Microstructure evolution in neutron irradiated Reactor Pressure Vessel （RPV） steels was experimentally simulated through an improved degradation procedure in this study. The degradation procedure includes austenitiz...Microstructure evolution in neutron irradiated Reactor Pressure Vessel （RPV） steels was experimentally simulated through an improved degradation procedure in this study. The degradation procedure includes austenitizing at 1 150℃ and water quench, deformation 10% and 30% respectively, and then thermal aging at 500℃ for different period of time. The microstructure of the specimens was analyzed in details using transmission electron microscopy （TEM）. The micro-hardness test results showed that all the hardness curves of undeformed, 10% pre-deformed and 30% pre-deformed specimens have two micro-hardness peaks with the first peak value corresponding to different thermal aging time of 1 hour, 5 hours and 10 hours, respectively. It was revealed that the hardness curves were influenced by the precipitation of Cu-rich precipitates （CRPs） and carbides, deposition of martensite and work hardening.展开更多
动脉粥样硬化是心血管疾病重要的病理生理基础,延缓和防治动脉粥样硬化对于减少和降低心血管疾病的发病率及病死率具有重要意义。高密度脂蛋白(high density lipoprotein,HDL)通过参与介导胆固醇逆向转运(reverse cholesterol transport...动脉粥样硬化是心血管疾病重要的病理生理基础,延缓和防治动脉粥样硬化对于减少和降低心血管疾病的发病率及病死率具有重要意义。高密度脂蛋白(high density lipoprotein,HDL)通过参与介导胆固醇逆向转运(reverse cholesterol transport,RCT)在抗动脉粥样硬化的形成和进展中发挥了重要作用。Preβ-1高密度脂蛋白(prebeta-1 high density lipoprotein,Preβ-1HDL)作为HDL的一种亚类,是外周细胞移出胆固醇的最初接受体,直接参与了RCT的起始步骤,并在随后的胆固醇酯化及转运中起着重要作用。本文就Preβ-1HDL的结构、代谢及其与心血管疾病的关系作一简要综述。展开更多
A PCR-DGGE (denaturing gradient gel electrophoresis of polymerase chain reaction) protocol was used for monitoring the dynamic changes in the microbial population during photohydrogen production. Total DNA was extract...A PCR-DGGE (denaturing gradient gel electrophoresis of polymerase chain reaction) protocol was used for monitoring the dynamic changes in the microbial population during photohydrogen production. Total DNA was extracted directly from the mixed bacterial community in the reactor and subjected to PCR with V3-16S rDNA and pufM gene primers, and the amplifications were then analyzed by DGGE. The DGGE patterns demonstrated the dynamics of community structure and the shift of microbial diversity, which correspond...展开更多
A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determini...A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous. The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships. A mathe-matic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement.展开更多
Enantioselective hydrogenation of ethyl 2-oxo-4-phenylbutyrate to ethyl （R）-2-hydroxy-4-phenyl- bu- tyrate on Pt/γ-Al2O3 modified by 10,11-dihydrocinchonidine was studied by investigating the influences of the amou...Enantioselective hydrogenation of ethyl 2-oxo-4-phenylbutyrate to ethyl （R）-2-hydroxy-4-phenyl- bu- tyrate on Pt/γ-Al2O3 modified by 10,11-dihydrocinchonidine was studied by investigating the influences of the amount of modifier, initial concentration of reactant, pressure and temperature on conversion and enantiometric excess in a stirred autoclave and the effects of the liquid velocity, gas velocity, modifier concentration and various catalytic beds in a trickle-bed reactor. The maximum optical yields were about 50% and 60% in the two types of reactors, respectively. It was assumed that the total hydrogenation rate included the reaction rates over the unmodified and modified active sites on platinum surface and a kinetic model, which fitted the experimental data well in autoclave, was obtained. A simplified plug-flow model was proposed to describe the bed average efficiency of trickle-bed reactor.展开更多
A self-tuning reaching law based sliding mode control(SMC)theory is proposed to stabilize the nonlinear continuous stirred tank reactor(CSTR).T-S fuzzy logic is used to build a global fuzzy state-space linear model.Co...A self-tuning reaching law based sliding mode control(SMC)theory is proposed to stabilize the nonlinear continuous stirred tank reactor(CSTR).T-S fuzzy logic is used to build a global fuzzy state-space linear model.Combing the traits of SMC and CSTR,three fuzzy rules can meet the requirements of controlled system.The self-tuning switch control law which can drive the state variables to the sliding surface as soon as possible is designed to ensure the robustness of uncertain fuzzy system.Lyapunov equation is applied to proving the stability of the sliding surface.The simulations show that the proposed approach can achieve desired performance with less chattering problem.展开更多
The mechanical and fatigue properties of SA508-Ⅳ steel with martensite and granular bainite, respectively, were studied. The mechanical tests results showed that the ultimate tensile strength and impact toughness of ...The mechanical and fatigue properties of SA508-Ⅳ steel with martensite and granular bainite, respectively, were studied. The mechanical tests results showed that the ultimate tensile strength and impact toughness of the specimen with martensite were 830 MPa and 158 J, respectively, and those of the specimen with granular bainite were 811 MPa and 115 J, respectively. The former had higher tensile strength and impact toughness than the latter. The impact tests results showed that the former belonged to typical dimple fracture, while the latter belonged to brittle fracture. The fatigue tests results showed that the fatigue life of the specimen with martensite was 2717 cycles, and that of the specimen with granular bainite was 1545 cycles under the strain amplitude of ± 0.45%. The specimen with martensite had fewer crack initiation points, narrower fatigue striations separation, and larger volume fraction of high-angle grain boundaries than the latter. The fewer crack initiation points meant fewer fatigue cracks, the narrower fatigue striations separation meant slower crack propagation rate, and the larger volume fraction of high-angle grain boundaries could more effectively hinder fatigue crack propagation. Based on these facts, the fatigue life of the specimen with martensite was higher than that of the specimen with granular bainite.展开更多
Three parallel lab-scale expanded granular sludge bed(EGSB) reactors were employed to evaluate the start-up process of bio-hydrogen production from molasses wastewater.With other start-up parameters controlled the sam...Three parallel lab-scale expanded granular sludge bed(EGSB) reactors were employed to evaluate the start-up process of bio-hydrogen production from molasses wastewater.With other start-up parameters controlled the same,the effect of inoculating sludge pre-treatments was studied.Two methods of pre-treatments(pre-heating and pre-aeration) were conducted for the inoculating sludge in two reactors compared with a non-pre-treatment reactor(control reactor).The results showed that the reactors with pre-treatment performed better in the start-up process than the control one.The hydrogen-producing bacteria were efficiently enriched at the start-up period,shortening the start-up process.At the end of the start-up stage,the acidification rate of the pre-treatment reactors was 10%—30% more than the control one,and hydrogen production increased by 1.69—1.82 times.Considering cost and feasibility,the authors suggest applying the pre-aeration method to treat the inoculating sludge to get more efficient start-up in the industrial scale bio-hydrogen production plant.展开更多
文摘Microstructure evolution in neutron irradiated Reactor Pressure Vessel （RPV） steels was experimentally simulated through an improved degradation procedure in this study. The degradation procedure includes austenitizing at 1 150℃ and water quench, deformation 10% and 30% respectively, and then thermal aging at 500℃ for different period of time. The microstructure of the specimens was analyzed in details using transmission electron microscopy （TEM）. The micro-hardness test results showed that all the hardness curves of undeformed, 10% pre-deformed and 30% pre-deformed specimens have two micro-hardness peaks with the first peak value corresponding to different thermal aging time of 1 hour, 5 hours and 10 hours, respectively. It was revealed that the hardness curves were influenced by the precipitation of Cu-rich precipitates （CRPs） and carbides, deposition of martensite and work hardening.
文摘动脉粥样硬化是心血管疾病重要的病理生理基础,延缓和防治动脉粥样硬化对于减少和降低心血管疾病的发病率及病死率具有重要意义。高密度脂蛋白(high density lipoprotein,HDL)通过参与介导胆固醇逆向转运(reverse cholesterol transport,RCT)在抗动脉粥样硬化的形成和进展中发挥了重要作用。Preβ-1高密度脂蛋白(prebeta-1 high density lipoprotein,Preβ-1HDL)作为HDL的一种亚类,是外周细胞移出胆固醇的最初接受体,直接参与了RCT的起始步骤,并在随后的胆固醇酯化及转运中起着重要作用。本文就Preβ-1HDL的结构、代谢及其与心血管疾病的关系作一简要综述。
基金the National NaturalScience Foundation (No. 30570053)the Fund of CrossSubjects of Zhejiang University (No. 109000-812651)+2 种基金the National Natural Science Foundation of China (No.50406022)the National High Technology Research and Development Program of China (No. 2007AA10Z409)the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science &Technology of China (No. 2006BAJ08B01)
文摘A PCR-DGGE (denaturing gradient gel electrophoresis of polymerase chain reaction) protocol was used for monitoring the dynamic changes in the microbial population during photohydrogen production. Total DNA was extracted directly from the mixed bacterial community in the reactor and subjected to PCR with V3-16S rDNA and pufM gene primers, and the amplifications were then analyzed by DGGE. The DGGE patterns demonstrated the dynamics of community structure and the shift of microbial diversity, which correspond...
基金the State Key Development Program for Basic Research of China (No. G2000048005) the SINOPEC (No.X503023).
文摘A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous. The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships. A mathe-matic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement.
基金Project(50621063)supported by the National Natural Science Foundation of ChinaProject(2004CB619205)supported by the National Basic Research Program of ChinaProject(2007AA060902)supported by the High-tech Research and Development Program of China
文摘Enantioselective hydrogenation of ethyl 2-oxo-4-phenylbutyrate to ethyl （R）-2-hydroxy-4-phenyl- bu- tyrate on Pt/γ-Al2O3 modified by 10,11-dihydrocinchonidine was studied by investigating the influences of the amount of modifier, initial concentration of reactant, pressure and temperature on conversion and enantiometric excess in a stirred autoclave and the effects of the liquid velocity, gas velocity, modifier concentration and various catalytic beds in a trickle-bed reactor. The maximum optical yields were about 50% and 60% in the two types of reactors, respectively. It was assumed that the total hydrogenation rate included the reaction rates over the unmodified and modified active sites on platinum surface and a kinetic model, which fitted the experimental data well in autoclave, was obtained. A simplified plug-flow model was proposed to describe the bed average efficiency of trickle-bed reactor.
文摘A self-tuning reaching law based sliding mode control(SMC)theory is proposed to stabilize the nonlinear continuous stirred tank reactor(CSTR).T-S fuzzy logic is used to build a global fuzzy state-space linear model.Combing the traits of SMC and CSTR,three fuzzy rules can meet the requirements of controlled system.The self-tuning switch control law which can drive the state variables to the sliding surface as soon as possible is designed to ensure the robustness of uncertain fuzzy system.Lyapunov equation is applied to proving the stability of the sliding surface.The simulations show that the proposed approach can achieve desired performance with less chattering problem.
基金the Beijing Municipal Natural Science Foundation under No.2162026 and the 863 Program of China under Nos.2008AA031702 and 2012AA03A507 for financial support.
文摘The mechanical and fatigue properties of SA508-Ⅳ steel with martensite and granular bainite, respectively, were studied. The mechanical tests results showed that the ultimate tensile strength and impact toughness of the specimen with martensite were 830 MPa and 158 J, respectively, and those of the specimen with granular bainite were 811 MPa and 115 J, respectively. The former had higher tensile strength and impact toughness than the latter. The impact tests results showed that the former belonged to typical dimple fracture, while the latter belonged to brittle fracture. The fatigue tests results showed that the fatigue life of the specimen with martensite was 2717 cycles, and that of the specimen with granular bainite was 1545 cycles under the strain amplitude of ± 0.45%. The specimen with martensite had fewer crack initiation points, narrower fatigue striations separation, and larger volume fraction of high-angle grain boundaries than the latter. The fewer crack initiation points meant fewer fatigue cracks, the narrower fatigue striations separation meant slower crack propagation rate, and the larger volume fraction of high-angle grain boundaries could more effectively hinder fatigue crack propagation. Based on these facts, the fatigue life of the specimen with martensite was higher than that of the specimen with granular bainite.
文摘Three parallel lab-scale expanded granular sludge bed(EGSB) reactors were employed to evaluate the start-up process of bio-hydrogen production from molasses wastewater.With other start-up parameters controlled the same,the effect of inoculating sludge pre-treatments was studied.Two methods of pre-treatments(pre-heating and pre-aeration) were conducted for the inoculating sludge in two reactors compared with a non-pre-treatment reactor(control reactor).The results showed that the reactors with pre-treatment performed better in the start-up process than the control one.The hydrogen-producing bacteria were efficiently enriched at the start-up period,shortening the start-up process.At the end of the start-up stage,the acidification rate of the pre-treatment reactors was 10%—30% more than the control one,and hydrogen production increased by 1.69—1.82 times.Considering cost and feasibility,the authors suggest applying the pre-aeration method to treat the inoculating sludge to get more efficient start-up in the industrial scale bio-hydrogen production plant.
