The evolution due to temperature and pressure of shale reservoir permeability affects the productivity evaluation and development decision of shale gas reservoirs,which is very important for the exploration and develo...The evolution due to temperature and pressure of shale reservoir permeability affects the productivity evaluation and development decision of shale gas reservoirs,which is very important for the exploration and development of unconventional gas reservoirs.This study analyzed the coupling effects of temperature(25,50,and 75°C),effective stress(15 and 30 MPa),and pore pressure(0.5,2.0,4.0,and 8.0 MPa)on the permeability of the shale sample in the Longmaxi Formation.As the temperature and pressure increased,the apparent permeability exhibited a downward trend,and the absolute permeability decreased with the rise of temperature or effective stress.An in‐depth analysis of the gas slippage factors under the conditions of different temperature and pressure was conducted to evaluate the trend of the average pore width with temperature and pressure.The results were then verified by scanning electron microscopy(SEM).The results provide new insights into evaluating the permeability of the Longmaxi shale and can be used to enhance the gas recovery rate of deep shale gas reservoirs.展开更多
In this paper, five factors, namely the HF (hydrofluoric acid) concentration, field strength, illumination intensity as well as the oxidizing-power and conductivity of electrolytes were found to strongly affect the ...In this paper, five factors, namely the HF (hydrofluoric acid) concentration, field strength, illumination intensity as well as the oxidizing-power and conductivity of electrolytes were found to strongly affect the fast pore etching. The oxidizing power of aqueous HF electrolyte of different concentrations was especially measured and analysed. A positive correlation between optimal bias and HF concentration was generally observed and the relationship was semiquantitatively interpreted. Pore density notably increased with enhanced HF-concentration or bias even on patterned substrates where 2D (two-dimensional) nuclei were densely pre-textured. The etch rate can reach 400μm/h and the aspect ratio of pores can be readily driven up to 250.展开更多
Pores and fractures and their connectivity play a significant role in coalbed methane production.To investigate the growth characteristics and connectivity of pores and fractures in coal parallel and perpendicular to ...Pores and fractures and their connectivity play a significant role in coalbed methane production.To investigate the growth characteristics and connectivity of pores and fractures in coal parallel and perpendicular to the bedding plane,the pores and fractures of high-rank coal samples collected from the southern Qinshui Basin were measured by low-field nuclear magnetic resonance,X-ray-computed tomography and field emission scanning electron microscopy.Then,the determinants of their connectivity were further discussed.The results show that the high-rank coal samples have similar pore size distributions both parallel and perpendicular to the bedding plane.They primarily contain mesopores(2-50 nm in width),followed by macrospores(> 50 nm in width).The research indicated that the high-rank coal connectivity parallel to the bedding plane is significantly better than that perpendicular to the bedding plane.The connectivity of high-rank coal is mainly determined by throats,and the orientation of the pores and fractures.The two connectivity modes in high-rank coal are "pore connectivity," in which the throats are mainly pores with a low coordination number,and "microfissure connectivity",in which the throats are mainly microfissures with a high coordination number.展开更多
The leaf morphological and stomatal characteristics of four paper birch (Betula papyrifera Marsh) populations, grown at four treatment conditions of carbon dioxide [CO2] and soil water levels were investigated to dete...The leaf morphological and stomatal characteristics of four paper birch (Betula papyrifera Marsh) populations, grown at four treatment conditions of carbon dioxide [CO2] and soil water levels were investigated to determine whether future increases in atmospheric [CO2] and water deficit affected the leaf characteristics. The populations from Cussion Lake, Little Oliver, Skimikin and Wayerton were grown for 12 weeks under ambient (360 ppm) and elevated (720 ppm) [CO2] at both high and low water levels. The populations significantly differed in leaf area and stomatal characteristics due to the interaction effects of [CO2], water levels and population differences. Most leaf morphological characteristics and stomatal density varied due to the effects of [CO2] and/or populations, but not due to the effect of water levels. Although elevated [CO2] alone barely affected stomatal area of the birch populations, simultaneous elevated [CO2] at both water levels had stimulated stomatal characteristics within and among the populations. Overall, elevated [CO2] reduced leaf area and increased stomatal density;and low water level resulted in smaller stomatal area, pore area and guard cell width. However, the populations responded differently to an increase in [CO2] and water levels. All populations showed plastic responses with respect to [CO2] and water levels either by decreasing stomatal area under low water level or by increasing stomatal density under elevated [CO2]. Hence, integration between and within leaf characteristics had helped paper birch populations maintain balance between [CO2] gain and water loss.展开更多
The effects of parallel and angular butt designs with different gap widths on the microstructure and mechanical properties of the resultant magnesium joints in gas tungsten arc welding were investigated. The experimen...The effects of parallel and angular butt designs with different gap widths on the microstructure and mechanical properties of the resultant magnesium joints in gas tungsten arc welding were investigated. The experimental results displayed that the tensile strength of the joint made with angular butt joint and 0.3 ram-wide gap reached 266 MPa, the joint fractured through the heat-affected zone or base metal during tensile testing, and the microstructure examination showed that no macropore appeared in the fusion zone. However, macropores in diameter of larger than 200 micron occurred for other joint designs, the tensile strength of the resultant joints decreased, and the joints fractured through the fusion zone during tensile testing. The fracture surfaces were examined by scanning electron microscopy and the microhardness distribution in the joints was measured by using a Vickers microhardness tester.展开更多
基金National Natural Science Foundations of China,Grant/Award Numbers:51809264,52178375,52211530088Fundamental Research Funds for the Central Universities,Grant/Award Number:2023ZKPYLJ06。
文摘The evolution due to temperature and pressure of shale reservoir permeability affects the productivity evaluation and development decision of shale gas reservoirs,which is very important for the exploration and development of unconventional gas reservoirs.This study analyzed the coupling effects of temperature(25,50,and 75°C),effective stress(15 and 30 MPa),and pore pressure(0.5,2.0,4.0,and 8.0 MPa)on the permeability of the shale sample in the Longmaxi Formation.As the temperature and pressure increased,the apparent permeability exhibited a downward trend,and the absolute permeability decreased with the rise of temperature or effective stress.An in‐depth analysis of the gas slippage factors under the conditions of different temperature and pressure was conducted to evaluate the trend of the average pore width with temperature and pressure.The results were then verified by scanning electron microscopy(SEM).The results provide new insights into evaluating the permeability of the Longmaxi shale and can be used to enhance the gas recovery rate of deep shale gas reservoirs.
基金supported by Chinese National ‘863’ Project (Grant No 2006AA04Z312)‘973’ Project (Grant No 2006CB300403)the National Natural Science Foundation of China (Grant No 60772030)
文摘In this paper, five factors, namely the HF (hydrofluoric acid) concentration, field strength, illumination intensity as well as the oxidizing-power and conductivity of electrolytes were found to strongly affect the fast pore etching. The oxidizing power of aqueous HF electrolyte of different concentrations was especially measured and analysed. A positive correlation between optimal bias and HF concentration was generally observed and the relationship was semiquantitatively interpreted. Pore density notably increased with enhanced HF-concentration or bias even on patterned substrates where 2D (two-dimensional) nuclei were densely pre-textured. The etch rate can reach 400μm/h and the aspect ratio of pores can be readily driven up to 250.
基金supported by the Fundamental Research Funds for the Central Universities (No.2017XKQY017)。
文摘Pores and fractures and their connectivity play a significant role in coalbed methane production.To investigate the growth characteristics and connectivity of pores and fractures in coal parallel and perpendicular to the bedding plane,the pores and fractures of high-rank coal samples collected from the southern Qinshui Basin were measured by low-field nuclear magnetic resonance,X-ray-computed tomography and field emission scanning electron microscopy.Then,the determinants of their connectivity were further discussed.The results show that the high-rank coal samples have similar pore size distributions both parallel and perpendicular to the bedding plane.They primarily contain mesopores(2-50 nm in width),followed by macrospores(> 50 nm in width).The research indicated that the high-rank coal connectivity parallel to the bedding plane is significantly better than that perpendicular to the bedding plane.The connectivity of high-rank coal is mainly determined by throats,and the orientation of the pores and fractures.The two connectivity modes in high-rank coal are "pore connectivity," in which the throats are mainly pores with a low coordination number,and "microfissure connectivity",in which the throats are mainly microfissures with a high coordination number.
文摘The leaf morphological and stomatal characteristics of four paper birch (Betula papyrifera Marsh) populations, grown at four treatment conditions of carbon dioxide [CO2] and soil water levels were investigated to determine whether future increases in atmospheric [CO2] and water deficit affected the leaf characteristics. The populations from Cussion Lake, Little Oliver, Skimikin and Wayerton were grown for 12 weeks under ambient (360 ppm) and elevated (720 ppm) [CO2] at both high and low water levels. The populations significantly differed in leaf area and stomatal characteristics due to the interaction effects of [CO2], water levels and population differences. Most leaf morphological characteristics and stomatal density varied due to the effects of [CO2] and/or populations, but not due to the effect of water levels. Although elevated [CO2] alone barely affected stomatal area of the birch populations, simultaneous elevated [CO2] at both water levels had stimulated stomatal characteristics within and among the populations. Overall, elevated [CO2] reduced leaf area and increased stomatal density;and low water level resulted in smaller stomatal area, pore area and guard cell width. However, the populations responded differently to an increase in [CO2] and water levels. All populations showed plastic responses with respect to [CO2] and water levels either by decreasing stomatal area under low water level or by increasing stomatal density under elevated [CO2]. Hence, integration between and within leaf characteristics had helped paper birch populations maintain balance between [CO2] gain and water loss.
基金supported by the State Key Lab of Advanced Welding and Joining,Harbin Institute of Technology (Project No.09009)
文摘The effects of parallel and angular butt designs with different gap widths on the microstructure and mechanical properties of the resultant magnesium joints in gas tungsten arc welding were investigated. The experimental results displayed that the tensile strength of the joint made with angular butt joint and 0.3 ram-wide gap reached 266 MPa, the joint fractured through the heat-affected zone or base metal during tensile testing, and the microstructure examination showed that no macropore appeared in the fusion zone. However, macropores in diameter of larger than 200 micron occurred for other joint designs, the tensile strength of the resultant joints decreased, and the joints fractured through the fusion zone during tensile testing. The fracture surfaces were examined by scanning electron microscopy and the microhardness distribution in the joints was measured by using a Vickers microhardness tester.