Polyurethane foam as the most well-known absorbent materials has a suitable absorption coefficient only within a limited frequency range.The aim of this study was to improve the sound absorption coefficient of flexibl...Polyurethane foam as the most well-known absorbent materials has a suitable absorption coefficient only within a limited frequency range.The aim of this study was to improve the sound absorption coefficient of flexible polyurethane(PU)foam within the range of various frequencies using clay nanoparticles,polyacrylonitrile nanofibers,and polyvinylidene fluoride nanofibers.The response surface method was used to determine the effect of addition of nanofibers of PAN and PVDF,addition of clay nanoparticles,absorbent thickness,and air gap on the sound absorption coefficient of flexible polyurethane foam(PU)across different frequency ranges.The absorption coefficient of the samples was measured using Impedance Tubes device.Nano clay at low thicknesses as well as polyacrylonitrile nanofibers and polyvinyl fluoride nanofibers at higher thicknesses had a greater positive effect on absorption coefficient.The mean sound absorption coefficient in the composite with the highest absorption coefficient at middle and high frequencies was 0.798 and 0.75,respectively.In comparison with pure polyurethane foam with the same thickness and air gap,these values were 2.22 times at the middle frequencies and 1.47 times at high frequencies,respectively.Surface porosity rose with increasing nano clay,but decreased with increasing polyacrylonitrile nanofibers and polyvinyl fluoride nanofibers.The results indicated that the absorption coefficient was elevated with increasing the thickness and air gap.This study suggests that the use of a combination of nanoparticles and nanofibers can enhance the acoustic properties of flexible polyurethane foam.展开更多
For fragile products,packaging requires cushioning protection to prevent irreversible damage from accidental falls,transportation impacts,and other causes.The new polyurethane foam(PUF)material demonstrates superior c...For fragile products,packaging requires cushioning protection to prevent irreversible damage from accidental falls,transportation impacts,and other causes.The new polyurethane foam(PUF)material demonstrates superior cushioning and vibration isolation performance in practical applications,effectively minimizing damage from vibrations.Drop and vibration experiments were conducted on packages comprising novel PUF,expandable polyethylene,ethylene-vinyl acetate copolymer foam,and bracelets.Results verify that the new PUF material outperforms in cushioning and vibration isolation,as observed from the acceleration response.Furthermore,a random vibration analysis of a packaging unit involving different thicknesses of PUF materials and bracelets reveals the enhanced vibration isolation effect within a specific thickness range.The vibration results of the bracelet’s outer packaging align closely with finite element simulation results,validating the effectiveness of designing and optimizing the outer packaging.Through finite element simulation,deeper understanding and prediction of the bracelet’s vibration response under various conditions is achieved,facilitating optimized packaging design for better protection and vibration damping.展开更多
A facile strategy was developed to fabricate flexible polyurethane(PU)foam composites with exceptional flame retardancy.The approach involves the incorporation of graphene oxide(GO)into a silicone resin(SiR)solution,w...A facile strategy was developed to fabricate flexible polyurethane(PU)foam composites with exceptional flame retardancy.The approach involves the incorporation of graphene oxide(GO)into a silicone resin(SiR)solution,which is then deposited onto a PU foam surface via the dip-coating technique and cured.Fourier-transform infrared spectroscopy,scanning electron microscopy,and Raman spectroscopy measurements demonstrated that the SiR and GO were successfully coated onto the PU skeleton and the intrinsic porous structure of the PU foam remained intact.The effects of SiR and GO on the mechanical and thermal stability and flame retardancy of PU composites were evaluated through compression tests,thermogravimetric analysis,vertical combustion tests,and the limiting oxygen index.The measurement results revealed that the composites(PU@SiR-GO)showed superior flame retardancy and thermal and mechanical stability compared to pristine PU or PU coated with SiR alone.The mechanical and thermal stability and the flame-retardant properties of the PU composites were enhanced significantly with increasing GO content.Based on the composition,microstructure,and surface morphology of PU@SiR-GO composites before and after combustion tests,a possible flame-retardance mechanism is proposed.This work provides a simple and effective strategy for fabricating flame retardant composites with improved mechanical performance.展开更多
文摘Polyurethane foam as the most well-known absorbent materials has a suitable absorption coefficient only within a limited frequency range.The aim of this study was to improve the sound absorption coefficient of flexible polyurethane(PU)foam within the range of various frequencies using clay nanoparticles,polyacrylonitrile nanofibers,and polyvinylidene fluoride nanofibers.The response surface method was used to determine the effect of addition of nanofibers of PAN and PVDF,addition of clay nanoparticles,absorbent thickness,and air gap on the sound absorption coefficient of flexible polyurethane foam(PU)across different frequency ranges.The absorption coefficient of the samples was measured using Impedance Tubes device.Nano clay at low thicknesses as well as polyacrylonitrile nanofibers and polyvinyl fluoride nanofibers at higher thicknesses had a greater positive effect on absorption coefficient.The mean sound absorption coefficient in the composite with the highest absorption coefficient at middle and high frequencies was 0.798 and 0.75,respectively.In comparison with pure polyurethane foam with the same thickness and air gap,these values were 2.22 times at the middle frequencies and 1.47 times at high frequencies,respectively.Surface porosity rose with increasing nano clay,but decreased with increasing polyacrylonitrile nanofibers and polyvinyl fluoride nanofibers.The results indicated that the absorption coefficient was elevated with increasing the thickness and air gap.This study suggests that the use of a combination of nanoparticles and nanofibers can enhance the acoustic properties of flexible polyurethane foam.
基金the National Natural Science Foundation of China(Grant Numbers 12172151 and 12172149).
文摘For fragile products,packaging requires cushioning protection to prevent irreversible damage from accidental falls,transportation impacts,and other causes.The new polyurethane foam(PUF)material demonstrates superior cushioning and vibration isolation performance in practical applications,effectively minimizing damage from vibrations.Drop and vibration experiments were conducted on packages comprising novel PUF,expandable polyethylene,ethylene-vinyl acetate copolymer foam,and bracelets.Results verify that the new PUF material outperforms in cushioning and vibration isolation,as observed from the acceleration response.Furthermore,a random vibration analysis of a packaging unit involving different thicknesses of PUF materials and bracelets reveals the enhanced vibration isolation effect within a specific thickness range.The vibration results of the bracelet’s outer packaging align closely with finite element simulation results,validating the effectiveness of designing and optimizing the outer packaging.Through finite element simulation,deeper understanding and prediction of the bracelet’s vibration response under various conditions is achieved,facilitating optimized packaging design for better protection and vibration damping.
基金This work was supported by the National Key Research and Development Program(Grant No.2017YFB0307700)the Department of Scientific and Technology of Zhejiang Province(LGG18E030007,LGG19E030007)+1 种基金the Project for the Innovation of High Level Returned Overseas Scholars(or team)in Hangzhou.We also acknowledge the support from Collaborative Innovation Center of Zhejiang Province for the Manufacture of Fluorine and Silicone Fine Chemicals and Materials(FSi2018A028,FSi2018B004)professional development project for domestic visiting scholars in universities(FX2017054).
文摘A facile strategy was developed to fabricate flexible polyurethane(PU)foam composites with exceptional flame retardancy.The approach involves the incorporation of graphene oxide(GO)into a silicone resin(SiR)solution,which is then deposited onto a PU foam surface via the dip-coating technique and cured.Fourier-transform infrared spectroscopy,scanning electron microscopy,and Raman spectroscopy measurements demonstrated that the SiR and GO were successfully coated onto the PU skeleton and the intrinsic porous structure of the PU foam remained intact.The effects of SiR and GO on the mechanical and thermal stability and flame retardancy of PU composites were evaluated through compression tests,thermogravimetric analysis,vertical combustion tests,and the limiting oxygen index.The measurement results revealed that the composites(PU@SiR-GO)showed superior flame retardancy and thermal and mechanical stability compared to pristine PU or PU coated with SiR alone.The mechanical and thermal stability and the flame-retardant properties of the PU composites were enhanced significantly with increasing GO content.Based on the composition,microstructure,and surface morphology of PU@SiR-GO composites before and after combustion tests,a possible flame-retardance mechanism is proposed.This work provides a simple and effective strategy for fabricating flame retardant composites with improved mechanical performance.