Considering the action mechanisms of overpressure on physical changes in skeleton particles of deep reservoir rocks and the differences in physical changes of skeleton particles under overpressure and hydrostatic pres...Considering the action mechanisms of overpressure on physical changes in skeleton particles of deep reservoir rocks and the differences in physical changes of skeleton particles under overpressure and hydrostatic pressure, the sandstone of the Jurassic Toutunhe Formation in the southern margin of Junggar Basin was taken as an example for physical modeling experiment to analyze the action mechanisms of overpressure on the physical properties of deep reservoirs. (1) In the simulated ultra-deep layer with a burial depth of 6000-8000 m, the mechanical compaction under overpressure reduces the remaining primary pores by about a half that under hydrostatic pressure. Overpressure can effectively suppress the mechanical compaction to allow the preservation of intergranular primary pores. (2) The linear contact length ratio under overpressure is always smaller than the linear contact length ratio under hydrostatic pressure at the same depth. In deep reservoirs, the difference between the mechanical compaction degree under overpressure and hydrostatic pressure shows a decreasing trend, the effect of abnormally high pressure to resist the increase of effective stress is weakened, and the degree of mechanical compaction is gradually close to that under hydrostatic pressure. (3) The microfractures in skeleton particles of deep reservoirs under overpressure are thin and long, while the microfractures in skeleton particles of deep reservoirs under hydrostatic pressure are short and wide. This difference is attributed to the probable presence of tension fractures in the rocks containing abnormally high pressure fluid. (4) The microfractures in skeleton particles under overpressure were mainly formed later than that under hydrostatic pressure, and the development degree and length of microfractures both extend deeper. (5) The development stages of microfractures under overpressure are mainly controlled by the development stages of abnormally high pressure and the magnitude of effective stress acting on the skeleton particles. Moreover, the development stages of microfractures in skeleton particles are more than those under hydrostatic pressure in deep reservoir. The multi-stage abnormally high pressure plays an important role in improving the physical properties of deep reservoirs.展开更多
Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are...Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are discussed. The correlation between the pressure systems and hydrocarbon accumulation is addressed by analyzing the corresponding fluid characteristics. The results show that the Huatugou oil field as a whole has low formation pressure and low fluid energy; therefore, the hydrocarbons are hard to migrate, which facilitates the forming of primary reservoirs. The study reservoirs, located at the Xiayoushashan Formation (N1/2) and the Shangganchaigou Formation (N1) are relatively shallow and have medium porosity and low permeability. They are abnormal low-pressure reservoirs with an average formation pressure coefficient of 0.61 and 0.72 respectively. According to the pressure coefficient and geothermal anomaly, the N1 and N1/2 Formations belong to two independent temperature-pressure systems, and the former has slightly higher energy. The low-pressure compartments consist of a distal bar as the main body, prodelta mud as the top boundary, and shore and shallow lake mud or algal mound as the bottom boundary. They are vertically overlapped and horizontally paralleled. The formation water is abundant in the Cl^- ion and can be categorized as CaCl2 type with high safinity, which indicates that the abnormal low-pressure compartments are in good sealing condition and beneficial for oil and gas accumulation and preservation.展开更多
The characteristics of reservoir heterogeneity of the marine gravity flow tight sandstone from the Miocene Huangliu Formation under abnormally high pressure setting at LD10 area in Yinggehai Basin are studied,and the ...The characteristics of reservoir heterogeneity of the marine gravity flow tight sandstone from the Miocene Huangliu Formation under abnormally high pressure setting at LD10 area in Yinggehai Basin are studied,and the influencing factors on reservoir heterogeneity are discussed,based on modular formation dynamics test,thin sections,XRD analysis of clay minerals,scanning electron microscopy,measurement of pore throat image,porosity and permeability,and high pressure Hg injection,as well as the stimulation of burial thermal history.The aim is to elucidate characteristics of the heterogeneity and the evolution process of heterogeneity of the reservoir,and predict the favorable reservoirs distribution.(1)The heterogeneity of the reservoir is mainly controlled by the cement heterogeneity,pore throat heterogeneity,quality of the reservoir heterogeneity,and the diagenesis under an abnormally high pressure setting.(2)The differences in pore-throat structure caused by diagenetic evolution affected the intergranular material heterogeneity and the pore throat heterogeneity,and finally controlled the heterogeneity of reservoir quality.(3)Compared with the reservoir under normal pressure,abnormally high pressure restrains strength of the compaction and cementation and enhances the dissolution of the reservoir to some extent,and abnormally high pressure thus weakening the heterogeneity of the reservoir to a certain degree.The favorable reservoirs are mainly distributed in the gravity flow sand body under the strong overpressure zone in the middle and lower part of Huangliu Formation.展开更多
Based on the comprehensive research on core samples,well testing data and fluid parameters of the reservoirs,the depositional architecture of the abnormal low pressure compartment and fluid characteristics of Huatugou...Based on the comprehensive research on core samples,well testing data and fluid parameters of the reservoirs,the depositional architecture of the abnormal low pressure compartment and fluid characteristics of Huatugou oilfield of Qaidam basin were reported,and the correlation between the compartment and hydrocarbon accumulation was revealed. The result indicates that the reservoirs are located展开更多
Atmospheric pressure abnormal glow discharge (APAGD) was carried out simply with a transformer of 1 : 500 driven by a alternating current with a frequency of 50 Hz. Typical stable discharge parameters, namely volta...Atmospheric pressure abnormal glow discharge (APAGD) was carried out simply with a transformer of 1 : 500 driven by a alternating current with a frequency of 50 Hz. Typical stable discharge parameters, namely voltage of 400 V to 850 V and current of 60 mA to 110 mA were measured by oscillograph. Simulation of the discharge process suggested that the stable discharge was supported by the impedance from the secondary coil of the transformer, which offered a negative feedback to prevent the discharge from turning into an arc. An interpretation was given for the oscillogram of the sinuous discharge current and square voltage. Furthermore, the electron temperature and electron density averaged in the discharge channel of APAGD were estimated.展开更多
Ying-Qiong Basin in the west of South China Sea contains plenty of abnormal high-pressure gas reservoirs, whose stress sensitivity is crucial for well productivity. To explore the influence of stress sensitivity on pr...Ying-Qiong Basin in the west of South China Sea contains plenty of abnormal high-pressure gas reservoirs, whose stress sensitivity is crucial for well productivity. To explore the influence of stress sensitivity on production, the variable outlet back pressure stress sensitivity experiments were applied to test core sample permeability under different burden pressure and obtain the relational expression of power function of core stress sensitivity. Afterwards, new productivity equation is deduced in consideration of reservoir stress sensitivity, and the affection of stress sensitivity on production is analyzed. The result demonstrates close link between stress sensitivity and productivity, since single well production decreases dramatically when reservoir stress sensitivity has been taken into account. This research is constructive for well-testing data interpretation in stress sensitive gas reservoirs.展开更多
KeLa-2 gas reservoir is the largest uncompartimentalized gas field so far discovered in China, with a reserve of hundreds of billions of cubic meters of dry gas. It has such features as extremely long interval (550m)...KeLa-2 gas reservoir is the largest uncompartimentalized gas field so far discovered in China, with a reserve of hundreds of billions of cubic meters of dry gas. It has such features as extremely long interval (550m), high pressure (74.5MPa) and pressure coefficient (2.022). Gas reservoirs with a pressure coefficient of over 2.0 are not commonly found. The abnormal high-pressure reservoirs are quite different in characteristic and performance during the process of depletion exploitation. Therefore, it is necessary to know the property of pressure sensitivity for this abnormal high-pressure reservoir. The aim of this paper is to test the reservoir pressure sensitivity and to analyze its effect on the deliverability of gas. Through some experiments, the permeability change with the confining pressure of rock samples from KeLa-2 abnormal high-pressure gas reservoir is measured. A power function is used to match the measured data, and to derive an empirical equation to describe the change of permeability through the change of the reservoir pressure or effective overburden pressure. Considering the permeability change during the development of reservoirs, a conventional deliverability equation is modified, and the deliverability curve for KeLa-2 gas reservoir is predicted. The research indicates that the extent of the pressure sensitivity of rock samples from KeLa-2 is higher than that from the Daqing oilfield. KeLa-2 reservoir rock has the feature of an undercompaction state. The pressure sensitivity of a reservoir may decrease the well deliverability. It is concluded that for KeLa-2 reservoir the predicted absolute open flow (AOF), when the pressure sensitivity is taken into account, is approximately 70% of the AOF when permeability is constant and does not change with pressure.展开更多
The distribution and genetic mechanisms of abnormal pressures in the Bohai Bay Basin were systematically analyzed. Abnormal pressures are widely developed in the Bohai Bay Basin, primarily in the Paleogene E2s4, E2s3,...The distribution and genetic mechanisms of abnormal pressures in the Bohai Bay Basin were systematically analyzed. Abnormal pressures are widely developed in the Bohai Bay Basin, primarily in the Paleogene E2s4, E2s3, Es1, and Ed formations. From the onshore area of the Bohai Bay Basin to the center of the Bozhong area, the top depth of the overpressured zone in each depression increases gradually, the overpressured strata in each depression gradually move to younger formations, and the pressure structure successively alters from single-bottom- overpressure to double-bottom-overpressure and finally to double-top-overpressure. The distribution of overpressured area is consistent with the sedimentary migration controlled by the tectonic evolution of the Bohai Bay Basin, which is closely related to the hydrocarbon-generation capability of active source rocks. The overpressured strata are consistent with the source-rock intervals in each depression; the top of the overpressured zone is synchronous with the hydrocarbon generation threshold in each depression; the hydrocarbon generation capability is positively correlated with the overpressure magnitude in each formation. Undercompaction was the main mechanism of overpressure for depressions with fluid pressure coefficients less than 1.2, whereas hydrocarbon generation was the main mechanism for depressions with fluid pressure coefficients greater than 1.5.展开更多
The formation of abnormally low-pressure hydrocarbon reservoirs in petroliferous basins has a close relationship with tectonic uplift and the consequent erosion. In order to understand abnormally low-pressure reservoi...The formation of abnormally low-pressure hydrocarbon reservoirs in petroliferous basins has a close relationship with tectonic uplift and the consequent erosion. In order to understand abnormally low-pressure reservoirs and to provide a scientific basis for exploration and development, we established, through numerical simulation and theoretical analysis, a set of equations for the formation pressure in a closed system influenced by uplift-erosion, discussed the relationship between the genesis of abnormal pressure and uplift-erosion, and put forward the concept of balance pressure (P b ). The results showed that abnormally high pressure coefficient may form when the current formation pressure was higher than P b , and abnormally low pressure may form when the current formation pressure was lower than P b . In the Santanghu Basin, the current formation pressure of abnormally low pressure reservoirs is lower than P b , so tectonic uplift-erosion leads to the decrease of the pressure coefficient. There is a positive correlation between the pressure drop caused by the decrease of fluid temperature and the rebound of rock porosity and strata erosion. Calculation results indicated that the reservoir pressure of Jurassic strata in the Santanghu Basin was decreased by 11.6-17.1 MPa due to tectonic uplift-erosion during the Late Yanshanian period.展开更多
Aiming at the differential distribution of overpressure in vertical and lateral directions in the foreland thrust belt in the southern margin of Junggar Basin,the study on overpressure origin identification and overpr...Aiming at the differential distribution of overpressure in vertical and lateral directions in the foreland thrust belt in the southern margin of Junggar Basin,the study on overpressure origin identification and overpressure evolution simulation is carried out.Based on the measured formation pressure,drilling fluid density and well logging data,overpressure origin identification and overpressure evolution simulation techniques are used to analyze the vertical and lateral distribution patterns of overpressure,genetic mechanisms of overpressure in different structural belts and causes of the differential distribution of overpressure,and the controlling effects of overpressure development and evolution on the formation and distribution of oil and gas reservoirs.The research shows that overpressure occurs in multiple formations vertically in the southern Junggar foreland thrust belt,the deeper the formation,the bigger the scale of the overpressure is.Laterally,overpressure is least developed in the mountain front belt,most developed in the fold anticline belt,and relatively developed in the slope belt.The differential distribution of overpressure is mainly controlled by the differences in disequilibrium compaction and tectonic compression strengths of different belts.The vertical overpressure transmission caused by faults connecting the deep overpressured system has an important contribution to the further increase of the overpressure strength in this area.The controlling effect of overpressure development and evolution on hydrocarbon accumulation and distribution shows in the following aspects:When the strong overpressure was formed before reservoir becoming tight overpressure maintains the physical properties of deep reservoirs to some extent,expanding the exploration depth of deep reservoirs;reservoirs below the overpressured mudstone cap rocks of the Paleogene Anjihaihe Formation and Lower Cretaceous Tugulu Group are main sites for oil and gas accumulation;under the background of overall overpressure,both overpressure strength too high or too low are not conducive to hydrocarbon enrichment and preservation,and the pressure coefficient between 1.6 and 2.1 is the best.展开更多
Metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)with highly ordered porous structure,tunable bandgap,large specific surface area and structural diversity,provide an appealing platform for the develo...Metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)with highly ordered porous structure,tunable bandgap,large specific surface area and structural diversity,provide an appealing platform for the development of stimulus response,sensing,imaging and optoelectronics.Among various tuning methods,pressure engineering using the diamond anvil cell is a highly powerful in-situ technique,which can efficiently modulate the structural and optical properties of MOFs/COFs.This is beyond the realization of traditional chemical methods.This review outlines the research progress in the experimentoriented discovery of new phases or unique properties under high pressure,including phase transition,abnormal compression,photoluminescence(PL)discoloration and enhancement.Notably,the improvement of PL quantum yield in MOFs could be achieved by pressure-treated engineering and hydrogen-bonding cooperativity effect.We also propose and establish the relationship between structure and optical properties under high pressure.Finally,the challenge and outlook of the current fields are summarized.We hope that this review will supply guidance for comprehending the development of high-pressure MOF/COF-related research fields,and offer novel strategies for designing more high-performance MOF/COF materials to ultimately expand their applications.展开更多
基金Supported by PetroChina Science and Technology Project(2021DJ0202).
文摘Considering the action mechanisms of overpressure on physical changes in skeleton particles of deep reservoir rocks and the differences in physical changes of skeleton particles under overpressure and hydrostatic pressure, the sandstone of the Jurassic Toutunhe Formation in the southern margin of Junggar Basin was taken as an example for physical modeling experiment to analyze the action mechanisms of overpressure on the physical properties of deep reservoirs. (1) In the simulated ultra-deep layer with a burial depth of 6000-8000 m, the mechanical compaction under overpressure reduces the remaining primary pores by about a half that under hydrostatic pressure. Overpressure can effectively suppress the mechanical compaction to allow the preservation of intergranular primary pores. (2) The linear contact length ratio under overpressure is always smaller than the linear contact length ratio under hydrostatic pressure at the same depth. In deep reservoirs, the difference between the mechanical compaction degree under overpressure and hydrostatic pressure shows a decreasing trend, the effect of abnormally high pressure to resist the increase of effective stress is weakened, and the degree of mechanical compaction is gradually close to that under hydrostatic pressure. (3) The microfractures in skeleton particles of deep reservoirs under overpressure are thin and long, while the microfractures in skeleton particles of deep reservoirs under hydrostatic pressure are short and wide. This difference is attributed to the probable presence of tension fractures in the rocks containing abnormally high pressure fluid. (4) The microfractures in skeleton particles under overpressure were mainly formed later than that under hydrostatic pressure, and the development degree and length of microfractures both extend deeper. (5) The development stages of microfractures under overpressure are mainly controlled by the development stages of abnormally high pressure and the magnitude of effective stress acting on the skeleton particles. Moreover, the development stages of microfractures in skeleton particles are more than those under hydrostatic pressure in deep reservoir. The multi-stage abnormally high pressure plays an important role in improving the physical properties of deep reservoirs.
基金fmancially supported by the National Natural Science Foundation of China(No.40802027)the PetroChina Innovation Fund(No.0706d01040102)
文摘Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are discussed. The correlation between the pressure systems and hydrocarbon accumulation is addressed by analyzing the corresponding fluid characteristics. The results show that the Huatugou oil field as a whole has low formation pressure and low fluid energy; therefore, the hydrocarbons are hard to migrate, which facilitates the forming of primary reservoirs. The study reservoirs, located at the Xiayoushashan Formation (N1/2) and the Shangganchaigou Formation (N1) are relatively shallow and have medium porosity and low permeability. They are abnormal low-pressure reservoirs with an average formation pressure coefficient of 0.61 and 0.72 respectively. According to the pressure coefficient and geothermal anomaly, the N1 and N1/2 Formations belong to two independent temperature-pressure systems, and the former has slightly higher energy. The low-pressure compartments consist of a distal bar as the main body, prodelta mud as the top boundary, and shore and shallow lake mud or algal mound as the bottom boundary. They are vertically overlapped and horizontally paralleled. The formation water is abundant in the Cl^- ion and can be categorized as CaCl2 type with high safinity, which indicates that the abnormal low-pressure compartments are in good sealing condition and beneficial for oil and gas accumulation and preservation.
基金Supported by the Research on Exploration and Development Technology and New Exploration Field of High Temperature and Pressure Gas Reservoir in Western South China Sea(CNOOC-KJ135ZDXM38ZJ02ZJ)National Natural Science Foundation of China(41972129)National Science and Technology Key Project(2016ZX05024-005,2016ZX05026-003-005)。
文摘The characteristics of reservoir heterogeneity of the marine gravity flow tight sandstone from the Miocene Huangliu Formation under abnormally high pressure setting at LD10 area in Yinggehai Basin are studied,and the influencing factors on reservoir heterogeneity are discussed,based on modular formation dynamics test,thin sections,XRD analysis of clay minerals,scanning electron microscopy,measurement of pore throat image,porosity and permeability,and high pressure Hg injection,as well as the stimulation of burial thermal history.The aim is to elucidate characteristics of the heterogeneity and the evolution process of heterogeneity of the reservoir,and predict the favorable reservoirs distribution.(1)The heterogeneity of the reservoir is mainly controlled by the cement heterogeneity,pore throat heterogeneity,quality of the reservoir heterogeneity,and the diagenesis under an abnormally high pressure setting.(2)The differences in pore-throat structure caused by diagenetic evolution affected the intergranular material heterogeneity and the pore throat heterogeneity,and finally controlled the heterogeneity of reservoir quality.(3)Compared with the reservoir under normal pressure,abnormally high pressure restrains strength of the compaction and cementation and enhances the dissolution of the reservoir to some extent,and abnormally high pressure thus weakening the heterogeneity of the reservoir to a certain degree.The favorable reservoirs are mainly distributed in the gravity flow sand body under the strong overpressure zone in the middle and lower part of Huangliu Formation.
文摘Based on the comprehensive research on core samples,well testing data and fluid parameters of the reservoirs,the depositional architecture of the abnormal low pressure compartment and fluid characteristics of Huatugou oilfield of Qaidam basin were reported,and the correlation between the compartment and hydrocarbon accumulation was revealed. The result indicates that the reservoirs are located
基金National Natural Science Foundation of China(No.10475060)
文摘Atmospheric pressure abnormal glow discharge (APAGD) was carried out simply with a transformer of 1 : 500 driven by a alternating current with a frequency of 50 Hz. Typical stable discharge parameters, namely voltage of 400 V to 850 V and current of 60 mA to 110 mA were measured by oscillograph. Simulation of the discharge process suggested that the stable discharge was supported by the impedance from the secondary coil of the transformer, which offered a negative feedback to prevent the discharge from turning into an arc. An interpretation was given for the oscillogram of the sinuous discharge current and square voltage. Furthermore, the electron temperature and electron density averaged in the discharge channel of APAGD were estimated.
文摘Ying-Qiong Basin in the west of South China Sea contains plenty of abnormal high-pressure gas reservoirs, whose stress sensitivity is crucial for well productivity. To explore the influence of stress sensitivity on production, the variable outlet back pressure stress sensitivity experiments were applied to test core sample permeability under different burden pressure and obtain the relational expression of power function of core stress sensitivity. Afterwards, new productivity equation is deduced in consideration of reservoir stress sensitivity, and the affection of stress sensitivity on production is analyzed. The result demonstrates close link between stress sensitivity and productivity, since single well production decreases dramatically when reservoir stress sensitivity has been taken into account. This research is constructive for well-testing data interpretation in stress sensitive gas reservoirs.
文摘KeLa-2 gas reservoir is the largest uncompartimentalized gas field so far discovered in China, with a reserve of hundreds of billions of cubic meters of dry gas. It has such features as extremely long interval (550m), high pressure (74.5MPa) and pressure coefficient (2.022). Gas reservoirs with a pressure coefficient of over 2.0 are not commonly found. The abnormal high-pressure reservoirs are quite different in characteristic and performance during the process of depletion exploitation. Therefore, it is necessary to know the property of pressure sensitivity for this abnormal high-pressure reservoir. The aim of this paper is to test the reservoir pressure sensitivity and to analyze its effect on the deliverability of gas. Through some experiments, the permeability change with the confining pressure of rock samples from KeLa-2 abnormal high-pressure gas reservoir is measured. A power function is used to match the measured data, and to derive an empirical equation to describe the change of permeability through the change of the reservoir pressure or effective overburden pressure. Considering the permeability change during the development of reservoirs, a conventional deliverability equation is modified, and the deliverability curve for KeLa-2 gas reservoir is predicted. The research indicates that the extent of the pressure sensitivity of rock samples from KeLa-2 is higher than that from the Daqing oilfield. KeLa-2 reservoir rock has the feature of an undercompaction state. The pressure sensitivity of a reservoir may decrease the well deliverability. It is concluded that for KeLa-2 reservoir the predicted absolute open flow (AOF), when the pressure sensitivity is taken into account, is approximately 70% of the AOF when permeability is constant and does not change with pressure.
基金the National Natural Science Foundation(Grant No.41502129)the Important National Science & Technology Specific Projects(grant No.2016ZX05006-003)the Fundamental Research Funds for the Central Universities(grant No.14CX05015A)
文摘The distribution and genetic mechanisms of abnormal pressures in the Bohai Bay Basin were systematically analyzed. Abnormal pressures are widely developed in the Bohai Bay Basin, primarily in the Paleogene E2s4, E2s3, Es1, and Ed formations. From the onshore area of the Bohai Bay Basin to the center of the Bozhong area, the top depth of the overpressured zone in each depression increases gradually, the overpressured strata in each depression gradually move to younger formations, and the pressure structure successively alters from single-bottom- overpressure to double-bottom-overpressure and finally to double-top-overpressure. The distribution of overpressured area is consistent with the sedimentary migration controlled by the tectonic evolution of the Bohai Bay Basin, which is closely related to the hydrocarbon-generation capability of active source rocks. The overpressured strata are consistent with the source-rock intervals in each depression; the top of the overpressured zone is synchronous with the hydrocarbon generation threshold in each depression; the hydrocarbon generation capability is positively correlated with the overpressure magnitude in each formation. Undercompaction was the main mechanism of overpressure for depressions with fluid pressure coefficients less than 1.2, whereas hydrocarbon generation was the main mechanism for depressions with fluid pressure coefficients greater than 1.5.
基金supported by the National Natural Science Foundation of China (No. 40802027)China "973" Project (No. 2009CB219604)the Risk Innovation Foundation of PetroChina Co. Ltd. (No. 0706d01040102)
文摘The formation of abnormally low-pressure hydrocarbon reservoirs in petroliferous basins has a close relationship with tectonic uplift and the consequent erosion. In order to understand abnormally low-pressure reservoirs and to provide a scientific basis for exploration and development, we established, through numerical simulation and theoretical analysis, a set of equations for the formation pressure in a closed system influenced by uplift-erosion, discussed the relationship between the genesis of abnormal pressure and uplift-erosion, and put forward the concept of balance pressure (P b ). The results showed that abnormally high pressure coefficient may form when the current formation pressure was higher than P b , and abnormally low pressure may form when the current formation pressure was lower than P b . In the Santanghu Basin, the current formation pressure of abnormally low pressure reservoirs is lower than P b , so tectonic uplift-erosion leads to the decrease of the pressure coefficient. There is a positive correlation between the pressure drop caused by the decrease of fluid temperature and the rebound of rock porosity and strata erosion. Calculation results indicated that the reservoir pressure of Jurassic strata in the Santanghu Basin was decreased by 11.6-17.1 MPa due to tectonic uplift-erosion during the Late Yanshanian period.
基金PetroChina Science and Technology Development Project(2021DJ0105,2021DJ0203,2021DJ0303)National Natural Science Foundation of China(42172164,42002177)。
文摘Aiming at the differential distribution of overpressure in vertical and lateral directions in the foreland thrust belt in the southern margin of Junggar Basin,the study on overpressure origin identification and overpressure evolution simulation is carried out.Based on the measured formation pressure,drilling fluid density and well logging data,overpressure origin identification and overpressure evolution simulation techniques are used to analyze the vertical and lateral distribution patterns of overpressure,genetic mechanisms of overpressure in different structural belts and causes of the differential distribution of overpressure,and the controlling effects of overpressure development and evolution on the formation and distribution of oil and gas reservoirs.The research shows that overpressure occurs in multiple formations vertically in the southern Junggar foreland thrust belt,the deeper the formation,the bigger the scale of the overpressure is.Laterally,overpressure is least developed in the mountain front belt,most developed in the fold anticline belt,and relatively developed in the slope belt.The differential distribution of overpressure is mainly controlled by the differences in disequilibrium compaction and tectonic compression strengths of different belts.The vertical overpressure transmission caused by faults connecting the deep overpressured system has an important contribution to the further increase of the overpressure strength in this area.The controlling effect of overpressure development and evolution on hydrocarbon accumulation and distribution shows in the following aspects:When the strong overpressure was formed before reservoir becoming tight overpressure maintains the physical properties of deep reservoirs to some extent,expanding the exploration depth of deep reservoirs;reservoirs below the overpressured mudstone cap rocks of the Paleogene Anjihaihe Formation and Lower Cretaceous Tugulu Group are main sites for oil and gas accumulation;under the background of overall overpressure,both overpressure strength too high or too low are not conducive to hydrocarbon enrichment and preservation,and the pressure coefficient between 1.6 and 2.1 is the best.
基金supported by the National Natural Science Foundation of China(12304261,12274177)。
文摘Metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)with highly ordered porous structure,tunable bandgap,large specific surface area and structural diversity,provide an appealing platform for the development of stimulus response,sensing,imaging and optoelectronics.Among various tuning methods,pressure engineering using the diamond anvil cell is a highly powerful in-situ technique,which can efficiently modulate the structural and optical properties of MOFs/COFs.This is beyond the realization of traditional chemical methods.This review outlines the research progress in the experimentoriented discovery of new phases or unique properties under high pressure,including phase transition,abnormal compression,photoluminescence(PL)discoloration and enhancement.Notably,the improvement of PL quantum yield in MOFs could be achieved by pressure-treated engineering and hydrogen-bonding cooperativity effect.We also propose and establish the relationship between structure and optical properties under high pressure.Finally,the challenge and outlook of the current fields are summarized.We hope that this review will supply guidance for comprehending the development of high-pressure MOF/COF-related research fields,and offer novel strategies for designing more high-performance MOF/COF materials to ultimately expand their applications.