LSER-based modeling vapor pressures of(solvent+salt) systems by application of Xiang-Tan equation

The study deals with modeling the vapor pressures of(solvent + salt) systems depending on the linear solvation energy relation(LSER) principles. The LSER-based vapor pressure model clarifies the simultaneous impact of the vapor pressure of a pure solvent estimated by the Xiang-Tan equation, the solubility and solvatochromic parameters of the solvent and the physical properties of the ionic salt. It has been performed independently two structural forms of the generalized solvation model, i.e. the unified solvation model with the integrated properties(USMIP) containing nine physical descriptors and the reduced property-basis solvation model. The vapor pressure data of fourteen(solvent + salt) systems have been processed to analyze statistically the reliability of existing models in terms of a log-ratio objective function. The proposed vapor pressure approaches reproduce the observed performance relatively accurately, yielding the overall design factors of 1.0643 and1.0702 for the integrated property-basis and reduced property-basis solvation models.

The influence of pressure waves in tidal gravity records

For the reduction of atmospheric effects,observed gravity has initially been corrected by using the computed barometric admittance k of the in situ measured pressure,expressed in nms-2/hPa units and estimated by least squares method.However,the local pressure changes alone cannot account for the atmospheric mass attraction and loading when the coherent pressure field exceeds a specific size,i.e.,with increasing periodicities.To overcome this difficulty,it is necessary to compute the total atmospheric effect at each station using the global pressure field.However,the direct subtraction of the total gravity effect,provided by the models of pressure correction,is not yet satisfactory for S2 and other tidal components,such as K2 and P1,which include solar heating pressure tides.This paper identifies the origin of the problem and presents strategies to obtain a satisfactory solution.First,we set up a difference vector between the tidal factors of M2 and S2 after correction of the pressure and ocean tides effects.This vector,hereafter denoted as RES,presents the advantage of being practically insensitive to calibration errors.The minimum discrepancy between the tidal parameters of M2 and S2 corresponds to the minimum of the RES vector norm d.Secondly we adopt the hybrid pressure correction method,separating the local and the global pressure contribution of the models and replacing the local contribution by the pressure measured at the station multiplied by an admittance kATM.We tested this procedure on 8 stations from the IGETS superconducting gravimeters network(former GGP network).For stations at an altitude lower than 1000 m,the value of dopt is always smaller than0.0005.The discrepancy between the tidal parameters of the M2 and S2 waves is always lower than0.05% on the amplitude factors and 0.025° on the phases.For these stations,a correlation exists between the altitude and the value kopt.The results at the three Central European stations Conrad,Pecny and Vienna are in excellent agreement(0.05%) with the DDW99NH model for all the main tidal waves.

Coherence of wind pressure on domes

The concept of the coherence function is adopted to find the wind pressure correlation of two points on domes of different rise-span ratios. The pressure measurements are made on the dome roof models by the wind tunnel test. The coherence functions for different separation distances at several directions of the domes from different wind directions are examined. The results show that there is a strong correlation for two adjacent points at low frequency, but not for non-adjacent points. The coherence of the wind pressure increases with the decrease in the separation distance. Moreover, the coherence of the wind pressure is in the strongest correlation on the along-wind direction at the same separation, but the lowest correlation is on the cross-wind direction. The detailed derivation of the proposed exponential coherence model of the wind pressure from experimental data is also discussed. It is found that the proposed exponential coherence model can be appropriate, especially, for small separations and the change in the directions on domes. Based on the quasi-steady theory, the relationship between the wind pressure and the wind velocity on the basis of the coherence model is also examined. The coherence observed between the wind pressure and the wind velocity is not adequately predicted by the quasi-steady theory.

Modified Pressure Loss Model for T-junctions of Engine Exhaust Manifold

The T-junction model of engine exhaust manifolds significantly influences the simulation precision of the pressure wave and mass flow rate in the intake and exhaust manifolds of diesel engines. Current studies have focused on constant pressure models, constant static pressure models and pressure loss models. However, low model precision is a common disadvantage when simulating engine exhaust manifolds, particularly for turbocharged systems. To study the performance of junction flow, a cold wind tunnel experiment with high velocities at the junction of a diesel exhaust manifold is performed, and the variation in the pressure loss in the T-junction under different flow conditions is obtained. Despite the trend of the calculated total pressure loss coefficient, which is obtained by using the original pressure loss model and is the same as that obtained from the experimental results, large differences exist between the calculated and experimental values. Furthermore, the deviation becomes larger as the flow velocity increases. By improving the Vazsonyi formula considering the flow velocity and introducing the distribution function, a modified pressure loss model is established, which is suitable for a higher velocity range. Then, the new model is adopted to solve one-dimensional, unsteady flow in a D6114 turbocharged diesel engine. The calculated values are compared with the measured data, and the result shows that the simulation accuracy of the pressure wave before the turbine is improved by 4.3% with the modified pressure loss model because gas compressibility is considered when the flow velocities are high. The research results provide valuable information for further junction flow research, particularly the correction of the boundary condition in one-dimensional simulation models.

An analytical p-y curve method based on compressive soil pressure model in sand soil

With the high-quality development of urban buildings,higher requirements are come up with for lateral bearing capacity of laterally loaded piles.Consequently,a more accurate analysis to predict the lateral response of the pile within an allowable displacement is an important issue.However,the current p-y curve methods cannot fully take into account the pile-soil interaction,which will lead to a large calculation difference.In this paper,a new analytical p-y curve is established and a finite difference method for determining the lateral response of pile is proposed,which can consider the separation effect of pile-soil interface and the coefficient of circumferential friction resistance.In particular,an analytical expression is developed to determine the compressive soil pressure by dividing the compressive soil pressure into two parts:initial compressive soil pressure and increment of compressive soil pressure.In addition,the relationship between compressive soil pressure and horizontal displacement of the pile is established based on the reasonable assumption.The correctness of the proposed method is verified through four examples.Based on the verified method,a parametric analysis is also conducted to investigate the influences of factors on lateral response of the pile,including internal friction angle,pile length and elastic modulus of pile.

Influence of fault slip on mining-induced pressure and optimization ofroadway support design in fault-influenced zone

This paper presents an investigation on the characteristics of overlying strata collapse and mining-induced pressure in fault-influenced zone by employing the physical modeling in consideration of fault structure. The precursory information of fault slip during the underground mining activities is studied as well. Based on the physical modeling, the optimization of roadway support design and the field verification in fault-influenced zone are conducted. Physical modeling results show that, due to the combined effect of mining activities and fault slip, the mining-induced pressure and the extent of damaged rock masses in the fault-influenced zone are greater than those in the uninfluenced zone. The sharp increase and the succeeding stabilization of stress or steady increase in displacement can be identified as the precursory information of fault slip. Considering the larger mining-induced pressure in the fault-influenced zone, the new support design utilizing cables is proposed. The optimization of roadway support design suggests that the cables can be anchored in the stable surrounding rocks and can effectively mobilize the load bearing capacity of the stable surrounding rocks. The field observation indicates that the roadway is in good condition with the optimized roadway support design.

Attenuation-type and failure-type curve models on accumulated pore water pressure in saturated normal consolidated clay

Based on dynamic triaxial test results of saturated soft clay, similarities of variations between accumulated pore water pressure and accumulated deformation were analyzed. The Parr＇s equation on accumulated deformation was modified to create an attenuation-type curve model on accumulated pore water pressure in saturated normal consolidation clay. In this model, dynamic strength was introduced and a new parameter called equivalent dynamic stress level was added. Besides, based on comparative analysis on variations between failure-type and attenuatiun-type curves, a failure-type curve model was created on accumulated pore water pressure in saturated normal consolidation clay. Two models can take cycle number, coupling of static and dynamic deviator stress, and consolidation way into consideration. The models are verified by test results. The correlation coefficients are more than 0.98 for optimization of test results based on the two models, and there is good agreement between the optimized and test curves, which shows that the two models are suitable to predict variations of accumulated pore water pressure under different loading cases and consolidation ways. In order to improve prediction accuracy, it is suggested that loading cases and consolidation ways should be consistent with in-situ conditions when dynamic triaxial tests are used to determine the constants in the models.

An efficient FEM for pressure analysis of oil film in a piston pump

The paper concerns numerical analysis of pressure distribution of an oil film on the valve plate in the variable height gap of an axial piston pump. The analysis employs the finite element method. For determination of oil pressure variations in the gap, the Reynolds equation, commonly applied in the theory of lubrication, is applied. The equation is solved numerically with the use of self-developed program based on the finite element method. In order to obtain high accuracy of the results, an adaptive mesh refinement based on residual estimations of solution errors is applied. The calculation results are represented as dependent on the geometric and working parameters of the pump.

Model test study of frost heaving pressures in tunnels excavated in fractured rock mass in cold regions

Based on the similarity theory, taking the horseshoe, city-gate and round linings as examples, the value and distribution regularities of normal frost heaving pressures （hereinafter as frost heaving pressures） in tunnels excavated in fractured rock mass in cold regions under different constraints and freezing depths were studied by a test model. It was found that the larger the frozen depth, the larger the frost heaving pressure, and the stronger the top constraint, the larger the frost heaving pressure. For the horseshoe lining and city-gate lining, the top constraint has a greater effect on the frost heaving pressures on the arch and the inverted arch. For the round lining, the influences of the top constraint on the frost heaving pressure in all linings are almost the same. The frost heaving pressure is maximum on the city-gate lining and minimal on the round lining. The largest frost heaving pressure all occur near the foot of the inverted arch for the three kinds of lining. Thus, the test data basically coincide with the observed in situ data.

Temporal and spatial variability of the carbon cycle in the east of China's seas:a three-dimensional physical-biogeochemical modeling study

In the east of China＇s seas, there is a wide range of the continental shelf. The nutrient cycle and the carbon cycle in the east of China＇s seas exhibit a strong variability on seasonal to decadal time scales. On the basis of a regional ocean modeling system（ROMS）, a three dimensional physical-biogeochemical model including the carbon cycle with the resolution（1/12）°×（1/12）° is established to investigate the physical variations, ecosystem responses and carbon cycle consequences in the east of China＇s seas. The ROMS-Nutrient Phytoplankton Zooplankton Detritus（NPZD） model is driven by daily air-sea fluxes（wind stress, long wave radiation, short wave radiation, sensible heat and latent heat, freshwater fluxes） that derived from the National Centers for Environmental Prediction（NCEP） reanalysis2 from 1982 to 2005. The coupled model is capable of reproducing the observed seasonal variation characteristics over the same period in the East China Sea. The integrated air-sea CO_2 flux over the entire east of China＇s seas reveals a strong seasonal cycle, functioning as a source of CO_2 to the atmosphere from June to October, while serving as a sink of CO_2 to the atmosphere in the other months. The 24 a mean value of airsea CO_2 flux over the entire east of China＇s seas is about 1.06 mol/（m^2·a）, which is equivalent to a regional total of3.22 Mt/a, indicating that in the east of China＇s seas there is a sink of CO_2 to the atmosphere. The partial pressure of carbon dioxide in sea water in the east of China＇s seas has an increasing rate of 1.15 μatm/a（1μtm/a=0.101 325Pa）, but p H in sea water has an opposite tendency, which decreases with a rate of 0.001 3 a^（–1） from 1982 to 2005.Biological activity is a dominant factor that controls the pCO_2 air in the east of China＇s seas, and followed by a temperature. The inverse relationship between the interannual variability of air-sea CO_2 flux averaged from the domain area and Ni？o3 SST Index indicates that the carbon cycle in the east of China＇s seas has a high correlation with El Ni？o-Southern Oscillation（ENSO）.

A Pressure-Drop Model for Oil-Gas Two-Phase Flow in Horizontal Pipes

The accurate prediction of the pressure distribution of highly viscous fluids in wellbores and pipelines is of great significance for heavy oil production and transportation.The flow behavior of high-viscosity fluids is quite different with respect to that of low-viscosity fluids.Currently,the performances of existing pressure-drop models seem to be relatively limited when they are applied to high-viscosity fluids.In this study,a gas-liquid two-phase flow experiment has been carried out using a 60 mm ID horizontal pipe with air and white oil.The experimental results indicate that viscosity exerts a significant influence on the liquid holdup and pressure drop.At the same gas and liquid volume,both the liquid holdup and pressure drop increase with an increase in the viscosity.Combining two existing models,a modified pressure drop method is developed,which is applicable to horizontal pipes for different viscosities and does not depend on the flow pattern.This new method displays a high accuracy in predicting the new experimental data presented here and other published data in literature.

A NEW MODEL FOR CALCULATING PROPAGATION PRESSURE AND INITIATION PRESSURE OF PIPELINES WITH A LOCAL DENT

An analytical model of a ring with six yield hinges and two deformable arc segments is presented for. the prediction of the buckle propagation pressure and initiation pressure in offshore pipelines. The configuration of a fully collapsed ring is considered as a real dumbbell shape with a line touch between two 'bells', instead of the dumbbell shape with a point touch of two diametrically opposite points. Calculations are performed assuming that the dominant effect on the plastic energy dissipation has the circumferential bending mode. For the linear strain-hardening materials it is found that theoretical predictions based on the above model for both propagation pressure and initiation nressure are in good agreement with experimental results of Kyriakides et al.

Elasto-plasticity and pore-pressure coupled analysis on the pullout behaviors of a plate anchor

A numerical method is proposed for the elasto-plasticity and pore-pressure coupled analysis on the pull- out behaviors of a plate anchor. The bounding-surface plasticity （BSP） model combined with Blot＇s consol- idation theory is employed to simulate the cyclic loading induced elasto-plastic deformation of the soil skeleton and the accompanying generation/dissipation of the excess pore water pressure. The suction force generated around the anchor due to the cyclic variation of the pore water pressure has much effect on the pullout capacity of the plate anchor. The calculated pullout capacity with the proposed method （i.e., the coupled analysis） gets lower than that with the conventional total stress analysis for the case of long-term sustained loading, but slightly higher for the case of short-term monotonic loading. The cyclic loading induced accumulation of pore water pressure may result in an obvious decrease of the stiffness of the soil-Plate anchor svstem.

Spatial Pressure Distribution of Cultivated Land and the Analysis of Food Safety in Kunming City,China

The social and economical condition,cultivated land resources and general situation of grain production of research area are introduced.According to relevant data of cultivated land of Kunming City in 2006,taking the minimum per capita cultivated land and index model of cultivated land pressure,and combining with two conditions of per capita grain demand which are 300 kg and 400 kg,the comparative research method was used to calculate and analyze the minimum per capita cultivated land and index model of cultivated land pressure.The results show that when per capita grain demand-Gr is 300 kg,the per capita cultivated land in Kunming City has regional differences,reflects different regular patterns of spatial distribution,and presents obvious and typical radial distribution.Urban area of Kunming has the lowest point and be taken as the center,per capita cultivated land decreases progressively from suburban to the periphery;when per capita grain demand-Gr is 400 kg,under the same consumption level,cultivated land pressures of each county in Kunming City are different,and so are the driven factors;when per capita grain demand-Gr is 300 kg or 400 kg,the indexes of cultivated land pressure in Kunming are all greater than 1,cultivated land pressure is enormous,the indexes of cultivated land pressure of each county(district) have two conditions-greater than 1 and less than 2,and the reasons differ from one another.Combining with the spatial distribution characteristics of the cultivated land and food and the situation of industrial development,the countermeasures and suggestions are put forwarded to make full use of back-up cultivated land,to plan the distribution of industrial structure in each county(district) of Kunming City as a whole,to dispose cultivated land resources reasonably and so on.

Establishment of refractory high intracrinal pressure model in dogs

Objective We expect to have a profound understanding of refractory high intracranial pressure after traumatic brain injury by making a reproducible animal model in dogs experimentally. Methods Ten adult dogs were used to make acute epidural balloon compression and decompression models.

Regional ecological security anddiagnosisof obstaclefactors in underdevelopedregions：acasestudy in Yunnan Province,China

In order toclarify regional ecological security status and formation mechanism of regional ecological security barriers in underdeveloped regions of China,we took Yunnan province as a case to evaluate its regional ecological security by using entropy matter-element model,comprehensive index and GIS spatial method,and we diagnosed itsobstacle factors through obstacle degree model. We found a low overall level of regional ecological security in Yunnan. Only Kunmingfell into the good level, 68% of the regions were below the critical safe level. For the vast majority of regions in Yunnan, their regional ecological security was unstable. The indexes related to per capita resources, geological and topographyenvironment, economic, and technologywere at the unsafe or dangerous level.The indexes related to urban expansion, level of income, cultivated land quality were at the level of critical safety. The indexes concerning urban management capacity, airqualityand waterenvironment were at the good or ideallevel. Yunnan's regional ecological security was not good due to natural obstructive environment itself, simultaneously lower backward economic and social level restricted the ability of ecological security response to manage ragile ecological environment. The results of the composite index wereroughly consistent with those of the entropy weight matterelement model. The mean values of the classification index,from high to low, were: the state index>the response index>the pressure index. The state index and the response index had a significant mutual promotion to each other.The regions with good composite index, state index and response index mainly distributed in the central regions of Yunnan Province. Spatial autocorrelation of regional ecological security level in Yunnan was not obvious. Water resources, economic and social development were main obstacle factors of the regional ecological security.When distinguishing with obstacle type, Kunming belonged to natural ecological environment barrier type, while other regions belonged to economic and social barrier type.

Experimental Study on Heavy Oil Drag Reduction in Horizontal Pipelines by Water Annular Conveying

Transportation of heavy oil by the so-called water-ring technique is a very promising method by which pressure drop and pollution can be significantly reduced.Dedicated experiments have been carried out by changing the phase’s density,viscosity,velocity and interfacial tension to systematically analyze the characteristics of the water ring.On the basis of such experimental data,a mathematical model for pressure drop prediction has been introduced.This research shows that as long as the density of oil and water remains the same,a concentric water ring can effectively be formed.In such conditions,the oil-water viscosity difference has little effect on the shape of water ring,and it only affects the pressure drop.The greater the viscosity of heavy oil,the smaller the pressure drop of the oil-water ring transportation system.The influence of phases’interfacial tension on the characteristics and pressure drop of the heavy oil-water ring can be considered negligible.The pressure drop prediction model introduced on the basis of the Buckingham’s principle provides values in good agreement(95%)with the experimental data.

Behaviour of large post-liquefaction deformation in saturated sand-gravel composites

The laboratory tests on the post-liquefaction deformation of saturated sand-gravel composites were performed to investigate the characteristics of stress-strain relation and the dissipation of pore water pressure by the hollow cylinder apparatus. It is found that the stress-strain response and the dissipation process of pore water pressure are composed of three stages, including the low intensive strength stage, the superlinear strength recovery stage and the sublinear strength recovery stage, and the demarcation points of the curve of pore water pressure are lag behind those of the stress-strain response. The comparison results of the behaviour of large post-liquefaction deformation between saturated sand-gravel composites and Nanjing fine sand show that the low intensive strength stage and the superlinear strength recovery stage of saturated sand-gravel composites are shorter while the sublinear strength recovery stage is longer. A stress-strain model and a dissipation model of excess pore water pressure of liquefied sand-gravel composites are established, in which the initial confining pressure and the relative density can be considered synthetically. And it is found that the predicted results by the two models are in good agreement with experimental data.

Behavior of large post-liquefaction deformation in saturated Nanjing fine sand

Laboratory tests on the large post-liquefaction deformation of saturated Nanjing fine sand were performed by using a hollow cylinder apparatus. The stress-strain responses and the characteristics of excess pore water pressure after liquefaction were studied. It was found that the relationship between deviatoric stress and axial strain presented a sigmoid curve, and there was a good linearity relationship between normalized pore water pressure and deviatoric stress. On this basis, a constitutive model of stress-strain responses and a dissipation model of excess pore water pressure were established. It was found that the results predicted by the two models were in good agreement with the experimental data. The influence of relative densities and confining pressure on the characteristics of liquefied soil were studied, The results showed the relative densities and initial effective confining pressure all had an important influence on the stress-strain responses of liquefied saturated Nanjing fine sand. However, the dissipation model of excess pore water pressure after liquefaction was only affected by the confining pressure.

CO_2 permeability of fractured coal subject to confining pressures and elevated temperature: Experiments and modeling

The CO_2 permeability of fractured coal is of great significance to both coalbed gas extraction and CO_2 storage in coal seams, but the effects of high confining pressure, high injection pressure and elevated temperature on the CO_2 permeability of fractured coal with different fracture extents have not been investigated thoroughly. In this paper, the CO_2 permeability of fractured coals sampled from a Pingdingshan coal mine in China and artificially fractured to a certain extent is investigated through undrained triaxial tests. The CO_2 permeability is measured under the confining pressure with a range of 10–25 MPa, injection pressure with a range of 6–12 MPa and elevated temperature with a range of 25–70°C. A mechanistic model is then proposed to characterize the CO_2 permeability of the fractured coals. The effects of thermal expansion, temperature-induced reduction of adsorption capacity, and thermal micro-cracking on the CO_2 permeability are explored. The test results show that the CO_2 permeability of naturally fractured coal saliently increases with increasing injection pressure. The increase of confining pressure reduces the permeability of both naturally fractured coal and secondarily fractured coal. It is also observed that initial fracturing by external loads can enhance the permeability, but further fracturing reduces the permeability. The CO_2 permeability decreases with the elevation of temperature if the temperature is lower than 44°C, but the permeability increases with temperature once the temperature is beyond 44°C. The mechanistic model well describes these compaction mechanisms induced by confining pressure, injection pressure and the complex effects induced by elevated temperature.