Recently, the textile industry has increasingly advocated for natural resource-based healthcare textiles. This research presents a facile and eco-friendly approach to developing durable antibacterial polyester fabrics...Recently, the textile industry has increasingly advocated for natural resource-based healthcare textiles. This research presents a facile and eco-friendly approach to developing durable antibacterial polyester fabrics. Polyester fabric was first subjected to an alkaline hydrolysis to impart hydroxyl groups on the fiber surface. A natural antibacterial agent, betaine, was then covalently bonded to the hydrolyzed polyester fiber surface through esterification. XPS, Raman, SEM, and Wicking measurements were carried out to verify the esterification reaction. Antibacterial tests confirmed that betaine treatment grafted polyester fabrics revealed a remarkable antibacterial effect with inhibition rates > 99.9% against both E. coli and S. aureus and still remained inhibition rates of up to 91.5% against both bacteria after home washing for 20 cycles. Moreover, the modification significantly increased the capillary effect of polyester fabric but did not cause apparent adverse effects on the fabric’s hand or tensile strength. Overall, this grafting strategy for durable, antibacterial polyester fabric represents a significant practicality in the textile industry.展开更多
Without any preprocessing,polyester fabric has lower ability to hold on water and inks due to the smooth morphology of polyester fibers. Therefore, patterns directly printed with pigment inks have poor color yields an...Without any preprocessing,polyester fabric has lower ability to hold on water and inks due to the smooth morphology of polyester fibers. Therefore, patterns directly printed with pigment inks have poor color yields and bleed easily. Pretreatments of polyester fabric were carried out with atmospheric air plasma under different experimental conditions. After plasma treatment the samples were printed with magenta pigment ink. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analyses indicated that the enhanced color performance was mainly contributed by not only the etching effect but also oxygen-containing polar groups induced onto fiber surfaces through plasma treatment. Thereby the surface modification of polyester fabrics using atmospheric-pressure air plasma offers a potential way to fabric pretreatment for pigment inkjet printing with the advantages of environmental friendly and energy saving over traditional pretreatment methods.展开更多
The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. Tbe effects of parameters such as tbe concentration of TiO2 solution, pH valu...The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. Tbe effects of parameters such as tbe concentration of TiO2 solution, pH value, and drying temperature on the photocatalytic degradation of the formaldehyde gas were also studied. The results showed that the photodegradation efficiency of the formaldehyde gas increased rapidly with the increasing of the concentration of TiO2 solution up to 15g/L, but when the concentration was in excess of 15g/L, the photodegradation efficiency decreased gradually and fluctuated due to light obstruction and disperse state of TiO2. Adjusting the pH value in the solution, the efficiency of photocatalytic degradation of the formaldehyde gas could be improved. The mechanisms of the reaction and the role of the additives were also investigated. After 42hours, TiO2/ polyester non-woven fabric showed no significant loss of the photocatalytic activity.展开更多
This study intended to develop a healthy and environmentally friendly super-hydrophobic PET polyester textile fabric using a specific Fluoro Silane finish(SHF).A novel SHF was prepared and applied on a polyester fabri...This study intended to develop a healthy and environmentally friendly super-hydrophobic PET polyester textile fabric using a specific Fluoro Silane finish(SHF).A novel SHF was prepared and applied on a polyester fabric using a pad-dry-cure method.The finished fabric was evaluated for the degree of hydrophobicity,durability and stain repellence.The finished fabric exhibited static water contact angle greater than 170o and received 90 AATCC(4 ISO)rating that is recognized as super-hydrophobicity and this property was maintained even after a 50,000-cycle abrasion test.FTIR analysis identified the characteristic peaks related to Si-O-Si and C-F asymmetric stretching bands of the finish on the fabric indicating a robust attachment on the fabric.Finished fabric did not show any change in appearance or tactile characteristics of the fabric.展开更多
The electremagnetic radicalization has become more serious. The shielding effectiveness of polyester fabrics with different inlaid distance of parallel metal fibres to electromagnetic wave was studied in this paper on...The electremagnetic radicalization has become more serious. The shielding effectiveness of polyester fabrics with different inlaid distance of parallel metal fibres to electromagnetic wave was studied in this paper on special instrument made by ourselves. The results of test show that the fabric with different inlaid distances of metal fibres and the testing angle between electric field plane and parallel metal fibres of have obvious effect on the shielding effectiveness of electromagnetic wave.展开更多
MIL-53(Fe) was successfully prepared and deposited on the surface carboxylated polyester(PET) fiber by an optimized conventional solvothermal or industrialized high temperature pressure exhaustion(HTPE) process to dev...MIL-53(Fe) was successfully prepared and deposited on the surface carboxylated polyester(PET) fiber by an optimized conventional solvothermal or industrialized high temperature pressure exhaustion(HTPE) process to develop a PET fiber supported MIL-53(Fe) photocatalyst(MIL-Fe@PET) for the degradation of polyvinyl alcohol(PVA) in water under light emitting diode(LED) visible irradiation. On the basis of several characterizations, MIL-Fe@PET was tested for the photocalytic ability and degradation mechanism. It was found that temperature elevation significantly enhanced the formation and deposition of MIL-53(Fe) with better photocatalytic activity. However, higher temperature than 130℃ was not in favor of its photocatalytic activity. Increasing the number of surface carboxyl groups of the modified PET fiber could cause a liner improvement in MIL-53(Fe) loading content and photocatalytic ability. High visible irradiation intensity also dramatically increased photocatalytic ability and PVA degradation efficiency of MIL-Fe@PET. Na_(2)S_(2)O_(8) was used to replace H_(2)O_(2) as electron acceptor for further promoting PVA degradation in this system. MIL-Fe@PET prepared by HTPE process showed higher MIL-53(Fe) loading content and slightly lower PVA degradation efficiency than that prepared by solvothermal process at the same conditions. These findings provided a practical strategy for the large-scale production of the supported MIL-53(Fe) as a photocatalyst in the future.展开更多
Superior long-term anchorage of the bridging stent-grafts from the fenestrated main body endograft could be achieved with the addition of a flared cuff,capable of preventing the previously observed fabric fraying arou...Superior long-term anchorage of the bridging stent-grafts from the fenestrated main body endograft could be achieved with the addition of a flared cuff,capable of preventing the previously observed fabric fraying around the fenestration as a result of the balloon angioplasty of the seal zone.This novel stent cuff design will also facilitate more complete biointegration of the devices,eliminate the hemodynamic variation as well as significantly reduce the possibility of a Type III endoleak.The feasibility of this concept is demonstrated by observations made from in-situ tests performed in a Beta endograft design.Flared cuffs made of poly(ε-caprolactone)supported with a weft-knitted polyester structure can be manufactured with various configurations to optimize the transition from the main body of the endograft,thus preventing the currently marketed designs’hemodynamic perturbation while also promoting endograft biointegration.This concept represents an evolution in branch graft design,which may enhance the long-term durability of customized fenestrations and open new applications for in-vivo graft fenestration in the near future.Further ongoing investigation to optimize its structure,X-ray opacity,fixation to the flared stent,and material biocompatibility are still required to build upon this concept’s proof.展开更多
文摘Recently, the textile industry has increasingly advocated for natural resource-based healthcare textiles. This research presents a facile and eco-friendly approach to developing durable antibacterial polyester fabrics. Polyester fabric was first subjected to an alkaline hydrolysis to impart hydroxyl groups on the fiber surface. A natural antibacterial agent, betaine, was then covalently bonded to the hydrolyzed polyester fiber surface through esterification. XPS, Raman, SEM, and Wicking measurements were carried out to verify the esterification reaction. Antibacterial tests confirmed that betaine treatment grafted polyester fabrics revealed a remarkable antibacterial effect with inhibition rates > 99.9% against both E. coli and S. aureus and still remained inhibition rates of up to 91.5% against both bacteria after home washing for 20 cycles. Moreover, the modification significantly increased the capillary effect of polyester fabric but did not cause apparent adverse effects on the fabric’s hand or tensile strength. Overall, this grafting strategy for durable, antibacterial polyester fabric represents a significant practicality in the textile industry.
基金New Century Excellent Talents of China ( NCET,No.040495)National Natural Science Foundation of China(NSFC, No.20474025)+1 种基金National Key Technology R&DProgram,China (No.2007BAE40B01)Innovative Research Team of Jiangnan University,China
文摘Without any preprocessing,polyester fabric has lower ability to hold on water and inks due to the smooth morphology of polyester fibers. Therefore, patterns directly printed with pigment inks have poor color yields and bleed easily. Pretreatments of polyester fabric were carried out with atmospheric air plasma under different experimental conditions. After plasma treatment the samples were printed with magenta pigment ink. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analyses indicated that the enhanced color performance was mainly contributed by not only the etching effect but also oxygen-containing polar groups induced onto fiber surfaces through plasma treatment. Thereby the surface modification of polyester fabrics using atmospheric-pressure air plasma offers a potential way to fabric pretreatment for pigment inkjet printing with the advantages of environmental friendly and energy saving over traditional pretreatment methods.
文摘The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. Tbe effects of parameters such as tbe concentration of TiO2 solution, pH value, and drying temperature on the photocatalytic degradation of the formaldehyde gas were also studied. The results showed that the photodegradation efficiency of the formaldehyde gas increased rapidly with the increasing of the concentration of TiO2 solution up to 15g/L, but when the concentration was in excess of 15g/L, the photodegradation efficiency decreased gradually and fluctuated due to light obstruction and disperse state of TiO2. Adjusting the pH value in the solution, the efficiency of photocatalytic degradation of the formaldehyde gas could be improved. The mechanisms of the reaction and the role of the additives were also investigated. After 42hours, TiO2/ polyester non-woven fabric showed no significant loss of the photocatalytic activity.
文摘This study intended to develop a healthy and environmentally friendly super-hydrophobic PET polyester textile fabric using a specific Fluoro Silane finish(SHF).A novel SHF was prepared and applied on a polyester fabric using a pad-dry-cure method.The finished fabric was evaluated for the degree of hydrophobicity,durability and stain repellence.The finished fabric exhibited static water contact angle greater than 170o and received 90 AATCC(4 ISO)rating that is recognized as super-hydrophobicity and this property was maintained even after a 50,000-cycle abrasion test.FTIR analysis identified the characteristic peaks related to Si-O-Si and C-F asymmetric stretching bands of the finish on the fabric indicating a robust attachment on the fabric.Finished fabric did not show any change in appearance or tactile characteristics of the fabric.
基金This study is supported by Shaanxi Provincial Laboratory of Functional Textiles and Academy Laboratory of Xi’an University of Engineer-ing Science and Technology in Xi’an city ,P.R.Chian
文摘The electremagnetic radicalization has become more serious. The shielding effectiveness of polyester fabrics with different inlaid distance of parallel metal fibres to electromagnetic wave was studied in this paper on special instrument made by ourselves. The results of test show that the fabric with different inlaid distances of metal fibres and the testing angle between electric field plane and parallel metal fibres of have obvious effect on the shielding effectiveness of electromagnetic wave.
基金supported by Innovation&Pioneering Talents Plan of Jiangsu Province(No.2015-340)。
文摘MIL-53(Fe) was successfully prepared and deposited on the surface carboxylated polyester(PET) fiber by an optimized conventional solvothermal or industrialized high temperature pressure exhaustion(HTPE) process to develop a PET fiber supported MIL-53(Fe) photocatalyst(MIL-Fe@PET) for the degradation of polyvinyl alcohol(PVA) in water under light emitting diode(LED) visible irradiation. On the basis of several characterizations, MIL-Fe@PET was tested for the photocalytic ability and degradation mechanism. It was found that temperature elevation significantly enhanced the formation and deposition of MIL-53(Fe) with better photocatalytic activity. However, higher temperature than 130℃ was not in favor of its photocatalytic activity. Increasing the number of surface carboxyl groups of the modified PET fiber could cause a liner improvement in MIL-53(Fe) loading content and photocatalytic ability. High visible irradiation intensity also dramatically increased photocatalytic ability and PVA degradation efficiency of MIL-Fe@PET. Na_(2)S_(2)O_(8) was used to replace H_(2)O_(2) as electron acceptor for further promoting PVA degradation in this system. MIL-Fe@PET prepared by HTPE process showed higher MIL-53(Fe) loading content and slightly lower PVA degradation efficiency than that prepared by solvothermal process at the same conditions. These findings provided a practical strategy for the large-scale production of the supported MIL-53(Fe) as a photocatalyst in the future.
基金This work was supported by“the Fundamental Research Funds for the Central Universities”(2232019D3-16)(China)the 111 Project 2.0“Biomedical Textile Materials Science and Technology”(B07024)(China)+3 种基金the Shanghai Science and Technology Support Project(18441902600)(China)the Engineering Research Center of Technical Textiles Ministry of Education(China)the Department of Surgery at Laval University(Quebec,Canada)the Fonds de Recherche de chirurgie vasculaire of the CHU(Quebec,Canada).The generous gift of device,by Medtronic and Vascutek is greatly acknowledged.The authors extend their appreciation to Boyin Qin,Yvan Douville,Pascal Rheaume,and Raymond Labbe.
文摘Superior long-term anchorage of the bridging stent-grafts from the fenestrated main body endograft could be achieved with the addition of a flared cuff,capable of preventing the previously observed fabric fraying around the fenestration as a result of the balloon angioplasty of the seal zone.This novel stent cuff design will also facilitate more complete biointegration of the devices,eliminate the hemodynamic variation as well as significantly reduce the possibility of a Type III endoleak.The feasibility of this concept is demonstrated by observations made from in-situ tests performed in a Beta endograft design.Flared cuffs made of poly(ε-caprolactone)supported with a weft-knitted polyester structure can be manufactured with various configurations to optimize the transition from the main body of the endograft,thus preventing the currently marketed designs’hemodynamic perturbation while also promoting endograft biointegration.This concept represents an evolution in branch graft design,which may enhance the long-term durability of customized fenestrations and open new applications for in-vivo graft fenestration in the near future.Further ongoing investigation to optimize its structure,X-ray opacity,fixation to the flared stent,and material biocompatibility are still required to build upon this concept’s proof.