In this study, the precipitation transformation and age hardening of solution-treated Mg-9Gd-4Y-2Zn-0.5Zr(wt.%) alloy were investigated at different aging treatment parameters. The precipitation sequences of the alloy...In this study, the precipitation transformation and age hardening of solution-treated Mg-9Gd-4Y-2Zn-0.5Zr(wt.%) alloy were investigated at different aging treatment parameters. The precipitation sequences of the alloy aged at 200℃, 250℃ and 300℃ are β’’(DO19) → β’(BCO) → β(FCC), β’’(DO19) → β’(BCO) → β_(1)(FCC) → β(FCC) and β(FCC), respectively. The streaks sequences of the alloy aged at 200℃, 250℃ and 300℃ are SF, SF → 14H-LPSO and SF → 14H-LPSO, respectively. For the alloy aged at 200℃ and 250℃, the increase in hardness with increasing aging time is contributed from the increase in precipitate volume fraction and the transformation from β’’ to β’ phase with basal → prismatic and spherical → spindle-like precipitate changes. The decrease in hardness after the peak-aging stage is attributed to the appearance of micro-sized β precipitates. Because of the smaller size of precipitates and the triangular arrangement of β’ precipitate, the hardness of the alloy aged at 200℃ is higher than that aged at 250℃. For the alloy aged at 300℃, the appearance of only micro-sized β precipitate and its coarsening with increasing aging time leads to the lowest hardness and an overall decrease in hardness with the aging time.展开更多
To research the effect of large precipitates(size 〉 0.2 μm) on strain-induced dynamic transformation, the variation of V contents in large precipitates has been investigated quantitatively in two V–Ti micro-alloy...To research the effect of large precipitates(size 〉 0.2 μm) on strain-induced dynamic transformation, the variation of V contents in large precipitates has been investigated quantitatively in two V–Ti micro-alloyed steels. The results showed that high N content promoted V precipitation on the surface of Ti large precipitates rapidly. Subsequently,large precipitates containing V induced the formation of intragranular ferrite, which accelerated the dynamic transformation process remarkably, promoted the occurrence of continuous dynamic recrystallization of ferrite and improved the refinement effect.展开更多
Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were cha...Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were characterized with X-ray diffraction (XRD) and scanning electron microscopy (SEM). The growth mechanism was studied, indicating that the initial generated Y(OH)3 gradually translated into YF3 and then transformed into com stick-like H-NaYF4 nanoparticles owing to the crucial role of fluorine ions in the solution. The up-conversion (UC) luminescence properties of H-NaYF4:20%Yb3+,2%Er3+ nanocrystals were discussed. The intensive green emission in the range of 510-570 nm was attributed to the (2Hll/2, 4S3/2)----4It5/2 transition and the weaker red emission between 640 and 680 nm was originating from the 4F9/2----4115/2 transition.展开更多
The shape memory behavior of [111]-oriented Ni_(51)Ti_(49) (at.%) single crystals was investigated after stressassisted aging at 500 °C for 1.5 h under a compressive stress of-150 MPa.It was found that a si...The shape memory behavior of [111]-oriented Ni_(51)Ti_(49) (at.%) single crystals was investigated after stressassisted aging at 500 °C for 1.5 h under a compressive stress of-150 MPa.It was found that a single family of Ni_4Ti_3 precipitates with two crystallographically equivalent variants was formed after aging under compressive stress.Stressassisted aging resulted in tensile two-way shape memory effect strain of 1.56% under-5 MPa.Thermal cycling under-600 MPa resulted in a transformation strain of-2.15%,while the subsequent thermal cycling under-5 MPa resulted in a tensile two-way shape memory effect strain of 2.2%.展开更多
基金financially supported by the Key R&D program of Shanxi Province (International Cooperation) (No.201903D421036)the Natural Science Foundation of Shanxi Province (No.201901D111176)+5 种基金the Joint Funds of the National Natural Science Foundation of China (Grant No.U20A20230)the Bureau of Science,Technology and Industry for National Defense of China (No.WDZC2019JJ006)the National Natural Science Foundation of China (Grant No.52075501)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No.201802072)the National Defense Basic Scientific Research Program (No.JCKY2018408B003)the XX Supporting Scientific Research Project (No.xxxx-2019-021)。
文摘In this study, the precipitation transformation and age hardening of solution-treated Mg-9Gd-4Y-2Zn-0.5Zr(wt.%) alloy were investigated at different aging treatment parameters. The precipitation sequences of the alloy aged at 200℃, 250℃ and 300℃ are β’’(DO19) → β’(BCO) → β(FCC), β’’(DO19) → β’(BCO) → β_(1)(FCC) → β(FCC) and β(FCC), respectively. The streaks sequences of the alloy aged at 200℃, 250℃ and 300℃ are SF, SF → 14H-LPSO and SF → 14H-LPSO, respectively. For the alloy aged at 200℃ and 250℃, the increase in hardness with increasing aging time is contributed from the increase in precipitate volume fraction and the transformation from β’’ to β’ phase with basal → prismatic and spherical → spindle-like precipitate changes. The decrease in hardness after the peak-aging stage is attributed to the appearance of micro-sized β precipitates. Because of the smaller size of precipitates and the triangular arrangement of β’ precipitate, the hardness of the alloy aged at 200℃ is higher than that aged at 250℃. For the alloy aged at 300℃, the appearance of only micro-sized β precipitate and its coarsening with increasing aging time leads to the lowest hardness and an overall decrease in hardness with the aging time.
基金financially supported by the National Natural Science Foundation of China(No.51171162)the Key R&D Projects of Hebei Province(No.09215139D)
文摘To research the effect of large precipitates(size 〉 0.2 μm) on strain-induced dynamic transformation, the variation of V contents in large precipitates has been investigated quantitatively in two V–Ti micro-alloyed steels. The results showed that high N content promoted V precipitation on the surface of Ti large precipitates rapidly. Subsequently,large precipitates containing V induced the formation of intragranular ferrite, which accelerated the dynamic transformation process remarkably, promoted the occurrence of continuous dynamic recrystallization of ferrite and improved the refinement effect.
基金supported by the National Natural Science Foundation(NSF)of China(51202066)Program for New Century Excellent Talents supported by the China Education Ministry(NCET-13-0784)+5 种基金Study Abroad Program sponsored by China Scholarship Council(201308430385)Scientific Research Fund of Hunan Provincial Education Department(12A047)Research of Science and Technology Department of Hunan Province(2013SK3162)State Key Laboratory Program of Rare Earth Resource Utilization of China(RERU2013019)State Key Laboratory Programs of Inorganic Synthesis and Preparative Chemistry of China(2013-26)Key Laboratory Program of Ecological Impacts of Hydraulic-projects and Restoration of Aquatic Ecosystem in Ministry of Water Resources of China(2013001)
文摘Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were characterized with X-ray diffraction (XRD) and scanning electron microscopy (SEM). The growth mechanism was studied, indicating that the initial generated Y(OH)3 gradually translated into YF3 and then transformed into com stick-like H-NaYF4 nanoparticles owing to the crucial role of fluorine ions in the solution. The up-conversion (UC) luminescence properties of H-NaYF4:20%Yb3+,2%Er3+ nanocrystals were discussed. The intensive green emission in the range of 510-570 nm was attributed to the (2Hll/2, 4S3/2)----4It5/2 transition and the weaker red emission between 640 and 680 nm was originating from the 4F9/2----4115/2 transition.
基金supported in part by the NASA Fundamental Aeronautics ProgramSupersonics Project and the NASA EPSCOR program(Grant No.NNX11AQ31A)RFBR Project(Grant No.10-03-0154-a)
文摘The shape memory behavior of [111]-oriented Ni_(51)Ti_(49) (at.%) single crystals was investigated after stressassisted aging at 500 °C for 1.5 h under a compressive stress of-150 MPa.It was found that a single family of Ni_4Ti_3 precipitates with two crystallographically equivalent variants was formed after aging under compressive stress.Stressassisted aging resulted in tensile two-way shape memory effect strain of 1.56% under-5 MPa.Thermal cycling under-600 MPa resulted in a transformation strain of-2.15%,while the subsequent thermal cycling under-5 MPa resulted in a tensile two-way shape memory effect strain of 2.2%.