Analyze the Performance of Electroactive Anticorrosion Coating of Medical Magnesium Alloy Using Deep Learning

Electroactive anticorrosion coatings are specialized surface treatments that prevent or minimize corrosion. Thestudy employs strategic thermodynamic equilibriumcalculations to pioneer a novel factor in corrosion protection.A first-time proposal, the total acidity (TA) potential of the hydrogen (pH) concept significantly shapes medicalmagnesium alloys. These coatings are meticulously designed for robust corrosion resistance, blending theoreticalinsights and practical applications to enhance our grasp of corrosion prevention mechanisms and establisha systematic approach to coating design. The groundbreaking significance of this study lies in its innovativeintegration of the TA/pH concept,which encompasses the TA/pH ratio of the chemical environment. This approachsurpasses convention by acknowledging the intricate interplay between the acidity and pH levels within thecoating formulation, thereby optimizing metal-phosphate-based conversion coatings and transforming corrosionmitigation strategies. To authenticate the TA/pH concept, the study comprehensively compares its findings withexisting research, rigorously validating the theoretical framework and reinforcing the correlates among TA/pHvalues and observed corrosion resistance in the coatings. The influence of mutations that occur naturally inthe detergent solution on persistent phosphorus changes is shown by empirical confirmation, which improvescorrosion resistance. This realization advances the field ofmaterials and the field’s knowledge of coated generation,particularly anticorrosion converter layers.

Multiphase Interfacial Regulation Based on Hierarchical Porous Molybdenum Selenide to Build Anticorrosive and Multiband Tailorable Absorbers

Electromagnetic wave(EMW)absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control.And in order to cope with the complex electromagnetic environment,the design of multifunctional and multiband high efficiency EMW absorbers remains a tremendous challenge.In this work,we designed a three-dimensional porous structure via the salt melt synthesis strategy to optimize the impedance matching of the absorber.Also,through interfacial engineering,a molybdenum carbide transition layer was introduced between the molybdenum selenide nanoparticles and the three-dimensional porous carbon matrix to improve the absorption behavior of the absorber.The analysis indicates that the number and components of the heterogeneous interfaces have a significant impact on the EMW absorption performance of the absorber due to mechanisms such as interfacial polarization and conduction loss introduced by interfacial engineering.Wherein,the prepared MoSe_(2)/MoC/PNC composites showed excellent EMW absorption performance in C,X,and Ku bands,especially exhibiting a reflection loss of−59.09 dB and an effective absorption bandwidth of 6.96 GHz at 1.9 mm.The coordination between structure and components endows the absorber with strong absorption,broad bandwidth,thin thickness,and multi-frequency absorption characteristics.Remarkably,it can effectively reinforce the marine anticorrosion property of the epoxy resin coating on Q235 steel substrate.This study contributes to a deeper understanding of the relationship between interfacial engineering and the performance of EMW absorbers,and provides a reference for the design of multifunctional,multiband EMW absorption materials.

Developing single-atom catalyst-based epoxy coating with active nanocatalytic anticorrosion performance in oxygen environment

The stimuli-responsive anticorrosion coatings have drawn great attention as a prospective corrosion protection approach due to their smart self-repairing properties.In contrast to passive protection mechanism based on post-corrosion microenvironmental changes,a unique active protection strategy based on nanocatalytic oxygen depletion is proposed in this work to inhibit the occurrence of corrosion.Porous FeeNeC catalysts with outstanding oxygen reduction reaction(ORR)activity(half-wave potential of 0.89 V)is firstly synthesized through pre-coordination with organosilane precursor to obtain homogeneously distributed active sites.When this catalyst is introduced into the coating matrix,uniformly distributed FeeNeC not only compensates the defects but plays a crucial role in adsorption and consumption of diffused oxygen in the coating.Under this dual action,the penetration of corrosive medium,especially oxygen,through coating to metal substrate is greatly suppressed,resulting in effective corrosion inhibition and a significant increase in corrosion resistance of the composite coating compared to pure epoxy coating.This work provides a new perspective and the starting point for the design of high-performance smart coating with active anticorrosion properties.

Improvement of anticorrosion and adhesion to magnesium alloy by phosphate coating formed at room temperature

A new surface protection process was developed to magnesium alloy against corrosion in aggressive environments.Firstly,a phosphate coating was formed on rinsed magnesium alloy.Then,powder painting was carried out on the phosphated magnesium alloy.Surface morphologies and phase compositions of the phosphate coating were investigated by X-ray diffraction(XRD) and scanning electron microscope(SEM) .The results show that the phosphate coatings formed in bath containing earth additives at room temperature have dense and fine microstructure.The phosphate coating provides excellent paint adhesion to the magnesium alloy. Salt spray tests indicate that the corrosion resistance of the phosphate coating plus paint could meet the demand of magnesium alloy automobile components in aggressive environments.

Developing polydopamine modified molybdenum disulfide/epoxy resin powder coatings with enhanced anticorrosion performance and wear resistance on magnesium lithium alloys

Epoxy resin powder coating has been successfully applied on the corrosion protection of magnesium lithium alloys.However,poor wear resistance and microcracks formed during the solidification have limited it extensive application.There are limited approaches to exploit such anti-corrosion and mechanical properties of magnesium lithium alloys.Herein,the epoxy resin powder coating with polydopamine modified molybdenum disulfide(MoS_(2)@PDA-EP powder coating with 0,0.1,0.2,0.5,1.0 wt.%loading)was well prepared by melt extrusion to investigate its anticorrosion performance and wear resistance.The results revealed that the addition of MoS_(2)@PDA enhanced the adhesion strength between coatings and alloys,wear resistance and corrosion protection of the powder coatings.Among them,the optimum was obtained by 0.2 wt.%MoS_(2)@PDA-EP powder coating which could be attributed to well dispersion and efficient adhesion with coating matrix.To conclude,MoS_(2)@PDA-EP powder coating is meaningfully beneficial for the anticorrosive and wear performance improvement of magnesium lithium alloys.

Fabrication of superhydrophobic reduced-graphene oxide/nickel coating with mechanical durability,self-cleaning and anticorrosion performance

There is a great challenge to fabricate superhydrophobic coating with excellent mechanical durability and corrosion resistance.Inspired by the pinecone-shaped structure,a novel reduced-graphene oxide(rGO)/Ni composite coating with pinecone-like micro/nanostructures was fabricated successfully on a stainless steel substrate using a simple electrodeposition method combining Ni pre-deposition and an elevated current assistant approach.The results show that the coating is of self-cleaning and superhydrophicity with a water contact angle(CA)of 162.7°±0.8°and a sliding angle(SA)of 2.5°±1.0°.Importantly,the coating still maintains the excellent self-cleaning and superhydrophicity,water CA of 155.8°±1.2°and SA of 5.9°±1.2°,even after 100-cycle mechanical abrasion.Meanwhile,the coating also exhibits good anticorrosion performance in 3.5 wt%NaCl solution,with 99.98%inhibition efficiency.The simple fabrication method may provide a cost-effective way to prepare mechanically durable,anticorrosive,self-cleaning and superhydrophobic coatings on metal substrates.

A New Type Anticorrosion Coating for Ocean Reinforced Concrete Structures

Corrosion of reinforced concrete structures is a serious problem in ocean engineering. As an orientation of study, anticorrosion coating technique is developed and widely applied, but many problems need to be solved. LSW-2 type anticorrosion coating for maritime reinforced concrete structures is characterized by sea water resistance, salt fog resistance, moisture and heal resistance as well as impermeability to chlorions. The new type coating can be applied to wet concrete surface by conventional construction technique. It is a breakthrough in solving the above mentioned problem. The paper mainly introduces the test results, the property indices, coating procedure, construction technique and economic benefit of Ihe coating.

Anticorrosion performance of the coating/metal system by electrochemical impedance spectra

In order to investigate the anticorrosion performance of the organic coating/metal system, electrochemical impedance spectra （EIS） were measured in the 3.5wt% NaCl solution, the chemical component and the formation of corrosion products scale were analyzed by laser Raman microspectroscopy, and the pattern of the organic coating/metal system was observed by scanning electron microscopy （SEM）. The characteristics and the delamination process of the organic coating/metal system were investigated systematically, and the emphases were on the transportation of the corrosive medium and the changes of the coating/metal interface. The results show that the impedance decreases at the initial immersion, then increases at the middle-immersion, and again decreases at last, which is related to the corrosion products scale. The concentration of Cl in the coating, which destroys the corrosion products scale, increases with the immersion time.

Anticorrosive and antibacterial smart integrated strategy for biomedical magnesium

Biomedical magnesium is an ideal material for hard tissue repair and replacement.However,its rapid degradation and infection after implantation significantly hindersclinical applications.To overcome these two critical drawbacks,we describe an integrated strategybased on the changes in pH and Mg^(2+)triggered by magnesiumdegradation.This system can simultaneously offer anticorrosion and antibacterial activity.First,nanoengineered peptide-grafted hyperbranched polymers(NPGHPs)with excellent antibacterial activity were introduced to sodium alginate(SA)to construct a sensitive NPGHPs/SA hydrogel.The swelling degree,responsiveness,and antibacterial activity were then investigated,indicating that the system can perform dual stimulation of pH and Mg^(2+)with controllable antimicrobial properties.Furthermore,an intelligent platform was constructed by coating hydrogels on magnesium with polydopamine as the transition layer.The alkaline environment generated by the corrosion of magnesium reduces the swelling degree of the coatingso that the liquid is unfavorable for contacting the substrate,thus exhibiting superior corrosion resistance.Antibacterial testing shows that the material can effectively fight against bacteria,while hemolytic and cytotoxicity testing suggest that it is highly biocompatible.Thus,this work realizes the smart integration of anticorrosion and antibacterial properties of biomedical magnesium,thereby providing broader prospects for the use of magnesium.

Smart anticorrosion coating based on stimuli-responsive micro/nanocontainer:a review

Smart coating for corrosion protection of metal materials(steel,magnesium,aluminum and their alloys)has drawn great attention because of their capacity to prevent crack propagation in the protective coating by releasing functional molecules(healing agents or corrosion inhibitors)on demand from delivery vehicle,that is,micro/nanocontainer made up of a shell and core material or a coating layer,in a controllable manner.Herein,we summarize the recent achievements during the last 10 years in the field of the micro/nanocontainer with different types of stimuli-responsive properties,i.e.,pH,electrochemical potential,redox,aggressive corrosive ions,heat,light,magnetic field,and mechanical impact,for smart anticorrosion coating.The state-of-the-art design and fabrication of micro/nanocontainer are emphasized with detailed examples.

Competitive Adsorption of Anticorrosion and Antiwear Additives

Simulated adsorptive experiments using the axletree and lubricating oil containing anticorrosion additive were conducted,and the UV absorbance of the lubricating oil before and after the adsorptive experiments was measured.Through the UV spectral measurements the difference in UV absorbance of the lubricating oil before and after the adsorptive experiments was identified,the adsorbed quantity of anticorrosion additive in the interfacial film between lubricating oil and bearing was calculated using the Lambert-Bell principle to verify the adsorption of corrosion inhibitor on the surface of friction pairs.Adsorption experiments on lubricating oil containing both antiwear and anticorrosion additives were carried out and the UV absorbance of lubricating oil samples before and after the experiments was measured to determine the difference in the UV absorbance among lubricating oil samples with the same mass fraction of anticorrosion additive and different mass fractions of antiwear additive.By measuring the ultraviolet spectral absorbance of lubricating oil samples and calculating the adsorbed quantity of anticorrosion additive in the interfacial film it was possible to determine the influence of antiwear additive on the quantity of adsorbed anticorrosion additive on the surface of friction pairs and verify the competitive adsorption relationship between the antiwear additive and the anticorrosion additive.

Anticorrosion of WO₃-Modified TiO₂Thin Film Prepared by Peroxo Sol-Gel Method

The aim of this study was to develop a method to prepare WO3-TiO2 film which has high anticorrosion property when it was coated on type 304 stainless steel. A series of WO3-modified TiO2 sols were synthesized by peroxo-sol gel method using TiCl4 and Na2WO4 as the starting materials. TiCl4 was converted to Ti(OH)4 gel. H2O2 and Na2WO4 were added in Ti(OH)4 solution and heated at 95°C. The WO3-TiO2 sol was transparent, in neutral (pH^7) solution, stable suspension without surfactant, nano-crystallite and no annealing is needed after coating, and very stable for 2 years in stock. WO3-TiO2 sol was formed with anatase crystalline structure. These sols were characterized by XRD, TEM, and XPS. The sol was used to coat on stainless steel 304 by dip-coating. The WO3-TiO2 was anatase in structure as characterized by X-ray diffraction. There were no WO3 XRD peaks in the WO3-TiO2 sols, indicating that WO3 particles were very small, possibly incorporating into TiO2 structure, providing the amount of WO3 was very small. The TiO2 particles were rhombus shape. WO3-TiO2 had smaller size area than pure TiO2. The SEM results showed that the film coated on the glass substrate was very uniform. All films were nonporous and dense films. Its hardness reached 2 H after drying at 100°C, and reached 5 H after annealing at 400°C. The WO3-TiO2 film coated on 304 stainless steel had better anticorrosion capability than the unmodified TiO2 film under UV light illumination. The optimum weight ratio of TiO2: WO3 was 100:4.

石墨烯改性环氧云铁中间漆的制备和性能研究

为了进一步提高环氧云铁中间漆的阻隔效果,解决其在高湿和夏天高热的水工环境中防护长效性不足的问题。将薄层石墨烯添加到环氧云铁中间漆中,利用二维纳米石墨烯比表面积大的特点,研究了石墨烯添加量对涂层附着力、耐冲击性、耐淡水性、耐盐水性和电化学性能的影响。结果表明:纳米级石墨烯和微米级云母氧化铁的片层结构相结合提供了微纳协同屏蔽的机理,添加微量石墨烯后明显提高了涂层的各项性能,尤其是耐水渗透性、耐冲击性和在水中浸泡后涂层的附着力,使得石墨烯改性环氧云铁中间漆对处于高湿高热应用环境的水工钢结构能够提供更有效、更耐久的腐蚀防护。

有压热闷渣微粉对环氧涂料的性能影响

以有压热闷渣为研究对象,采用超细立式粉磨机处理有压热闷渣形成微粉,利用有压热闷渣微粉替代传统防腐填料与环氧树脂、二甲苯、正丁醇及聚酰胺形成有压热闷渣/环氧复合防腐涂料.根据《色漆和清漆摆杆阻尼试验》(GB/T 1730—2007)、《漆膜划圈试验》(GB/T 1720—2020)、《色漆和清漆耐磨性的测定旋转橡胶砂轮法》(GB/T 1768—2006)、《漆膜、腻子膜柔韧性测定法》(GB/T 1731—2020)测定涂层的硬度、附着力、耐磨性、柔韧性,《色漆和清漆耐中性盐雾性能》(GB/T 1771—2007)与《漆膜吸水率测定法》(HG/T 3344—2012)测定涂层的耐盐雾性能及吸水率.采用接触角测量仪、精密阻抗测试仪和电化学工作站测定涂层的接触角、阻抗模量和腐蚀电位.采用扫描电子显微镜、X射线荧光光谱仪、X射线衍射仪和激光粒度分析仪测试微观形貌、化学成分、矿物组成和粒度分布.研究有压热闷渣微粉对环氧复合防腐涂料涂层力学性能、防腐性能的影响,及其作用机理.结果表明有压热闷渣的主要矿物成分C_(3)S、C_(2)S、Ca(OH)_(2)、C_(2)F、RO相和f-CaO等,其具有硅酸盐特性可以提高耐久性.利用超细立式粉磨机对有压热闷渣进行加工,有利于f-CaO矿化,减小颗粒粒径、增大比表面积.当有压热闷渣微粉的粒径均匀度为2.240,其添加量为5%时有压热闷渣/环氧复合防腐涂料涂层的性能最佳,即摆杆硬度测试结果为115.75 s、附着力为3级、磨损量最小、柔韧性为4 mm、阻抗模量为10^(6.1)Ω·cm^(2)、腐蚀电位E为0.143 V.有压热闷渣微粉作为一种刚性粒子,将其加入环氧涂料体系中,一方面可以改善涂层的硬度、耐摩擦、力学等性能,另一方面合理的粒径均匀度可以增强涂层的密实度,提升防腐性能.开启有压热闷渣在非建材领域高值化利用的新途径,实现钢铁行业“以废增效”、涂料行业“以废降本”的目的.

纳米复合智能防腐涂层在金属表面上的应用研究

智能防腐涂料能可有效地提高金属的使用寿命,因而具有自愈功能的智能防腐涂料越来越受到人们的重视。概述了pH响应、光刺激响应、离子响应等不同触发机制的纳米智能防腐机制研究,总结了不同金属表面纳米复合智能防腐涂层研究进展,最后提出金属表面智能自修复防腐涂层发展所面临的挑战和未来发展前景。

船舶涂料研究进展

对船舶涂料的分类进行梳理,为今后进一步探索船舶涂料的新材料、新工艺和新应用提供指导。

软模板法制备聚苯胺干凝胶及在水性防腐涂料中的应用

分别以双十八烷基二甲基氯化铵和双十二烷基二甲基氯化铵为软模板,采用化学氧化法制备聚苯胺干凝胶。通过傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)等对聚苯胺干凝胶进行结构表征;将制备的聚苯胺干凝胶应用于水性防腐涂料中,考察其对水性涂料防腐性能的影响。结果表明,制得的聚苯胺水性防腐涂料具有较好的耐水、耐酸、耐碱、耐中性盐雾性。

新型石墨烯复合材料在金属防腐蚀领域的研究进展

介绍了石墨烯复合材料的防腐蚀原理,总结了国内外石墨烯和氧化石墨烯防护膜在金属防腐蚀领域的研究现状及存在的问题。简要介绍了改性石墨烯复合涂层的制备工艺及其效果。从无机纳米氧化物/石墨烯复合材料、聚苯胺/石墨烯复合材料、聚氨酯/石墨烯复合材料和硅烷/石墨烯复合材料等四方面综述了改性石墨烯复合材料在金属防护中的应用,指出目前我国石墨烯复合材料存在的主要问题,并对石墨烯复合材料在金属防腐蚀领域的研究方向进行了展望。

稠油井内衬保温油管热损失分析及开采参数优化

针对塔河油田稠油开采过程中原油热量损失大、资源浪费的问题,开展内衬保温油管开采技术研究。基于井筒稳态热传递与地层非稳态热传递理论,建立了稠油井井筒热传递数学模型,评价了不同内衬材料油管的保温性能,揭示了含水率、日产液量及内衬保温油管下深对井筒温度的影响规律。研究表明:内衬聚酮防腐层与气凝胶保温层的保温油管保温性能最佳,日产液量和保温油管下深对井口温度影响较大,含水率对井口温度的影响较小;日产液量大于72 t/d且保温油管下深大于3 500 m时,可满足稠油开采的温度要求。该研究明确了内衬保温油管保温的可行性,可为油田保温油管内衬的选材、稠油开采工艺参数的制订提供技术依据。

侏罗系油井套管破损原因分析及采油工艺防腐措施优化

在侏罗系油井套管破损严重区块典型油井套管破损规律和破损原因调研分析的基础上,通过室内试验和现场腐蚀监测结果,探讨加深花管采油工艺防腐措施的可行性。结果表明:典型套管破损位置均在动液面以下,即主要集中在1000 m以下管段;套管破损以内腐蚀穿孔为主要特征,套管破损井段平均温度约为60℃;含水率及CO_(2)含量过高是导致套管发生腐蚀的主要原因;加深花管的采油工艺防腐措施使油套环空中油水界面位置下移,从而避开CO_(2)腐蚀的敏感温度区间,其在一定程度上可缓解侏罗系油井套管的腐蚀程度,但需与其他配套防护措施联合使用。最后,指出了采油工艺防腐措施的进一步优化方向。