A simple electrochemical sensor for dopamine detection, is based on molecularly imprinted and electropolymerized over-oxidized polypyrrole (OPPy). The MIP-based electrode is obtained by electrocopolymerization of pyrr...A simple electrochemical sensor for dopamine detection, is based on molecularly imprinted and electropolymerized over-oxidized polypyrrole (OPPy). The MIP-based electrode is obtained by electrocopolymerization of pyrrole (0.1 M) in the presence of the template molecular (dopamine, DA) (10<sup>-3</sup> M). The square wave voltammetry (SWV) is used for the detection of dopamine in buffer solution. The current peak obtained at the MIP electrode was proportional to the logarithm of the DA concentration in the range of 10<sup>-11</sup> to 5 × 10<sup>-8</sup> M with a detection limit of 10<sup>-11</sup> M. The proposed sensor was used for the detection of DA in spiked blood serum, satisfactory results were obtained.展开更多
Lithium/polypyrrole （Li/PPy） batteries were fabricated using lithium sheet as cathode, PPy as anode, microporous membrane polypropylene/polyethylene/polypropylene （PP/PE/PP） composite as separator and LiPF6/ethyle...Lithium/polypyrrole （Li/PPy） batteries were fabricated using lithium sheet as cathode, PPy as anode, microporous membrane polypropylene/polyethylene/polypropylene （PP/PE/PP） composite as separator and LiPF6/ethylene carbonate-dimethyl carbonate-methyl ethyl carbonate （EC-DMC-EMC） as electrolyte. Polypyrrole was prepared by chemical polymerization. Certain fundamental electrochemical performances were investigated. Properties of the batteries were characterized and tested by SEM, galvanostatic charge/discharge tests, cyclic voltammetry （CV）, and a.c. impedance spectroscopy. The influences of separator, morphology, and conductivity of PPy anode, cold-molded pressure, and electric current on the performances of the batteries were studied. Using PP/PE/PP membranes as separator, the battery showed good storage stability and cycling property. The conductivity of materials rather than morphology affected the behavior of the battery. The higher the conductivity, the better performances the cells had. Proper cold-molded pressure 20 MPa of the anode pellet would make the properties of the cells good and the fitted charge/discharge current was 0.1 mA. The cells showed excellent performance with 97%-100% coulombic efficiency. The highest discharge capacity of 95.2 mAh/g was obtained.展开更多
文摘A simple electrochemical sensor for dopamine detection, is based on molecularly imprinted and electropolymerized over-oxidized polypyrrole (OPPy). The MIP-based electrode is obtained by electrocopolymerization of pyrrole (0.1 M) in the presence of the template molecular (dopamine, DA) (10<sup>-3</sup> M). The square wave voltammetry (SWV) is used for the detection of dopamine in buffer solution. The current peak obtained at the MIP electrode was proportional to the logarithm of the DA concentration in the range of 10<sup>-11</sup> to 5 × 10<sup>-8</sup> M with a detection limit of 10<sup>-11</sup> M. The proposed sensor was used for the detection of DA in spiked blood serum, satisfactory results were obtained.
基金the Foundation of Science and Technology Department of Heibei Province (No. 05547003D-4)the Foundation of the Education Department of Hebei Province, China (No. 2005356).
文摘Lithium/polypyrrole （Li/PPy） batteries were fabricated using lithium sheet as cathode, PPy as anode, microporous membrane polypropylene/polyethylene/polypropylene （PP/PE/PP） composite as separator and LiPF6/ethylene carbonate-dimethyl carbonate-methyl ethyl carbonate （EC-DMC-EMC） as electrolyte. Polypyrrole was prepared by chemical polymerization. Certain fundamental electrochemical performances were investigated. Properties of the batteries were characterized and tested by SEM, galvanostatic charge/discharge tests, cyclic voltammetry （CV）, and a.c. impedance spectroscopy. The influences of separator, morphology, and conductivity of PPy anode, cold-molded pressure, and electric current on the performances of the batteries were studied. Using PP/PE/PP membranes as separator, the battery showed good storage stability and cycling property. The conductivity of materials rather than morphology affected the behavior of the battery. The higher the conductivity, the better performances the cells had. Proper cold-molded pressure 20 MPa of the anode pellet would make the properties of the cells good and the fitted charge/discharge current was 0.1 mA. The cells showed excellent performance with 97%-100% coulombic efficiency. The highest discharge capacity of 95.2 mAh/g was obtained.
