Pore structure formation and hydration characteristics of cement paste with temperature rising inhibitor

The early-age thermal cracking easily generates and severely impairs the durability of concrete.The temperature rising inhibitor(TRI)was utilized to regulate the temperature evolution by controlling the cement hydration process.This paper aimed to investigate the pore structure formation and hydration characteristics of cement paste containing TRI by low-field nuclear magnetic resonance.The experiment showed that the T_(2) peak of cement paste shifted from 7.32 ms to 0.23 ms regardless of TRI addition.But the pattern of pore structure formation was changed with TRI addition,that is,the pore structure formation was delayed,and the pore successively shifted to left in two parts.In addition,TRI addition significantly prolonged the duration of gel pore formation and greatly decreased the increase rate of gel water,which implied that TRI introduction hindered the growth of C-S-H,and subsequently decreased the hydration rates and delayed the main hydration peak.Meanwhile,TRI dissolved and diffused rapidly at 40℃,delaying the hydration of cement paste seriously.Moreover,TRI brought about the C-S-H nucleation homogeneous and the ion concentration uniform,which might reduce the localized curvature occurring on the sheet of C-S-H,and then decreased the T_(2) intensity of capillary water and gel water.

Fractal characteristic of microscopic pore structure of tight sandstone reservoirs in Kalpintag Formation in Shuntuoguole area,Tarim Basin

Using the fractal geometry method,the microscopic pore structures of tight sandstone reservoirs in Kalpintag Formation of Shuntuoguole area in Tarim Basin were conducted fractal characterization on the base of test analysis data such as physical property,cast thin section,scanning electron microscope and mercury injection,and the genetic mechanism of pore structure heterogeneity was investigated.The storage spaces are dominated by intergranular dissolved pore,intragranular dissolved pore and residual intergranular pore,and the throat type consists of the necking throat,lamellar throat,curved lamellar throat and tube-shaped throat.The microscopic structure type includes Type Ⅰ(fractal dimension≤2.350),Type Ⅱ(2.350<fractal dimension<2.580),Type Ⅲ(fractal dimension>2.580)and fracture type.The most favorable reservoirs with Type-Ⅰ microscopic pore structure are mainly distributed in the Upper Member of Kalpintag Formation,while the reservoirs with Type-Ⅱ and Type-Ⅲ microscopic pore structures are mainly in the Lower Member of Kalpintag Formation.The sedimentation controls the heterogeneity of microscopic pore structure,and the differences on composition and particle size of sandstone lead to differentiation of microscopic pore structures.The Lower Member of the Kalpintag Formation experiences stronger compaction and cementation but weaker dissolution than the Upper Member of the Kalpingtag Formation,and thus the microscopic pore structure of Upper Member of the Kalpintag Formation is significantly worse that of the Lower Member o the Kalpingtag Formation.The Upper Member of the Kalpintag Formation with high content of brittle mineral develops microscopic fractures due to tectonic rupture,thus the permeability is improved and the heterogeneity of microscopic pore structures is enhanced;but the Lower Member of Kalpintag Formation is characterized by attrition crushing of particles and strong compaction.