The synthesis of diamond single crystal in the Fe64Ni36-C system with h-BN additive is investigated at pressure 6.5 GPa and temperature range of 1300-1400℃. The color of the obtained diamond crystals translates from ...The synthesis of diamond single crystal in the Fe64Ni36-C system with h-BN additive is investigated at pressure 6.5 GPa and temperature range of 1300-1400℃. The color of the obtained diamond crystals translates from yellow to dark green with increasing the h-BN addition. Fourier-transform infrared （FTIR） results indicate that sp2 hybridization B-N-B and B-N structures generate when the additive content reaches a certain value in the system. The two peaks are located at 745 and 1425cm-1, respectively. Fhrthermore, the FTIR characteristic peak resulting from nitrogen pairs is noticed and it tends to vanish when the h-BN addition reaches 1.1 wt%. Furthermore, Raman peak of the synthesized diamond shifts down to a lower wavenumber with increasing the h-BN ~ddition content in the synthesis system.展开更多
For more than a half century, my colleagues and I in the Stony Brook High Pressure Laboratory have profited from collaborations with French scientists in their laboratories in Orsay, Paris, Toulouse, Lille, Lyon, Stra...For more than a half century, my colleagues and I in the Stony Brook High Pressure Laboratory have profited from collaborations with French scientists in their laboratories in Orsay, Paris, Toulouse, Lille, Lyon, Strasbourg and </span><span style="font-family:Verdana;">Rennes. These interactions have included postdoctoral appointments of French colleagues in our laboratory as well as two année sabbatique by me;in 1983-84</span><span style="font-family:Verdana;">, in the Laboratoire de Géophysique et Géodynamique Interne at the Université Paris XI in Orsay and in 2020-2003 in the Laboratoire des Méchanismes et Transfert en Géologie at the Université Paul Sabatier in Toulouse. The objective of this report is to relate this history and to illustrate the scientific advances which </span></span><span style="font-family:Verdana;">resulted</span><span style="font-family:Verdana;"> from these collaborations.展开更多
Solid liquid state pressure bonding of Si 3N 4 ceramics with aluminum based alloys, which contain a small amount of intermetallic compounds Al 3Ti or Al 3Zr, was investigated. With this new method, the heat resistant ...Solid liquid state pressure bonding of Si 3N 4 ceramics with aluminum based alloys, which contain a small amount of intermetallic compounds Al 3Ti or Al 3Zr, was investigated. With this new method, the heat resistant properties of the bonding zone metal are improved, and the joints’ strengths at high temperature is increased. The joints’ shear strength at room temperature and at 600 ℃ reach 126～133 MPa and 32～34 MPa, respectively, with suitable bonding pressure. The reaction between aluminum and Si 3N 4 ceramics, which produces Al Si N O type compounds is the dominant interfacial reaction, while the reactions between the second active element Ti or Zr in the aluminum based alloys and Si 3N 4 ceramics also occur to some extend. [展开更多
This paper presents an all-SiC fiber-optic Fabry-Perot(FP)pressure sensor based on the hydrophilic direct bonding technology for the applications in the harsh environment.The operating principle,fabrication,interface ...This paper presents an all-SiC fiber-optic Fabry-Perot(FP)pressure sensor based on the hydrophilic direct bonding technology for the applications in the harsh environment.The operating principle,fabrication,interface characteristics,and pressure response test of the proposed all-SiC pressure sensor are discussed.The FP cavity is formed by hermetically direct bonding of two-layer SiC wafers,including a thinned SiC diaphragm and a SiC wafer with an etched cavity.White light interference is used for the detection and demodulation of the sensor pressure signals.Experimental results demonstrate the sensing capabilities for the pressure range up to 800 kPa.The all-SiC structure without any intermediate layer can avoid the sensor failure caused by the thermal expansion coefficient mismatch and therefore has a great potential for pressure measurement in high temperature environments.展开更多
With improvements on high-pressure experimental techniques in multi-anvil apparatus and the development of new analytical tools, major progress has been made on diffusion in garnets in the past several decades. The da...With improvements on high-pressure experimental techniques in multi-anvil apparatus and the development of new analytical tools, major progress has been made on diffusion in garnets in the past several decades. The data obtained in the experimental determination of diffusion coefficients in garnets are of fundamental importance for diffusion modeling and timescales of geological and planetary processes. In this review, we have compiled experimental data on self-diffusion(Si, O, cations), trace element diffusion(Li, Y, Ga, Cr, Sr, REEs), and interdiffusion(Ca–Fe/Mg, Si–Al) in garnet in the light of new advances and recent applications. In addition, some empirical relationships among diffusion parameters(pre-exponential factor D_0,activation energy E, ionic radius) are also discussed. We hope that this review can provide a useful data digest and guide to future study of diffusion in garnet.展开更多
Understanding the behaviour of Ar diffusion in potassium-containing minerals is a basic aspect of geochronology. At first the studies were mainly concentrated on the temperature effect of Ar diffusion. Afterwards, Fol...Understanding the behaviour of Ar diffusion in potassium-containing minerals is a basic aspect of geochronology. At first the studies were mainly concentrated on the temperature effect of Ar diffusion. Afterwards, Foland did single face orthoclase experiment of Ar diffusion, using isotropic sphere model at 500°— 800℃ and 1—5 kbar, and calculated the diffusion coefficient. Giletti et al. treated Ar diffusion on phlogpite in vacuum and hydrothermal conditions at 600°—1080℃ and 1—5 kbar. They did not try more higher pressure, and con-展开更多
B i-Sr-Ca-Cu-O(BSCCO)高温超导材料在电力工程中拥有广阔的应用前景。本文全面概述了国内外研究B i系高温超导材料连接技术的现状和不足,重点介绍了BSCCO带材常规冷压成形后再高温反应退火的扩散焊连接技术,另外,阐述了近几年采用高温...B i-Sr-Ca-Cu-O(BSCCO)高温超导材料在电力工程中拥有广阔的应用前景。本文全面概述了国内外研究B i系高温超导材料连接技术的现状和不足,重点介绍了BSCCO带材常规冷压成形后再高温反应退火的扩散焊连接技术,另外,阐述了近几年采用高温加压直接扩散连接的最新研究成果。展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 51172089the Natural Science Foundation of Guizhou Province Education Department under Grant No KY[2013]183the Natural Science Foundation of Guizhou Province Science and Technology Agency under Grant Nos LH[2015]7232 and LH[2015]7228
文摘The synthesis of diamond single crystal in the Fe64Ni36-C system with h-BN additive is investigated at pressure 6.5 GPa and temperature range of 1300-1400℃. The color of the obtained diamond crystals translates from yellow to dark green with increasing the h-BN addition. Fourier-transform infrared （FTIR） results indicate that sp2 hybridization B-N-B and B-N structures generate when the additive content reaches a certain value in the system. The two peaks are located at 745 and 1425cm-1, respectively. Fhrthermore, the FTIR characteristic peak resulting from nitrogen pairs is noticed and it tends to vanish when the h-BN addition reaches 1.1 wt%. Furthermore, Raman peak of the synthesized diamond shifts down to a lower wavenumber with increasing the h-BN ~ddition content in the synthesis system.
文摘For more than a half century, my colleagues and I in the Stony Brook High Pressure Laboratory have profited from collaborations with French scientists in their laboratories in Orsay, Paris, Toulouse, Lille, Lyon, Strasbourg and </span><span style="font-family:Verdana;">Rennes. These interactions have included postdoctoral appointments of French colleagues in our laboratory as well as two année sabbatique by me;in 1983-84</span><span style="font-family:Verdana;">, in the Laboratoire de Géophysique et Géodynamique Interne at the Université Paris XI in Orsay and in 2020-2003 in the Laboratoire des Méchanismes et Transfert en Géologie at the Université Paul Sabatier in Toulouse. The objective of this report is to relate this history and to illustrate the scientific advances which </span></span><span style="font-family:Verdana;">resulted</span><span style="font-family:Verdana;"> from these collaborations.
文摘Solid liquid state pressure bonding of Si 3N 4 ceramics with aluminum based alloys, which contain a small amount of intermetallic compounds Al 3Ti or Al 3Zr, was investigated. With this new method, the heat resistant properties of the bonding zone metal are improved, and the joints’ strengths at high temperature is increased. The joints’ shear strength at room temperature and at 600 ℃ reach 126～133 MPa and 32～34 MPa, respectively, with suitable bonding pressure. The reaction between aluminum and Si 3N 4 ceramics, which produces Al Si N O type compounds is the dominant interfacial reaction, while the reactions between the second active element Ti or Zr in the aluminum based alloys and Si 3N 4 ceramics also occur to some extend. [
基金This work was supported by the National Natural Science Foundation of China(Grant No.51935011)the fund for Shanxi"1331 Project"Key Subject Construction,Shanxi Natural Science Foundation(Grant Nos.201801D121157 and 201801D221203)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(Grant No.1810600108MZ).
文摘This paper presents an all-SiC fiber-optic Fabry-Perot(FP)pressure sensor based on the hydrophilic direct bonding technology for the applications in the harsh environment.The operating principle,fabrication,interface characteristics,and pressure response test of the proposed all-SiC pressure sensor are discussed.The FP cavity is formed by hermetically direct bonding of two-layer SiC wafers,including a thinned SiC diaphragm and a SiC wafer with an etched cavity.White light interference is used for the detection and demodulation of the sensor pressure signals.Experimental results demonstrate the sensing capabilities for the pressure range up to 800 kPa.The all-SiC structure without any intermediate layer can avoid the sensor failure caused by the thermal expansion coefficient mismatch and therefore has a great potential for pressure measurement in high temperature environments.
基金supported by the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (XDB 18010401)the 1000Plan Program for Young Talents and Hundred Talent Program of CASNSF of China (41303048)
文摘With improvements on high-pressure experimental techniques in multi-anvil apparatus and the development of new analytical tools, major progress has been made on diffusion in garnets in the past several decades. The data obtained in the experimental determination of diffusion coefficients in garnets are of fundamental importance for diffusion modeling and timescales of geological and planetary processes. In this review, we have compiled experimental data on self-diffusion(Si, O, cations), trace element diffusion(Li, Y, Ga, Cr, Sr, REEs), and interdiffusion(Ca–Fe/Mg, Si–Al) in garnet in the light of new advances and recent applications. In addition, some empirical relationships among diffusion parameters(pre-exponential factor D_0,activation energy E, ionic radius) are also discussed. We hope that this review can provide a useful data digest and guide to future study of diffusion in garnet.
基金Project supported by the National Natural Science Foundation of China.
文摘Understanding the behaviour of Ar diffusion in potassium-containing minerals is a basic aspect of geochronology. At first the studies were mainly concentrated on the temperature effect of Ar diffusion. Afterwards, Foland did single face orthoclase experiment of Ar diffusion, using isotropic sphere model at 500°— 800℃ and 1—5 kbar, and calculated the diffusion coefficient. Giletti et al. treated Ar diffusion on phlogpite in vacuum and hydrothermal conditions at 600°—1080℃ and 1—5 kbar. They did not try more higher pressure, and con-
