Mechanical behavior analysis of high power commercial lithium-ion batteries

In application,lithium-ion cells undergo expansion during cycling.The mechanical behavior and the impact of external stress on lithium-ion battery are important in vehicle application.In this work,18 Ah high power commercial cell with Li Ni_(0.5)Co_(0.2)Mn_(0.3)O_(2)/graphite electrode were adopted.A commercial compress machine was applied to monitor the mechanical characteristics under different stage of charge(SOC),lifetime and initial external force.The dynamic and steady force was obtained and the results show that the dynamic force increases as the SOC increasing,obviously.During the lifetime with high power driving mode,different external force is shown to have a great impact on the long-term cell performance,with higher stresses result in higher capacity decay rates and faster impedance increases.A proper initial external force(900 N)provides lower impedance increasing.Postmortem analysis of the cells with2000 N initial force suggests a close correlation between electrochemistry and mechanics in which higher initial force leads to higher direct current internal resistance(DCIR)increase rate.In addition,for the cell with higher external force,deformation of the cathode and thicker solid electrolyte interface(SEI)film on the surface of anode and separator are observed.Porosity reduction and closure was also verified after cycles which is an obstacle to the lithium ion transferring.The largest cause of the observed capacity decline was the loss of active lithium through autopsy analysis.In addition,for the cell with higher external force,deformation of the cathode and thicker SEI film on the surface of anode and separator are observed.Porosity reduction and closure was also verified after cycles which is an obstacle to the lithium ion transferring.The largest cause of the observed capacity decline was the loss of active lithium through autopsy analysis.

CHARACTERISTCS OF FLUID FILM IN OPTIMIZED SPIRAL GROOVE MECHANICAL SEAL

In order to investigate the sealing performance variation resulted from the thermal deformation of the end faces, the equations to calculate the fluid film pressure distribution, the bearing force and the leakage rate are derived, for the fluid film both in parallel gap and in wedgy gap. The geometrical parameters of the sealing members are optimized by means of heat transfer analysis and complex method. The analysis results indicate that the shallow spiral grooves can generate hydrodynamic pressure while the rotating ring rotates and the bearing force of the fluid film in spiral groove end faces is much larger than that in the flat end faces. The deformation increases the bearing force of the fluid film in flat end faces, but it decreases the hydrodynamic pressure of the fluid film in spiral groove end faces. The gap dimensions which determine the characteristics of the fluid film is obtained by coupling analysis of the frictional heat and the thermal deformation in consideration of the equilibrium condition of the bearing force and the closing force. For different gap dimensions, the relation- ship between the closing force and the leakage rate is also investigated, based on which the leakage rate can be controlled by adjusting the closing force.

Fluctuation pressure on a bio-membrane confined within a parabolic potential well

A compliant bio-membrane with a nominally fiat reference configuration is prone to random transverse deflections when placed in water, due primarily to the Brownian motion of the water molecules. On the average, these fluctuations result in a state of thermodynamic equilibrium between the entropic energy of the water and the total free en- ergy of the membrane. When the membrane is in close proximity to a parallel surface, that surface restricts the fluctuations of the membrane which, in turn, results in an increase in its free energy. The amount of that increase depends on the degree of confinement, and the resulting gradient in free energy with degree of confinement implies the existence of a confining pressure. In the present study, we assume that the confinement is in the form of a continuous parabolic po- tential well resisting fluctuation. Analysis leads to a closed form expression for the mean pressure resulting from this confinement, and the results are discussed within the broader context of results in this area. In particular, the results provide insights into the roles of membrane stiffness, number of degrees of freedom in the model of the membrane and other system parameters.

Pressure State in Deep Crust and Formation Depth of UHP Metamorphic Rocks

This paper presents some questions to the formula of pressure=depth×specific gravity from the viewpoint that the hydrostatic pressure is equal to the gravity of overlying rocks and the rocks in a static fluid state, which is drawn from the research and analysis of the research field and the corresponding problems of the pressure state in the deep crust and the formation depth of the UHP metamorphic rocks. In this research, the underground rocks are considered as the solid possessing some rheological behaviors to discuss the polysource stress state and to obtain a more reasonable method for the calculation of depths using the model of the unbalanced force solid. It is suggested from this paper that the P/SW method for the calculation of the ultrahigh pressure stemming only from the gravity has obviously overstated the formation depth of the UHP metamorphism. The formation model emphasizing the effect of the gravity, the tectonic force and the metamorphic force of the facies change concludes that such UHP minerals as coesite may have been produced in the inner crust.

Effect of Fluorides and Cerium Dioxide Additives onEP and Antiwear Performance of Grease

CeF3. CaF2, (CF)n, SbF3, and CeO2 were selected as the high temperature solid additives in a lithium grease, and their friction, wear, and extreme pressure properties were evaluated on an Optimol-SRV wear tester. The effect of additive on the fiber structure of soap was studied by means of the transmission electron microscopy(TEM). The corrosive property of grease containing additive was evaluated by copper strip corrosion test. Thermal decomposition behaviors of the additives were studied by thermogravimetry(TG) tester. The adhesive strength of rubbing surface film was measured by automatic scratch tester and the wear surface was detected by means of X-ray photoelectron spectroscopy (XPS). The test results showed that the grease containing CeF3 has good anti-wear, anti-friction, and EP performances, and has high adhesive strength of rubbing surface film.The greases containing CaF2 or (CF)n are good in antiwear and anti-friction properties, but poor in extreme pressure function. The tribological properties of the grease containing SbF3 are decreased.And the addition of CeO2 in grease was useless. Finally the mechanism of fluoride additive was proposed in this paper.

Mechanical instability of veins under internal pressure

Introduction Tortuous veins are often seen in the retina,cerebrum,and human legs. Venous tortuosity may affect blood flow and the wall remodeling process,both of which are associated with venous diseases. It has been shown that tortuous or vari-

Dynamic Mechanical Characteristics and Damage Evolution Model of Granite

By using the technique of the split Hopkinson pressure bar（ SHPB）,impact tests at different stress wavelengths（ 0. 8-2. 0 m） and strain rates（ 20-120 s^（-1）） were conducted to study the dynamic mechanical properties and damage accumulation evolution lawof granite. Test results showthat the dynamic compressive strength and strain rate of granite have a significantly exponential correlation;the relationship between peak strain and strain rate is approximately linear,and the increase of wavelengths generally makes the level of peak strain uplift. The multiple-impacts test at a lowstrain rate indicates that at the same wavelength,the cumulative damage of granite shows an exponential increasing form with the increase of strain rate; when keeping the increase of strain rate constant and increasing the stress wavelength,the damage accumulation effect of granite is intensified and still shows an exponential increasing form; under the effect of multiple impacts,the damage development trend of granite is similar overall,but the increase rate is accelerating. Therefore the damage evolution model was established on the basis of the exponential function while the physical meaning of parameters in the model was determined. The model can reflect the effect of the wave parameters and multiple impacts. The validity of the model and the physical meaning of the parameters were verified by the test,which further offer a reference for correlational research and engineering application for the granite.

Two-phase sink vortex suction mechanism and penetration dynamic characteristics in ladle teeming process

At the late stage of continuous casting（CC）ladle teeming,sink vortex can suck the liquid slag into tundish,and cause negative influences on the cleanliness of molten steel.To address this issue,a twophase fluid mechanical modeling method for ladle teeming was proposed.Firstly,a dynamic model for vortex suction process was built,and the profiles of vortex flow field were acquired.Then,based on the level set method（LSM）,a two-phase 3Dinterface coupling model for slag entrapment was built.Finally,in combination with high-order essentially non-oscillatory（ENO）and total variation diminishing（TVD）methods,a LSM-based numerical solution method was proposed to obtain the 3Dcoupling evolution regularities in vortex suction process.Numerical results show that the vortex with higher kinetic energy can form an expanded sandglass-shape region with larger slag fraction and lower rotating velocity;there is a pressure oscillation phenomenon at the vortex penetration state,which is caused by the energy shock of two-phase vortex penetration coupling.

MECHANISM OF WALL PRESSURE FLUCTUATIONS BENEATH THE OPEN CHANNEL FLOW

Based on the measured results that wall pressure fluctuations are mainly de- cided by coherent structures of turbulence, the relationship between root-mean- square wall pressure and wall shear stress in turbulent shear flow and that between the intensities of pressure and fluctuating velocity in homogeneous and isotropic turbulence are established in this paper. These relationships are consistent with former works, and have good agreement with experimental data. The paper also dis- cusses the concept of 'apparent pressure' on the wall in mean flow.

One-step synthesis of basic magnesium sulfate whiskers by atmospheric pressure reflux

We have developed a one-step process for the synthesis of basic magnesium sulfate （5Mg（OH）2-MgSO4-3H20, abbreviated as 513MOS） whiskers from MgSO4,7H20 and MgO by refluxing at atmospheric pressure. The process shows potential for the low-cost mass production of controlled- structure whiskers. Their 0.3-1.0 μm diameter and 40-80 μm length correspond to an aspect ratio of 40-260. The 513MOS whisker morphology is related closely to MgSO4 concentration and reflux time. The optimized MgSO4 concentration is 1.2-1.5 mol/L with a 25-30 h reflux time. X-ray diffractometry revealed that the b-axis is the predominant growth direction of the whiskers. Their growth mechanism is by the relatively slow liquid-phase deposition of Mg2＋, OH-, and SO42-. The long reaction time and high MgSO4 concentration are conducive to the formation of 513MOS whiskers under gentle reaction conditions. Porous MgO whiskers with a fibrous structure were obtained after calcination of the 513MOS whiskers at 1020 ℃.

Dynamic mechanical behavior of ultra-high strength steel 30CrMnSiNi2A at high strain rates and elevated temperatures

During high speed machining in the field of manufacture,chip formation is a severe plastic deformation process including large strain,high strain rate and high temperature.And the strain rate in high speed cutting process can be achieved to 105 s^（-1）.30CrMnSiNi2Asteel is a kind of important high-strength low-alloy structural steel with wide application range.Obtaining the dynamic mechanical properties of30CrMnSiNi2Aunder the conditions of high strain rate and high temperature is necessary to construct the constitutive relation model for high speed machining.The dynamic compressive mechanical properties of30CrMnSiNi2Asteel were studied using split Hopkinson pressure bar（SHPB）tests at 30-700°C and3000-10000s^（-1）.The stress-strain curves of 30CrMnSiNi2Asteel at different temperatures and strain rates were investigated,and the strain hardening effect and temperature effect were discussed.Experimental results show that 30CrMnSiNi2Ahas obvious temperature sensitivity at 300°C.Moreover,the flow stress decreased significantly with the increase of temperature.The strain hardening effect of the material at high strain rate is not significant with the increase of strain.The strain rate hardening effect is obvious with increasing the temperature.According to the experimental results,the established Johnson-Cook（J-C）constitutive model of 30CrMnSiNi2Asteel could be used at high strain rate and high temperature.

Potential application of high pressure carbon dioxide in treated wastewater and water disinfection:Recent overview and further trends

Recently emerging disadvantages in conventional disinfection have heightened the need for finding a new solution. Developments in the use of high pressure carbon dioxide for food preservation and sterilization have led to a renewed interest in its applicability in wastewater treatment and water disinfection. Pressurized CO2 is one of the most investigated methods of antibacterial treatment and has been used extensively for decades to inhibit pathogens in dried food and liquid products. This study reviews the literature concerning the utility of CO2 as a disinfecting agent, and the pathogen inactivation mechanism of CO2 treatment is evaluated based on all available research. In this paper, it will be argued that the successful application and high effectiveness of CO2 treatment in liquid foods open a potential opportunity for its use in wastewater treatment and water disinfection. The findings from models with different operating conditions（pressure, temperature, microorganism, water content, media …） suggest that most microorganisms are successfully inhibited under CO2 treatment. It will also be shown that the bacterial deaths under CO2 treatment can be explained by many different mechanisms.Moreover, the findings in this study can help to address the recently emerging problems in water disinfection, such as disinfection by-products（resulting from chlorination or ozone treatment）.