By conducting organic geochemical analysis of the samples taken from the drilled wells in Baiyun Sag of Pearl River Mouth Basin,China,the development characteristics of hydrocarbon source rocks in the sag are clarifie...By conducting organic geochemical analysis of the samples taken from the drilled wells in Baiyun Sag of Pearl River Mouth Basin,China,the development characteristics of hydrocarbon source rocks in the sag are clarified.Reconstruct the current geothermal field of the sag and restore the tectonic-thermal evolution process to predict the type,scale,and distribution of resources in Baiyun Sag through thermal pressure simulation experiments and numerical simulation.The Baiyun Sag is characterized by the development of Paleogene shallow lacustrine source rocks,which are deposited in a slightly oxidizing environment.The source rocks are mainly composed of terrestrial higher plants,with algae making a certain contribution,and are oil and gas source rocks.Current geothermal field of the sag was reconstructed,in which the range of geothermal gradients is(3.5–5.2)℃/100 m,showing an overall increasing trend from northwest to southeast,with significant differences in geothermal gradients across different sub-sags.Baiyun Sag has undergone two distinct periods of extensional process,the Eocene and Miocene,since the Cenozoic era.These two periods of heating and warming events have been identified,accelerating the maturation and evolution of source rocks.The main body of ancient basal heat flow value reached its highest at 13.82 Ma.The basin modelling results show that the maturity of source rocks is significantly higher in Baiyun main sub-sag than that in other sub-sags.The Eocene Wenchang Formation is currently in the stage of high maturity to over maturity,while the Eocene Enping Formation has reached the stage of maturity to high maturity.The rock thermal simulation experiment shows that the shallow lacustrine mudstone of the Wenchang Formation has a good potential of generating gas from kerogen cracking with high gas yield and long period of gas window.Shallow lacustrine mudstone of the Enping Formation has a good ability to generate light oil,and has ability to generate kerogen cracking gas in the late stage.The gas yield of shallow lacustrine mudstone of the Enping Formation is less than that of shallow lacustrine mudstone of the Wenchang Formation and the delta coal-bearing mudstone of the Enping Formation.The numerical simulation results indicate that the source rocks of Baiyun main sub-sag generate hydrocarbons earlier and have significantly higher hydrocarbon generation intensity than other sub-sags,with an average of about 1200×10^(4)t/km^(2).Oil and gas resources were mainly distributed in Baiyun main sub-sag and the main source rocks are distributed in the 3^(rd)and 4^(th)members of Wenchang Formation.Four favorable zones are selected for the division and evaluation of migration and aggregation units:No.(1)Panyu 30 nose-shaped structural belt,No.(3)Liuhua 29 nose-shaped uplift belt and Liwan 3 nose-shaped uplift belt,No.(2)gentle slope belt of Baiyun east sag,and No.(8)Baiyun 1 low-uplift.展开更多
Hot Dry Rock (HDR) refers to those generally deeply buried impermeable metamorphic or crystallized biotite gneiss, granite and granodiorite rock bodies, with a burial depth greater than 2000 m, containing no water o...Hot Dry Rock (HDR) refers to those generally deeply buried impermeable metamorphic or crystallized biotite gneiss, granite and granodiorite rock bodies, with a burial depth greater than 2000 m, containing no water or vapor. HDR is as implied, hot and dry, with temperatures ranging from 150 to 650℃, and it can be utilized as a heat resource. Because this type of heat system does not require porosity, permeability and fluids and is widespread at the drillable depth range of 10 kin, it is thereby an infinite resource type. By contrast, thermal power generation results in copious pollution; wind power is irregular and unstable; solar energy occupies large areas.展开更多
Cap rocks with high thermal insulation are important for deep geothermal systems at a depth of 3000‒6000 m.Based on the deep geothermal geological conditions in the Fujian-Guangdong-Hainan area of South China,this stu...Cap rocks with high thermal insulation are important for deep geothermal systems at a depth of 3000‒6000 m.Based on the deep geothermal geological conditions in the Fujian-Guangdong-Hainan area of South China,this study established an ideal geological model of reservoir-cap rock assemblages and simulated the geothermal field distribution of cap rocks of different thicknesses and thermal conductivity.The simulation results show that the vertical geothermal temperature distribution in an uplifted area of a depression was present as inverted mirror reflections relative to the elevated area of the basement.Specifically,the isotherms above the elevated area are convex in shape,while those below the elevated area are concave.There is a temperature equilibrium line between the convex and concave isotherms.The heat flow moves from the depressed area to the uplifted area below the temperature equilibrium line and migrates in an opposite direction above the line.On this base,this study conducted the inversion of geothermal temperature fields in typical areas with thin,moderately thick,and thick cap rocks.The results indicate that,at the depth of 3000e6000 m,areas with thin cap rocks(igneous rock zone in the coastal area of Fujian)mainly host moderate-to low-temperature hydrothermal resources;areas with moderately thick cap rocks(Yuezhong Depression)have the geothermal temperature ranging between 100℃and 200℃and may develop moderate-to high-temperature hydrothermal resources and hot dry rocks(HDRs),with the former superimposing on the latter;and areas with thick cap rocks(onshore Beibuwan Basin)have a geothermal temperature of 120‒220℃,and contains mainly moderate-to high-temperature hydrothermal resources and HDRs.Therefore,it is recommended that the evaluation,exploitation,and utilization of deep geothermal resources be carried out according to the burial depth of the temperature equilibrium line and the specific demand for geothermal resources.展开更多
Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the...Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the lack of low-maturity source rocks in deep petroliferous basins.We considered the Ediacaran microbial dolomite in the Sichuan Basin,the largest high-maturity marine gas layer in China,to exhibit a method that quantitatively characterizes the hydrocarbon expulsion of high-maturity marine source rocks.The experiment of fluid inclusion,rock pyrolysis,and vitrinite reflectance(Ro)of 119 microbial dolomite core samples obtained from the Dengying Formation were performed.A hydrocarbon expulsion model of high-maturity source rock was established,and its resource potential was evaluated.The results showed that the Ediacaran microbial dolomite in the Sichuan Basin is a good source rock showing vast resource potential.The hydrocarbon expulsion threshold is determined to be vitrinite reflectance at 0.92%.The hydrocarbon expulsion intensities in the geologic history is high with maximum of 1.6×10^(7)t/km^(2).The Ediacaran microbial dolomite expelled approximately 1.008×10^(12)t of hydrocarbons,and the recoverable resource was 1.5×10^(12)m^(3).The region can be categorized into areasⅠ,Ⅱ,Ⅲ,andⅣ,in decreasing order of hydrocarbon expulsion intensity.Areas with a higher hydrocarbon expulsion intensity have a lower drilling risk and should be prioritized for exploration in the orderⅠ>Ⅱ>Ⅲ>Ⅳ.Two areas,northern and central parts of Ediacaran in the Sichuan Basin,were selected as prospects which had the drilling priority in the future gas exploration.The production data of 55 drilled wells verified the high reliability of this method.This model in this study does not require low-maturity samples and can be used for evaluating high-maturity marine source rocks,which has broad applicability in deep basins worldwide.展开更多
The world petroleum exploration suggests that,about70%of the world’s potash resources were discovered during oil and gas exploration(Zheng et al.,2007).The Kuqa depression in the Tarim basin is abundant with petroleu...The world petroleum exploration suggests that,about70%of the world’s potash resources were discovered during oil and gas exploration(Zheng et al.,2007).The Kuqa depression in the Tarim basin is abundant with petroleum exploration data,and展开更多
1 Introduction The Gremyachinskoye potassium salt field lies within the Safronovskaya area and is confined to the preoverthrust zone–the 20-25 kilometer band conventionally recognized in the southern termination of t...1 Introduction The Gremyachinskoye potassium salt field lies within the Safronovskaya area and is confined to the preoverthrust zone–the 20-25 kilometer band conventionally recognized in the southern termination of the Volga展开更多
Potash is one of the long-term scare deposits in China,and potash prospecting has long been listed as a key brainstorm project for our nation and geological prospecting units.There have been considerable studies in se...Potash is one of the long-term scare deposits in China,and potash prospecting has long been listed as a key brainstorm project for our nation and geological prospecting units.There have been considerable studies in search for potash deposits in the Kuqa depression of the Tarim basin(Jackson et al.,1991;Gemmer et al.,2004;Vendeville,2005;Vendeville and Jackson,1992a,1992b),展开更多
In order to study the hydrocarbon generation(HCGE)characteristics of coal-bearing basins,the coal-measure source rocks of the Middle Jurassic-Lower Jurassic(MLJ)of the piedmont thrust belt in the southern margin of th...In order to study the hydrocarbon generation(HCGE)characteristics of coal-bearing basins,the coal-measure source rocks of the Middle Jurassic-Lower Jurassic(MLJ)of the piedmont thrust belt in the southern margin of the Junggar Basin in Northwest China are taken as research objects.More than 60 MLJ samples were collected from outcrops and wells.Total organic carbon(TOC),rock pyrolysis(Rock-Eval),organic petrological,vitrinite reflectance(%Ro),and hydrous pyrolysis were performed to analyze the relevant samples.The pyrolysis gases and liquid products were measured,and then the chemical composition,as well as carbon isotopes of the gases,were analyzed.The results indicate that the MLJ source rocks have the capacity for large-scale gas generation.In addition,for coal-measure source rocks,the heavier the carbon isotope of kerogen(δ^(13)C_(kerogen)),the lower the liquid hydrocarbon and hydrocarbon gas yield,and the easier it is to produce non-hydrocarbon gas.It is worth noting that when theδ^(13)C_(kerogen)in organic matter(OM)is relatively heavier,the fractionation of its products may become weaker in the evolutionary process.The vital contribution of the MLJ source rock to natural gas resources in the study area was further confirmed by comparing it with the Jurassic source gas.展开更多
Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T3xs) in the Western Sichuan Basin (WSD) are currently regarded as the most prolific emerging unconventional gas plays in ...Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T3xs) in the Western Sichuan Basin (WSD) are currently regarded as the most prolific emerging unconventional gas plays in China. This study conducted a conventional evaluation of T3x5 source rocks in the WSD, and investigated their hydrocarbon generation and expulsion characteristics, including intensity, efficiency and amount. The results show that, the T3x5 source rocks are thick (generally 〉200 m), and have a high total organic content (TOC), ranging from 2.5 to 4.5 wt%. It is thus indivative of a great hydrocarbon generation potential when they underwent high thermal evolution (Ro〉1.2%) in the area. In addition, an improved method of hydrocarbon generation potential is applied, indicating that the source rocks reached a hydrocarbon expulsion threshold with vitrinite reflectance (Ro) reaching 1.06%. and that the comprehensive hydrocarbon expulsion efficiency is about 60%. The amount of hydrocarbon generation and expulsion from Tax5 source rocks is 3.14x10^10 t and 1.86x10^10 t, respectively, with a residual amount of 1.28x10^10t within them. Continuous-type tight-sand gas is predicted to have developed in the Jurassic in the Chengdu Sag of the WSD because of the good source-reservoir configuration; the Jurassic sandstone reservoirs are tight, and the gas expelled from the T3xs source rocks migrates for very short distances vertically and horizontally. The amount of gas accumulation in the Jurassic reservoirs derived from T3x5 source rocks is up to 9.3x10s t. Geological resources of shale gas are up to 1.05x10TM t. Small differences between the amounts calculated by the volumetric method and those obtained by hydrocarbon generation potential method may be due to other gas accumulations present within interbedded sands associated with gas shales.展开更多
The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.U...The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.Understanding the formation and distribution of multi-component gas hydrates in fractures is crucial in accurately evaluating the hydrate reservoir resources in this area.The hydrate formation experiments were carried out using the core samples drilled from hydrate-bearing sediments in Qilian Mountain permafrost area and the multi-component gas with similar composition to natural gas hydrates in Qilian Mountain permafrost area.The formation and distribution characteristics of multi-component gas hydrates in core samples were observed in situ by X-ray Computed Tomography(X-CT)under high pressure and low temperature conditions.Results show that hydrates are mainly formed and distributed in the fractures with good connectivity.The ratios of volume of hydrates formed in fractures to the volume of fractures are about 96.8%and 60.67%in two different core samples.This indicates that the fracture surface may act as a favorable reaction site for hydrate formation in core samples.Based on the field geological data and the experimental results,it is preliminarily estimated that the inventory of methane stored in the fractured gas hydrate in Qilian Mountain permafrost area is about 8.67×1013 m3,with a resource abundance of 8.67×108 m3/km2.This study demonstrates the great resource potential of fractured gas hydrate and also provides a new way to further understand the prospect of natural gas hydrate and other oil and gas resources in Qilian Mountain permafrost area.展开更多
Peninsular Malaysia is already well known for having rare earth(RE)resources.However,pertinent data and information on upstream RE resources and reserve potential in Malaysia are yet to be established.It is vital to i...Peninsular Malaysia is already well known for having rare earth(RE)resources.However,pertinent data and information on upstream RE resources and reserve potential in Malaysia are yet to be established.It is vital to identify opportunities and challenges for value addition to rare earth elements(REEs)deposits in Malaysia.Therefore,this study evaluates the potential of Malaysian geological formations to serve as repositories for RE resources,such as rare earth minerals(REMs)and REEs,by elucidating the geological processes that are considered critical to the formation of the various deposit types.This paper concisely reviews possible REE mineralization in alkaline igneous rocks,pegmatites,placer deposits:monazite and xenotime,marine sediments,river and lake sediments,ion adsorption clays(IAC)deposits,and shale/coal deposits found in Malaysia.Comparisons between Malaysian deposits revealed that these deposits are potentially enriched with RE resources showing geological formations across the world.The paper reviews the methods and flowsheets used for the recovery of REMs and REEs from primary,secondary as well as alternative resources,with special consideration to the hydrometallurgical procedures comprising of leaching with acids and alkalis tailed by ion exchange,solvent extraction,or precipitation.The REEs ecosystem of Malaysia has also been discussed by considering the latest information from the Malaysian Investment Development Authority(MIDA),the REEs processing center,the Academy of Science of Malaysia(ASM),the People’s Republic of China(PRC),Lynas Malaysia Sdn.Bhd.(Lynas),Ministry of Energy and Natural Resources(NRECC),Jabatan Mineral&Geosains(JMG),Ministry of Science,Technology,and Innovation(MOSTI),and the Malaysian Chamber of Mines.The information on upstream RE resources and recent hydrometallurgical approaches provided in this study will contribute to developing and enhancing midstream and downstream RE-based manufacturing and processing operations in Malaysia.展开更多
A suite of potassium-bearing minerals from the Walgidee Hills lamproite intrusion in the Kimberley region of Western Australia was selected for 39Ar/40Ar dating. These included wadeite, jeppeite, priderite, potassium ...A suite of potassium-bearing minerals from the Walgidee Hills lamproite intrusion in the Kimberley region of Western Australia was selected for 39Ar/40Ar dating. These included wadeite, jeppeite, priderite, potassium richterite, and phlogopite. All recorded excellent plateau ages, with the mean age of the combined data set being 17.3±0.3 Ma. Phlogopite recorded the largest uncertainty, whereas, of the other minerals,wadeite gave the best precision. Although rare to absent in common magmatic rocks, these minerals are widely distributed in alkaline complexes and in lamproite, kimberlite and orangeite intrusions. The results indicate this suite of minerals is excellent for 39Ar/40Ar dating and that they can be used singly or in combination to obtain the precise magmatic crystallization ages of ultra-alkaline rocks. Because of the stability of potassium richterite at mantle depths, 39Ar/40Ar dating of MARID(micaamphibole-rutile-ilmenite-diopside) xenoliths should be a more widely-applied technique to investigating mantle geodynamics.展开更多
Drilling plays a significant role in the history of human civilization.The exploration of greater depths,extreme environments,or hazardous areas calls for more energy-efficient and high levels of autonomous drilling t...Drilling plays a significant role in the history of human civilization.The exploration of greater depths,extreme environments,or hazardous areas calls for more energy-efficient and high levels of autonomous drilling technologies with reduced cost and improved safety.Meanwhile,nature presents numerous biological boring examples that can be a source of inspiration to renovate our current drilling technologies.This paper reviews both man-made and biological drilling strategies and quantifies their performance by the dimensionless specific drilling energy and the rate of penetration.The results highlight that rotary drilling(including tunnel boring machines)remains the most popular method for subsurface drilling due to its advanced technical status and fewer environmental concerns.For harder rocks,the specific energy of rotary drilling increases dramatically,while percussion drilling requires nearly the same if not lower specific energy but with compromised bit durability that can significantly slow down the drilling operation.Innovative drilling technologies developed and tested in the laboratory still demand improved energy efficiency and penetration rate to be competitive.Bio-boring by natural organisms mostly outperforms man-made drilling technologies in terms of energy efficiency,penetration rate,or both.Studying the underlying mechanisms of bio-boring and translating such knowledge into developing innovative drilling technologies are of significance to subsurface construction and exploration.展开更多
基金Supported by the National Oil and Gas Resource Evaluation Project for the 14th Five Year Plan of the Ministry of Natural Resources(QGYQZYPJ2022-3)China National Offshore Oil Corporation"14th Five Year Plan"Major Science and Technology Project(KJGG2022-0103-03)。
文摘By conducting organic geochemical analysis of the samples taken from the drilled wells in Baiyun Sag of Pearl River Mouth Basin,China,the development characteristics of hydrocarbon source rocks in the sag are clarified.Reconstruct the current geothermal field of the sag and restore the tectonic-thermal evolution process to predict the type,scale,and distribution of resources in Baiyun Sag through thermal pressure simulation experiments and numerical simulation.The Baiyun Sag is characterized by the development of Paleogene shallow lacustrine source rocks,which are deposited in a slightly oxidizing environment.The source rocks are mainly composed of terrestrial higher plants,with algae making a certain contribution,and are oil and gas source rocks.Current geothermal field of the sag was reconstructed,in which the range of geothermal gradients is(3.5–5.2)℃/100 m,showing an overall increasing trend from northwest to southeast,with significant differences in geothermal gradients across different sub-sags.Baiyun Sag has undergone two distinct periods of extensional process,the Eocene and Miocene,since the Cenozoic era.These two periods of heating and warming events have been identified,accelerating the maturation and evolution of source rocks.The main body of ancient basal heat flow value reached its highest at 13.82 Ma.The basin modelling results show that the maturity of source rocks is significantly higher in Baiyun main sub-sag than that in other sub-sags.The Eocene Wenchang Formation is currently in the stage of high maturity to over maturity,while the Eocene Enping Formation has reached the stage of maturity to high maturity.The rock thermal simulation experiment shows that the shallow lacustrine mudstone of the Wenchang Formation has a good potential of generating gas from kerogen cracking with high gas yield and long period of gas window.Shallow lacustrine mudstone of the Enping Formation has a good ability to generate light oil,and has ability to generate kerogen cracking gas in the late stage.The gas yield of shallow lacustrine mudstone of the Enping Formation is less than that of shallow lacustrine mudstone of the Wenchang Formation and the delta coal-bearing mudstone of the Enping Formation.The numerical simulation results indicate that the source rocks of Baiyun main sub-sag generate hydrocarbons earlier and have significantly higher hydrocarbon generation intensity than other sub-sags,with an average of about 1200×10^(4)t/km^(2).Oil and gas resources were mainly distributed in Baiyun main sub-sag and the main source rocks are distributed in the 3^(rd)and 4^(th)members of Wenchang Formation.Four favorable zones are selected for the division and evaluation of migration and aggregation units:No.(1)Panyu 30 nose-shaped structural belt,No.(3)Liuhua 29 nose-shaped uplift belt and Liwan 3 nose-shaped uplift belt,No.(2)gentle slope belt of Baiyun east sag,and No.(8)Baiyun 1 low-uplift.
文摘Hot Dry Rock (HDR) refers to those generally deeply buried impermeable metamorphic or crystallized biotite gneiss, granite and granodiorite rock bodies, with a burial depth greater than 2000 m, containing no water or vapor. HDR is as implied, hot and dry, with temperatures ranging from 150 to 650℃, and it can be utilized as a heat resource. Because this type of heat system does not require porosity, permeability and fluids and is widespread at the drillable depth range of 10 kin, it is thereby an infinite resource type. By contrast, thermal power generation results in copious pollution; wind power is irregular and unstable; solar energy occupies large areas.
基金This work was funded by several scientific research programs including Evaluation and Optimal Target Selection of Deep Geothermal Resources in the Igneous Region of South China(No.:2019YFC0604903)Analysis and Geothermal Reservoir Stimulation Methods of Deep High-temperature Geothermal Systems in East China(No.:2021YFA0716004)+1 种基金the National Key Research and Development Program of China,Deep Geological Processes and Resource Effects of Basins(No.:U20B6001)the Joint Fund Program of the National Natural Science Foundation of China and Sinopec,and Siting and Target Evaluation of Deep Geothermal Resources in Key Areas of Southeastern China(No.:P20041-1)of the Sinopec Science and Technology Research Program.
文摘Cap rocks with high thermal insulation are important for deep geothermal systems at a depth of 3000‒6000 m.Based on the deep geothermal geological conditions in the Fujian-Guangdong-Hainan area of South China,this study established an ideal geological model of reservoir-cap rock assemblages and simulated the geothermal field distribution of cap rocks of different thicknesses and thermal conductivity.The simulation results show that the vertical geothermal temperature distribution in an uplifted area of a depression was present as inverted mirror reflections relative to the elevated area of the basement.Specifically,the isotherms above the elevated area are convex in shape,while those below the elevated area are concave.There is a temperature equilibrium line between the convex and concave isotherms.The heat flow moves from the depressed area to the uplifted area below the temperature equilibrium line and migrates in an opposite direction above the line.On this base,this study conducted the inversion of geothermal temperature fields in typical areas with thin,moderately thick,and thick cap rocks.The results indicate that,at the depth of 3000e6000 m,areas with thin cap rocks(igneous rock zone in the coastal area of Fujian)mainly host moderate-to low-temperature hydrothermal resources;areas with moderately thick cap rocks(Yuezhong Depression)have the geothermal temperature ranging between 100℃and 200℃and may develop moderate-to high-temperature hydrothermal resources and hot dry rocks(HDRs),with the former superimposing on the latter;and areas with thick cap rocks(onshore Beibuwan Basin)have a geothermal temperature of 120‒220℃,and contains mainly moderate-to high-temperature hydrothermal resources and HDRs.Therefore,it is recommended that the evaluation,exploitation,and utilization of deep geothermal resources be carried out according to the burial depth of the temperature equilibrium line and the specific demand for geothermal resources.
基金supported by the Open Fund Project of State Key Laboratory of Lithospheric Evolution [SKL-K202103]support of the Exploration and Development Research Institute of Petro China Southwest Oil & Gas Field
文摘Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the lack of low-maturity source rocks in deep petroliferous basins.We considered the Ediacaran microbial dolomite in the Sichuan Basin,the largest high-maturity marine gas layer in China,to exhibit a method that quantitatively characterizes the hydrocarbon expulsion of high-maturity marine source rocks.The experiment of fluid inclusion,rock pyrolysis,and vitrinite reflectance(Ro)of 119 microbial dolomite core samples obtained from the Dengying Formation were performed.A hydrocarbon expulsion model of high-maturity source rock was established,and its resource potential was evaluated.The results showed that the Ediacaran microbial dolomite in the Sichuan Basin is a good source rock showing vast resource potential.The hydrocarbon expulsion threshold is determined to be vitrinite reflectance at 0.92%.The hydrocarbon expulsion intensities in the geologic history is high with maximum of 1.6×10^(7)t/km^(2).The Ediacaran microbial dolomite expelled approximately 1.008×10^(12)t of hydrocarbons,and the recoverable resource was 1.5×10^(12)m^(3).The region can be categorized into areasⅠ,Ⅱ,Ⅲ,andⅣ,in decreasing order of hydrocarbon expulsion intensity.Areas with a higher hydrocarbon expulsion intensity have a lower drilling risk and should be prioritized for exploration in the orderⅠ>Ⅱ>Ⅲ>Ⅳ.Two areas,northern and central parts of Ediacaran in the Sichuan Basin,were selected as prospects which had the drilling priority in the future gas exploration.The production data of 55 drilled wells verified the high reliability of this method.This model in this study does not require low-maturity samples and can be used for evaluating high-maturity marine source rocks,which has broad applicability in deep basins worldwide.
基金financially supported by the project of investigation and evaluation of potash deposits in the Cretaceous-Tertiary salt basin of the Tarim basin from potash investigation project of China Geological Survey (1212011220790)
文摘The world petroleum exploration suggests that,about70%of the world’s potash resources were discovered during oil and gas exploration(Zheng et al.,2007).The Kuqa depression in the Tarim basin is abundant with petroleum exploration data,and
文摘1 Introduction The Gremyachinskoye potassium salt field lies within the Safronovskaya area and is confined to the preoverthrust zone–the 20-25 kilometer band conventionally recognized in the southern termination of the Volga
基金financially supported by the project of investigation and evaluation of potash deposits in the Cretaceous-Tertiary salt basin of the Tarim basin frompotash investigation project of China Geological Survey
文摘Potash is one of the long-term scare deposits in China,and potash prospecting has long been listed as a key brainstorm project for our nation and geological prospecting units.There have been considerable studies in search for potash deposits in the Kuqa depression of the Tarim basin(Jackson et al.,1991;Gemmer et al.,2004;Vendeville,2005;Vendeville and Jackson,1992a,1992b),
基金financially supported by Xinjiang Oilfield Company of China(Grant No.2020-C4006)。
文摘In order to study the hydrocarbon generation(HCGE)characteristics of coal-bearing basins,the coal-measure source rocks of the Middle Jurassic-Lower Jurassic(MLJ)of the piedmont thrust belt in the southern margin of the Junggar Basin in Northwest China are taken as research objects.More than 60 MLJ samples were collected from outcrops and wells.Total organic carbon(TOC),rock pyrolysis(Rock-Eval),organic petrological,vitrinite reflectance(%Ro),and hydrous pyrolysis were performed to analyze the relevant samples.The pyrolysis gases and liquid products were measured,and then the chemical composition,as well as carbon isotopes of the gases,were analyzed.The results indicate that the MLJ source rocks have the capacity for large-scale gas generation.In addition,for coal-measure source rocks,the heavier the carbon isotope of kerogen(δ^(13)C_(kerogen)),the lower the liquid hydrocarbon and hydrocarbon gas yield,and the easier it is to produce non-hydrocarbon gas.It is worth noting that when theδ^(13)C_(kerogen)in organic matter(OM)is relatively heavier,the fractionation of its products may become weaker in the evolutionary process.The vital contribution of the MLJ source rock to natural gas resources in the study area was further confirmed by comparing it with the Jurassic source gas.
基金supported by the National Natural Science Foundation of China(U6212205)the Chinese Postdoctoral Science Foundation(2014M550984)
文摘Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T3xs) in the Western Sichuan Basin (WSD) are currently regarded as the most prolific emerging unconventional gas plays in China. This study conducted a conventional evaluation of T3x5 source rocks in the WSD, and investigated their hydrocarbon generation and expulsion characteristics, including intensity, efficiency and amount. The results show that, the T3x5 source rocks are thick (generally 〉200 m), and have a high total organic content (TOC), ranging from 2.5 to 4.5 wt%. It is thus indivative of a great hydrocarbon generation potential when they underwent high thermal evolution (Ro〉1.2%) in the area. In addition, an improved method of hydrocarbon generation potential is applied, indicating that the source rocks reached a hydrocarbon expulsion threshold with vitrinite reflectance (Ro) reaching 1.06%. and that the comprehensive hydrocarbon expulsion efficiency is about 60%. The amount of hydrocarbon generation and expulsion from Tax5 source rocks is 3.14x10^10 t and 1.86x10^10 t, respectively, with a residual amount of 1.28x10^10t within them. Continuous-type tight-sand gas is predicted to have developed in the Jurassic in the Chengdu Sag of the WSD because of the good source-reservoir configuration; the Jurassic sandstone reservoirs are tight, and the gas expelled from the T3xs source rocks migrates for very short distances vertically and horizontally. The amount of gas accumulation in the Jurassic reservoirs derived from T3x5 source rocks is up to 9.3x10s t. Geological resources of shale gas are up to 1.05x10TM t. Small differences between the amounts calculated by the volumetric method and those obtained by hydrocarbon generation potential method may be due to other gas accumulations present within interbedded sands associated with gas shales.
基金the financial support of the National Natural Science Foundation of China(42176212,41976074 and 41302034)the Marine S&T Fund of Shandong Province for Laoshan Laboratory(2021QNLM020002)the Marine Geological Survey Program(DD20221704)。
文摘The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.Understanding the formation and distribution of multi-component gas hydrates in fractures is crucial in accurately evaluating the hydrate reservoir resources in this area.The hydrate formation experiments were carried out using the core samples drilled from hydrate-bearing sediments in Qilian Mountain permafrost area and the multi-component gas with similar composition to natural gas hydrates in Qilian Mountain permafrost area.The formation and distribution characteristics of multi-component gas hydrates in core samples were observed in situ by X-ray Computed Tomography(X-CT)under high pressure and low temperature conditions.Results show that hydrates are mainly formed and distributed in the fractures with good connectivity.The ratios of volume of hydrates formed in fractures to the volume of fractures are about 96.8%and 60.67%in two different core samples.This indicates that the fracture surface may act as a favorable reaction site for hydrate formation in core samples.Based on the field geological data and the experimental results,it is preliminarily estimated that the inventory of methane stored in the fractured gas hydrate in Qilian Mountain permafrost area is about 8.67×1013 m3,with a resource abundance of 8.67×108 m3/km2.This study demonstrates the great resource potential of fractured gas hydrate and also provides a new way to further understand the prospect of natural gas hydrate and other oil and gas resources in Qilian Mountain permafrost area.
文摘Peninsular Malaysia is already well known for having rare earth(RE)resources.However,pertinent data and information on upstream RE resources and reserve potential in Malaysia are yet to be established.It is vital to identify opportunities and challenges for value addition to rare earth elements(REEs)deposits in Malaysia.Therefore,this study evaluates the potential of Malaysian geological formations to serve as repositories for RE resources,such as rare earth minerals(REMs)and REEs,by elucidating the geological processes that are considered critical to the formation of the various deposit types.This paper concisely reviews possible REE mineralization in alkaline igneous rocks,pegmatites,placer deposits:monazite and xenotime,marine sediments,river and lake sediments,ion adsorption clays(IAC)deposits,and shale/coal deposits found in Malaysia.Comparisons between Malaysian deposits revealed that these deposits are potentially enriched with RE resources showing geological formations across the world.The paper reviews the methods and flowsheets used for the recovery of REMs and REEs from primary,secondary as well as alternative resources,with special consideration to the hydrometallurgical procedures comprising of leaching with acids and alkalis tailed by ion exchange,solvent extraction,or precipitation.The REEs ecosystem of Malaysia has also been discussed by considering the latest information from the Malaysian Investment Development Authority(MIDA),the REEs processing center,the Academy of Science of Malaysia(ASM),the People’s Republic of China(PRC),Lynas Malaysia Sdn.Bhd.(Lynas),Ministry of Energy and Natural Resources(NRECC),Jabatan Mineral&Geosains(JMG),Ministry of Science,Technology,and Innovation(MOSTI),and the Malaysian Chamber of Mines.The information on upstream RE resources and recent hydrometallurgical approaches provided in this study will contribute to developing and enhancing midstream and downstream RE-based manufacturing and processing operations in Malaysia.
文摘A suite of potassium-bearing minerals from the Walgidee Hills lamproite intrusion in the Kimberley region of Western Australia was selected for 39Ar/40Ar dating. These included wadeite, jeppeite, priderite, potassium richterite, and phlogopite. All recorded excellent plateau ages, with the mean age of the combined data set being 17.3±0.3 Ma. Phlogopite recorded the largest uncertainty, whereas, of the other minerals,wadeite gave the best precision. Although rare to absent in common magmatic rocks, these minerals are widely distributed in alkaline complexes and in lamproite, kimberlite and orangeite intrusions. The results indicate this suite of minerals is excellent for 39Ar/40Ar dating and that they can be used singly or in combination to obtain the precise magmatic crystallization ages of ultra-alkaline rocks. Because of the stability of potassium richterite at mantle depths, 39Ar/40Ar dating of MARID(micaamphibole-rutile-ilmenite-diopside) xenoliths should be a more widely-applied technique to investigating mantle geodynamics.
基金supported by the National Science Foundation Engineering Research Center for Bio-mediated and Bio-inspired Geotechnics(EEC-1449501).
文摘Drilling plays a significant role in the history of human civilization.The exploration of greater depths,extreme environments,or hazardous areas calls for more energy-efficient and high levels of autonomous drilling technologies with reduced cost and improved safety.Meanwhile,nature presents numerous biological boring examples that can be a source of inspiration to renovate our current drilling technologies.This paper reviews both man-made and biological drilling strategies and quantifies their performance by the dimensionless specific drilling energy and the rate of penetration.The results highlight that rotary drilling(including tunnel boring machines)remains the most popular method for subsurface drilling due to its advanced technical status and fewer environmental concerns.For harder rocks,the specific energy of rotary drilling increases dramatically,while percussion drilling requires nearly the same if not lower specific energy but with compromised bit durability that can significantly slow down the drilling operation.Innovative drilling technologies developed and tested in the laboratory still demand improved energy efficiency and penetration rate to be competitive.Bio-boring by natural organisms mostly outperforms man-made drilling technologies in terms of energy efficiency,penetration rate,or both.Studying the underlying mechanisms of bio-boring and translating such knowledge into developing innovative drilling technologies are of significance to subsurface construction and exploration.