Quasi-solid-state polymer plastic crystal electrolyte for subzero lithium-ion batteries

Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)have attracted considerable attention as solid-state electrolytes owing to their high ionic conductivities similar to those of liquid electrolytes,excellent contacts with the electrodes,and good mechanic properties.As a crucial property of a solid-state electrolyte,the ionic conductivity of the PPCE directly depends on the interactions between the constituent parts including the polymer,lithium salt,and SN.A few studies have focused on the effects of polymer–lithium–salt and polymer–SN interactions on the PPCE ionic conductivity.Nevertheless,the impact of the lithium–salt–SN combination on the PPCE ionic conductivity has not been analyzed.In particular,tuning of the lithium-salt–SN interaction to fabricate a subzero PPCE with a high low-temperature ionic conductivity has not been reported.In this study,we design and fabricate five PPCE membranes with different weight ratios of Li N(SO2 CF3)2(Li TFSI)and SN to investigate the effect of the Li TFSI–SN interaction on the PPCE ionic conductivity.The ionic conductivities of the five PPCEs are investigated in the temperature range of–20 to 60°C by electro-chemical impedance spectroscopy.The interaction is analyzed by Fourier-transform infrared spectroscopy,Raman spectroscopy,and differential scanning calorimetry.The Li TFSI–SN interaction significantly influences the melting point of the PPCE,dissociation of the Li TFSI salt,and thus the PPCE ionic conductivity.By tuning the Li TFSI–SN interaction,a subzero workable PPCE membrane having an excellent low-temperature ionic conductivity(6×10-4 S cm–1 at 0°C)is obtained.The electro-chemical performance of the optimal PPCE is evaluated by using a Li Co O2/PPCE/Li4 Ti5 O12 cell,which confirms the application feasibility of the proposed quasisolid-state electrolyte in subzero workable lithium-ion batteries.

Humanoid Based Intelligence Control Strategy of Plastic Cement Die Press Work-Piece Forming Process for Polymer Plastics

The plastic cement belongs to a sort of polymer material, the chemical composition is very complex, and the plastic cement work-piece is generally manufactured by die press forming. Aimed at being difficult to control in parameters of forming process, the paper explored the humanoid based intelligence control strategy. In the paper, it made the anatomy in control puzzle resulted in uncertainty such as chemical component of plastic cement etc., summarized up the characteristic of cybernetics in forming process, researched on the humanoid based intelligence control strategy, and constructed the control algorithm of forming process in plastic cement work-piece. Taking the process experiment of temperature and pressure control as an example, it validated the good dynamic and static control quality through simulation of control algorithm constructed in this paper. The experimental results show that the control algorithm explored in this paper is reasonably available.

Damage Detection for CFRP Based on Planar Electrical Capacitance Tomography

Due to the widespread use of carbon fiber reinforced polymer/plastic(CFRP),the nondestructive structural health monitoring for CFRP is playing an increasingly essential role.As a nonrad iative,noninvasive and nondestructive detection technique,planar electrical capacitance tomography(PECT)electrodes array is employed in this paper to reconstruct the damage image according to the calculated dielectric constant changes.The shape and duty ratio of PECT electro-des are optimized according to the relations between sensitivity distribution and the dielectric constant of different anisotropic degrees.The sensitivity matrix of optimized PECT sensor is more uniform as the result shows,because the sensitiv-ity of insensitivity area can be increased by adding rotation of optimized electro-des.The reconstructed image qualities due to different PECT arrays and different damage locations are investigated at last.The simulation results indicate that:PECT can be used to detect the surface damage of CFRP;the sensitivity matrix of PECT for CFRP is highly relevant with the degree of anisotropic dielectric con-stant;the rotatable PECT sensor with rotation has better performance in unifor-mity of sensitivity;for different damage locations,the rotatable sensor with rotation has better image quality in most cases.

Recycling and Upgrading Utilization of Polymer Plastics

Due to the current situation of massive waste consumption and accumulation,the recycling and upgrading utilization of polymer materials is an effective technology to solve environmental pollution.In this work,the recycling and upgrading methods of polymers are summarized,and the latest progress in polymer upcycling is discussed from the perspective of upgrading materials.The common polymer recovery methods,including mechanical recovery,chemical recovery,biocatalysis,and photocatalytic recovery,are discussed based on their mechanism and industrialized application.The upgrading products of polymers are divided into monomers,fuels and fine chemicals.The challenges and prospects of polymer degradation technology are discussed.

Flexural Behavior of FRP-Reinforced Concrete Composite Member

Concrete Filled FRP （Reinforced Polymeric Plastic） Tubes （CFFT） and Reinforced Concrete Filled FRP Tubes （RCFFT） are known to have the capability to enhance structural performance in terms of structural stability, ductility, as well as chemical resistance when compared with conventional concrete members. In this study, the authors evaluate the structural performance of the CFFT and the RCFFT through flexural tests for the purpose of applying the members as flexural ones. Moreover, the compressive behavior of the CFFT and the RCFFT members was investigated to examine their confinement effects. Based on the experimental and analytical results of the compressive behavior of the members, equations for estimating the ultimate compressive strengths of the CFFT and the RCFFT were proposed. In addition, the degree of improvement on the flexural performance of the RCFFT member strengthened by the FRP was analyzed from the flexural tests.

Flexural Experimental Study on Continuous Reinforced Concrete Beams Strengthened with Basalt Fiber Reinforced Polymer/Plastic

This paper discusses a new fibrous composite known as continuous basalt fiber reinforced polymer /plastic(BFRP).Compared with other fiber reinforced polymer/plastic,BFRP has many advantages,such as ductility,high thermal resistance,corrosion resistance and economic cost.To test mechanical properties and failure modes of flexural members strengthened with BFRP,flexural experiment is conducted on four two-span T-section continuous beams strengthened with BFRP and one un-strengthened comparative beam.The experimental result shows that the strengthened beams perform remarkably in terms of yield strength,ultimate strength and ductility.BFRP has good prospects in retrofitting and strengthening of concrete structures which require good ductility and corrosion resistance.