at 1 900 ℃,interlayer spacing(d002) and crystallite size(Lc) reach 0.336 8 and 21.2 nm respectively.Contrarily,the values of d002 and Lc are 0.341 4 and 7.4 nm respectively when the bare carbon fibers were heat-treated at 2 800 ℃.Compared with the bare carbon fibers,PB can make the heat treatment temperature(HTT) drop more than 500 ℃ in order to reach the same extent of graphitization.Furthermore,the research results show that PB content also has a certain influence on the extent of graphitization at the same HTT. 展开更多
关键词 聚丙烯腈基碳纤维 催化石墨化 普鲁士蓝 石墨化程度 热处理温度 聚丙烯腈基炭纤维 阳极电沉积 包覆
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CoS Nanosheets Coated with Dopamine-Derived Carbon Standing on Carbon Fiber Cloth as Binder-Free Anode for Li-ion Batteries
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作者 Lianyuan Ji Mingchen Shi +1 位作者 Zengkai Feng Hui Yang 《Journal of Renewable Materials》 EI CAS 2024年第2期259-274,共16页
Cobalt sulphides attract much attention as anode materials for Li-ion batteries(LIBs).However,its poor conductivity,low initial column efficiency and large volume changes during cycling have hindered its further devel... Cobalt sulphides attract much attention as anode materials for Li-ion batteries(LIBs).However,its poor conductivity,low initial column efficiency and large volume changes during cycling have hindered its further development.Herein,novel interlaced CoS nanosheets were firstly prepared on Carbon Fiber Cloth(CFC)by two hydrothermal reactions followed with carbon coating via carbonizing dopamine(CoS NS@C/CFC).As a freestanding anode,the nanosheet structure of CoS not only accommodates the volume variation,but also provides a large interface area to proceed the charge transfer reaction.In addition,CFC works as both a three-dimensional skeleton and an active substance which can further improve the areal capacity of the resulting electrode.Furthermore,the coated carbon combined with the CFC work as a 3D conductive network to facilitate the electron conduction.The obtained CoS NS@C/CFC,and the contrast sample prepared with the same procedure but without carbon coating(CoS NS/CFC),are characterized with XRD,SEM,TEM,XPS and electrochemical measurements.The results show that the CoS NS@C/CFC possesses much improved electrochemical performance due to the synergistic effect of nanosheet CoS,the coated carbon and the CFC substrate,exhibiting high initial columbic efficiency(~87%),high areal capacity(2.5 at 0.15 mA cm−2),excellent rate performance(1.6 at 2.73 mA cm−2)and improved cycle stability(87.5%capacity retention after 300 cycles).This work may provide a new route to explore freestanding anodes with high areal specific capacity for LIBs. 展开更多
关键词 Lithium-ion battery cobalt sulfide carbon coating carbon fiber cloth freestanding anode
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Small but mighty:Empowering sodium/potassium-ion battery performance with S-doped SnO2 quantum dots embedded in N,S codoped carbon fiber network
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作者 Shengnan He Hui Wu +4 位作者 Shuang Li Ke Liu Yaxiong Yang Hongge Pan Xuebin Yu 《Carbon Energy》 SCIE EI CAS CSCD 2024年第5期186-200,共15页
SnO_(2) has been extensively investigated as an anode material for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)due to its high Na/K storage capacity,high abundance,and low toxicity.However,the sluggish ... SnO_(2) has been extensively investigated as an anode material for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)due to its high Na/K storage capacity,high abundance,and low toxicity.However,the sluggish reaction kinetics,low electronic conductivity,and large volume changes during charge and discharge hinder the practical applications of SnO_(2)-based electrodes for SIBs and PIBs.Engineering rational structures with fast charge/ion transfer and robust stability is important to overcoming these challenges.Herein,S-doped SnO_(2)(S-SnO_(2))quantum dots(QDs)(≈3 nm)encapsulated in an N,S codoped carbon fiber networks(S-SnO_(2)-CFN)are rationally fabricated using a sequential freeze-drying,calcination,and S-doping strategy.Experimental analysis and density functional theory calculations reveal that the integration of S-SnO_(2) QDs with N,S codoped carbon fiber network remarkably decreases the adsorption energies of Na/K atoms in the interlayer of SnO_(2)-CFN,and the S doping can increase the conductivity of SnO_(2),thereby enhancing the ion transfer kinetics.The synergistic interaction between S-SnO_(2) QDs and N,S codoped carbon fiber network results in a composite with fast Na+/K+storage and extraordinary long-term cyclability.Specifically,the S-SnO_(2)-CFN delivers high rate capacities of 141.0 mAh g^(−1) at 20 A g^(−1) in SIBs and 102.8 mAh g^(−1) at 10 A g^(−1) in PIBs.Impressively,it delivers ultra-stable sodium storage up to 10,000 cycles at 5 A g^(−1) and potassium storage up to 5000 cycles at 2 A g^(−1).This study provides insights into constructing metal oxide-based carbon fiber network structures for high-performance electrochemical energy storage and conversion devices. 展开更多
关键词 carbon fiber network heteroatom doping potassium-ion battery sodium-ion battery S-SnO2 quantum dot
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Carbon Fiber Breakage Mechanism in Aluminum(Al)/Carbon Fibers(CFs) Composite Sheet during Accumulative Roll Bonding(ARB) Process
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作者 胡淑芬 SUN Zhenzhong +3 位作者 SHEN Fanghua DENG Jun 杨卫平 杨浩坤 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期167-173,共7页
We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surf... We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters. 展开更多
关键词 Al/CFs composite sheet accumulative roll bonding tensile strength plastic instability carbon fiber breakage
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Preparation and Analysis of Carbon Fiber-Silicon Carbide Thermally Conductive Asphalt Concrete
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作者 Zhiyong Yang Enjie Hu +3 位作者 Lei Xi Zhi Chen Feng Xiong Chuanhai Zhan 《Fluid Dynamics & Materials Processing》 EI 2024年第4期705-723,共19页
An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented.The main objective of this study was to verify the possibility of using SiC powder instead of min... An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented.The main objective of this study was to verify the possibility of using SiC powder instead of mineral powder as the thermal conductive filler to prepare a new type of asphalt concrete and improve the efficiency of electrothermal snow and ice melting systems accordingly.The thermal conductivity of asphalt concrete prepared with different thermally conductive fillers was tested by a transient plane source method,and the related performances were measured.Then the temperature rise rate and surface temperature were studied through field heating tests.Finally,the actual ice melting efficiency of the thermally conductive asphalt concrete was evaluated using an effective electrothermal system.As shown by the experimental results,the composite made of SiC powder and carbon fiber has a high thermal conductivity.When SiC replaces mineral powder,the thermal conductivity of the asphalt mixture increases first and then decreases with the increase of carbon fiber content.In the present study,in particular,the thermal conductivity attained a peak when the carbon fiber content was 0.2%of the aggregate mass. 展开更多
关键词 carbon fiber silicon carbide thermally conductive asphalt concrete road performance electrothermal snow melting
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Study of damage behavior and repair effectiveness of patch repaired carbon fiber laminate under quasi-static indentation loading
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作者 Alok Kumar Chinmaya Kumar Sahoo A.Arockiarajan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期29-41,共13页
Damage caused due to low-velocity impacts in composites leads to substantial deterioration in their residual strength and eventually provokes structural failure.This work presents an experimental investigation on the ... Damage caused due to low-velocity impacts in composites leads to substantial deterioration in their residual strength and eventually provokes structural failure.This work presents an experimental investigation on the effects of different patch and parent laminate stacking sequences on the enhancement of impact strength of Carbon Fiber Reinforced Polymers(CFRP)composites by utilising the adhesively bonded external patch repair technique.Damage evolution study is also performed with the aid of Acoustic Emission(AE).Two different quasi-isotropic configurations were selected for the parent laminate,viz.,[45°/45°/0°/0°]s and[45°/0°/45°/0°]s.Quasi Static Indentation(QSI)test was performed on both the pristine laminates,and damage areas were detected by using the C-scan inspection technique.Damaged laminates were repaired by using a single-sided patch of two different configurations,viz.,[45°/45°/45°/45°]and[45°/0°/0°/45°],and employing a circular plug to fill the damaged hole.Four different combinations of repaired laminates with two configurations of each parent and patch laminate were produced,which were further subjected to the QSI test.The results reveal the effectiveness of the repair method,as all the repaired laminates show higher impact resistance compared to the respective pristine laminates.Patches of[45°/0°/0°/45°]configuration when repaired by taking[45°/45°/0°/0°]s and[45°/0°/45°/0°]s as parents exhibited 68%and 73%higher peak loads,respectively,than the respective pristine laminates.Furthermore,parent and patch of configuration[45°/0°/45°/0°]s and[45°/0°/0°/45°],respectively,attain the highest peak load,whereas[45°/45°/0°/0°]s and[45°/45°/45°/45°]combinations possess the most gradual decrease in the load. 展开更多
关键词 carbon fiber reinforced polymers(CFRP) Quasi-isotropic laminate Quasi static indentation(QSI) Acoustic emission(AE) Composite repair
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Study of the Diffusion Behavior of Seawater Absorption in Multi-Walled Carbon Nanotubes/Halloysite Nanotubes Hybrid Nanofillers Modified Epoxy-Based Glass/Carbon Fiber Composites
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作者 Praful Choudhari Vivek Kulkarni Sanjeevakumar Khandal 《Modern Mechanical Engineering》 2024年第2期25-38,共14页
In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in har... In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in harsh seawater conditions is a concern. Researchers address this by exploring three approaches: coating fiber surfaces, hybridizing fibers and matrices with or without nanofillers, and interply rearrangement. This study focuses on evaluating the synergistic effects of interply rearrangement of glass/carbon fibers and hybrid nanofillers, specifically Multi-walled carbon nanotubes (MWCNT) and Halloysite nanotubes (HNT). The aim is to enhance impact properties by minimizing moisture absorption. Hybrid nanocomposites with equal-weight proportions of two nanofillers: 0 wt.%, 1 wt.%, and 2 wt.% were exposed to seawater for 90 days. Experimental data was subjected to modelling through the application of Predictive Fick’s Law. The study found that the hybrid composite containing 2 wt.% hybrid nanofillers exhibited a 22.10% increase in impact performance compared to non-modified counterparts. After 90 days of seawater aging, the material exhibited enhanced resistance to moisture absorption (15.74%) and minimal reduction in impact strength (8.52%) compared to its dry strength, with lower diffusion coefficients. 展开更多
关键词 Glass/carbon fiber Hybrid Composites Multiwall carbon Nanotubes (MWCNTs) Halloysite Nanotubes (HNTs) Diffusion Behaviour Impact Properties Seawater Aging
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Indirect Electroanalysis of 3-Methyl-4-Nitrophenol in Water Using Carbon Fiber Microelectrode Modified with Nickel Tetrasulfonated Phthalocyanine Complex
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作者 Yibor Fabrice Roland Bako Serge Foukmeniok Mbokou +2 位作者 Boukaré Kaboré Issa Tapsoba Maxime Pontié 《Materials Sciences and Applications》 2024年第2期25-35,共11页
Electrochemical detection of 3-methyl-4-nitrophenol (MNP) in direct phenol oxidation occurs at high potentials and generally leads to progressive passivation of the electrochemical sensor. This study describes the use... Electrochemical detection of 3-methyl-4-nitrophenol (MNP) in direct phenol oxidation occurs at high potentials and generally leads to progressive passivation of the electrochemical sensor. This study describes the use of a carbon fiber microelectrode modified with a tetrasulfonated nickel phthalocyanine complex for the detection of MNP at a lower potential than that of direct phenol oxidation. The MNP voltammogram showed the presence of an anodic peak at -0.11 V vs SCE, corresponding to the oxidation of the hydroxylamine group generated after the reduction of the nitro group. The effect of buffer pH on the peak current and SWV parameters such as frequency, scan increment, and pulse amplitude were studied and optimized to have better electrochemical response of the proposed sensor. With these optimal parameters, the calibration curve shows that the peak current varied linearly as a function of MNP concentration, leading to a limit of detection (LoD) of 1.1 μg/L. These results show an appreciable sensitivity of the sensor for detecting the MNP at relatively low potentials, making it possible to avoid passivation phenomena. 展开更多
关键词 3-Methyl-4-Nitrophenol carbon fiber Microelectrode Nickel Tetrasulfonated Phthalocyanine Indirect Electroanalysis Square Wave Voltammetry
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Heat-induced Internal Strain Relaxation and its Effect on the Microstructure of Polyacrylonitrile-based Carbon Fiber 被引量:5
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作者 Denghua Li Chunxiang Lu +5 位作者 Gangping Wu Yu Yang Zhihai Feng Xiutao Li Feng An Baoping Zhang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2014年第10期1051-1058,共8页
The transformation of the internal strain and its effect on the microstructure of polyacrylonitrile-based carbon fiber during the high-temperature graphitization were investigated. The internal compressive strain with... The transformation of the internal strain and its effect on the microstructure of polyacrylonitrile-based carbon fiber during the high-temperature graphitization were investigated. The internal compressive strain within the carbon turbostratic structure was confirmed through a careful analysis by wide-angle X-ray diffraction and Raman spectroscopy. Heat-induced strain/stress relaxation along the fiber axis was observed and was found to have a profound effect on the structure of both the crystallites and microvoids. The results indicated that, the relaxation of residual strain changed the graphite layers from a wrinkled and distorted morphology to a straight and smooth one, and consequently led the crystallites to stack closely and orderly with increasing stack height. The strain relaxation also changed the morphology of crystallites and microvoids, resulting in an anisotropic growth for the latters. 展开更多
关键词 Graphitizafion Internal strain MICROSTRUCTURES NANOCRYSTALLINE carbon fiber
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Adsorption characteristics of carbon tetrachloride from aqueous solution onto polyacrylonitrile-based activated carbon fiber 被引量:5
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作者 刘文霞 官宝红 于洁 《Journal of Central South University》 SCIE EI CAS 2010年第5期972-978,共7页
The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regenerat... The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regeneration of PAN-ACF was also studied.Freundlich and Dubinin-Radushkevich(D-R) adsorption equations can well describe the adsorption isotherm.CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion.The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model,and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model.The ACF can be recycled through thermal regeneration,whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration.78%-94%of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale,which confirms the efficacy of ACF under industrial conditions.The results indicate that PAN-ACF is applicable to CT removal from wastewater. 展开更多
关键词 聚丙烯腈基活性炭纤维 四氯化碳 吸附特性 聚丙烯腈活性炭纤维 水溶液 吸附动力学 吸附等温线 连续流动
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"Three-in-One" Multi-Scale Structural Design of Carbon Fiber-Based Composites for Personal Electromagnetic Protection and Thermal Management 被引量:3
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作者 Ming Zhou Shujuan Tan +3 位作者 Jingwen Wang Yue Wu Leilei Liang Guangbin Ji 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第10期317-333,共17页
Wearable devices with efficient thermal management and electromagnetic interference(EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers(CF) @ po... Wearable devices with efficient thermal management and electromagnetic interference(EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers(CF) @ polyaniline(PANI)/silver nanowires(Ag NWs) composites with a “branch-trunk” interlocked micro/nanostructure were achieved through "three-in-one" multi-scale design. The reasonable assembly of the three kinds of one-dimensional(1D) materials can fully exert their excellent properties i.e., the superior flexibility of CF, the robustness of PANI, and the splendid conductivity of Ag NWs. Consequently, the constructed flexible composite demonstrates enhanced mechanical properties with a tensile stress of 1.2 MPa, which was almost 6 times that of the original material. This is mainly attributed to the fact that the PNAI(branch) was firmly attached to the CF(trunk) through polydopamine(PDA), forming a robust interlocked structure. Meanwhile, the composite possesses excellent thermal insulation and heat preservation capacity owing to the synergistically low thermal conductivity and emissivity. More importantly, the conductive path of the composite established by the three 1D materials greatly improved its EMI shielding property and Joule heating performance at low applied voltage. This work paves the way for rational utilization of the intrinsic properties of 1D materials, as well as provides a promising strategy for designing wearable electromagnetic protection and thermal energy management devices. 展开更多
关键词 Electromagnetic shielding Multi-scale design One-dimensional materials carbon fiber Thermal management
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Microwave Absorption and Mechanical Properties of Short-cutted Carbon Fiber/glass Fiber Hybrid Veil Reinforced Epoxy Composites 被引量:1
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作者 陈威 ZHEN Bowen +4 位作者 XIE Yuxuan 贺行洋 SU Ying WANG Jun WU Yan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第1期248-254,共7页
This work aims at investigating the microwave absorption and mechanical properties of short-cutted carbon fiber/glass fiber hybrid veil reinforced epoxy composites.The short-cutted carbon fibers(CFs)/glass fibers(GFs)... This work aims at investigating the microwave absorption and mechanical properties of short-cutted carbon fiber/glass fiber hybrid veil reinforced epoxy composites.The short-cutted carbon fibers(CFs)/glass fibers(GFs)hybrid veil were prepared by papermaking technology,and composites liquid molding was employed to manufacture CFs/GFs hybrid epoxy composites.The microstructure,microwave absorbing properties and mechanical properties of the hybrid epoxy composites were studied by using SEM,vector network analyzer and universal material testing,respectively.The reflection coefficient of the composites were calculated by the measured complex permittivity and permeability in the X-band(8.2-12.4 GHz)range.The optimum microwave absorption properties can be obtained when the content of CFs in the hybrid veil is 6 wt%and the thickness of the composites is 2 mm,the minimum reflection coefficient of-31.8 dB and the effective absorption bandwidth is 2.1 GHz,which is ascribed to benefitting impedance matching characteristic and dielectric loss of the carbon fiber.Simultaneously the tensile strength and modulus can achieve 104.0 and 2.98GPa,demonstrating that the CFs/GFs hybrid epoxy composites can be a promising candidate of microwave absorbing materials with high mechanical properties. 展开更多
关键词 microwave absorption fiber reinforced composites PAPERMAKING carbon fiber
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Boosting Capacitive Deionization Performance of Commercial Carbon Fibers Cloth via Structural Regulation Based on Catalytic-Etching Effect 被引量:1
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作者 Chunjie Zhang Dong Wang +5 位作者 Zhen Wang Guangshuai Zhang Zhichao Liu Jie Wu Jin Hu Guangwu Wen 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第1期242-252,共11页
Monolithic carbon electrodes with robust mechanical integrity and porous architecture are highly desired for capacitive deionization but remain challenging.Owing to the excellent mechanical strength and electroconduct... Monolithic carbon electrodes with robust mechanical integrity and porous architecture are highly desired for capacitive deionization but remain challenging.Owing to the excellent mechanical strength and electroconductivity,commercial carbon fibers cloth demonstrates great potential as high-performance electrodes for ions storage.Despite this,its direct application on capacitive deionization is rarely reported in terms of limited pore structure and natural hydrophobicity.Herein,a powerful metal-organic framework-engaged structural regulation strategy is developed to boost the desalination properties of carbon fibers.The obtained porous carbon fibers features hierarchical porous structure and hydrophilic surface providing abundant ions-accessible sites,and continuous graphitized carbon core ensuring rapid electrons transport.The catalytic-etching mechanism involving oxidation of Co and subsequent carbonthermal reduction is proposed and highly relies on annealing temperature and holding time.When directly evaluated as a current collector-free capacitive deionization electrode,the porous carbon fibers demonstrates much superior desalination capability than pristine carbon fibers,and remarkable cyclic stability up to 20 h with negligible degeneration.Particularly,the PCF-1000 showcases the highest areal salt adsorption capacity of 0.037 mg cm^(−2) among carbon microfibers.Moreover,monolithic porous carbon fibers-carbon nanotubes with increased active sites and good structural integrity by in-situ growth of carbon nanotubes are further fabricated to enhance the desalination performance(0.051 mg cm^(−2)).This work demonstrates the great potential of carbon fibers in constructing high-efficient and robust monolithic electrode for capacitive deionization. 展开更多
关键词 capacitive deionization carbon fibers cloth catalytic-etching monolithic electrodes
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Mechanical Property Evaluation of Glass-carbon-durian Skin Fiber Reinforced Polylactic Acid Composites
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作者 Boonsin Nadondu Prayoon Surin Jakawat Deeying 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第1期244-247,共4页
The main objective of this work was to study and develop composite materials by experiments with mixtures of synthetic(glass fiber, carbon fiber) and natural fiber(durian skin fiber) reinforcements on a polylactic aci... The main objective of this work was to study and develop composite materials by experiments with mixtures of synthetic(glass fiber, carbon fiber) and natural fiber(durian skin fiber) reinforcements on a polylactic acid(PLA) matrix composite, because of its excellent mechanical properties. Durian skin fiber(DSF) is a natural waste throughout Thailand, and an alternative to recycling is to realize its potential as a new reinforcement through mixing and the injection molding processes. The flexural strength(σ_(F)) and flexural modulus(E_(F)) of the composites from specimens showed a maximum value by content of durian skin fiber at 10 wt%, for good performance relative to particle dispersion between the matrix and the fiber, and showed a minimum value by content of durian skin fiber at 20 wt%, because the reinforcement material affects the mechanical properties in the experiments. 展开更多
关键词 glass fiber carbon fiber durian skin fiber polylactic acid mechanical properties
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Optimization of Photo-Fenton Catalyst Preparation Based Bamboo Carbon Fiber by Response Surface Methodology
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作者 Yizhang Wang Zhaoyang Yu +5 位作者 Jinbo Hu Shanshan Chang Yuan Liu Ting Li Gonggang Liu Xiaodong(Alice)Wang 《Journal of Renewable Materials》 SCIE EI 2023年第1期147-165,共19页
In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based cat... In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based catalyst was excellent and its optimal preparation process was also explored by response surface methodology.First,bamboo-carbon fiber was selected as the photo-Fenton catalyst carrier.Subsequently,the surface of the car-bon fiber was modified,with which dopamine,nano-Fe_(3)O_(4) and nano-TiO_(2) were successively loaded by hydro-thermal method.After the single factor tests,four factors including dopamine concentration,ferric chloride mass,P25 titanium dioxide mass and liquid-solid ratio were selected as the characteristic values.The degradation efficiency of photo-Fenton catalyst to methylene blue(MB)solution was treated as the response value.After the analysis of the response surface optimization,it was shown that the significance sequence of the selected 4 factors in terms of the MB degradation efficiency was arranged as follows:dopamine concentration>liquid-solid ratio>P25 titanium dioxide quality>ferric chloride quality.The optimal process parameters of fiber-carbon catalyst were affirmed as follows:the 1.7 mg/mL concentration of dopamine,the 1.2 g mass of ferric chloride,the 0.2 g mass of P25 titanium dioxide and the liquid-solid ratio of 170 mL/g.The experiment-measured average MB degra-dation efficiency performed by the optimized catalyst was 99.3%,which was nearly similar to the model-predicted value of 98.9%.It showed that the prediction model and response surface model were accurate and reliable.The results from response surface optimization could provide a good reference to design bamboo-based Fenton-like catalyst with excellent catalytic performance. 展开更多
关键词 Photo-fenton catalysis bamboo fiber carbon fiber response surface optimization methylene blue
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Tetris-Style Stacking Process to Tailor the Orientation of Carbon Fiber Scaffolds for Efficient Heat Dissipation
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作者 Shida Han Yuan Ji +4 位作者 Qi Zhang Hong Wu Shaoyun Guo Jianhui Qiu Fengshun Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第9期310-324,共15页
As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the hea... As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the heat toward heat sink for highly efficient heat dissipation.Pitch-based carbon fiber(CF)with ultrahigh axial thermal conductivity and aspect ratios exhibits great potential for developing thermally conductive composites as TIMs.However,it is still hard to fabricate composites with aligned carbon fiber in a general approach to fully utilize its excellent axial thermal conductivity in specific direction.Here,three types of CF scaffolds with different oriented structure were developed via magnetic field-assisted Tetris-style stacking and carbonization process.By regulating the magnetic field direction and initial stacking density,the self-supporting CF scaffolds with horizontally aligned(HCS),diagonally aligned and vertically aligned(VCS)fibers were constructed.After embedding the polydimethylsiloxane(PDMS),the three composites exhibited unique heat transfer properties,and the HCS/PDMS and VCS/PDMS composites presented a high thermal conductivity of 42.18 and 45.01 W m^(−1)K^(−1)in fiber alignment direction,respectively,which were about 209 and 224 times higher than that of PDMS.The excellent thermal conductivity is mainly ascribed that the oriented CF scaffolds construct effective phonon transport pathway in the matrix.In addition,fishbone-shaped CF scaffold was also produced by multiple stacking and carbonization process,and the prepared composites exhibited a controlled heat transfer path,which can allow more versatility in the design of thermal management system. 展开更多
关键词 carbon fiber Magnetic field Thermal management Thermally conductive composites
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Influence of recycled carbon fiber addition on the microstructure and creep response of extruded AZ91 magnesium alloy
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作者 Sinan Kandemir Jan Bohlen Hajo Dieringa 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第7期2518-2529,共12页
In this study,the recycled short carbon fiber(CF)-reinforced magnesium matrix composites were fabricated using a combination of stir casting and hot extrusion.The objective was to investigate the impact of CF content(... In this study,the recycled short carbon fiber(CF)-reinforced magnesium matrix composites were fabricated using a combination of stir casting and hot extrusion.The objective was to investigate the impact of CF content(2.5 and 5.0 wt.%)and fiber length(100 and 500μm)on the microstructure,mechanical properties,and creep behavior of AZ91 alloy matrix.The microstructural analysis revealed that the CFs aligned in the extrusion direction resulted in grain and intermetallic refinement within the alloy.In comparison to the unreinforced AZ91 alloy,the composites with 2.5 wt.%CF exhibited an increase in hardness by 16-20%and yield strength by 5-15%,depending on the fiber length,while experiencing a reduction in ductility.When the reinforcement content was increased from 2.5 to 5.0 wt.%,strength values exhibited fluctuations and decline,accompanied by decreased ductility.These divergent outcomes were discussed in relation to fiber length,clustering tendency due to higher reinforcement content,and the presence of interfacial products with micro-cracks at the CF-matrix interface.Tensile creep tests indicated that CFs did not enhance the creep resistance of extruded AZ91 alloy,suggesting that grain boundary sliding is likely the dominant deformation mechanism during creep. 展开更多
关键词 Metal matrix composites Magnesium alloys Recycled carbon fiber Extrusion Microstructure Mechanical properties CREEP
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High-sensitivity phase imaging eddy current magneto-optical system for carbon fiber reinforced polymers detection
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作者 Jiang-Shan Ai Quan Zhou +5 位作者 Yi-Ping Liang Chun-Rui Feng Bing Long Li-Bing Bai Yong-Gang Wang Chao Ren 《Journal of Electronic Science and Technology》 EI CSCD 2023年第4期48-59,共12页
This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems... This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems, the proposed system employs a fixed position excitation coil while enabling the detection point to move within the detection region. This configuration effectively mitigates the interference caused by the lift-off effect, which is commonly observed in systems with moving excitation coils. Correspondingly, the relationship between the defect characteristics (orientation and position) and the surface vertical magnetic field distribution (amplitude and phase) is studied in detail by theoretical analysis and numerical simulations. Experiments conducted on woven CFRP plates demonstrate that the designed PI-ECMO system is capable of effectively detecting both surface and internal cracks, as well as impact defects. The excitation current is significantly reduced compared with traditional eddy current magneto-optical (ECMO) systems. 展开更多
关键词 carbon fiber reinforced polymers Defect detection Eddy current magneto-optical Nondestructive testing Phase imaging
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Assessment of the Mechanical Properties of Carbon-Fiber Heating Cables in Snow and Ice Melting Applications
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作者 Zhiyong Yang Jiacheng Zhang +3 位作者 Henglin Xiao Zhi Chen Tian Bao Yin Liu 《Fluid Dynamics & Materials Processing》 EI 2023年第9期2267-2288,共22页
The use of carbon-fiber heating cables(CFHC)to achieve effective melting of snow and ice deposited on roads is a method used worldwide.In this study,tensile and compressive tests have been conducted to analyze the mech... The use of carbon-fiber heating cables(CFHC)to achieve effective melting of snow and ice deposited on roads is a method used worldwide.In this study,tensile and compressive tests have been conducted to analyze the mechan-ical properties of the CFHC and assess whether the maximum tensile and compressive strengths can meet the pavement design specifications.In order to study the aging produced by multiple cycles of heating and cooling,in particular,the CFHC was repeatedly heated in a cold chamber with an ambient temperature ranging between-20℃ and+40℃.Moreover,to evaluate how the strength of the pavement is affected by its presence,the CFHC was embedded at different depths and concrete blocks with different curing ages were subjected to relevant com-pression and splitting tensile tests.Numerical simulations based on the ANSYS software have also been performed and compared with the outcomes of the static loading tests.The results show that the CFHC embedded in the concrete does not affect the compressive splitting tensile strengths of the pavement.Overall,the CFHC meets the conditions required for continued use in road ice melting applications. 展开更多
关键词 carbon fiber cable snow and ice melting concrete pavement compressive strength splitting tensile strength
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