Gas drainage is an efective technology for gas control in coal mines.A high borehole-sealing quality is the fundamental precondition for efcient gas drainage.The expansibilities of cement pastes used in borehole-seali...Gas drainage is an efective technology for gas control in coal mines.A high borehole-sealing quality is the fundamental precondition for efcient gas drainage.The expansibilities of cement pastes used in borehole-sealing processes are critical for the borehole-sealing efect.Nanosized magnesia expansive agents are used to improve the expansibilities of cement pastes and improve the borehole-sealing efect.Nuclear magnetic resonance spectrometry and scanning electron microscopy were adopted to study the efects of nanosized magnesia on the hydration of borehole-sealing cements used with diferent preparation methods.The results showed that an increase in the mass fraction of the nanosized magnesia promoted cement hydration,and the mass fraction was positively correlated with the promotion efect.The use of diferent preparation methods did not change the water-phase distribution in the cement.When using the wet-mixing preparation method,nanosized magnesia promoted the induction,acceleration,and deceleration periods of hydration;when using the dry-mixing preparation method,the nanosized magnesia promoted the induction period of cement hydration,and the promotion efect was less obvious than that seen when using the wet-mixing method.When using the wet-mixing preparation method,the nanosized magnesia was uniformly dispersed,thus enlarging the surface area of the reaction,which provided more nucleation sites for the hydration products of the cement and therefore accelerated the hydration reaction.When using the dry-mixing preparation method,the nanosized magnesia powders were dispersed nonuniformly and aggregated.Under these conditions,only a few nanosized magnesia particles on the surfaces of the aggregated clusters took part in hydration,so only a small number of nucleation sites were provided for the hydration products of cement.This led to inconsistent hydration of cement pastes prepared using the dry-mixing method.The surface porosity of the cement prepared with the wet-mixing preparation method frst decreased and then increased with increases in the mass fraction of the nanosized magnesia.The cement surface exhibited compact hydration products and few pores,and the surface was relatively smooth.In comparison,the surface porosity of the cement prepared using the dry-mixing method fuctuated with increasing mass fraction of the nanosized magnesia,resulting in a rough cement surface and microfractures on some surfaces.The two preparation methods both reduced the surface porosity of the cement.The wet-mixing preparation was more efective and consistent in improving the compactness of the cement than the dry-mixing preparation.These results provide important guidance on the addition of nanosized magnesia in borehole-sealing engineering and the selection of cement preparation methods,and they also lay a solid foundation for realizing safe and efcient gas drainage.展开更多
Marine algae are valuable sources of health-promoting molecules that have been consumed by Asians for decades.Among aquatic flora,marine algae stand out in terms of high content of marine algae polysaccharides(MAP)suc...Marine algae are valuable sources of health-promoting molecules that have been consumed by Asians for decades.Among aquatic flora,marine algae stand out in terms of high content of marine algae polysaccharides(MAP)such as carrageenan,alginate,fucoidan,laminaran,agarose,rhamnan,and ulvan.When hydrolyzed,MAP generate marine algae oligosaccharides(MAO),which have attracted interest in recent years due to their superior solubility compared with MAP.Besides,MAO have been demonstrated numerous biological activities including antioxidant,antidiabetic,anti-inflammatory,antimicrobial,and prebiotic activities.Thus,this review summarizes the main chemical classes of MAO,their sources,and the main processes used for their production(i.e.,physical,chemical,and biological methods),coupled with a discussion of the advantages and disadvantages of these methods.Highlights of the biological activities of MAO and their potential applications in food,nutraceutical,and pharmaceuticals would also be discussed and summarized.展开更多
Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely comme...Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.展开更多
High-entropy materials(HEMs)have better mechanical,thermal,and electrical properties than traditional materials due to their special"high entropy effect".They can also adjust the performance of high entropy ...High-entropy materials(HEMs)have better mechanical,thermal,and electrical properties than traditional materials due to their special"high entropy effect".They can also adjust the performance of high entropy ceramics by adjusting the proportion of raw materials,and have broad application prospects in many fields.This article provides a review of the high entropy effect,preparation methods,and main applications of high entropy ceramic materials,especially exploring relevant research on high entropy perovskite ceramics.It is expected to provide reference for the promotion of scientific research and the development of further large-scale applications of high-entropy ceramic materials.展开更多
Influence of three different preparation methods, i.e. impregnation, coprecipitation, and inverse coprecipitation, on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO2 catalysts has been inves...Influence of three different preparation methods, i.e. impregnation, coprecipitation, and inverse coprecipitation, on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO2 catalysts has been investigated and CuO-CeO2 catalysts are characterized using BET, XPS, XRD, UV Raman, and TPR techniques. The results show that the catalysts prepared by coprecipitation have smaller particle sizes, well-dispersed CuOx species, more oxygen vacancies, and are more active in the PROX than those prepared by the other methods. However. the inverse coprecipitation depresses the catalytic performance of CuO-CeO2 catalysts and causes the growth of CuO-CeO2 because of different pH value in the precipitation process.展开更多
Al2O3 dispersion copper alloy powder was prepared by intemal oxidation, and three consolidation methods--high-velocity compaction (HVC), hot pressing (HP), and hot extrusion (HE)--were used to prepare Al2O3 disp...Al2O3 dispersion copper alloy powder was prepared by intemal oxidation, and three consolidation methods--high-velocity compaction (HVC), hot pressing (HP), and hot extrusion (HE)--were used to prepare Al2O3 dispersion-strengthened copper (Cu-Al2O3) alloys. The microstructures and properties of these alloys were investigated and compared. The results show that the alloys prepared by the HP and HE methods exhibited the coarsest and finest grain sizes, respectively. The alloy prepared by the HVC method exhibited the lowest relative density (98.3% vs. 99.5% for HP and 100% for HE), which resulted in the lowest electrical conductivity (81% IACS vs. 86% IACS for HP and 87% IACS for HE). However, this alloy also exhibited the highest hardness (77 HRB vs. 69 HRB for HP and 70 HRB for HE), the highest compressive strength (443 MPa vs. 386 MPa for I/P and 378 MPa for HE), and the best hardness retention among the investigated alloys. The results illustrate that the alloy prepared by the HVC method exhibits high softening temperature and good mechanical properties at high temperatures, which imply long service life when used as spot-welding electrodes.展开更多
In this work,NiMo catalysts with various contents of MoO_(3)were prepared through incipient wetness impregnation by a twostep method(NMxA)and onepot method(NMxB).The catalysts were then characterized by XRD,XPS,NH3TPD...In this work,NiMo catalysts with various contents of MoO_(3)were prepared through incipient wetness impregnation by a twostep method(NMxA)and onepot method(NMxB).The catalysts were then characterized by XRD,XPS,NH3TPD,H_(2)TPR,HRTEM,and N_(2)adsorptiondesorption technologies.The performance of the NiMo/Al_(2)O_(3) catalysts was investigated by hydrocracking lowtemperature coal tar.When the MoO3 content was 15 wt%,the interaction between Ni species and Al_(2)O_(3) on the NM15B catalyst was stronger than that on the NM15A catalyst,resulting in the poor performance of the former.When the MoO^(3) content was 20 wt%,MoO_(3) agglomerated on the surface of the NM20A catalyst,leading to decreased number of active sites and specific surface area and reduced catalytic performance.The increase in the number of MoS_(2) stack layers strengthened the interaction between Ni and Mo species of the NM20B catalyst and consequently improved its catalytic performance.When the MoO_(3) content reached 25 wt%,the active metals agglomerated on the surface of the NiMo catalysts,thereby directly decreasing the number of active sites.In conclusion,the twostep method is suitable for preparing catalysts with large pore diameter and low MoO_(3) content loading,and the onepot method is more appropriate for preparing catalysts with large specific surface area and high MoO_(3) content.Moreover,the NMxA catalysts had larger average pore diameter than the NMxB catalysts and exhibited improved desulfurization performance.展开更多
Bi 2O 3 nanoparticles were prepared by means of ammonia precipitation, polyol mediated methods and microemulsion chemical method. The structure and properties of the as-prepared nanoparticles, having been submitted to...Bi 2O 3 nanoparticles were prepared by means of ammonia precipitation, polyol mediated methods and microemulsion chemical method. The structure and properties of the as-prepared nanoparticles, having been submitted to a heat-treatment test at 750 ℃, were characterized by means of XRD, BET, XPS and UV-Vis absorption techniques. The photocatalytic oxidation reactions of benzene, toluene and xylene were used as the model reaction to measure the photocatalytic activity of Bi 2O 3 nanoparticles, respectively. The results show that the crystallite size of Bi 2O 3 prepared with different methods and calcined at 750 ℃ were 50.6, 38.5 and 31.5 nm, respectively. The photocatalytic activity of Bi 2O 3 nanoparticles prepared with the microemulsion chemical method was higher than that of the particles prepared with the polyol mediated method; and that of the particles prepared with the micromulsion chemical method was the highest among the three. The degradation rates of the three pollutants xylene, toluene and benzene decreased in sequence.展开更多
Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane (OCM) were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the be...Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane (OCM) were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the best catalytic performance among all samples. In addition, the effects of different addition sequences of Na, W, Mn, Zr, S and P on the catalytic performance were studied. The absence of Na before the addition of Mn and Zr in the catalysts preparation depressed the formation of the active phases of Mn2O3 and ZrO2 and decreased the activities of the catalysts significantly.展开更多
Three kinds of Pt/alumina catalysts were prepared by impregnation-hydrogen reduction, impregnation-hydrazine reduction and electroless plating methods. Their differences in the structures, specific areas and particle ...Three kinds of Pt/alumina catalysts were prepared by impregnation-hydrogen reduction, impregnation-hydrazine reduction and electroless plating methods. Their differences in the structures, specific areas and particle sizes were characterized by XRD, BET and TEM, respectively. Furthermore, their catalytic activities for the hydrogen iodide (HI) decomposition were evaluated in a fixed bed reactor. The results show that the catalyst 5%Pt/Al2O3 prepared by the electroless plating has the optimum catalytic properties for HI decomposition owing to the high dispersion of the platinum nano-particles (〈5 nm) on the alumina supports.展开更多
In recent years,smart textiles have attracted the attention of scholars from all walks of life,but there is an imbalance between functionality and usability,which affects their marketization process.Firstly,five repre...In recent years,smart textiles have attracted the attention of scholars from all walks of life,but there is an imbalance between functionality and usability,which affects their marketization process.Firstly,five representative smart textiles are introduced and their respective wearability is described around preparation methods.Secondly,it is concluded that the preparation methods of smart textiles can be divided into two categories:fiber methods and finishing methods.The fiber methods refer to making smart fibers into smart textiles.Textiles made by fiber methods are breathable and feel good in the hand,but the mechanical properties are influenced by the production equipment,and the process cost is high.The finishing methods refer to the functional finishing of ordinary textiles.Although the finishing method is simple and convenient,it may reduce the comfort of the textile.Finally,applications and new research in various fields of smart textiles are presented with promising prospects.It is anticipated that this review will serve as a theoretical basis for future research and development of smart textiles.Researchers are expected to create new technologies to overcome the tension between functionality and usability,as well as to increase user comfort and convenience.展开更多
Because ice-high foundation soil is widely distributed in permafrost regions,the correct preparation of ice-high specimens is of critical interest in engineering design for foundation stability.Past research has shown...Because ice-high foundation soil is widely distributed in permafrost regions,the correct preparation of ice-high specimens is of critical interest in engineering design for foundation stability.Past research has shown that the uniaxial compression strength of ice-high frozen soils changes as the ice or total water content increases; the differences of different methods of specimen preparation are analyzed here and the advantages and disadvantages of them are presented.It is confirmed that the role of crushed ice is significantly different from that of naturally frozen ice in frozen soils,and the size and amount of crushed ice will influence the strength and deformation mechanism of frozen soils.Therefore,it is strongly recommended that when a ice-high specimen is artificially prepared,the ice should be frozen through natural means and not be replaced with crushed ice.展开更多
Flavored vegetable oils have attracted more and more attentions from consumers and researchers due to their high oxidative stability and sensory quality.In the present study,the quality indices,chemical composition an...Flavored vegetable oils have attracted more and more attentions from consumers and researchers due to their high oxidative stability and sensory quality.In the present study,the quality indices,chemical composition and frying performance of galangal flavored sunflower oil prepared by infusion method(GFSO-I),combination pressing method(GFSO-C)and direct addition method(GFSO-A)were investigated.The results displayed that the preparation time,the levels for the acid value(AV),peroxide value(PV),p-anisidine value(AnV),total oxidation value(TOTOX),and the values for total polar compounds(TPC),thiobarbituric acid(TBA),K232 and K268 of GFSO-C were prominently low(P<0.05),compared with that of GFSO-I and GFSO-A,while the fatty acid composition of them were similar.In the frying of Chinese Maye(tradional Chinese food,fried dough stick)at 180°C for 30 h,the values for TPC,TBA,K232 and K268,polymer,viscosity and b*of GFSO-C were obviously low(P<0.05),while the value for L*was obviously high(P<0.05),compared with that of GFSO-I and GFSO-A.In the sensory evaluation,the flavor,taste,crispness and overall acceptance of Chinese Maye fried by GFSO-C were better than that of Chinese Maye fried by GFSO-I and GFSO-A.Consequently,GFSO-C is more suitable for cooking,and the combination pressing method is optimal for industrial production of GFSO.展开更多
The comparative study of the tensile plastic deformation of nano(n)-TiO2 ceramic prepared byphysical gas condensation (P) and chemical hydrolysis precipitation (C) methods was conductedby a gas pressure forming techni...The comparative study of the tensile plastic deformation of nano(n)-TiO2 ceramic prepared byphysical gas condensation (P) and chemical hydrolysis precipitation (C) methods was conductedby a gas pressure forming technique at 750~800℃. The results show that n-TiO2 (P) possessesexcellent property of tensile pIastic deformation comparing with n-TiO2(C). The reason for thisis attributed to the surface cleanness and soft agglomeration of n-TiO2 (P) particfe prepared inreIatively cIean vacuum condition.展开更多
With the rapid development of society and economy, the excessive consumption of fossil energy has led to the global energy and environment crisis. In order to explore the sustainable development of new energy, researc...With the rapid development of society and economy, the excessive consumption of fossil energy has led to the global energy and environment crisis. In order to explore the sustainable development of new energy, research based on electrocatalysis has attracted extensive attention in the academic circle. The main challenge in this field is to develop nano-catalysts with excellent electrocatalytic activity and selectivity for target products. The state of the active site in catalyst plays a decisive role in the activity and selectivity of the reaction. In order to design efficient and excellent catalysts, it is an effective means to adjust the electronic structure of catalysts. Electronic effects are also called ligand effects. By alloying with rare earth(RE) elements, electrons can be redistributed between RE elements and transition metal elements, achieving accurate design of the electronic structure of the active site in the alloy. Because of the unique electronic structure of RE, it has been paid attention in the field of catalysis. The outermost shell structure of RE elements is basically the same as that of the lower shell, except that the number of electrons in the 4f orbital is different, but the energy level is similar, so their properties are very similar. When RE elements form compounds, both the f electrons in the outermost shell and the d electrons in the lower outer shell can participate in bonding. In addition, part of the 4f electrons in the third outer shell can also participate in bonding.In order to improve the performance of metal catalysts, alloying provides an effective method to design advanced functional materials. RE alloys can integrate the unique electronic structure and catalytic behavior of RE elements into metal materials, which not only provides an opportunity to adjust the electronic structure and catalytic activity of the active component, but also enhances the structural stability of the alloy and is expected to significantly improve the catalytic performance of the catalyst. From the perspective of electronic and catalytic activity, RE elements have unique electronic configuration and lanthanide shrinkage effect. Alloying with RE elements will make the alloy have more abundant electronic structure, activity, and spatial arrangement, effectively adjusting the reaction kinetics of the electrochemical process of the catalyst. In this paper, the composition,structure, synthesis of RE alloys and their applications in the field of electrocatalysis are summarized, including the hydrogen evolution reaction, the oxygen evolution reaction, the oxygen reduction reaction, the methanol oxidation reaction, the ethanol oxidation reaction, and other catalytic reactions. At the same time, the present challenges of RE alloy electrocatalytic materials are summarized and their future development direction is pointed out. In the field of electrocatalysis, the cost of catalyst is too high and the stability is not strong. Therefore, the testing process should be related to the actual application, and the test method should be standardized, so as to carry forward the field of electrocatalysis.展开更多
The quantitative determination of heavy metals in aquatic products is of great importance for food security issues.Laser-induced breakdown spectroscopy(LIBS)has been used in a variety of foodstuff analysis,but is stil...The quantitative determination of heavy metals in aquatic products is of great importance for food security issues.Laser-induced breakdown spectroscopy(LIBS)has been used in a variety of foodstuff analysis,but is still limited by its low sensitivity when targeting trace heavy metals.In this work,we compare three sample enrichment methods,namely drying,carbonization,and ashing,for increasing detection sensitivity by LIBS analysis for Pb and Cr in oyster samples.The results demonstrate that carbonization can remove a significant amount of the contributions of organic elements C,H,N and O;meanwhile,the signals of the metallic elements such as Cu,Pb,Sr,Ca,Cr and Mg are enhanced by3–6 times after carbonization,and further enhanced by 5–9 times after ashing.Such enhancement is not only due to the more concentrated metallic elements in the sample compared to the dried ones,but also the unifying of the matter in carbonized and ashed samples from which higher plasma temperature and electron density are observed.This condition favors the detection of trace elements.According to the calibration curves with univariate and multivariate analysis,the ashing method is considered to be the best choice.The limits of detection of the ashing method are 0.52 mg kg-1 for Pb and0.08 mg kg-1 for Cr,which can detect the presence of heavy metals in the oysters exceeding the maximum limits of Pb and Cr required by the Chinese national standard.This method provides a promising application for the heavy metal contamination monitoring in the aquatic product industry.展开更多
Boron carbide(B_(4)C)has excellent high-temperature oxidation resistance,high hardness,low relative density,high melting point and excellent abrasive resistance,which is widely used in fields such as refractories,wear...Boron carbide(B_(4)C)has excellent high-temperature oxidation resistance,high hardness,low relative density,high melting point and excellent abrasive resistance,which is widely used in fields such as refractories,wear-resistant materials and lightweight protective materials.The research progress and application of B_(4)C materials in China and overseas in recent years were summarized.The influences of sintering processes(pressureless sintering,hot-pressing sintering,hot isostatic pressing sintering,spark plasma sintering and microwave sintering)and sintering additives(simple substances,oxides and carbides)on the B_(4)C densification were analyzed.The development of B_(4)C materials was prospected.展开更多
The novel nickel-based catalysts with a nickel content of 12 wt% were prepared with the zirconia-alumina composite as the supports. The new carriers, ZrO2 improved alumina, were synthesized by three methods, i.e., imp...The novel nickel-based catalysts with a nickel content of 12 wt% were prepared with the zirconia-alumina composite as the supports. The new carriers, ZrO2 improved alumina, were synthesized by three methods, i.e., impregnation-precipitation, co-precipitation, and impregnation method. The catalytic properties of these catalysts were investigated in the methanation of carbon dioxide, and the samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), temperature-programmed reduction (TPR) and temperature-programmed desorption (TPD) techniques. The new catalysts showed higher catalytic activity and better stability than Ni/γ-Al2O3. Furthermore, as a support for new nickel catalyst, the ZrO2-Al2O3 composite prepared by the impregnation-precipitation method was more efficient than the other supports in the methanation of carbon dioxide. The highly dispersed zirconium oxide on the surface of γ-Al2O3 inhibited the formation of nickel aluminate-like phase, which was responsible for the better dispersion of Ni species and easier reduction of NiO species, leading to the enhanced catalytic performance of corresponding catalyst.展开更多
A different method was employed for the preparation of a metal supported perovskite catalyst for the catalytic combustion of methane.The prepared metallic catalysts were characterized by means of X-ray diffractometer(...A different method was employed for the preparation of a metal supported perovskite catalyst for the catalytic combustion of methane.The prepared metallic catalysts were characterized by means of X-ray diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and also by ultrasonic and thermal shock tests and catalytic activity.It was found that the process factors during the preparation,e.g.the preparation of the catalyst precursor and the coating slurry,the calcination te...展开更多
Nanofluid offers more opportunities and challenges over the traditional surfactant and polymer solutions during enhanced oil recovery(commonly referred to as tertiary oil recovery)due to its remarkable properties.This...Nanofluid offers more opportunities and challenges over the traditional surfactant and polymer solutions during enhanced oil recovery(commonly referred to as tertiary oil recovery)due to its remarkable properties.This review mainly discusses the preparation methods of amphiphilic nanoparticles due to their higher interface activity than sole hydrophilic or hydrophobic nanoparticles(SHNPs).The nanofluids’stability is reviewed in this work.Moreover,the mechanisms of nanofluids in enhancing oil recovery(N-EOR)in terms of interfacial tension reduction,wettability alteration,foam stabilization,emulsion stabilization,structural disjoining pressure,and depressurization-increasing injection are mainly summarized and reviewed.Also,the synergistic effects of nanofluids and traditional surfactants and polymers are discussed.Finally,nanofluids’challenges and prospects are also outlined.The nanofluids can still be regarded as an outstanding candidate for enhancing oil recovery significantly in the future although there are limitations on their applications from laboratory scale to field scale.展开更多
基金supported by“Overall Rationing System”Project of Chongqing Talent Program(cstc2022ycjh-bgzxm0077)the National Natural Science Foundation of China(52074041)+1 种基金Natural Science Foundation of Chongqing,China(cstc2020jcyj-msxmX0836)Fundamental Research Funds for the Central Universities(2020CDJ-LHZZ-002),which are gratefully acknowledged.
文摘Gas drainage is an efective technology for gas control in coal mines.A high borehole-sealing quality is the fundamental precondition for efcient gas drainage.The expansibilities of cement pastes used in borehole-sealing processes are critical for the borehole-sealing efect.Nanosized magnesia expansive agents are used to improve the expansibilities of cement pastes and improve the borehole-sealing efect.Nuclear magnetic resonance spectrometry and scanning electron microscopy were adopted to study the efects of nanosized magnesia on the hydration of borehole-sealing cements used with diferent preparation methods.The results showed that an increase in the mass fraction of the nanosized magnesia promoted cement hydration,and the mass fraction was positively correlated with the promotion efect.The use of diferent preparation methods did not change the water-phase distribution in the cement.When using the wet-mixing preparation method,nanosized magnesia promoted the induction,acceleration,and deceleration periods of hydration;when using the dry-mixing preparation method,the nanosized magnesia promoted the induction period of cement hydration,and the promotion efect was less obvious than that seen when using the wet-mixing method.When using the wet-mixing preparation method,the nanosized magnesia was uniformly dispersed,thus enlarging the surface area of the reaction,which provided more nucleation sites for the hydration products of the cement and therefore accelerated the hydration reaction.When using the dry-mixing preparation method,the nanosized magnesia powders were dispersed nonuniformly and aggregated.Under these conditions,only a few nanosized magnesia particles on the surfaces of the aggregated clusters took part in hydration,so only a small number of nucleation sites were provided for the hydration products of cement.This led to inconsistent hydration of cement pastes prepared using the dry-mixing method.The surface porosity of the cement prepared with the wet-mixing preparation method frst decreased and then increased with increases in the mass fraction of the nanosized magnesia.The cement surface exhibited compact hydration products and few pores,and the surface was relatively smooth.In comparison,the surface porosity of the cement prepared using the dry-mixing method fuctuated with increasing mass fraction of the nanosized magnesia,resulting in a rough cement surface and microfractures on some surfaces.The two preparation methods both reduced the surface porosity of the cement.The wet-mixing preparation was more efective and consistent in improving the compactness of the cement than the dry-mixing preparation.These results provide important guidance on the addition of nanosized magnesia in borehole-sealing engineering and the selection of cement preparation methods,and they also lay a solid foundation for realizing safe and efcient gas drainage.
基金financially supported by grants from the National Natural Science Foundation of China(31901692)2020 Li Ka Shing Foundation Cross-Disciplinary Research Grant(2020LKSFG02E)Natural Science Foundation of Guangdong Province,China(2021A1515011495)。
文摘Marine algae are valuable sources of health-promoting molecules that have been consumed by Asians for decades.Among aquatic flora,marine algae stand out in terms of high content of marine algae polysaccharides(MAP)such as carrageenan,alginate,fucoidan,laminaran,agarose,rhamnan,and ulvan.When hydrolyzed,MAP generate marine algae oligosaccharides(MAO),which have attracted interest in recent years due to their superior solubility compared with MAP.Besides,MAO have been demonstrated numerous biological activities including antioxidant,antidiabetic,anti-inflammatory,antimicrobial,and prebiotic activities.Thus,this review summarizes the main chemical classes of MAO,their sources,and the main processes used for their production(i.e.,physical,chemical,and biological methods),coupled with a discussion of the advantages and disadvantages of these methods.Highlights of the biological activities of MAO and their potential applications in food,nutraceutical,and pharmaceuticals would also be discussed and summarized.
基金This work was supported by the National Natural Science Foundation of China(52203066,51973157,61904123)the Tianjin Natural Science Foundation(18JCQNJC02900)+3 种基金the National innovation and entrepreneurship training program for college students(202310058007)the Tianjin Municipal college students’innovation and entrepreneurship training program(202310058088)the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(Grant No.2018KJ196)the State Key Laboratory of Membrane and Membrane Separation,Tiangong University.
文摘Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.
文摘High-entropy materials(HEMs)have better mechanical,thermal,and electrical properties than traditional materials due to their special"high entropy effect".They can also adjust the performance of high entropy ceramics by adjusting the proportion of raw materials,and have broad application prospects in many fields.This article provides a review of the high entropy effect,preparation methods,and main applications of high entropy ceramic materials,especially exploring relevant research on high entropy perovskite ceramics.It is expected to provide reference for the promotion of scientific research and the development of further large-scale applications of high-entropy ceramic materials.
文摘Influence of three different preparation methods, i.e. impregnation, coprecipitation, and inverse coprecipitation, on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO2 catalysts has been investigated and CuO-CeO2 catalysts are characterized using BET, XPS, XRD, UV Raman, and TPR techniques. The results show that the catalysts prepared by coprecipitation have smaller particle sizes, well-dispersed CuOx species, more oxygen vacancies, and are more active in the PROX than those prepared by the other methods. However. the inverse coprecipitation depresses the catalytic performance of CuO-CeO2 catalysts and causes the growth of CuO-CeO2 because of different pH value in the precipitation process.
基金financially supported by Guangdong Provincial Industrial High-tech Project (No. 2015A010105020)Guangzhou Science & Technology New Star of Pearl River Project (No. 2012J2200096)+3 种基金the Open Research Fund of State Key Laboratory of Powder Metallurgy of Central South UniversityGuangdong Provincial Innovation Ability Construction Project (No. 2016B070701024)Guangzhou Innovation Platform Construction and Sharing Project (No. 201509010003)Guangdong Provincial Science & Technology Basic Condition Construction Field Project (No. 2014B030301012)
文摘Al2O3 dispersion copper alloy powder was prepared by intemal oxidation, and three consolidation methods--high-velocity compaction (HVC), hot pressing (HP), and hot extrusion (HE)--were used to prepare Al2O3 dispersion-strengthened copper (Cu-Al2O3) alloys. The microstructures and properties of these alloys were investigated and compared. The results show that the alloys prepared by the HP and HE methods exhibited the coarsest and finest grain sizes, respectively. The alloy prepared by the HVC method exhibited the lowest relative density (98.3% vs. 99.5% for HP and 100% for HE), which resulted in the lowest electrical conductivity (81% IACS vs. 86% IACS for HP and 87% IACS for HE). However, this alloy also exhibited the highest hardness (77 HRB vs. 69 HRB for HP and 70 HRB for HE), the highest compressive strength (443 MPa vs. 386 MPa for I/P and 378 MPa for HE), and the best hardness retention among the investigated alloys. The results illustrate that the alloy prepared by the HVC method exhibits high softening temperature and good mechanical properties at high temperatures, which imply long service life when used as spot-welding electrodes.
基金Financial support from the National Natural Science Foundation of China (21968034) is gratefully acknowledged.
文摘In this work,NiMo catalysts with various contents of MoO_(3)were prepared through incipient wetness impregnation by a twostep method(NMxA)and onepot method(NMxB).The catalysts were then characterized by XRD,XPS,NH3TPD,H_(2)TPR,HRTEM,and N_(2)adsorptiondesorption technologies.The performance of the NiMo/Al_(2)O_(3) catalysts was investigated by hydrocracking lowtemperature coal tar.When the MoO3 content was 15 wt%,the interaction between Ni species and Al_(2)O_(3) on the NM15B catalyst was stronger than that on the NM15A catalyst,resulting in the poor performance of the former.When the MoO^(3) content was 20 wt%,MoO_(3) agglomerated on the surface of the NM20A catalyst,leading to decreased number of active sites and specific surface area and reduced catalytic performance.The increase in the number of MoS_(2) stack layers strengthened the interaction between Ni and Mo species of the NM20B catalyst and consequently improved its catalytic performance.When the MoO_(3) content reached 25 wt%,the active metals agglomerated on the surface of the NiMo catalysts,thereby directly decreasing the number of active sites.In conclusion,the twostep method is suitable for preparing catalysts with large pore diameter and low MoO_(3) content loading,and the onepot method is more appropriate for preparing catalysts with large specific surface area and high MoO_(3) content.Moreover,the NMxA catalysts had larger average pore diameter than the NMxB catalysts and exhibited improved desulfurization performance.
基金the National Natural Science Foundation of China(No.2 0 2 770 15 )
文摘Bi 2O 3 nanoparticles were prepared by means of ammonia precipitation, polyol mediated methods and microemulsion chemical method. The structure and properties of the as-prepared nanoparticles, having been submitted to a heat-treatment test at 750 ℃, were characterized by means of XRD, BET, XPS and UV-Vis absorption techniques. The photocatalytic oxidation reactions of benzene, toluene and xylene were used as the model reaction to measure the photocatalytic activity of Bi 2O 3 nanoparticles, respectively. The results show that the crystallite size of Bi 2O 3 prepared with different methods and calcined at 750 ℃ were 50.6, 38.5 and 31.5 nm, respectively. The photocatalytic activity of Bi 2O 3 nanoparticles prepared with the microemulsion chemical method was higher than that of the particles prepared with the polyol mediated method; and that of the particles prepared with the micromulsion chemical method was the highest among the three. The degradation rates of the three pollutants xylene, toluene and benzene decreased in sequence.
基金supported by the financial support from National Natural Science Foundation of China (20676116)
文摘Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane (OCM) were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the best catalytic performance among all samples. In addition, the effects of different addition sequences of Na, W, Mn, Zr, S and P on the catalytic performance were studied. The absence of Na before the addition of Mn and Zr in the catalysts preparation depressed the formation of the active phases of Mn2O3 and ZrO2 and decreased the activities of the catalysts significantly.
基金the Foundational Research Project of National Defence(No.A1420080145)for thefinancial support.
文摘Three kinds of Pt/alumina catalysts were prepared by impregnation-hydrogen reduction, impregnation-hydrazine reduction and electroless plating methods. Their differences in the structures, specific areas and particle sizes were characterized by XRD, BET and TEM, respectively. Furthermore, their catalytic activities for the hydrogen iodide (HI) decomposition were evaluated in a fixed bed reactor. The results show that the catalyst 5%Pt/Al2O3 prepared by the electroless plating has the optimum catalytic properties for HI decomposition owing to the high dispersion of the platinum nano-particles (〈5 nm) on the alumina supports.
基金Innovation Team Building Program of Beijing Institute of Fashion Technology,China。
文摘In recent years,smart textiles have attracted the attention of scholars from all walks of life,but there is an imbalance between functionality and usability,which affects their marketization process.Firstly,five representative smart textiles are introduced and their respective wearability is described around preparation methods.Secondly,it is concluded that the preparation methods of smart textiles can be divided into two categories:fiber methods and finishing methods.The fiber methods refer to making smart fibers into smart textiles.Textiles made by fiber methods are breathable and feel good in the hand,but the mechanical properties are influenced by the production equipment,and the process cost is high.The finishing methods refer to the functional finishing of ordinary textiles.Although the finishing method is simple and convenient,it may reduce the comfort of the textile.Finally,applications and new research in various fields of smart textiles are presented with promising prospects.It is anticipated that this review will serve as a theoretical basis for future research and development of smart textiles.Researchers are expected to create new technologies to overcome the tension between functionality and usability,as well as to increase user comfort and convenience.
基金supported by the Excellent National Key Laboratory Special Fund of China (No.41023003)the National Natural Science Foundation of China (No.41101068)+1 种基金the National Key Basic Research Program of China (973 Program) (No.2012CB026102)the project of the State Key Laboratory of Frozen Soil Engineering (No.SKLFSE-ZT-07)
文摘Because ice-high foundation soil is widely distributed in permafrost regions,the correct preparation of ice-high specimens is of critical interest in engineering design for foundation stability.Past research has shown that the uniaxial compression strength of ice-high frozen soils changes as the ice or total water content increases; the differences of different methods of specimen preparation are analyzed here and the advantages and disadvantages of them are presented.It is confirmed that the role of crushed ice is significantly different from that of naturally frozen ice in frozen soils,and the size and amount of crushed ice will influence the strength and deformation mechanism of frozen soils.Therefore,it is strongly recommended that when a ice-high specimen is artificially prepared,the ice should be frozen through natural means and not be replaced with crushed ice.
基金the China Agriculture Research System of MOF and MARA.
文摘Flavored vegetable oils have attracted more and more attentions from consumers and researchers due to their high oxidative stability and sensory quality.In the present study,the quality indices,chemical composition and frying performance of galangal flavored sunflower oil prepared by infusion method(GFSO-I),combination pressing method(GFSO-C)and direct addition method(GFSO-A)were investigated.The results displayed that the preparation time,the levels for the acid value(AV),peroxide value(PV),p-anisidine value(AnV),total oxidation value(TOTOX),and the values for total polar compounds(TPC),thiobarbituric acid(TBA),K232 and K268 of GFSO-C were prominently low(P<0.05),compared with that of GFSO-I and GFSO-A,while the fatty acid composition of them were similar.In the frying of Chinese Maye(tradional Chinese food,fried dough stick)at 180°C for 30 h,the values for TPC,TBA,K232 and K268,polymer,viscosity and b*of GFSO-C were obviously low(P<0.05),while the value for L*was obviously high(P<0.05),compared with that of GFSO-I and GFSO-A.In the sensory evaluation,the flavor,taste,crispness and overall acceptance of Chinese Maye fried by GFSO-C were better than that of Chinese Maye fried by GFSO-I and GFSO-A.Consequently,GFSO-C is more suitable for cooking,and the combination pressing method is optimal for industrial production of GFSO.
文摘The comparative study of the tensile plastic deformation of nano(n)-TiO2 ceramic prepared byphysical gas condensation (P) and chemical hydrolysis precipitation (C) methods was conductedby a gas pressure forming technique at 750~800℃. The results show that n-TiO2 (P) possessesexcellent property of tensile pIastic deformation comparing with n-TiO2(C). The reason for thisis attributed to the surface cleanness and soft agglomeration of n-TiO2 (P) particfe prepared inreIatively cIean vacuum condition.
基金financial support from the National Key R&D Program of China (2022YFB3506200)the National Nature Science Foundation of China (22122113)。
文摘With the rapid development of society and economy, the excessive consumption of fossil energy has led to the global energy and environment crisis. In order to explore the sustainable development of new energy, research based on electrocatalysis has attracted extensive attention in the academic circle. The main challenge in this field is to develop nano-catalysts with excellent electrocatalytic activity and selectivity for target products. The state of the active site in catalyst plays a decisive role in the activity and selectivity of the reaction. In order to design efficient and excellent catalysts, it is an effective means to adjust the electronic structure of catalysts. Electronic effects are also called ligand effects. By alloying with rare earth(RE) elements, electrons can be redistributed between RE elements and transition metal elements, achieving accurate design of the electronic structure of the active site in the alloy. Because of the unique electronic structure of RE, it has been paid attention in the field of catalysis. The outermost shell structure of RE elements is basically the same as that of the lower shell, except that the number of electrons in the 4f orbital is different, but the energy level is similar, so their properties are very similar. When RE elements form compounds, both the f electrons in the outermost shell and the d electrons in the lower outer shell can participate in bonding. In addition, part of the 4f electrons in the third outer shell can also participate in bonding.In order to improve the performance of metal catalysts, alloying provides an effective method to design advanced functional materials. RE alloys can integrate the unique electronic structure and catalytic behavior of RE elements into metal materials, which not only provides an opportunity to adjust the electronic structure and catalytic activity of the active component, but also enhances the structural stability of the alloy and is expected to significantly improve the catalytic performance of the catalyst. From the perspective of electronic and catalytic activity, RE elements have unique electronic configuration and lanthanide shrinkage effect. Alloying with RE elements will make the alloy have more abundant electronic structure, activity, and spatial arrangement, effectively adjusting the reaction kinetics of the electrochemical process of the catalyst. In this paper, the composition,structure, synthesis of RE alloys and their applications in the field of electrocatalysis are summarized, including the hydrogen evolution reaction, the oxygen evolution reaction, the oxygen reduction reaction, the methanol oxidation reaction, the ethanol oxidation reaction, and other catalytic reactions. At the same time, the present challenges of RE alloy electrocatalytic materials are summarized and their future development direction is pointed out. In the field of electrocatalysis, the cost of catalyst is too high and the stability is not strong. Therefore, the testing process should be related to the actual application, and the test method should be standardized, so as to carry forward the field of electrocatalysis.
基金supported by the National Key Research and Development Program of China(No.2019YFD0901701)National Natural Science Foundation of China(Nos.12174359and 61975190)Provincial Key Research and Development Program of Shandong,China(No.2019GHZ010)。
文摘The quantitative determination of heavy metals in aquatic products is of great importance for food security issues.Laser-induced breakdown spectroscopy(LIBS)has been used in a variety of foodstuff analysis,but is still limited by its low sensitivity when targeting trace heavy metals.In this work,we compare three sample enrichment methods,namely drying,carbonization,and ashing,for increasing detection sensitivity by LIBS analysis for Pb and Cr in oyster samples.The results demonstrate that carbonization can remove a significant amount of the contributions of organic elements C,H,N and O;meanwhile,the signals of the metallic elements such as Cu,Pb,Sr,Ca,Cr and Mg are enhanced by3–6 times after carbonization,and further enhanced by 5–9 times after ashing.Such enhancement is not only due to the more concentrated metallic elements in the sample compared to the dried ones,but also the unifying of the matter in carbonized and ashed samples from which higher plasma temperature and electron density are observed.This condition favors the detection of trace elements.According to the calibration curves with univariate and multivariate analysis,the ashing method is considered to be the best choice.The limits of detection of the ashing method are 0.52 mg kg-1 for Pb and0.08 mg kg-1 for Cr,which can detect the presence of heavy metals in the oysters exceeding the maximum limits of Pb and Cr required by the Chinese national standard.This method provides a promising application for the heavy metal contamination monitoring in the aquatic product industry.
文摘Boron carbide(B_(4)C)has excellent high-temperature oxidation resistance,high hardness,low relative density,high melting point and excellent abrasive resistance,which is widely used in fields such as refractories,wear-resistant materials and lightweight protective materials.The research progress and application of B_(4)C materials in China and overseas in recent years were summarized.The influences of sintering processes(pressureless sintering,hot-pressing sintering,hot isostatic pressing sintering,spark plasma sintering and microwave sintering)and sintering additives(simple substances,oxides and carbides)on the B_(4)C densification were analyzed.The development of B_(4)C materials was prospected.
基金supported by the Southwest Research & Design Institute of Chemical Industy (SKLIV GR-22010-01)the National Basic Research Program of China (973 Program, 2011CB201202) of Ministry of Science and Technology
文摘The novel nickel-based catalysts with a nickel content of 12 wt% were prepared with the zirconia-alumina composite as the supports. The new carriers, ZrO2 improved alumina, were synthesized by three methods, i.e., impregnation-precipitation, co-precipitation, and impregnation method. The catalytic properties of these catalysts were investigated in the methanation of carbon dioxide, and the samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), temperature-programmed reduction (TPR) and temperature-programmed desorption (TPD) techniques. The new catalysts showed higher catalytic activity and better stability than Ni/γ-Al2O3. Furthermore, as a support for new nickel catalyst, the ZrO2-Al2O3 composite prepared by the impregnation-precipitation method was more efficient than the other supports in the methanation of carbon dioxide. The highly dispersed zirconium oxide on the surface of γ-Al2O3 inhibited the formation of nickel aluminate-like phase, which was responsible for the better dispersion of Ni species and easier reduction of NiO species, leading to the enhanced catalytic performance of corresponding catalyst.
基金supported by the Ministry of Science and Technology of Beijing (20081D0500500142)
文摘A different method was employed for the preparation of a metal supported perovskite catalyst for the catalytic combustion of methane.The prepared metallic catalysts were characterized by means of X-ray diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and also by ultrasonic and thermal shock tests and catalytic activity.It was found that the process factors during the preparation,e.g.the preparation of the catalyst precursor and the coating slurry,the calcination te...
基金financial support of the Science Foundation of China University of PetroleumBeijing(Grant No.2462020XKBH013)+1 种基金Financial supports from the National Natural Science Foundation of China(Grant No.51804316)the Science Foundation of China University of Petroleum,Beijing(Grant No.2462017YJRC037)
文摘Nanofluid offers more opportunities and challenges over the traditional surfactant and polymer solutions during enhanced oil recovery(commonly referred to as tertiary oil recovery)due to its remarkable properties.This review mainly discusses the preparation methods of amphiphilic nanoparticles due to their higher interface activity than sole hydrophilic or hydrophobic nanoparticles(SHNPs).The nanofluids’stability is reviewed in this work.Moreover,the mechanisms of nanofluids in enhancing oil recovery(N-EOR)in terms of interfacial tension reduction,wettability alteration,foam stabilization,emulsion stabilization,structural disjoining pressure,and depressurization-increasing injection are mainly summarized and reviewed.Also,the synergistic effects of nanofluids and traditional surfactants and polymers are discussed.Finally,nanofluids’challenges and prospects are also outlined.The nanofluids can still be regarded as an outstanding candidate for enhancing oil recovery significantly in the future although there are limitations on their applications from laboratory scale to field scale.