Exploring the effect of cooling rate on non-isothermal crystallization of copolymer polypropylene by fast scanning calorimetry

Polypropylene is commonly used as a binder for ceramic injection molding,and rapid cooling is often encountered during processing.However,the crystallization behavior of polypropylene shows a strong dependence on cooling rate due to its semi-crystalline characteristics.Therefore,the influence of cooling rate on the quality of final product cannot be ignored.In this study,the fast differential scanning calorimetry(FSC)test was performed to study the influence of cooling rate on the non-isothermal crystallization behavior and non-isothermal crystallization kinetics of a copolymer polypropylene(PP BC03B).The results show that the crystallization temperatures and crystallinity decrease as the cooling rate increases.In addition,two exothermic peaks occur when cooling rate ranges from 30 to 300 K·s^(-1),indicating the formation of another crystal phase.Avrami,Ozawa and Mo equations were used to explore the non-isothermal crystallization kinetics,and it can be concluded that the Mo method is suitable for this study.

Characterization and Modeling of Mechanical Properties of Additively Manufactured Coconut Fiber-Reinforced Polypropylene Composites

In the face of the increased global campaign to minimize the emission of greenhouse gases and the need for sustainability in manufacturing, there is a great deal of research focusing on environmentally benign and renewable materials as a substitute for synthetic and petroleum-based products. Natural fiber-reinforced polymeric composites have recently been proposed as a viable alternative to synthetic materials. The current work investigates the suitability of coconut fiber-reinforced polypropylene as a structural material. The coconut fiber-reinforced polypropylene composites were developed. Samples of coconut fiber/polypropylene (PP) composites were prepared using Fused Filament Fabrication (FFF). Tests were then conducted on the mechanical properties of the composites for different proportions of coconut fibers. The results obtained indicate that the composites loaded with 2 wt% exhibited the highest tensile and flexural strength, while the ones loaded with 3 wt% had the highest compression strength. The ultimate tensile and flexural strength at 2 wt% were determined to be 34.13 MPa and 70.47 MPa respectively. The compression strength at 3 wt% was found to be 37.88 MPa. Compared to pure polypropylene, the addition of coconut fibers increased the tensile, flexural, and compression strength of the composite. In the study, an artificial neural network model was proposed to predict the mechanical properties of polymeric composites based on the proportion of fibers. The model was found to predict data with high accuracy.

Efficient and selective removal of Pb(Ⅱ) from landfill leachate using L-serine-modified polyethylene/polypropylene nonwoven fabric synthesized via radiation grafting technique

In this study,to efficiently remove Pb(Ⅱ) from aqueous environments,a novel L-serine-modified polyethylene/polypropylene nonwoven fabric sorbent(NWF-serine)was fabricated through the radiation grafting of glycidyl methacrylate and subsequent L-serine modification.The effect of the absorbed dose was investigated in the range of 5–50 kGy.NWF-serine was characterized by Fourier transform infrared spectroscopy,thermogravimetric analysis,and scanning electron microscopy.Batch adsorption tests were conducted to investigate the influences of pH,adsorption time,temperature,initial concentration,and sorbent dosage on the Pb(Ⅱ) adsorption performance of NWF-serine.The results indicated that Pb(Ⅱ) adsorption onto NWF-serine was an endothermic process,following the pseudo-second-order kinetic model and Langmuir isotherm model.The saturated adsorption capacity was 198.1 mg/g.NWF-serine exhibited Pb(Ⅱ) removal rates of 99.8% for aqueous solutions with initial concentrations of 100 mg/L and 82.1% for landfill leachate containing competitive metal ions such as Cd,Cu,Ni,Mn,and Zn.Furthermore,NWF-serine maintained 86% of its Pb(Ⅱ) uptake after five use cycles.The coordination of the carboxyl and amino groups with Pb(Ⅱ) was confirmed using X-ray photoelectron spectroscopy and extended X-ray absorption fine structure analysis.

Effects of cement content, polypropylene fiber length and dosage on fluidity and mechanical properties of fiber-toughened cemented aeolian sand backfill

Using aeolian sand(AS)for goaf backfilling allows coordination of green mining and AS control.Cemented AS backfill(CASB)exhibits brittle fracture.Polypropylene(PP)fibers are good toughening materials.When the toughening effect of fibers is analyzed,their influence on the slurry conveying performance should also be considered.Additionally,cement affects the interactions among the hydration products,fibers,and aggregates.In this study,the effects of cement content(8wt%,9wt%,and 10wt%)and PP fiber length(6,9,and 12 mm)and dosage(0.05wt%,0.1wt%,0.15wt%,0.2wt%,and 0.25wt%)on fluidity and mechanical properties of the fibertoughened CASB(FCASB)were analyzed.The results indicated that with increases in the three aforementioned factors,the slump flow decreased,while the rheological parameters increased.Uniaxial compressive strength(UCS)increased with the increase of cement content and fiber length,and with an increase in fiber dosage,it first increased and then decreased.The strain increased with the increase of fiber dosage and length.The effect of PP fibers became more pronounced with the increase of cement content.Digital image correlation(DIC)test results showed that the addition of fibers can restrain the peeling of blocks and the expansion of fissure,and reduce the stress concentration of the FCASB.Scanning electron microscopy(SEM)test indicated that the functional mechanisms of fibers mainly involved the interactions of fibers with the hydration products and matrix and the spatial distribution of fibers.On the basis of single-factor analysis,the response surface method(RSM)was used to analyze the effects of the three aforementioned factors and their interaction terms on the UCS.The influence surface of the two-factor interaction terms and the three-dimensional scatter plot of the three-factor coupling were established.In conclusion,the response law of the FCASB properties under the effects of cement and PP fibers were obtained,which provides theoretical and engineering guidance for FCASB filling.

A Circular Economy Use of Post-Consumer Polypropylene Packaging for Low Thermal Conductive and Fire-Retardant Building Material Applications

Wastes from polypropylene(PP)packages are accumulating every year because it is one of the most widely consumed and short lifecycle products.This paper aims to develop low thermal conductive and fire-retardant materials from post-consumer PP(pPP)packages.Ammonium polyphosphate(APP)and hollow glass microsphere(HGM)were further added to improve the fire retardancy and thermal conductivity of pPP.The influence of APP and HGM on the mechanical and thermal properties,fire retardancy and thermal conductivity of pPP were investigated and compared with that of virgin PP(vPP).HGM was constantly added at 5 wt%while the content of APP was varied from 5 to 20 wt%.Experimental results showed that the tensile and flexural strengths were reduced with increasing APP concentrations.A morphological study confirmed the poor interfacial adhesion and debonding of each component during the applied load.Formulations containing APP less than 10 wt%did not show a satisfying fire retardancy rating due to the long self-extinguishing time.Further flame dipping and cotton ignition were observed for these formulations.With 15 and 20 wt%APP,the fire rating was significantly improved from no rating to V-0.The conductive heat transfer coefficient(k)was reduced by the presence of HGM.Based on these results,the formulation with 15 and 20 wt%could be used as a low k,fire-retardant building material.

表面改性剂对填充PP型滑石粉的研究

研究了滑石粉表面改性后对聚丙烯(PP)管材的影响规律。将滑石粉、聚丙烯、表面改性剂等原料在塑料混炼机上充分混合,制成复合材料,用万能试验机测试其力学性能,采用傅里叶红外变换仪及XRD等分析复合材料的微观结构及官能团。结果表明,改性滑石粉与聚丙烯很有规律的复合,微观结构分布均匀,官能团发生了较大变化,PP∶滑石粉(改性后)=1∶3的复合材料力学性能达最佳。

度伐利尤单抗联合PP化疗方案治疗Ⅲ期非小细胞肺癌患者的效果

目的:观察度伐利尤单抗联合PP化疗方案治疗Ⅲ期非小细胞肺癌(NSCLC)患者的效果。方法:回顾性分析2021年5月至2023年5月该院收治的66例Ⅲ期NSCLC患者临床资料,按治疗方案不同将其分为观察组和对照组各33例。对照组采用PP化疗方案治疗,观察组在对照组基础上联合度伐利尤单抗注射液治疗,比较两组疾病缓解率、KPS评分、癌症治疗功能评价系统-肺癌模块(FACT-L)评分、血清生化因子[Ⅳ型胶原蛋白α3(COL4A3)、G蛋白偶联受体相关分选蛋白1(GASP-1)]水平和不良反应发生率。结果:观察组疾病缓解率为60.61%,明显高于对照组的36.36%,差异有统计学意义(P<0.05);治疗后,两组KPS评分高于治疗前,且观察组高于对照组,两组FACT-L评分和血清COL4A3、GASP-1水平低于治疗前,且观察组低于对照组,差异均有统计学意义(P<0.05);治疗期间,两组腹泻、脱发、骨髓抑制、恶心等不良反应发生率比较,差异均无统计学意义(P>0.05)。结论:度伐利尤单抗联合PP化疗方案治疗Ⅲ期NSCLC患者可提高疾病缓解率和KPS评分,降低FACT-L评分及血清COL4A3、GASP-1水平,效果优于单纯PP化疗方案治疗。

枳PtrPP2C51基因克隆与非生物胁迫表达分析

克隆枳PP2C基因家族的PtrPP2C51基因,分析其在低温、高温和干旱等胁迫下的表达规律,探究其在非生物胁迫中的功能。以1年生枳苗为试材,从嫩叶克隆到PtrPP2C51基因cDNA序列,采用生物信息学方法对其进行分析,利用实时荧光定量PCR仪(qRT-PCR)检测枳苗在低温、高温和干旱(15%PEG-6000)处理下的PtrPP2C51基因表达模式。克隆获得PtrPP2C51基因编码区CDS序列长度为879 bp,编码292个氨基酸,其蛋白分子量为31.36 ku,理论等电点4.9,脂肪系数79.52,不稳定系数39.57,亲水性平均值-0.279。PtrPP2C51蛋白的二级结构中α-螺旋、β-转角、延伸链和无规则卷曲占比分别为40.07%、7.88%、18.15%和33.90%。PtrPP2C51蛋白与克里曼丁橘的PP2C蛋白在同一小分支上,亲缘关系最近。经低温(0℃)、高温(38℃)和干旱(15%PEG-6000)3种不同胁迫处理,PtrPP2C51基因的相对表达量均表现持续上调趋势,并且均在处理12 h时表达量达到最高值。PtrPP2C51基因可能参与枳的抗逆胁迫调控机制。

不同官能团修饰碳纳米管填充PP复合材料分子模拟

随着光伏发电和海上发电等新型清洁能源的迅速发展,对薄膜电容器的工作温度提出了更高的要求。然而,当前使用最泛的双向拉伸聚丙烯(BOPP)电容器薄膜在高温以上时无法胜任应用需求。基于实验与仿真的方法,对聚丙烯(PP)、碳纳米管及羟基、氨基、羧基功能化碳纳米管(CNTs-COOH)填充PP复合体系进行热重试验、玻璃化转变温度、热导率、自由体积分数和均方位移等性能的研究。结果表明,经羧基修饰的碳纳米管与PP复合后的热学性能增加效果最为显著,氨基、羟基修饰的碳纳米管体系次之。CNTs-COOH复合材料具有更优异的性能,其起始热分解温度和玻璃化转变温度分别提高了76.15℃和40.33℃,热导率较纯PP体系提高了18.27%,自由体积分数降低至17.96%。羧基的加入能够有效占据PP/CNTs复合体系中的空穴,减缓复合体系分子链段的移动和降低复合体系的均方位移,使得PP复合体系保持良好的热稳定性。研究结果可为适用于高温条件的PP电容器薄膜材料提供参考。

PPR冷热水管专用树脂性能与结构分析

分析了3种不同短期静液压性能无规共聚聚丙烯(PPR)冷热水管专用树脂(分别记为PPR-1,PPR-2,PPR-3)的相对分子质量及其分布、分子序列结构、热结晶分级、熔融温度和结晶温度等,研究了短期静液压性能与聚丙烯树脂结构组成的关联性。结果表明:3种PPR冷热水管专用树脂的熔体流动速率、相对分子质量及其分布、乙烯含量均基本一致,但共聚单体乙烯分散度和聚丙烯链规整度均存在差异。PPR-1的共聚单体乙烯分散度和聚丙烯链规整度均较低,且共聚单体乙烯更多分布在相对分子质量较小的分子链上,使材料局部强度较低,管材在高压下发生局部破坏的可能性较大,短期静液压性能较低。

RCEP与CPTPP的比较和融合之道

当前,竞争政策在自由贸易协定中的地位愈发重要,约有五分之四的自由贸易协定涉及竞争条款。发达国家对于竞争法和区域自由贸易协定中的竞争条款都具有先进性,中国作为发展中国家对于竞争条款仍处于起步阶段,因此要在研究CPTPP等发达国家竞争条款的基础上,制定和完善符合发展中国家利益的竞争政策。

基于改性PP成型的工控机电路板支撑架注射模设计

针对工控机电路板支撑架大型塑件的成型,选用了一种玻纤改性增强聚丙烯(PP)复合材料用于塑件的注射成型。模具结构为三板模结构,分3次开模打开。为保证塑件模腔充填均衡性、饱满性而设计了两个点浇口用于模腔的浇注。针对塑件二级子特征较多,特别是异型螺柱深筋位较多的特点,设计了多个局部镶件用于这些局部特征的成型,在提高局部成型镶件强度的同时,降低了这些成型件的加工难度。针对模腔局部位置排气难点,设置了多个透气镶件以增强排气。设置了锁扣机构、定距拉杆机构用于模具的开模闭模控制;设计了弹料机构用于流道废料的可靠脱模、定位机构以确保塑件的成型精度和模具工作寿命;3个滑块机构用于塑件侧壁直壁及直壁上侧孔的成型与脱模。模具结构形式合理,成型件便于加工且实用可靠,能为同类模具设计提供有益借鉴。

废弃PP纤维再生混凝土基本力学性能试验

目的 针对纤维体积掺量、长径比、再生骨料取代率等因素,探究废弃PP纤维对再生混凝土力学性能的影响,提高废弃纤维利用率。方法 以废弃PP打包带制成不同长径比的纤维作为筋材,以不同体积掺量与不同再生骨料取代率的再生混凝土混合制成11组废弃PP纤维再生混凝土试块,对其进行抗压和抗拉试验。结果 立方体抗压、抗拉强度最佳时的废弃PP纤维体积掺量为1.5%,长径比为47.85;废弃PP纤维再生混凝土的立方体抗压、抗拉强度与再生骨料取代率有关,其强度与再生骨料取代率近似呈线性关系。结论 废弃PP纤维的掺入可以提高再生混凝土的立方体抗压强度和抗拉强度。

Influence ofβ-nucleating Compound Agents on the Mechanical Properties and Crystallization Behavior of Polypropylene Random Copolymer

A novel polypropylene random(PPR)composite materials with optimized properties was developed by addingβ-nucleating compound agents(rare earth complex WBG-2 and aryl amide derivative TMB-5)and ternary compound modifier(TPE/WBG-2/CaCO_(3)).The effects of differentβ-nucleating agents and ternary compound modifier on the mechanical properties and crystallization behavior of PPR were analyzed.The results show that,compared with pure PPR materials,both WBG-2 and TMB-5 could significantly improve the impact strength of PPR.The crystallization temperature of PPR increased with the addition ofβ-nucleating agent.The modified PPR prepared with ternary compound modifier showed the most excellent comprehensive properties.

过滤吸油用PP/PE双组分熔喷非织造布的性能测试研究

以不同质量比的聚丙烯(PP)、聚乙烯(PE)为原料制得PP/PE双组分熔喷非织造布,测试分析了PP/PE双组分熔喷非织造布的性能。结果表明:PP/PE双组分熔喷非织造布的纤网呈现蓬松杂乱的三维结构,纤维直径较细,孔隙率较高;随着PE添加比例增大,PP/PE双组分熔喷非织造布的面密度和厚度增大,拉伸断裂强力、顶破强力略有下降,硬挺度下降,透气性增大;当PP/PE质量比为73时,PP/PE双组分熔喷非织造布的水接触角在129°左右,吸油倍数为18.75,20 s内吸油高度为1.7 mm,空气过滤效率为56.82%,综合性能较好,可应用于过滤、吸油等领域。

Properties of PEG/thermally modified wood flour/polypropylene (PP) composites

In order to improve the dimensional stability of wood-polymer composites, wood flour pre-treated by polyethylene glycol （PEG） at two different concentrations and then thermally treated at 140℃, was used as raw material to produce wood flour/poly- propylene （PP） composites at a wood content of 40%. The structure of modified wood flour was analyzed with a scanning electron microscope （SEM） and its effect on the physical and mechanical properties of wood flour/PP composites was evaluated. The SEM results indicated the ＂bulking＂ effect of PEG on wood flour, which resulted in reduced water uptake. The combination of PEG and heat treatment further improved the moisture resistance of the composites. However, PEG modification had a negative effect on the flexural modulus of rupture （MOR） and the modulus of elasticity （MOE）; whereas heat treatment partly compensated for this reduc- tion. For dynamic mechanical properties, PEG treatment decreased the storage modulus （E＇）. However, the heat treatment resulted in an increase orE＇ of the wood flour/PP composites, with the temperature of loss factor peaks shifting to a higher temperature.

Rotator cuff repair with an interposition polypropylene mesh:A biomechanical ovine study

BACKGROUND Chronic large to massive rotator cuff tears are difficult to treat and re-tears are common even after surgical repair.We propose using a synthetic polypropylene mesh to increase the tensile strength of rotator cuff repairs.We hypothesize that using a polypropylene mesh to bridge the repair of large rotator cuff tears will increase the ultimate failure load of the repair.AIM To investigate the mechanical properties of rotator cuff tears repaired with a polypropylene interposition graft in an ovine ex-vivo model.METHODS A 20 mm length of infraspinatus tendon was resected from fifteen fresh sheep shoulders to simulate a large tear.We used a polypropylene mesh as an interposition graft between the ends of the tendon for repair.In seven specimens,the mesh was secured to remnant tendon by continuous stitching while mattress stitches were used for eight specimens.Five specimens with an intact tendon were tested.The specimens underwent cyclic loading to determine the ultimate failure load and gap formation.RESULTS The mean gap formation after 3000 cycles was 1.67 mm in the continuous group,and 4.16 mm in the mattress group(P=0.001).The mean ultimate failure load was significantly higher at 549.2 N in the continuous group,426.4 N in the mattress group and 370 N in the intact group(P=0.003).CONCLUSION The use of a polypropylene mesh is biomechanically suitable as an interposition graft for large irreparable rotator cuff tears.

自成核行为在CF/PPS复合材料中的差异性与普适性

以半结晶高分子为基体的碳纤维增强热塑性复合材料,其基体的结晶行为将受到碳纤维表面性质与热历史的共同影响。当这种材料在经历反复加热冷却的热循环过程时,基体会产生自成核行为,其结晶过程变得更加复杂。通过三种T300级碳纤维分别制备了碳纤维增强聚苯硫醚(CF/PPS)复合材料,并探究了二次熔融温度与CF/PPS复合材料结晶行为的关系,揭示了不同碳纤维表面性质对CF/PPS复合材料自成核行为的影响。在此基础上阐明了CF/PPS复合材料基体自成核与CF异相成核的竞争关系。最后,通过冲压成型制得具有自成核行为的CF/PPS复合材料角片,验证了自成核对于CF/PPS复合材料二次热成型技术的有效性与重要性。

Preparation of Ultra-nano Talcum in Sand Mill and Its Application in the Polypropylene

The grinding of ultra-fine talcum powder and its application in a polypropylene （PP） matrix were investigated. Ultra-fine talcum powder was prepared by adjusting the grinding parameters of the physical milling process. The talcum powder exhibited polymodal distribution. The layered morphology of talcum particles in a horizontal sand mill was rarely damaged or destroyed. PP-talcum nanocomposites were prepared by melt blending using a twin-screw extruder. Nano talcum can be seen as a single particle, although it is not very apparent. The bending strength of talcum-filled PP was gradually increased by approximately 28%. The impact strength linearly decreased as the filler weight ratio increased. The overall maximum improvement in mechanical properties was recorded when the filler ratios increased from 15 wt% to 20 wt%.

Functionalization of Polypropylene with High Dielectric Properties: Applications in Electric Energy Storage

Biaxial-oriented polypropylene (BOPP) thin films are currently used as dielectrics in state-of-the-art capacitors that show many advantages, such as low energy loss and high breakdown strength, but a limited energy density ( 600 MV/m. The PP-OH dielectric demonstrates a linear reversible charge storage behavior with high releasing energy density > 7 J/cm3 (2 - 3 times of BOPP) after an applied electric field at E = 600 MV/m, without showing any significant increase of energy loss and remnant polarization at zero electric field. On the other hand, a cross-linked polypropylene (x-PP) exhibits an ε ~ 3, which is independent of a wide range of temperatures and frequencies, slim polarization loops, high breakdown strength (E = 650 MV/m), narrow breakdown distribution, and reliable energy storage capacity > 5 J/cm3 (double that of state-of-the-art BOPP capacitors), without showing any increase in energy loss.