Experimental and theoretical analysis were made on the natural humic acid removal and the membrane fouling of ultrafiltration （UF） with in-line coagulation. The results showed dissolved organic carbon （DOC） and UV...Experimental and theoretical analysis were made on the natural humic acid removal and the membrane fouling of ultrafiltration （UF） with in-line coagulation. The results showed dissolved organic carbon （DOC） and UV254 removals by the UF with in-line coagulation at pH 7 were increased from 28% to 53% and 40% to 78% in comparison with direct UF treatment respectively. At the same time, the analysis of high performance liquid chromatography showed that UF with coagulation had significant improvement of removal of humic acid with molecular weights less than 6000 Da in particular. Compared to direct UF, the in-line coagulation UF also kept more constant permeate flux and very slight increase oftransmembrane pressure during a filtration circle. Two typical membrane fouling models were used by inducing two coefficients Kc and Kp corresponding to cake filtration model and pore narrowing model respectively. It was found that membrane fouling by pore-narrowing effect was effectively alleviated and that by cake-filtration was much decreased by in-line coagulation. Under the condition of coagulation prior to ultrafiltration at pH 7, the cake layer formed on the membrane surface became thicker, but the membrane filtration resistance was lower than that at pH 5 with the extension of operation time.展开更多
Palm oil industry is the most important agro-industry in Malaysia, but its by-product-palm oil mill effluent （POME）, posed a great threat to water environment. In the past decades, several treatment and disposal met...Palm oil industry is the most important agro-industry in Malaysia, but its by-product-palm oil mill effluent （POME）, posed a great threat to water environment. In the past decades, several treatment and disposal methods have been proposed and investigated to solve this problem. A two-stage pilot-scale plant was designed and constructed for POME treatment. Anaerobic digestion and aerobic biodegradation constituted the first biological stage, while ultrafiltration （UF） and reverse osmosis （RO） membrane units were combined as the second membrane separation stage. In the anaerobic expanded granular sludge bed （EGSB） reactor, about 43% organic matter in POME was converted into biogas, and COD reduction efficiency reached 93% and 22% in EGSB and the following aerobic reactor, respectively. With the treatment in the first biological stage, suspended solids and oil also decreased to a low degree. All these alleviated the membrane fouling and prolonged the membrane life. In the membrane process unit, almost all the suspended solids were captured by UF membranes, while RO membrane excluded most of the dissolved solids or inorganic salts from RO permeate. After the whole treatment processes, organic matter in POME expressed by BOD and COD was removed almost thoroughly. Suspended solids and color were not detectable in RO permeate any more, and mineral elements only existed in trace amount （except for K and Na）. The high-quality effluent was crystal clear and could be used as the boiler feed water.展开更多
Membrane science and technology has been developed very fast in recent years in China.The Zhong Ke Membrane Re-search & Development Centre of Beijing(its predecessor is the Polymer Division of Research Centre for ...Membrane science and technology has been developed very fast in recent years in China.The Zhong Ke Membrane Re-search & Development Centre of Beijing(its predecessor is the Polymer Division of Research Centre for Eco-EnvironmentalSciences,Chinese Academy of Science)is one of the main institutions on membrane research and development,has been de-voted itself to the study and application of the membrane science and technology and has obtained great achievements since1975.More than ten kinds of polymers or their blend have been used for manufacturing ultrafiltration(UF)membranes withmolecular weight cut off from 3000 to 150000 dalton for plate membrane and from 6000-100000 dalton for hollow fiber展开更多
水厂排泥水处理过程中会产生较大量的污泥脱水液。为避免南水北调引江水资源的浪费,同时积极推进水厂的“零排放”建设目标,面向以引江水为水源的超滤处理工艺,评价了将污泥脱水液回流至原水池进行稀释回用的可行性。考察了不同污泥脱水...水厂排泥水处理过程中会产生较大量的污泥脱水液。为避免南水北调引江水资源的浪费,同时积极推进水厂的“零排放”建设目标,面向以引江水为水源的超滤处理工艺,评价了将污泥脱水液回流至原水池进行稀释回用的可行性。考察了不同污泥脱水液/引江原水混合比例下超滤系统的运行特性,发现当污泥脱水液适当稀释后,其对超滤净水效果和膜污染的影响急剧降低,当稀释比例达到1∶800时,出水水质与跨膜压增长曲线已接近引江原水直接超滤的情况。试验中引江原水的跨膜压增长速率为19.7 k Pa/d,而污泥脱水液原液则达到25.8 k Pa/d。当两者以1∶800比例稀释后,跨膜压增长速率下降为21.3 k Pa/d,接近于引江原水。膜表面微观表征结果显示随着稀释比例的提高,滤饼层厚度、溶解性有机物、特征官能团红外峰强、污染元素相对质量分数均显著降低,逐渐下降到与原水直接超滤相近的水平。引江原水组的超滤膜滤饼层厚度为1.77μm,而污泥脱水液原液组的滤饼层厚度为4.00μm,污染程度较重。两者按1∶800比例稀释后的滤饼层厚度降低至1.82μm,污染程度显著降低。研究结果可为南水北调受水城市超滤水厂的“零排放”建设提供参考。但值得注意的是,污泥脱水液的合理处置与利用问题目前仍处于起步和探索阶段,未来仍需从水质生物安全性和化学安全性的角度加以系统评估。同时可考虑氧化、吸附、微滤分离等预处理手段,以提高污泥脱水液回用过程的安全性。展开更多
基金The National Natural Science Foundation of China (No. 50138020)
文摘Experimental and theoretical analysis were made on the natural humic acid removal and the membrane fouling of ultrafiltration （UF） with in-line coagulation. The results showed dissolved organic carbon （DOC） and UV254 removals by the UF with in-line coagulation at pH 7 were increased from 28% to 53% and 40% to 78% in comparison with direct UF treatment respectively. At the same time, the analysis of high performance liquid chromatography showed that UF with coagulation had significant improvement of removal of humic acid with molecular weights less than 6000 Da in particular. Compared to direct UF, the in-line coagulation UF also kept more constant permeate flux and very slight increase oftransmembrane pressure during a filtration circle. Two typical membrane fouling models were used by inducing two coefficients Kc and Kp corresponding to cake filtration model and pore narrowing model respectively. It was found that membrane fouling by pore-narrowing effect was effectively alleviated and that by cake-filtration was much decreased by in-line coagulation. Under the condition of coagulation prior to ultrafiltration at pH 7, the cake layer formed on the membrane surface became thicker, but the membrane filtration resistance was lower than that at pH 5 with the extension of operation time.
文摘Palm oil industry is the most important agro-industry in Malaysia, but its by-product-palm oil mill effluent （POME）, posed a great threat to water environment. In the past decades, several treatment and disposal methods have been proposed and investigated to solve this problem. A two-stage pilot-scale plant was designed and constructed for POME treatment. Anaerobic digestion and aerobic biodegradation constituted the first biological stage, while ultrafiltration （UF） and reverse osmosis （RO） membrane units were combined as the second membrane separation stage. In the anaerobic expanded granular sludge bed （EGSB） reactor, about 43% organic matter in POME was converted into biogas, and COD reduction efficiency reached 93% and 22% in EGSB and the following aerobic reactor, respectively. With the treatment in the first biological stage, suspended solids and oil also decreased to a low degree. All these alleviated the membrane fouling and prolonged the membrane life. In the membrane process unit, almost all the suspended solids were captured by UF membranes, while RO membrane excluded most of the dissolved solids or inorganic salts from RO permeate. After the whole treatment processes, organic matter in POME expressed by BOD and COD was removed almost thoroughly. Suspended solids and color were not detectable in RO permeate any more, and mineral elements only existed in trace amount （except for K and Na）. The high-quality effluent was crystal clear and could be used as the boiler feed water.
文摘Membrane science and technology has been developed very fast in recent years in China.The Zhong Ke Membrane Re-search & Development Centre of Beijing(its predecessor is the Polymer Division of Research Centre for Eco-EnvironmentalSciences,Chinese Academy of Science)is one of the main institutions on membrane research and development,has been de-voted itself to the study and application of the membrane science and technology and has obtained great achievements since1975.More than ten kinds of polymers or their blend have been used for manufacturing ultrafiltration(UF)membranes withmolecular weight cut off from 3000 to 150000 dalton for plate membrane and from 6000-100000 dalton for hollow fiber
文摘水厂排泥水处理过程中会产生较大量的污泥脱水液。为避免南水北调引江水资源的浪费,同时积极推进水厂的“零排放”建设目标,面向以引江水为水源的超滤处理工艺,评价了将污泥脱水液回流至原水池进行稀释回用的可行性。考察了不同污泥脱水液/引江原水混合比例下超滤系统的运行特性,发现当污泥脱水液适当稀释后,其对超滤净水效果和膜污染的影响急剧降低,当稀释比例达到1∶800时,出水水质与跨膜压增长曲线已接近引江原水直接超滤的情况。试验中引江原水的跨膜压增长速率为19.7 k Pa/d,而污泥脱水液原液则达到25.8 k Pa/d。当两者以1∶800比例稀释后,跨膜压增长速率下降为21.3 k Pa/d,接近于引江原水。膜表面微观表征结果显示随着稀释比例的提高,滤饼层厚度、溶解性有机物、特征官能团红外峰强、污染元素相对质量分数均显著降低,逐渐下降到与原水直接超滤相近的水平。引江原水组的超滤膜滤饼层厚度为1.77μm,而污泥脱水液原液组的滤饼层厚度为4.00μm,污染程度较重。两者按1∶800比例稀释后的滤饼层厚度降低至1.82μm,污染程度显著降低。研究结果可为南水北调受水城市超滤水厂的“零排放”建设提供参考。但值得注意的是,污泥脱水液的合理处置与利用问题目前仍处于起步和探索阶段,未来仍需从水质生物安全性和化学安全性的角度加以系统评估。同时可考虑氧化、吸附、微滤分离等预处理手段,以提高污泥脱水液回用过程的安全性。
