PREDICTIVE VARIABLE STRUCTURE CONTROL FOR A CLASS OF NONLINEAR SYSTEM

Nonlinear sliding m ode predictive controller is designed for a class of nonlinear system w ith unm odeled dynam ic characteristics and nonlinear term . The m ethod is based on nonlinear opti- m alpredictive control. The variable structure controllaw m inim izes the quadratic index ofa predic- tive sliding m ode, w hich contains thecostfunction ofcontrolpreventing the controleffectfrom satu- ration for in m ostpracticalim plem entation the controlinputs are bounded by physicalconstraints and energy constraints. According to the im m easurable states, the variable structure observer for nonlin- ear system sisadapted. The variablestructure system m ethod isaptto therealization ofobserverw ith variable param eters and uncertainty. The proofshow s thatthe states ofthe observer asym ptotically convergence to the realstates ofthe system although itisofuncertainty and nonlinear term s. Final- ly, the digitalsim ulation results prove the effectiveness ofthe proposed m ethod.

Prediction of Gas Chromatographic Retention Indices of Organophosphates by DFT and VSMP Method

Polychlorinated dibenzothiophenes（PCDTs） are a group of important persistent organic pollutants.In the present study,geometrical optimization and electrostatic potential calculations have been performed for all 135 PCDTs congeners at the B3LYP/6-31G＊ level of theory.By means of the VSMP（variable selection and modeling based on prediction） program,one optimal descriptor（molecular polarizability,α） was selected to develop a QSRR model for the prediction of gas chromatographic retention indices（GC-RI） of PCDTs.The estimated correlation coefficients（r2） and LOO-validated correlation coefficients（q2）,all more than 0.99,were built by multiple linear regression,which shows a good estimation ability and stability of the models.A prediction power for the external samples was validated by the model built from the training set with 17 polychlorinated dibenzothiophenes.

A hybrid spatial-temporal deep learning prediction model of industrial methanol-to-olefins process

Methanol-to-olefins,as a promising non-oil pathway for the synthesis of light olefins,has been successfully industrialized.The accurate prediction of process variables can yield significant benefits for advanced process control and optimization.The challenge of this task is underscored by the failure of traditional methods in capturing the complex characteristics of industrial processes,such as high nonlinearities,dynamics,and data distribution shift caused by diverse operating conditions.In this paper,we propose a novel hybrid spatial-temporal deep learning prediction model to address these issues.Firstly,a unique data normalization technique called reversible instance normalization is employed to solve the problem of different data distributions.Subsequently,convolutional neural network integrated with the self-attention mechanism are utilized to extract the temporal patterns.Meanwhile,a multi-graph convolutional network is leveraged to model the spatial interactions.Afterward,the extracted temporal and spatial features are fused as input into a fully connected neural network to complete the prediction.Finally,the outputs are denormalized to obtain the ultimate results.The monitoring results of the dynamic trends of process variables in an actual industrial methanol-to-olefins process demonstrate that our model not only achieves superior prediction performance but also can reveal complex spatial-temporal relationships using the learned attention matrices and adjacency matrices,making the model more interpretable.Lastly,this model is deployed onto an end-to-end Industrial Internet Platform,which achieves effective practical results.