A kinetic model of the pozzolanic reaction for the preparation of flue gas desulfurizers from fly ash and Ca(OH)_(2) was deduced on the basis of solid phase reaction kinetic theory.Kinetic expressions and parameters w...A kinetic model of the pozzolanic reaction for the preparation of flue gas desulfurizers from fly ash and Ca(OH)_(2) was deduced on the basis of solid phase reaction kinetic theory.Kinetic expressions and parameters were obtained and verified by experiment.A comparison of calculated results with experimental results showed that precision in kinetic expressions was good.The apparent reaction rate constants of the pozzolanic reaction could be raised by increasing the specific surface area of fly ash and the hydration temperature,and by using a suitable additive.展开更多
Volume instability of expansive soils due to moisture fluctuations is often disastrous,causing severe damages and distortions in the supported structures.It is,therefore,necessary to adequately improve the performance...Volume instability of expansive soils due to moisture fluctuations is often disastrous,causing severe damages and distortions in the supported structures.It is,therefore,necessary to adequately improve the performance of such soils that they can favorably fulfil the post-construction stability requirements.This can be achieved through chemical stabilization using additives such as lime,cement and fly ash.In this paper,suitability of such additives under various conditions and their mechanisms are reviewed in detail.It is observed that the stabilization process primarily involves hydration,cation exchange,flocculation and pozzolanic reactions.The degree of stabilization is controlled by several factors such as additive type,additive content,soil type,soil mineralogy,curing period,curing temperature,delay in compaction,pH of soil matrix,and molding water content,including presence of nano-silica,organic matter and sulfate compounds.Provision of nano-silica not only improves soil packing but also accelerates the pozzolanic reaction.However,presence of deleterious compounds such as sulfate or organic matter can turn the treated soils unfavorable at times even worser than the unstabilized ones.展开更多
The reactivity of the recycled glass powder (GP) in a cementitious medium has been studied over time by means of X-ray diffraction and thermal gravimetric analysis. Two different mixtures based on cement/glass powder ...The reactivity of the recycled glass powder (GP) in a cementitious medium has been studied over time by means of X-ray diffraction and thermal gravimetric analysis. Two different mixtures based on cement/glass powder (0 or 20 wt% GP) and lime/glass powder (70 wt% GP) were considered. Analysis revealed the coexistence of both hydration and pozzolanic reaction during the hardening of the mortars. At young age, the cement hydration would prevail over the pozzolanic one resulting in a decrease of physico-chemical </span></span><a name="_GoBack"></a><span><span><span style="font-family:"">and mechanical properties of the material due to the dilution effect. The pozzolanic reaction that predominates from 91 days, would induce the formation of supplementary C-S-H leading to improve the material properties.展开更多
文摘A kinetic model of the pozzolanic reaction for the preparation of flue gas desulfurizers from fly ash and Ca(OH)_(2) was deduced on the basis of solid phase reaction kinetic theory.Kinetic expressions and parameters were obtained and verified by experiment.A comparison of calculated results with experimental results showed that precision in kinetic expressions was good.The apparent reaction rate constants of the pozzolanic reaction could be raised by increasing the specific surface area of fly ash and the hydration temperature,and by using a suitable additive.
文摘Volume instability of expansive soils due to moisture fluctuations is often disastrous,causing severe damages and distortions in the supported structures.It is,therefore,necessary to adequately improve the performance of such soils that they can favorably fulfil the post-construction stability requirements.This can be achieved through chemical stabilization using additives such as lime,cement and fly ash.In this paper,suitability of such additives under various conditions and their mechanisms are reviewed in detail.It is observed that the stabilization process primarily involves hydration,cation exchange,flocculation and pozzolanic reactions.The degree of stabilization is controlled by several factors such as additive type,additive content,soil type,soil mineralogy,curing period,curing temperature,delay in compaction,pH of soil matrix,and molding water content,including presence of nano-silica,organic matter and sulfate compounds.Provision of nano-silica not only improves soil packing but also accelerates the pozzolanic reaction.However,presence of deleterious compounds such as sulfate or organic matter can turn the treated soils unfavorable at times even worser than the unstabilized ones.
文摘The reactivity of the recycled glass powder (GP) in a cementitious medium has been studied over time by means of X-ray diffraction and thermal gravimetric analysis. Two different mixtures based on cement/glass powder (0 or 20 wt% GP) and lime/glass powder (70 wt% GP) were considered. Analysis revealed the coexistence of both hydration and pozzolanic reaction during the hardening of the mortars. At young age, the cement hydration would prevail over the pozzolanic one resulting in a decrease of physico-chemical </span></span><a name="_GoBack"></a><span><span><span style="font-family:"">and mechanical properties of the material due to the dilution effect. The pozzolanic reaction that predominates from 91 days, would induce the formation of supplementary C-S-H leading to improve the material properties.
