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Clean Coal &High Carbon Efficiency Energy Engineering
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作者 Stefan Petters Kalvin Tse 《Journal of Power and Energy Engineering》 2015年第4期348-355,共8页
Today we live in a world of Hydrocarbon Energy Carriers, where Carbon is always used as a Carrier for Hydrogen 1) Biomass (CH1.44O0.66 or C6H12O6);2) Natural Gas [NG] (CH4);3) Water Gas [C+H2O];4) Gasoline (C6H12, C7H... Today we live in a world of Hydrocarbon Energy Carriers, where Carbon is always used as a Carrier for Hydrogen 1) Biomass (CH1.44O0.66 or C6H12O6);2) Natural Gas [NG] (CH4);3) Water Gas [C+H2O];4) Gasoline (C6H12, C7H18, C8H18, etc.);5) Kerosene (C17H36, C18H38, C19H40, C20H42, C21H44, C22H46, etc.) and;6) Crude Oil. The Carbon aggregates are all storable and have worthwhile, logistically manageable energy densities. But whenever recovering Energy from the Carbon molarities, CO2 gets emitted into the atmosphere, while separate use of Hydrogen Energy contents carried by the Carbon moieties would just generate water vapor. Hydrogen is also the most important intermediary in Refineries, hydrogenating lower grade Hydrocarbons into higher potencies, or for removing Sulfur by the formation of Hydrogen Sulfur, that can be dissociated after its segregation from the Hydrocarbon products. But most of the internal Hydrogen yields in Refineries today is used for onsite production of Ammonia as a basis for Energy fertilizers in high performance agriculture. Because Hydrogen is awkward to store and transport, most of it is currently used captive within large size centralized plants as a reactant for producing Hydrocarbon energy carriers, using the Carbon as a carrier for the Hydrogen moieties, to then be distributed over big enough areas for consumption of the such large scale plants’ volumes. With recently proven achievements of Hydrogen production from excess Wind & Solar Power by electrolysis, Hydrogen could become available in abundant quantities, to be distributed locally within the coverage area of the transmission grid such Wind & Solar installations are feeding into. In combination with Carbon as a reactant such abundant Hydrogen could also be synthesized into Hydrocarbon Energy Carriers and substitute fossil commodities. 展开更多
关键词 Atmospheric carbon carbon EFFICIENCY carbon Metabolism carbon Re-Use Chemical ENERGY Content Controlled Microbial Composting ENERGY Carriers Fossil Substitute Commodities INTERMEDIARIES Heating Value Hybrid Power Plant Hydrocarbon Hydrogen Organic Waste VALORIZATION Photosynthesis Productivity REFINERIES
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Modelling of a post-combustion carbon dioxide capture absorber using potassium carbonate solvent in Aspen Custom Modeller 被引量:1
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作者 Yue Wu Fan Wu +3 位作者 Guoping Hu Nouman R.Mirza Geoffrey W.Stevens Kathryn A.Mumford 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第11期2327-2336,共10页
The process models for an equilibrium CO_2 absorber and a rate based CO_2 absorber using potassium carbonate(K2 CO3) solvents were developed in Aspen Custom Modeller(ACM) to remove CO_2 from a flue gas. The process mo... The process models for an equilibrium CO_2 absorber and a rate based CO_2 absorber using potassium carbonate(K2 CO3) solvents were developed in Aspen Custom Modeller(ACM) to remove CO_2 from a flue gas. The process model utilised the Electrolyte Non-Random Two Liquid(ENRTL) thermodynamic model and various packing correlations. The results from the ACM equilibrium model shows good agreement with an inbuilt Aspen Plus?model when using the same input conditions. By further introducing a Murphree efficiency which is related to mass transfer and packing hydraulics, the equilibrium model can validate the experimental results from a pilot plant within a deviation of 10%. A more rigorous rate based model included mass and energy flux across the interface and the enhancement effect resulting from chemical reactions. The rate based model was validated using experimental data from pilot plants and was shown to predict the results to within 10%. A parametric sensitivity analysis showed that inlet flue gas flowrate and K2 CO3 concentration in the lean solvent has significant impact on CO_2 recovery. Although both models can provide reasonable predictions based on pilot plant results, the rate based model is more advanced as it can explain mass and heat transfer, transport phenomena and chemical reactions occurring inside the absorber without introducing an empirical Murphree efficiency. 展开更多
关键词 EQUILIBRIUM Rate based MODELLING ABSORBER potassium carbonATE
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Carbon foam with microporous structure for high performance symmetric potassium dual-ion capacitor 被引量:12
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作者 Yanhong Feng Suhua Chen +1 位作者 Jue Wang Bingan Lu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第4期129-138,共10页
A novel carbon foam with microporous structure(CFMS),with the advantages of a simple fabrication process,low energy consumption,large specific surface area and high conductivity,has been prepared by a facile one-step ... A novel carbon foam with microporous structure(CFMS),with the advantages of a simple fabrication process,low energy consumption,large specific surface area and high conductivity,has been prepared by a facile one-step carbonization.In addition,the carbon foam possesses suitable interlayer spacing in short range which is flexible to accommodate the deformation of carbon layer caused by the ion insertion and deinsertion at the charge and discharge state.Furthermore,a low cost carbon-based symmetric potassium dual-ion capacitor(PDIC),which integrates the virtues of potassium ion capacitors and dual-ion batteries,is successfully established with CFMS as both the battery-type cathode and the capacitor-type anode.PDIC displays a superior rate performance,an ultra-long cycle life(90%retention after 10000 cycles),and a high power density of 7800 W kg^-1 at an energy density of 39Whkg^-1.The PDIC also exhibits excellent ultrafast charge and slow discharge properties,with a full charge in just 60 s and a discharge time of more than 3000 s. 展开更多
关键词 carbon foam SYMMETRIC potassium-based dual-ion CAPACITOR High energy/power density Ultrafast charge and SLOW discharge
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New Strategy for Chemically Attachment of Imine Group on Multi-Walled Carbon Nanotubes Surfaces: Synthesis, Characterization and Study of DC Electrical Conductivity
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作者 Omar Al-Shuja’a Abeer Obeid +2 位作者 Yousuf El-Shekeil Mohamed Hashim Zinab Al-Washali 《Journal of Materials Science and Chemical Engineering》 2017年第2期11-21,共11页
This paper used a new approach of preparing poly-composites by covalent linkage between the MWCNT’s by imine group. The Poly (Imine)/MWCNT Composite was synthesized by the solution blending method from reacted amino ... This paper used a new approach of preparing poly-composites by covalent linkage between the MWCNT’s by imine group. The Poly (Imine)/MWCNT Composite was synthesized by the solution blending method from reacted amino multi-walled carbon nanotubes (MWCNT-NH2) with Terephthalaldehyde (TPAL). The obtained poly-composite was characterized by FT-IR, UV-Vis, XRD, TEM, SEM, TGA, DSC and DC electrical conductivity. The formation of Poly (Imine)/MWCNT composite was confirmed. The DC electrical conductivity of poly-composites was within the range 2.3 × 10–4 - 5.3 × 10–4 S/cm due to the interaction between the nanotubes. 展开更多
关键词 Amino Multi-Walled carbon Nanotubes (MWCNT-NH2) Polymer Nanocomposites FUNCTIONALIZATION Solution Blending IMINE Terephthalaldehyde FTIR SEM TEM XRD UV DSC TGA and DC Electrical Conductivity
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A Three-Dimensional Numerical Model for Predicting the Weld Bead Geometry Characteristics in Laser Overlap Welding of Low Carbon Galvanized Steel 被引量:1
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作者 Kamel Oussaid Abderrazak El Ouafi 《Journal of Applied Mathematics and Physics》 2019年第10期2169-2186,共18页
Laser welding (LW) becomes one of the most economical high quality joining processes. LW offers the advantage of very controlled heat input resulting in low distortion and the ability to weld heat sensitive components... Laser welding (LW) becomes one of the most economical high quality joining processes. LW offers the advantage of very controlled heat input resulting in low distortion and the ability to weld heat sensitive components. To exploit efficiently the benefits presented by LW, it is necessary to develop an integrated approach to identify and control the welding process variables in order to produce the desired weld characteristics without being forced to use the traditional and fastidious trial and error procedures. The paper presents a study of weld bead geometry characteristics prediction for laser overlap welding of low carbon galvanized steel using 3D numerical modelling and experimental validation. The temperature dependent material properties, metallurgical transformations and enthalpy method constitute the foundation of the proposed modelling approach. An adaptive 3D heat source is adopted to simulate both keyhole and conduction mode of the LW process. The simulations are performed using 3D finite element model on commercial software. The model is used to estimate the weld bead geometry characteristics for various LW parameters, such as laser power, welding speed and laser beam diameter. The calibration and validation of the 3D numerical model are based on experimental data achieved using a 3 kW Nd:Yag laser system, a structured experimental design and confirmed statistical analysis tools. The results reveal that the modelling approach can provide not only a consistent and accurate prediction of the weld characteristics under variable welding parameters and conditions but also a comprehensive and quantitative analysis of process parameters effects on the weld quality. The results show great concordance between predicted and measured values for weld bead geometry characteristics, such as depth of penetration, bead width at the top surface and bead width at the interface between sheets, with an average accuracy greater than 95%. 展开更多
关键词 LASER WELDING Low carbon Galvanized Steel Overlap WELDING Weld BEAD Geometry CHARACTERISTICS 3D Modeling Prediction Model Finite Elements METHOD Taguchi METHOD ANOVA Nd:YAG LASER Source
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Modelling of the Usefulness of Carbon Nanotubes as Antiviral Compounds for Treating Alzheimer Disease
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作者 Hakim Al Garalleh 《Advances in Alzheimer's Disease》 2018年第3期79-92,共14页
The new generations of nano-devices successfully apply with great promise as drug carriers in the treatment of different diseases. The proposed model aims to determine the pharmacological targets and evaluate the bio-... The new generations of nano-devices successfully apply with great promise as drug carriers in the treatment of different diseases. The proposed model aims to determine the pharmacological targets and evaluate the bio-safety of usefulness of carbon nanotube conjugated with two different antiviral compounds, Acetylcholine and Ravastigmine, for treating Alzheimer disease. We also obtain the medicinal model mathematically to evaluate the interaction energy arising from encapsulation of each antiviral compound inside the single-walled carbon nanotube. Acetylcholine is modelled as two-connected spheres, while Ravastigmine has two possible structures which are an ellipsoid and cylinder, all interacting with the interior wall of single-walled carbon nanotubes with variant radii rc . Our calculations show that the single-walled carbon nanotube of radius rc greater than 3.391 &#197;that will accept both drugs which are quite closer to the recent findings. 展开更多
关键词 carbon Nanotubes (CNTs) Alzheimer Disease (AD) Acetylcholine (ACh) (Aricept) Ravastigmine (RAV) (Exelon) Mitochondria (MTCDH) LYSOSOMES Van Der WAALS Interaction and LENNARD-JONES Potential
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计及碳排放交易的Carbon-IRP模型模拟分析 被引量:2
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作者 祖国海 马向春 杨玲玲 《水电能源科学》 北大核心 2010年第10期154-157,共4页
针对电力工业具有较强的碳锁定效应可实现节能减排的长效可持续性,在分析引入碳排放交易的基础上,构建了计及碳排放交易的Carbon-IRP模型,并就给定排放约束模拟分析了不同排放权价格对机组发电量及CO2排放的影响。结果表明,该模型在满... 针对电力工业具有较强的碳锁定效应可实现节能减排的长效可持续性,在分析引入碳排放交易的基础上,构建了计及碳排放交易的Carbon-IRP模型,并就给定排放约束模拟分析了不同排放权价格对机组发电量及CO2排放的影响。结果表明,该模型在满足系统可靠性的同时可有效降低系统总装机容量及发电量,CO2排放量显著减少,在排放权价格较低时减排效果不明显,但随排放权价格升高减排效果逐渐凸显。 展开更多
关键词 Model CO2
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Carbon Black and Multi Wall Carbon Nanotubes Loaded Polyurethane Foam Composite Flexible Thermal Radiator
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作者 R. Wijesiriwardana 《Journal of Materials Science and Chemical Engineering》 2015年第7期119-126,共8页
Carbon black (CB) or multi walled carbon nanotubes (MWCNT) loaded polyurethane conductive foams are used as heaters, electrodes, radar absorbers and shielding. This paper discusses the performance of an innovative fle... Carbon black (CB) or multi walled carbon nanotubes (MWCNT) loaded polyurethane conductive foams are used as heaters, electrodes, radar absorbers and shielding. This paper discusses the performance of an innovative flexible thermal radiator (FTR) constructed with CB filled or MWCNT filled conductive foam and powering electrode structure constructed with textiles manufacturing process (knitting, weaving or nonwoven). Silver (Ag) yarns are used for the powering electrodes construction. This paper discusses the construction, electro-thermal analysis, performance and applications of FTR. Also this paper compare the thermal and electrical characteristics of CB filled and MWCNT filled FTRs. The electro-thermal model is simulated by using finite element methods. 展开更多
关键词 carbon Black (CB) Multi Walled carbon Nanotubes (MWCNT) FLEXIBLE THERMAL RADIATOR (FTR) Ag Yarns KNITTING Electro-Thermal FEM Conductive Foam Weaving and Nonwoven
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Use of venous-to-arterial carbon dioxide tension difference to guide resuscitation therapy in septic shock 被引量:29
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作者 Jihad Mallat Malcolm Lemyze +2 位作者 Laurent Tronchon Beno?t Vallet Didier Thevenin 《World Journal of Critical Care Medicine》 2016年第1期47-56,共10页
The mixed venous-to-arterial carbon dioxide(CO_2)tension difference[P(v-a) CO_2]is the difference between carbon dioxide tension(PCO_2) in mixed venous blood(sampled from a pulmonary artery catheter) and the PCO_2 in ... The mixed venous-to-arterial carbon dioxide(CO_2)tension difference[P(v-a) CO_2]is the difference between carbon dioxide tension(PCO_2) in mixed venous blood(sampled from a pulmonary artery catheter) and the PCO_2 in arterial blood.P(v-a) CO_2 depends on the cardiac output and the global CO_2 production,and on the complex relationship between PCO_2 and CO_2 content.Experimental and clinical studies support the evidence that P(v-a) CO_2 cannot serve as an indicator of tissue hypoxia,and should be regarded as an indicator of the adequacy of venous blood to wash out the total CO_2generated by the peripheral tissues.P(v-a) CO_2 can be replaced by the central venous-to-arterial CO_2 difference(△PCO_2),which is calculated from simultaneous sampling of central venous blood from a central vein catheter and arterial blood and,therefore,more easy to obtain at the bedside.Determining the △PCO_2 during the resuscitation of septic shock patients might be useful when deciding when to continue resuscitation despite a central venous oxygen saturation(SCVO_2) > 70%associated with elevated blood lactate levels.Because high blood lactate levels is not a discriminatory factor in determining the source of that stress,an increased △PCO_2(> 6 mmHg)could be used to identify patients who still remain inadequately resuscitated.Monitoring the △PCO_2 from the beginning of the reanimation of septic shock patients might be a valuable means to evaluate the adequacy of cardiac output in tissue perfusion and,thus,guiding the therapy.In this respect,it can aid to titrate inotropes to adjust oxygen delivery to CO_2 production,or to choose between hemoglobin correction or fluid/inotrope infusion in patients with a too low ScvO_2 related to metabolic demand.The combination of P(v-a) CO_2 or △PCO_2 with oxygen-derived parameters through the calculation of the P(v-a) CO_2 or △PCO_2/arteriovenous oxygen content difference ratio can detect the presence of global anaerobic metabolism. 展开更多
关键词 Venous-to-arterial carbon dioxide tension difference carbon dioxide production OXYGEN supply dependency Cardiac output tissue hypoxia Anaerobic metabolism OXYGEN consumption RESUSCITATION SEPTIC shock
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Potassium and calcium channels in different nerve cells act as therapeutic targets in neurological disorders
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作者 Qing Qiu Mengting Yang +2 位作者 Danfeng Gong Haiying Liang Tingting Chen 《Neural Regeneration Research》 SCIE CAS 2025年第5期1258-1276,共19页
The central nervous system, information integration center of the body, is mainly composed of neurons and glial cells. The neuron is one of the most basic and important structural and functional units of the central n... The central nervous system, information integration center of the body, is mainly composed of neurons and glial cells. The neuron is one of the most basic and important structural and functional units of the central nervous system, with sensory stimulation and excitation conduction functions. Astrocytes and microglia belong to the glial cell family, which is the main source of cytokines and represents the main defense system of the central nervous system. Nerve cells undergo neurotransmission or gliotransmission, which regulates neuronal activity via the ion channels, receptors, or transporters expressed on nerve cell membranes. Ion channels, composed of large transmembrane proteins, play crucial roles in maintaining nerve cell homeostasis. These channels are also important for control of the membrane potential and in the secretion of neurotransmitters. A variety of cellular functions and life activities, including functional regulation of the central nervous system, the generation and conduction of nerve excitation, the occurrence of receptor potential, heart pulsation, smooth muscle peristalsis, skeletal muscle contraction, and hormone secretion, are closely related to ion channels associated with passive transmembrane transport. Two types of ion channels in the central nervous system, potassium channels and calcium channels, are closely related to various neurological disorders, including Alzheimer's disease, Parkinson's disease, and epilepsy. Accordingly, various drugs that can affect these ion channels have been explored deeply to provide new directions for the treatment of these neurological disorders. In this review, we focus on the functions of potassium and calcium ion channels in different nerve cells and their involvement in neurological disorders such as Parkinson's disease, Alzheimer's disease, depression, epilepsy, autism, and rare disorders. We also describe several clinical drugs that target potassium or calcium channels in nerve cells and could be used to treat these disorders. We concluded that there are few clinical drugs that can improve the pathology these diseases by acting on potassium or calcium ions. Although a few novel ion-channelspecific modulators have been discovered, meaningful therapies have largely not yet been realized. The lack of target-specific drugs, their requirement to cross the blood–brain barrier, and their exact underlying mechanisms all need further attention. This review aims to explain the urgent problems that need research progress and provide comprehensive information aiming to arouse the research community's interest in the development of ion channel-targeting drugs and the identification of new therapeutic targets for that can increase the cure rate of nervous system diseases and reduce the occurrence of adverse reactions in other systems. 展开更多
关键词 ASTROCYTES calcium channels central nervous system extracellular ion concentration MICROGLIA neurological disorders NEURONS potassium channels
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坡耕地土壤有机碳再分布特征及其迁移累积平衡 被引量:8
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作者 方华军 杨学明 +1 位作者 张晓平 梁爱珍 《核农学报》 CAS CSCD 北大核心 2005年第3期202-207,共6页
利用137Cs和飞灰示踪技术,研究坡耕地黑土近50年和近100年来土壤再分布过程,计算坡耕地土壤有机碳(SOC)迁移和累积平衡。结果表明:利用SOC的深度分布特征鉴定坡脚和坡足原始埋藏土壤的表面分别位于地表下70和80cm,其埋藏层的SOC含量分... 利用137Cs和飞灰示踪技术,研究坡耕地黑土近50年和近100年来土壤再分布过程,计算坡耕地土壤有机碳(SOC)迁移和累积平衡。结果表明:利用SOC的深度分布特征鉴定坡脚和坡足原始埋藏土壤的表面分别位于地表下70和80cm,其埋藏层的SOC含量分别比与其接壤的上覆土层SOC含量高5.2和0.4gkg。坡顶、坡肩和坡背均遭受侵蚀,年平均侵蚀的土壤厚度为0.2、5.0和2.2mmyr。坡脚和坡足部位飞灰到达的深度分别为70和80cm,与埋藏层表面相吻合。坡脚飞灰出现于埋藏A层之中,表明沉积区在蒸汽机车开始使用前已被开垦为农田(或已有侵蚀和堆积发生)。根据137Cs和飞灰分布深度构建了不同年代的坡型,结果表明侵蚀部位剥蚀的土壤多堆积在坡脚和坡足,且搬运的土壤物质先累积于坡脚,随着景观坡度变缓,土壤累积逐渐向坡足过渡。研究区(1m宽)坡顶、坡肩和坡背近百年来由于土壤侵蚀共失去683kgSOC,其中60%(418kgSOC)沉积在坡脚和坡足等低洼部位,其中有257kgSOC是近50年累积的。 展开更多
关键词 ^137CS SOC 100 50 使
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Damping Properties of Piezoelectric and Electrical Conductive of BaTiO_3/VGCF/CPE Composites: Effect of Carbon Fiber 被引量:3
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作者 晏雄 张慧萍 住田雅夫 《Journal of Donghua University(English Edition)》 EI CAS 2001年第3期11-13,共3页
A new damping composite of CPE/BaTiO3/VGCF has been developed on the basis of the piezo- effect and conductivity mechanism. The conductivity of composites varied with the VGCF content are tested and analyzed.The resul... A new damping composite of CPE/BaTiO3/VGCF has been developed on the basis of the piezo- effect and conductivity mechanism. The conductivity of composites varied with the VGCF content are tested and analyzed.The results indicate that the conductivity of composites grows up slowly as the VGCF content is in the range of 10%-20%. It is very useful for industrial application to control the conductivity of composites by adjusting the VGCF content. In addition, at the range of - 50 - 120°C,the dependence of loss factor on the VGCF content varied with the temperature are tested and analyzed by dynamic mechanical and dielectric behavior measurement of the composites, and expected results are obtained. 展开更多
关键词 Chlorinating polyethylene (CPE) BARIUM TITANATE ( BaTiO3 ) carbon fiber Dynamic mechanical behavior Dielectric behavior Electric conductivity PERCOLATION threshold Damping material.
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Growing Cover Crops to Improve Biomass Accumulation and Carbon Sequestration: A Phytotron Study 被引量:1
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作者 Qingren Wang Yuncong Li Ashok Alva 《Journal of Environmental Protection》 2010年第2期73-84,共12页
Cover crop system has shown a potential approach to improving carbon sequestration and environmental quality. Six of each winter and summer cover crops were subsequently grown in two soils, Krome gravelly loam soil (K... Cover crop system has shown a potential approach to improving carbon sequestration and environmental quality. Six of each winter and summer cover crops were subsequently grown in two soils, Krome gravelly loam soil (KGL), and Quincy fine sandy soil (QFS), in phytotrons at 3 temperatures (10/20, 15/25, 25/30oC for winter/summer cover crops) to investigate their contributions for carbon (C) sequestration. Among winter cover crops, the highest and the lowest amounts of C accumulated were by bellbean (Vicia faba L.), 597 g/m2 and white clover (Trifolium repens), 149 g/m2, respectively, in the QFS soil. Among summer cover crops, sunn hemp (Crotalaria juncea L.) accumulated the largest quantity of C (481 g/m2), while that by castorbean (Ricinus communis) was 102 g/m2 at 30oC in the KGL soil. The mean net C remained in the residues following the 127 d decomposition were 187 g/m2 of C (73% of the total) and 91 g/m2 (52% of the total) for the winter and summer cover crops, respectively. Following a whole cycle of winter and summer cover crops grown, the mean soil organic C (SOC) increased by 13.8 and 39.1% in the KGL and QFS soil, respectively, compared to the respective soils before. The results suggest that triticale, ryegrass, and bellbean are the promising winter cover crops in the QFS soil, while sunn hemp, velvetbean (Mucuna pruriens), and sorghum sudangrass (Sorghum bicolor &#215;S. bicolor) are recommended summer cover crops for both soils under favorable temperatures. 展开更多
关键词 carbon to Nitrogen Ratio (C:N) GREENHOUSE Gas (GHG) Krome Gravelly LOAM (KGL) Quincy Fine Sand (QFS) Soil Organic carbon (SOC)
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Geochemical Characteristics of the Trace and Rare Earth Elements in Reef Carbonates from the Xisha Islands(South China Sea): Implications for Sediment Provenance and Paleoenvironment 被引量:2
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作者 BI Dongjie ZHAI Shikui +5 位作者 ZHANG Daojun XIU Chun LIU Xinyu LIU Xiaofeng JIANG Longjie ZHANG Aibin 《Journal of Ocean University of China》 SCIE CAS CSCD 2019年第6期1291-1301,共11页
Based on the concentrations of the trace elements,rare earth elements(REE),and Sr isotopic compositions in reef carbonates from the well‘Xike-1’reef core of the Xisha Islands,the constraints on sediment provenance a... Based on the concentrations of the trace elements,rare earth elements(REE),and Sr isotopic compositions in reef carbonates from the well‘Xike-1’reef core of the Xisha Islands,the constraints on sediment provenance and paleoenvironment were defined.Variations of the terrigenous input into the paleoseawater were traced in detail and the paleoenvironment and sediment provenance were further investigated.The results show that the HREE/LREE values in the reef carbonates are negatively associated with their Th and Al concentrations;however,their Al and Th concentrations show positive correlation.The lowest 87 Sr/86 Sr values in the reef carbonates generally coincide with the lowest values of Al,Th concentrations and the highest values of HREE/LREE.These data indicate that the HREE/LREE,Al concentrations,and Th concentrations of the reef carbonates are useful indexes for evaluating the influence of the terrigenous inputs on the seawater composition in the study area.From top to bottom,the changing process of the HREE/LREE values and Al,Th concentrations can be divided into 6 intervals;they are H1(0–89.30 m,about 0–0.11 Myr),L1(89.30–198.30 m,about 0.11–2.2 Myr),H2(198.30–374.95 m,about 2.2–5.3 Myr),D(374.95–758.40 m,about 5.3–13.6 Myr),L2(758.40–976.86 m,about 13.6–15.5 Myr),and H3(976.86–1200.00 m,about 15.5–21.5 Myr).Moreover,the changing trend of the HREE/LREE values coincides with that of the seawater δ^13C values recorded by benthonic foraminiferal skeletons from the drill core of ODP site 1148 in the South China Sea(SCS),but not with that of the seawaterδ18O values.The high uplifting rates of the Qinghai-Tibet Plateau coincide with the high Th and Al concentrations and the low HREE/LREE values in the reef carbonates.These data indicate that the main factors controlling the changes of terrigenous flux in the SCS are the tectonic activities associated with Qinghai-Tibet Plateau uplifting and the variations of uplifting rates rather than paleoclimatic changes. 展开更多
关键词 TRACE and rare earth elements paleoenvironmental and sediment provenance REEF carbonATES the South China Sea(SCS) the UPLIFT of Qinghai-Tibet Plateau
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Distribution and exploration direction of medium-and large-sized marine carbonate gas fields in Sichuan Basin, SW China 被引量:9
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作者 MA Xinhua YANG Yu +1 位作者 WEN Long LUO Bing 《Petroleum Exploration and Development》 2019年第1期1-15,共15页
Based on the analysis of the basic characteristics of medium-and large-sized marine gas fields in Sichuan Basin, combined with the division of major reservoir forming geological units in the marine craton stage and th... Based on the analysis of the basic characteristics of medium-and large-sized marine gas fields in Sichuan Basin, combined with the division of major reservoir forming geological units in the marine craton stage and their control on key hydrocarbon accumulation factors, the distribution law of medium-and large-sized marine carbonate gas fields in the basin was examined and the exploration direction was pointed out. Through the analysis of the periodic stretching-uplifting background, it is concluded that five large scale paleo-rifts, three large scale paleo-uplifts, five large scale paleo erosion surfaces were formed in the marine craton stage of Sichuan Basin, and these geological units control the key reservoir forming factors of medium and large sized gas fields:(1) Large-scale paleo-rifts control the distribution of high-quality hydrocarbon generation centers.(2) The margin of large-scale paleo-rifts, high position of paleo-uplifts and paleo erosion surfaces control the distribution of high-quality reservoirs.(3) Large-scale paleo-rifts, paleo-uplifts, paleo erosion surfaces and present tectonic setting jointly control the formation of many types of large and medium-sized traps.(4) Natural gas accumulation is controlled by the inheritance evolution of traps in large geological units. Based on the comparative analysis of the distribution characteristics of medium-and large-sized gas fields and large geological units, it is proposed that the superimposition relationship between single or multiple geological units and the present structure controls the distribution of medium-and large-sized gas fields, and the "three paleo" superimposed area is the most advantageous. According to the above rules, the main exploration fields and directions of medium-and large-sized marine carbonate gas fields in Sichuan Basin include periphery of Deyang-Anyue paleo-rift, eastern margin of Longmenshan paleo-rift, margins of Kaijiang-Liangping oceanic trough and Chengkou-western Hubei oceanic trough, the high part of the subaqueous paleo-uplifts around Central Sichuan, paleo erosion surfaces of the top boundary of Maokou Formation in eastern and southern Sichuan Basin, paleo erosion surfaces of the top boundary of the Leikoupo Formation in central and western Sichuan Basin. 展开更多
关键词 Sichuan Basin marine carbonATES medium-and large-sized gas fields GEOLOGIC unit reservoir forming factors paleo-rifts paleo-uplifts paleo erosion surfaces
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STUDY ON THE ELECTROCHEMICAL BEHAVIOR OF ION EXCHANGE MEMBRANE IN PREPARING POTASSIUM CARBONATE
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作者 杨维驿 《Chinese Journal of Chemical Engineering》 SCIE EI CAS 1985年第1期31-47,共17页
This investigation describes the one step preparation of potassium carbonate by electrolysis of potas-sium chloride solution in electrolyzers with various Nation membranes.Potassium bicarbonate solution wasfed to the ... This investigation describes the one step preparation of potassium carbonate by electrolysis of potas-sium chloride solution in electrolyzers with various Nation membranes.Potassium bicarbonate solution wasfed to the cathode compartment,where it was converted into carbonate by reaction with the hydroxideformed at cathode.Because of the low OH^- concentration in the cathode compartment,the back migrationof OH^- through the membrane was almost negligible,resulting in a higher current efficiency,say 90% or more.In this study,electroconductivity,mass transfer,current efficiency and cell voltage were measured.Thefeasibility of the process was discussed and the optimal conditions examined. 展开更多
关键词 KOH STUDY ON THE ELECTROCHEMICAL BEHAVIOR OF ION EXCHANGE MEMBRANE IN PREPARING potassium carbonATE RATE
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四川盆地志留系层序地层及有利储集层分布 被引量:27
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作者 张林 魏国齐 +3 位作者 郭英海 汪泽成 吴世祥 沈珏红 《天然气工业》 EI CAS CSCD 北大核心 2005年第5期6-8,共3页
四川盆地志留系在加里东运动抬升剥蚀中仅残留下统地层,文章旨在研究其层序特征,指出有利勘探区。应用层序地层学方法,识别志留系进行层序界面,划分划分出5个层序、10个体系域,建立等时地层格架,分析储集层展布规律。志留系层序由加积... 四川盆地志留系在加里东运动抬升剥蚀中仅残留下统地层,文章旨在研究其层序特征,指出有利勘探区。应用层序地层学方法,识别志留系进行层序界面,划分划分出5个层序、10个体系域,建立等时地层格架,分析储集层展布规律。志留系层序由加积—退积的准层序组构成海侵体系和加积—进积的准层序组构成的高位体系域组成。储集岩有滨岸砂坝相的砂质岩和生物礁及生物浅滩碳酸盐岩,川东以“小河坝砂岩”碎屑岩储集层为主;川南以生物礁及生物浅滩灰岩储集层为主。 展开更多
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Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution 被引量:1
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作者 刘娜 赵兴雷 +1 位作者 王运东 费维扬 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第4期538-543,共6页
In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO2 using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate(K2CO3) and potassium bicarbon... In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO2 using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate(K2CO3) and potassium bicarbonate(KHCO3) were used to simulate the solution after absorbing CO2.Experiments were carried out at various electrodes,temperatures and current densities.The results indicate that the membrane electrolysis can in-crease concentration ratio of K2CO3 and KHCO3,and achieve 100%conversion.In this process,not only CO2 is desorbed from carbonate solution,but also hydrogen,as a byproduct,is generated at the cathode,which is the main contributor to reduce energy consumption.Thus,the membrane electrolysis is valuable in the regeneration of the K2CO3 absorbent. 展开更多
关键词 membrane electrolysis Benfield REGENERATION carbon dioxide
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Determination of Carbon and Nitrogen Isotope Fractions in Tartaric Acid, Oxalic Acid, Glucose and Fructose—National Center of High Technologies of Georgia
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作者 Lamzira Pharulava Levani Eliashvili +1 位作者 Vakhtang Betlemidze Bachana Sulava 《American Journal of Analytical Chemistry》 CAS 2024年第8期229-240,共12页
Tartaric acid, oxalic acid, glucose, and fructose are highly important compounds. A comprehensive study of these substances is fascinating from a scientific perspective. They are key components found in wine, vegetabl... Tartaric acid, oxalic acid, glucose, and fructose are highly important compounds. A comprehensive study of these substances is fascinating from a scientific perspective. They are key components found in wine, vegetables, and fruits. Understanding the isotopic compositions in organic compounds is crucial for comprehending various biochemical processes and the nature of substances present in different natural products. Tartaric acid, oxalic acid, glucose, and fructose are widely distributed compounds, including in vegetables and fruits. Tartaric acid plays a significant role in determining the quality and taste properties of wine, while oxalic acid is also prevalent but holds great interest for further research, especially in terms of carbon isotopic composition. We can unveil the mechanisms of processes that were previously impossible to study. Glucose and fructose are the most common monosaccharides in the hexose group, and both are found in fruits, with sweeter fruits containing higher amounts of these substances. In addition to fruits, wheat, barley, rye, onions, garlic, lentils, peppers, dried fruits, beans, broccoli, cabbage, tomatoes, and other foods are also rich sources of fructose and glucose. To determine the mass fraction of the carbon-13 isotope in these compounds, it is important to study their changes during natural synthesis. These compounds can be modified with a carbon center. According to the existing isotopic analysis method, these compounds are converted into carbon oxide or dioxide [1]. At this point, the average carbon content in the given compound is determined, but information about isotope-modified centers is lost. Dilution may occur through the transfer of other carbon-containing organic compounds in the sample or by dilution with natural carbon or carbon dioxide during the transfer process. This article discusses the possibility of carbon-13 isotope propagation directly in these compounds, both completely modified and modified with individual carbon centers. The literature provides information on determining carbon-13 substance in organic compounds, both with a general approach and for individual compounds [2] [3]. 展开更多
关键词 Tartaric Acid Oxalic Acid GLUCOSE FRUCTOSE Mass Spectrum Ion Current Intensity Mass Line Mass Number Molecular and Fragment Ions carbon carbon Center
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Lost circulation material for abnormally high temperature and pressure fractured-vuggy carbonate reservoirs in Tazhong block, Tarim Basin, NW China 被引量:1
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作者 SU Xiaoming LIAN Zhanghua +3 位作者 Fang Junwei XIONG Hanqiao WU Ruoning YUAN Yuan 《Petroleum Exploration and Development》 2019年第1期173-180,共8页
To effectively solve the problem of lost circulation and well kick frequently occurring during the drilling of abnormally high temperature and pressure fractured-vuggy reservoirs in the Tazhong block, a rigid particle... To effectively solve the problem of lost circulation and well kick frequently occurring during the drilling of abnormally high temperature and pressure fractured-vuggy reservoirs in the Tazhong block, a rigid particle material, GZD, with high temperature tolerance, high rigidity(> 8 MPa) and low abrasiveness has been selected based on geological characteristics of the theft zones in the reservoirs. Through static pressure sealing experiments, its dosage when used alone and when used in combination with lignin fiber, elastic material SQD-98 and calcium carbonate were optimized, and the formula of a new type(SXM-I) of compound lost circulation material with high temperature tolerance and high strength was formed. Its performance was evaluated by compatibility test, static sealing experiment and sand bed plugging experiment. The test results show that it has good compatibility with drilling fluid used commonly and is able to plug fractures and vugs, the sealed fractures are able to withstand the static pressure of more than 9 MPa and the cumulative leakage is 13.4 mL. The mud filtrate invasion depth is only 2.5 cm in 30 min when the sand bed is made of particles with sizes between 10 mesh and 20 mesh. Overall, with good sealing property and high temperature and high pressure tolerance, the lost circulation material provides strong technical support for the safety drilling in the block. 展开更多
关键词 carbonATE rock fractured-vuggy reservoir SEALING and plugging high temperature tolerance LOST circulation material drilling fluid central TARIM Basin
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