Ion dynamics into different pore size distributions in supercapacitors under compression

Compressing supercapacitor(SCs)electrode is essential for improving the energy storage characteristics and minimizing ions’distance travel,faradaic reactions,and overall ohmic resistance.Studies comprising the ion dynamics in SC electrodes under compression are still rare.So,the ionic dynamics of five aqueous electrolytes in electrodes under compression were studied in this work for tracking electrochemical and structural changes under mechanical stress.A superionic state is formed when the electrode is compressed until the micropores match the dimensions with the electrolyte’s hydrated ion sizes,which increases the capacitance.If excessive compression is applied,the accessible pore regions decrease,and the capacitance drops.Hence,as the studied hydrated ions have different dimensions,the match between ion/pore sizes differs.To the LiOH and NaClO4electrolytes,increasing the pressure from 60 to 120 and 100 PSI raised the capacitance from 13.5 to 35.2 F g^(-1)and 30.9 to 39.0 F g^(-1),respectively.So,the KOH electrolyte with the lowest and LiCl with the biggest combination of hydrated ion size have their point of maximum capacitance(39.5 and 36.7F g^(-1))achieved at 140 and 80 PSI,respectively.To LiCl and KCl electrolytes,overcompression causes a drop in capacitance higher than 23%.

Pore size distribution,their geometry and connectivity in deeply buried Paleogene Es1 sandstone reservoir,Nanpu Sag,East China

The study or pore characteristics is or great importance in reservoir evaluation,especially in deeply buried s andstone.It controls the storage mechanism and reservoir fluid properties of the permeable horizons.The first member of Eocene Shahejie Formation(Esl)sandstone is classified as feldspathic litharenite and lithic arkose.The present research investigates the pore characteristics and reservoir features of the deeply buried sandstone reservoir of Esl member of Shahejie Formation.The techniques including thin-section petrography,mercury injection capillary pressure(MICP),scanning electron microscopy and laser scanning confocal microscope images were used to demarcate the pores including primary intergranular pores and secondary intergranular,intragranular,dissolution and fracture pores.Mercury injection test and routine core analysis were led to demarcate the pore network characteristics of the studied reservoir.Pore size and pore throat size distribution are acquired from mercury injection test.Porosity values range from 0.5%to 30%,and permeability ranges 0.006-7000 mD.Pore radii of coarse-grained sandstone and fine-grained sandstone range from 0.2 to>4μm and 1 nm to 1.60μm,respectively,by MICP analysis.The mineral composition also plays an important role in protecting the pores with pressure from failure.Fractured sandstone and coarse-grained sandstone consist of large and interconnected pores that enhance the reservoir porosity and permeability,whereas fine-grained sandstone and siltstone consist of numerous pores but not well interconnected,and so they consist of high porosity with low permeability.

Exploring the interconnectivity of biomimetic hierarchical porous Mg scaffolds for bone tissue engineering:Effects of pore size distribution on mechanical properties,degradation behavior and cell migration ability

Interconnectivity is the key characteristic of bone tissue engineering scaffold modulating cell migration,blood vessels invasion and transport of nutrient and waste.However,efforts and understanding of the interconnectivity of porous Mg is limited due to the diverse architectures of pore struts and pore size distribution of Mg scaffold systems.In this work,biomimetic hierarchical porous Mg scaffolds with tailored interconnectivity as well as pore size distribution were prepared by template replication of infiltration casting.Mg scaffold with better interconnectivity showed lower mechanical strength.Enlarging interconnected pores would enhance the interconnectivity of the whole scaffold and reduce the change of ion concentration,pH value and osmolality of the degradation microenvironment due to the lower specific surface area.Nevertheless,the degradation rates of five tested Mg scaffolds were no different because of the same geometry of strut unit.Direct cell culture and evaluation of cell density at both sides of four typical Mg scaffolds indicated that cell migration through hierarchical porous Mg scaffolds could be enhanced by not only bigger interconnected pore size but also larger main pore size.In summary,design of interconnectivity in terms of pore size distribution could regulate mechanical strength,microenvironment in cell culture condition and cell migration potential,and beyond that it shows great potential for personalized therapy which could facilitate the regeneration process.

Pore Size Distribution of High Performance Metakaolin Concrete

The Compressive strength, porosity and pore size distribution of high performance metakaolin (MK) concrete were investigated. Concretes containing 0,5% , 10% and 20% metakaolin were prepared at a water / cementitious material ratio ( W/C) of 0. 30. In parallel, concrete mixtures with the replacement of cement by 20% fly ash or 5 and 10% silica fume were prepared for comparison. The specimens were cured in water at 27℃ for 3 to 90 days. The results show that at the early age of curing (3 days and 7 days), metakaolin replacements increase the compressive strength, but silica fume replacement slightly reduces the compressive strength. At the age of and after 28 days , the compressive strength of the concrete with metakaolin and silica fume replacement increases. A strong reduction in the total porosity and average pore diameter were observed in the concrete with MK 20% and 10% in the first 7 days.

A novel hybrid thermodynamic model for pore size distribution characterisation for shale

Scholars often see the gas adsorption technique as a straight-to-interpret technique and adopt the pore size distribution(PSD)given by the gas adsorption technique directly to interpret pore-structure-related issues.The oversimplification of interpreting shale PSD based on monogeometric thermodynamic models leads to apparent bias to the realistic pore network.This work aims at establishing a novel thermodynamic model for shale PSD interpretation.We simplified the pore space into two geometric types—cylinder-shaped and slit-shaped.Firstly,Low-temperature Nitrogen Adsorption data were analyzed utilizing two monogeometric models(cylindrical and slit)to generate PSD_(cyl).and PSD_(slit);Secondly,pore geometric segmentation was carried out using Watershed by flooding on typical SEM images to obtain the ratio of slit-shaped(∅_(s))and cylinder-shaped pores(∅_(c)).Combining the results of the two,we proposed a novel hybrid model.We performed pyrolysis,XRD,FE-SEM observation,quantitative comparison with the results obtained by the DFT model,and fractal analysis to discuss the validity of the obtained PSD_(Hybrid).The results showed that:the hybrid model proposed in this work could better reflect the real geometry of pore space and provide a more realistic PSD;compared with thermodynamic monogeometric models,PSD obtained from the hybrid model are closer to that from the DFT model,with an improvement in the deviation from the DFT model from 5.06%to 68.88%.The proposed hybrid model has essential application prospects for better interpretation of shale pore space.It is also worth noting that we suggest applying the proposed hybrid model for PSD analysis in the range of 5-100 nm.

Influence of Superplasticizer Type and Dosage on Early-age Drying Shrinkage of Cement Paste with Consideration of Pore Size Distribution and Water Loss

We introduced a parameter r_s(the radius of the pores where the meniscus forms),which is composed of two factors,i e,water loss and cumulative pore size distribution(PSD),to provide a better explanation of the influence of superplasticizers(SPs)on early-age drying shrinkage.In our experiments,it is found that the addition of three types of SPs leads to a significant increase in the early-age drying shrinkage of cement paste,and drying shrinkage increases with the dosage of SPs.Based on the results above,we further studied the mechanism of the effects of SPs on the early-age drying shrinkage of cement paste by PSD and water loss,which are two components of r_s.The experimental results indicate that r_s can be a better index for the early-age drying shrinkage of cement-based materials with SPs than a single factor.In addition,the effects of SPs on other factors such as hydration degree and elastic modulus were also investigated and discussed.

Pore Size Distribution and Its Quantitative Relationship with Strength of Corundum Based Castables

A series of corundum based castables with 0,2%,4%,6%,and 8% α-Al2O3 micropowders were prepared using tabular alumina aggregates （6-3,3-1 and ≤1 mm） and fines （≤0.088 and ≤0.045 mm）,calcium aluminate cement,and α-Al2O3 micropowders （d50=1.754 μm） as starting materials. Cold mechanical strength and pore size distribution of the castables specimens after heat treatment at 110,1 100 and 1 500 ℃ were tested,respectively. The quantitative relationship between strength and apparent porosity,and that between strength and median pore diameter were verified by Atzeni equation. The correlation between interval of pore size and mechanical strength of specimens was also studied by means of gray relational theory. The results show that：（1） the pore size distribution of castables is strongly influenced by both micropowders filling and matrix sintering; the addition of micropowders decreases median pore diameter while the sintering process increases it; （2） when adding a constant correction term,Atzeni equation can substantially describe the quantitative relationship between median pore diameter and strength of castables specimens after heat treatment at the same temperature; the significant differences of the gray relational degree between the interval of pore size and castables strength are characterized; it is also found that for the same interval of pore size,the gray relational degree isaffected by the heat treatment temperature; the pore size interval 〈0.5 μm has the highest gray relational degree with the strength at 110-1 500 ℃.

Modeling Water Adsorption and Retention of Building Materials From Pore Size Distribution

Water adsorption and capillarity are key phenomena involved during heat and moisture transfer in porous building materials.They account for interaction between solid matrix,liquid water and moist air.They are considered through Water Vapor Adsorption Isotherm(WVAI)and Retention Curve(RC)functions which are constitutive laws characterizing water activity within a porous medium.The objective of this paper is to present a water vapor adsorption and retention models built from multimodal Pore Size Distribution Function(PSDF)and to see how its parameters modify moisture storage for hygroscopic and near saturation ranges.The microstructure of the porous medium is represented statistically by a bundle of tortuous parallel pores through its PSDF.Firstly,the influence of contact angle and temperature on storage properties were investigated.Secondly,a parametric study was performed to see the influence of the PSDF shape on storage properties.Three cases were studied considering the number of modalities,the weight of each modality and the dispersion around mean radius.Finally,as a validation,the proposed model for WVAI were compared to existing model from literature showing a good agreement.This study showed that the proposed models are capable to reproduce various shapes of storage functions.It also highlighted the link between microstructure and adsorption-retention phenomena.

The influence of pore size distribution on thermal conductivity,permeability, and phase change behavior of hierarchical porous materials

Porous foams have been widely employed to improve heat storage rate and prevent leakage of phase change materials(PCMs).Actual porous foams have non-uniform or hierarchical pore size distribution, which is usually neglected in most researches.Here, we establish hierarchical porous models considering different pore size distributions by using Voronoi tessellations. Effects of pore size distribution on thermal conductivity, permeability, and phase change behavior of hierarchical porous foams/PCMs composites are investigated. Uneven pore size distributions are found to decrease the thermal conductivity of porous foams to some extent. On the other hand, the permeability can be reduced by 27.6%, and the heat storage rate can be improved by 7.7% by introducing moderate hierarchy without changing the total porosity. This work opens a new route to enhance heat storage performance of PCMs via leveraging hierarchy of pore size distribution of porous foams.

Pore size distribution of high volatile bituminous coal of the southern Junggar Basin: a full-scale characterization applying multiple methods

Studying on the pore size distribution of coal is vital for determining reasonable coalbed methane development strategies.The coalbed methane project is in progress in the southern Junggar Basin of northwestern China,where high volatile bituminous coal is reserved.In this study,with the purpose of accurately characterizing the full-scale pore size distribution of the high volatile bituminous coal of the southern Junggar Basin,two grouped coal samples were applied for mercury intrusion porosimetry,low-temperature nitrogen adsorption,low-field nuclear magnetic resonance,rate-controlled mercury penetration,scanning electron microscopy,and nano-CT measurements.A comprehensive pore size distribution was proposed by combining the corrected mercury intrusion porosimetry data and low-temperature nitrogen adsorption data.The relationship between transverse relaxation time(T2,ms)and the pore diameter was determined by comparing the T2 spectrum with the comprehensive pore size distribution.The macro-pore and throat size distributions derived from nano-CT and rate-controlled mercury penetration were distinguishingly analyzed.The results showed that:1)comprehensive pore size distribution analysis can be regarded as an accurate method to characterize the pore size distribution of high volatile bituminous coal;2)for the high volatile bituminous coal of the southern Junggar Basin,the meso-pore volume was the greatest,followed by the transition pore volume or macro-pore volume,and the micro-pore volume was the lowest;3)the relationship between T2 and the pore diameter varied for different samples,even for samples with close maturities;4)the throat size distribution derived from nano-CT was close to that derived from rate-controlled mercury penetration,while the macro-pore size distributions derived from those two methods were very different.This work can deepen the knowledge of the pore size distribution characterization techniques of coal and provide new insight for accurate pore size distribution characterization of high volatile bituminous coal.

Size Determination of Ultramicropores and Small Mesopores Using a Calculation Procedure Based on the Tangents of Comparison Plot

Pore size distribution（PSD） curves of synthesized hollow silica spheres with ultrmicropores and small mesopores were obtained from calculations based on the BJH,KJS,SF,MP,NLDFT models and Prof.Zhu＇s method.Comparisons indicate that Zhu＇s method not only gives reasonable small mesopore size but also could be further extended to the ultramicropores region for the PSD evaluation.

Effect of seepage-induced erosion on soil macropore structure

Internal erosion is one of the important factors causing geological disasters.The microstructure of soil can change with seepage erosion,resulting in changes in the hydraulic and mechanical properties of the soil.The evolution of seepage erosion is investigated with X-ray computed tomography(CT)in this study.The change in macropore structure characteristics during the seepage erosion test is quantified and the influence of seepage erosion on soil deformation is analyzed.Moreover,a pore network model(PNM)is established for the specimens and the evolution of the connected pore size characteristics is assessed.The results show that the macropore structure is significantly affected by seepage erosion,especially in terms of the porosity and pore geometry characteristics.The changes in macropore structure characteristics are most obvious in the lower part of the specimen.The influence of seepage erosion on the pore size distribution(PSD)and soil deformation is heterogeneous and closely dependent on the spatial location of the soil.Moreover,seepage erosion enhances macropore connectivity and has a directional impact on macropore orientation.These findings can provide a reference for the theoretical modeling and numerical simulation of the seepage erosion and improve the understanding of the seepage erosion evolution in engineering practice.

Influence of Acid Treatment on Pore Structure and Fractal Characterization of a Tight Sandstone:A Case Study from Wudun Sag,Dunhuang Basin

In this study,X-ray diffraction,N_(2)adsorption(N_(2)A),and mercury intrusion(MI)experiments were used to investigate the influence of acid treatment on pore structure and fractal characterization of tight sandstones.The results showed that acid treatment generated a certain number of ink-bottle pores in fine sandstone,aggravated the ink-bottle effect in the sandy mudstone,and transformed some smaller pores into larger ones.After the acid treatment,both the pore volume in the range of 2–11 nm and 0.271–8μm for the fine sandstone and the entire pore size range for the sandy mudstone significantly increased.The dissolution of sandstone cement causes the fine sandstone particles to fall off and fill the pores;the porosity increased at first but then decreased with acid treatment time.The fractal dimension obtained using the Frenkel-Halsey-Hill model was positively correlated with acid treatment time.However,the total fractal dimensions obtained by MI tests showed different changes with acid treatment time in fine sandstone and sandy mudstone.These results provide good guiding significance for reservoir acidification stimulation.

Pore throat structure heterogeneity and its effect on gas-phase seepage capacity in tight sandstone reservoirs:A case study from the Triassic Yanchang Formation,Ordos Basin

The microscopic heterogeneity of pore-throat structures in tight sandstone is a crucial parameter for understanding the transport mechanism of fluid flow.In this work,we firstly developed the new procedure to characterize the pore size distribution(PSD)and throat size distribution(TSD)by combining the nuclear magnetic resonance(NMR),cast thin section(CTS),and constant-rate mercury injection(CRMI)tests,and used the permeability estimated model to verify the full-scale PSD and TSD.Then,we respectively analyzed the fractal feature of the pore and throat,and characterized the heterogeneity of pores and throats.Finally,we elaborated the effect of the pore and throat heterogeneity on the gas-phase seepage capacity base on the analysis of the simple capillary tube model and gas-flooding experiment.The results showed that(1)The PSD and TSD of the tight sandstone sample ranged from 0.01 to 10 mm and from 0.1 to 57 mm,respectively,mainly contributed by the micropores and mesopores.Meanwhile,the permeability estimated by the PSD and TSD was consistent with the experimental permeability,and relative error was lower than 8%.(2)The PSD and TSD exhibited multifractal characteristics,and singularity strength range,Δα,could be used as the indicator for characterizing the heterogeneity of pore and throat.Furthermore,the throat of the sample showed stronger heterogeneity than that the pore.(3)The throats played an important role for the fluid transport in the tight sandstone,and the effect of the throat heterogeneity on the gas-phase seepage capacity was different under the lower and higher injection pressure.The macropores and micropores maybe respectively become the preferential migration pathways at the lower and higher injection pressure.In the end,the identification plate was established in our paper,and could be described the relationship among the throat heterogeneity,injection pressure,permeability and flow path of the gas phase in the tight sandstone.

Pore structure characterization based on NMR experiment: A case from the Shanxi Formation tight sandstones in the Daning-Jixian area, eastern Ordos Basin

The study of pore structure requires consideration of important factors including pore throat size,pore radius composition,and pore-throat configuration.As the nuclear magnetic resonance(NMR)experimental results contain rich information about pore structures and fluid occurrence states,this study investigated the pore structures of the tight sandstone reservoirs of the Shanxi Formation in the Daning-Jixian area,eastern Ordos Basin.Firstly,by making the inverse cumulative curve of the NMR T2 spectrum coincide with the capillary pressure curves which were obtained by the mercury injection capillary pressure(MICP)technique,this study derived a conversion coefficient that can be used to convert the NMR T2 spectrum into the pore throat radius distribution curves based on the NMR experimental results.Subsequently,we determined the pore radius intervals corresponding to irreducible water distribution using the NMR-derived pore radius distribution curves.Finally,the NMR T2 distribution curves based on the fractal theory were analyzed and the relationships between fractal dimensions and parameters,including permeability,porosity,reservoir quality index(RQI),flow zone indicator(FZI),irreducible water saturation,RT35,and RT50,were also discussed.The NMR-derived pore throat radius distribution curves of the study area are mainly unimodal,with some curves showing slightly bimodal distributions.The irreducible water mainly occurs in small pores with a pore radius less than 100 nm.As the permeability decreases,the contribution rate of small pores to the irreducible water gradually increases.The NMR-based fractal dimensions of pores show a two-segment distribution.Small pores have small fractal dimensions and are evenly distributed,while large pores have large fractal dimensions and complex pore structures.The fractal dimension of large pores(Dmax)is poorly correlated with porosity but strongly correlated with FZI,RQI,RT35,and RT50.These results indicate that large pores are the main pore zones that determine the seepage capacity of the reservoirs.Additionally,there is a certain correlation between Dmax and the irreducible water saturation.

Impact of rock type on the pore structures and physical properties within a tight sandstone reservoir in the Ordos Basin, NW China

The pore-throat systems and physical properties of tight sandstone reservoirs are complex,and deposition is thought to be a fundamental control for them.In this study,the impacts of the full ranges of rock types(from pebbly coarse sandstone to fine sandstone) on the pore structures and physical properties of the Permian tight sandstone reservoir in the eastern Ordos Basin were investigated comprehensively through a series of experiments including conventional physical testing,thin-section analysis,scanning electron microscopy,nuclear magnetic resonance analysis and high-pressure mercury injection tests.The results showed that the coarser-grained sandstones tend to have higher feldspar content and lower percentage of cements,leading to strong dissolution,weak cementation and improved porosity and permeability.The medium sandstone has the highest level of quartz and the lowest average content of feldspar,resulting in strong heterogeneity of physical properties.Only those medium sandstone reservoirs with relatively high content of feldspars have better physical properties.Additionally,the coarser-grained sandstones contain relatively large dissolution pores(nearly 200 μm),whereas the finer-grained sandstones have more intercrystalline pores with a relatively more homogeneous pore structure.The pebbly coarse sandstone and coarse sandstone reservoirs are favorable targets with best physical properties.

Microscopic Pore Structure of Asphalt Mixture Incorporating with MFL

In order to analyze the microstructure of salt anti-freezing asphalt concrete, i e, MFL（Mafilon） modified asphalt concrete, MIP（mercury intrusion porosity） method was used to obtain the data including porosity and pore size distribution in micro scale. Results show that the porosity grows up with the increase of immersion duration and the salt content. During the immersion, the amount of large pores（60-200 μm） grow up gradually and porosity also grows up correspondingly. Even with different immersion duration, most pores＇ size distribute is beyond 7000 nm.

Experiment on the silica sol imbibition of low-permeability rock mass:With silica sol particle sizes and rock permeability considered

It’s a universal engineering problem to seal micro-cracks of low-permeability argillaceous rock mass by grouting in the fields of civil engineering and mining.This paper achieved the grouting sealing of lowpermeability artificial rocks with the permeability of 0.1–40 mD by adopting silica sol imbibition grouting.The variation characteristics of particle size,viscosity,and contact angle of silica sol during solidification and the pore size distribution of low-permeability artificial rocks were measured,and spontaneous imbibition tests of the artificial rocks were carried out.Finally,combined with the imbibition theory,percolation theory,and fracture medium grouting principle,the silica sol imbibition mechanism of lowpermeability rocks and soil was discussed.The results show that:(1)Silica sol can be injected into artificial rocks with the minimum permeability of 0.1 mD through spontaneous imbibition;(2)The particle size increase of silica sol leads to decreased wettability,affinity,and injectability in grouting materials;and(3)In the range of 0.1–40 mD,the grout absorption first increases and then decreases with increased permeability.The number of large pores and fractures in the rock mass is related to injectability,and the number of small and medium pores is related to the internal driving force of imbibition.This study provides a theoretical basis for silica sol grouting sealing of low-permeability argillaceous rocks and is,therefore,an important reference for application.

APPLICATION OF COMPUTER NUMERICAL METHOD IN PORE STRUCTURE CALCULATION

This paper compares the results of calculating pore structure and graphing differential and integral pore size distribution by hand and computer, and presents that Lagrangian interpolation uesd by calculating pore structure is suitable and reliable.

Effects of Particle Size and Content of Silicon Powder on Strength and Microstructure of Coked Al_2O_3-ZrO_2-C Refractories

Effects of particle size （A：d50 = 336. 9 μm, B：d50 =123.5μm, C： d50=19.5 μm, D： dso=2.21μm） and content （1 wt% , 3 wt% , 5 wt% , 7 wt% ） of silicon powder on cold crushing strength （CCS） , pore size distribution and microstructure of Al2O3 - ZrO2 - C refractories coked at high temperature had been investigated by means of mercury porosimeter, SEM, EDS, tic. The results indicated that particle size and content of silicon powder affected the cold crushing strength of coked specimens. It increased with the addition of silicon powder and its finer particle size. However, it decreased greatly when using too fine silicon powder. The particle size and content of silicon powder also impacted the phase evolution and microstructure of coked specimens, much more β-SiC whiskers constituted network structure and well distributed in specimens with reduction of their slenderness ratios when finer silicon powder was added, corresponding to that, the specimens＇ pore size distribution range became narrower with smaller pore diameter, but β-SiC whiskers were distributed sparsely and the specific pore volume of small pores increased when much finer powder was added. It was worthly mentioned that some nitride could form in specimens with addition of appropriate particle size and content of silicon powder.