First principles calculation of intermetallic compounds in FeTiCoNiVCrMnCuAl system high entropy alloy

The structural, electronic and elastic properties of common intermetallic compounds in FeTiCoNiVCrMnCuAI system high entropy alloy were investigated by the first principles calculation. The calculation results of formation enthalpy and cohesive energy show that FeTi, Fe2Ti, AlCrFe2, Co2Ti, AlMn2V and Mn2Ti phases may form in the formation process of the alloy. Further studies show that FeTi, FezTi, AlCrFe2, Co2Ti and AlMn2V phases with higher shear modulus and elastic modulus would be excellent strengthening phases in high entropy alloy and would improve the hardness of the alloy. In addition, the partial density of states was investigated for revealing the bonding mode, and the analyses on the strength of p-d hybridization also reveal the underlying mechanism for the elastic properties of these compounds.

Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries

Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs.

Experimental Study and Simulation Principles of An Oil-Gas Multiphase Transportation System

Presented is an experimental study on the performance of an oil-gas multiphase transportation system, especially on the multiphase flow patterns, multiphase pumping and multiphase metering of the system. A dynamic simulation analysis is conducted to deduce simulation parameters of the system and similarity criteria under simplified conditions are obtained. The reliability and feasibility of two-phase flow experiment with oil and natural gas simulated by water and air are discussed by using the similarity criteria.

Variational principle and dynamical equations of discrete nonconservative holonomic systems

By analogue with the methods and processes in continuous mechanics, a Lagrangian formulation and a Hamiltonian formulation of discrete mechanics are obtained. The dynamical equations including Euler Lagrange equations and Hamilton＇s canonical equations of the discrete nonconservative holonomic systems are derived on a discrete variational principle. Some illustrative examples are also given.

Systematic analysis of corporate environmental responsibility:elements,structure,function,and principles

Corporate Environmental Responsibility(CER) is the subsystem of Corporate Social Responsibility(CSR),which continues to increase prominence in the global economy.Nowadays,CER becomes more important in corporate sustainable development.Based on Carroll's pyramid mode of CSR,this article explores the systematic feature of CER.From a systematic perspective,it sorts out its elements,structure,function,and principles of CER.And the four levels of economic,legal,ethical,and charitable structure are emphasized.With these considerations interpreted into practice,success will be achieved in potential cost savings,technological innovation,increased public acceptance,and better relations with governments.

THE VARIATIONAL PRINCIPLES OF COUPLED SYSTEMS IN PHOTOELASTICITY

This paper presents an energy principle, zero different principle of coupledsystems in photoelasticity, from which the potential energy, the complementary energy,generalized potential energy and generalized complementary energy variationalprinciples of the coupled systems in photoelasticity are derived What is called the coupled systems means that two deformational bodies, forwhich figures, sizes,loads and boundary conditions are the same and they are all inactual states but they are made of different materials.Prototype body and model body in photoelasticity are essentially the coupledsystems, therefore the above principles become the theoretical basis of defining theinflunce of Poissons ratio v on accuracy of the frozen-stress method.

Anisotropic etching mechanisms of 4H-SiC:Experimental and first-principles insights

Molten-alkali etching has been widely used to reveal dislocations in 4H silicon carbide(4H-SiC),which has promoted the identification and statistics of dislocation density in 4H-SiC single crystals.However,the etching mechanism of 4H-SiC is limited misunderstood.In this letter,we reveal the anisotropic etching mechanism of the Si face and C face of 4H-SiC by combining molten-KOH etching,X-ray photoelectron spectroscopy(XPS)and first-principles investigations.The activation energies for the molten-KOH etching of the C face and Si face of 4H-SiC are calculated to be 25.09 and 35.75 kcal/mol,respectively.The molten-KOH etching rate of the C face is higher than the Si face.Combining XPS analysis and first-principles calculations,we find that the molten-KOH etching of 4H-SiC is proceeded by the cycling of the oxidation of 4H-SiC by the dissolved oxygen and the removal of oxides by molten KOH.The faster etching rate of the C face is caused by the fact that the oxides on the C face are unstable,and easier to be removed with molten alkali,rather than the C face being easier to be oxidized.

The bond graph model of planar flexible multibody mechanical systems and its dynamic principle

In order to increase the efficiency and reliability of the dynamic analysis for flexible planar linkage containing the coupling of multi-energy domains, a method based on bond graph is introduced. From the viewpoint of power conservation, the peculiar property of bond graph multiport element MTF is discussed. The procedure of modeling planar flexible muhibody mechanical systems by bond graphs and its dynamic principle are deseribed. To overcome the algebraic difficulty brought by differential causality anti nonlinear junction structure, the constraint forces at joints can be considered as unknown effort sources and added to the corresponding O-junctions of system bond graph model. As a result, the automatic modeling on a computer is realized. The validity of the procedure is illustrated by a practical example.

Investigation of power-type variational principles in liquid-filled system

Starting from the basic equations of hydrodynamics, the maximum power- type variational principle of the hydrodynamics of viscous fluids was established by Weizang CHIEN in 1984. Through long-term research, it is clarified that the maximum power-type variational principle coincides with the Jourdian principle, which is one of the common principles for analytical mechanics. In the paper, the power-type variational principle is extended to rigid-body dynamics, elasto-dynamics, and rigid-elastic：liquid coupling dynamics. The governing equations of the rigid-elastic-liquid coupling dynamics in the liquid-filled system are obtained by deriving the stationary value conditions. The results show that, with the power-type variational principles studied directly in the state space, some transformations in the time domain space may be omitted in the establishing process, and the rigid-elastic-liqUid coupling dynamics can be easily numerically modeled. Moreover, the analysis of the coupling dynamics in the liquid-filled system in this paper agrees well with the numerical analyses of the coupling dynamics in the liquid-filled system offered in the literatures.

Maxi mumprinciple for the optimal control of an ablation-transpiration cooling system with free final time and phase constraints

This paper is concerned with an optimal control problem of an abhtion-transpiration cooling control system with Stefan-Signorini boundary condition. As the continuation of the authors＇previous paper, the Dubovits Rii-Milyutin fimctional approach is again adopted in investigation of the Pontryagin＇ s maximun principle of the system. The necessary optimality condition is presented for the problem with free final horizon and phase constraints.

Truly optimal semi-active damping to control free vibration of a single degree of freedom system

This paper studies a single degree of freedom system under free vibration and controlled by a general semiactive damping.A general integral of squared error is considered as the performance index.A one-time switching damping controller is proposed and optimized.The pontryagin maximum principle is used to prove that no other form of semi-active damping can provide the better performance than the proposed one-time switching damping.

First‑principles study on electronic structure,optical and magnetic properties of rare earth elements X(X=Sc,Y,La,Ce,Eu)doped with two‑dimensional GaSe

The electronic structure,magnetic,and optical properties of two-dimensional(2D)GaSe doped with rare earth elements X(X=Sc,Y,La,Ce,Eu)were calculated using the first-principles plane wave method based on den-sity functional theory.The results show that intrinsic 2D GaSe is a p-type nonmagnetic semiconductor with an indi-rect bandgap of 2.6611 eV.The spin-up and spin-down channels of Sc-,Y-,and La-doped 2D GaSe are symmetric,they are non-magnetic semiconductors.The magnetic moments of Ce-and Eu-doped 2D GaSe are 0.908μ_(B)and 7.163μ_(B),which are magnetic semiconductors.Impurity energy levels appear in both spin-up and spin-down chan-nels of Eu-doped 2D GaSe,which enhances the probability of electron transition.Compared with intrinsic 2D GaSe,the static dielectric constant of the doped 2D GaSe increases,and the polarization ability is strengthened.The ab-sorption spectrum of the doped 2D GaSe shifts in the low-energy direction,and the red-shift phenomenon occurs,which extends the absorption spectral range.The optical reflection coefficient of the doped 2D GaSe is improved in the low energy region,and the improvement of Eu-doped 2D GaSe is the most obvious.

General Optimal Trajectory Planning:Enabling Autonomous Vehicles with the Principle of Least Action

This study presents a general optimal trajectory planning(GOTP)framework for autonomous vehicles(AVs)that can effectively avoid obstacles and guide AVs to complete driving tasks safely and efficiently.Firstly,we employ the fifth-order Bezier curve to generate and smooth the reference path along the road centerline.Cartesian coordinates are then transformed to achieve the curvature continuity of the generated curve.Considering the road constraints and vehicle dynamics,limited polynomial candidate trajectories are generated and smoothed in a curvilinear coordinate system.Furthermore,in selecting the optimal trajectory,we develop a unified and auto-tune objective function based on the principle of least action by employing AVs to simulate drivers’behavior and summarizing their manipulation characteristics of“seeking benefits and avoiding losses.”Finally,by integrating the idea of receding-horizon optimization,the proposed framework is achieved by considering dynamic multi-performance objectives and selecting trajectories that satisfy feasibility,optimality,and adaptability.Extensive simulations and experiments are performed,and the results demonstrate the framework’s feasibility and effectiveness,which avoids both dynamic and static obstacles and applies to various scenarios with multi-source interactive traffic participants.Moreover,we prove that the proposed method can guarantee real-time planning and safety requirements compared to drivers’manipulation.

THE CONVERGENT RATE OF VISCOSITY METHOD FOR A VARIANT NON-ISENTROPIC SYSTEM OF POLYTROPIC GAS

In this short paper,we remove the restrictionγ∈(1,3]that was used in the paper"The rate of convergence of the viscosity method for a nonlinear hyperbolic system"(Nonlinear Analysis,1999,38:435-445)and obtain a global Holder continuous solution and the convergent rate of the viscosity method for the Cauchy problem of the variant nonisentropic system of polytropic gas for any adiabatic exponentγ>1.

The Five Principles of Peaceful Coexistence:Connotations in International Law and Contemporary Relevance

The year 2024 marks the 70th anniversary of the Five Principles of Peaceful Coexistence initiated by China.As an anchor foreign policy of New China and its first contribution of public product for the international community,the Five Principles have made a historic contribution to the building of a new type of just and equitable international relations,advancing the purposes and principles of the Charter of the United Nations,and becoming universally applicable basic norms for international relations and key fundamental principles of international law.

A model for the mean velocity of debris flow movement based on the minimum energy dissipation principle

The geomorphic minimum energy dissipation principle is important in the development of gully evolutionary theory.The impact of debris flows on channels during movement also adheres to this theory.A minimum energy dissipation model for debris flows has been obtained from previous studies,which is derived from the flow rules of runoff along a channel under rainfall or ice-snow meltwater conditions.However,the lack of consideration for erosion characteristics has hindered a comprehensive understanding of the movement characteristics of debris flow.In this paper,the phenomenon of volume increase resulting from the entrainment along debris flow movement is considered in order to derive a model for the mean velocity,reflecting the minimum energy dissipation principle.The entire expression of the mean velocity model is determined through 38 typical glacial and rainstorm debris flow cases.To evaluate the reliability of the proposed model,we employed 164 monitoring data from 1995 to 2000 in the Jiangjia gully,Yunnan,China.The results show that the velocity calculated by the proposed model are highly correlated with those obtained from the monitoring data.Additionally,a comparison is made between the mean velocities calculated by the proposed model and those obtained from previous studies,highlighting the exceptional applicability of the proposed model.This study will contribute to reveal the movement laws of debris flow along the channel.

Sabatier principle guiding the design of cathode catalysts for Li-CO_(2) batteries

The Sabatier principle has been widely used for designing electrocatalysts for energy conversion applications,but it is rarely mentioned in the research of cathode catalyst of Li-CO_(2) batteries.In our work,the"volcanic"relationship between the catalytic activity and the adsorption energy of the catalyst to the intermediates is first demonstrated based on the first-principles calculation,which meets the Sabatier principle and can be used to design the cathode catalysts.The increases in the number of nitrogenvacancy in WN shift the d-band center and increase the interaction with the reactants.The catalytic activity increases first and then decreases with the increase of adsorption energy,which was proved in the experiment.The optimal catalyst for moderate adsorption of intermediate makes the thin LiaCO_(3) distribute evenly.It exhibits a median voltage difference of 0.68 V and an energy efficiency of 84.33%at20μA cm^(-2)with a limited capacity of 200μA h cm^(-2).

Exploring the Implications of the Deformation Parameter and Minimal Length in the Generalized Uncertainty Principle

The breakdown of the Heisenberg Uncertainty Principle occurs when energies approach the Planck scale, and the corresponding Schwarzschild radius becomes similar to the Compton wavelength. Both of these quantities are approximately equal to the Planck length. In this context, we have introduced a model that utilizes a combination of Schwarzschild’s radius and Compton length to quantify the gravitational length of an object. This model has provided a novel perspective in generalizing the uncertainty principle. Furthermore, it has elucidated the significance of the deforming linear parameter β and its range of variation from unity to its maximum value.

Principles of Shiology——Revealing the Basic Rules of Human Shiance

The objective principles of shiology are mainly reflected in three fields as food acquisition, eaters' health and shiance order. Most of the objective principles in the field of food acquisition have been revealed by agronomy and foodstuff science. This research mainly focuses on 10 principles in the field of eaters' health and shiance order and in addition, there are also five lemmas that extend from the above principles. The 10 principles are the core theory of the shiology knowledge system, which play an important role in the objective principles revealed by human beings and constitute one of the basic principles of human civilization. Compared with the scientific principles of mathematics, physics, chemistry and economics, the principles of shiology have three characteristics as popularity, practicability and survivability. The principles of shiology in the field of eaters' health are all around us, and everyone can understand and master them. Using the principles of shiology can improve the healthy life span of 8 billion people. The principles of shiology in the field of shiance order is an important tool of social governance, which can reduce human social conflicts, reduce social involution, improve overall efficiency of social operation, and maintain the sustainable development of human beings.

Unruh Metric Tensor HUP via Planckian Space-Time Compared to HUP Based Complexity of Measured System Results to Obtain Inflaton Potential Magnitude

First of all, we restate a proof of a highly localized special case of a metric tensor uncertainty principle first written up by Unruh. Unruh did not use the Roberson-Walker geometry which we do, and it so happens that the dominant metric tensor we will be examining, is variation in δgtt. The metric tensor variations given by δgrr, δgθθand δgϕϕare negligible, as compared to the variation δgtt. Afterwards, what is referred to by Barbour as emergent duration of time δtis from the Heisenberg Uncertainty principle (HUP) applied to δgttin such a way as to be compared with ΔxΔp≥ℏ2+γ˜∂C∂Vwith V here a volume spatial term and γ˜a complexification strength term and ∂C∂Vinfluence of complexity of physical system being measured in order to obtain a parameterized value for the initial value of an inflaton which we call V0.