CHARACTERIZATION OF POLAR COMPONENTS IN HYTROTREATED NAPHTHENIC RUBBER PROCESS OIL

Polar components play a very important role toward light stability of hydrotreated naphthenic rubber process oil. Polar components in hydrotreated naphthenic rubber process oil are analyzed in detail. Polar components are firstly isolated from rubber process oil by column chromatography of silica gel, and then characterized by a series of instrument technology including elemental analysis, infrared spectroscopy, APCI/MS and XPS. The results show that the polar components comprise some hetero atoms compounds of sulfur, nitrogen and oxygen. Oxygen-containing compounds such as hydroxyl, carbonyl, and carboxyl groups constitute the main body of polar components. Nitrogen-containing compounds （NH2, NH, or NO2 and-N=N-） and sulfur-containing compounds (SO42- and PHSSPH) only account for minor percent of polar components. The molecular weight distribution of polar components mainly concentrates between 300 and 500 and a minor portion distributes from 180 to 300.

Techniques and Technological Aspects of Palm Oil (Elaeis guineensis) Processing in Cameroon

Crude palm Oil (CPO) processing is very popular in African Countries. In Cameroon, various actors are involved ranging from agro-industrial complexes to traditional processing by smallholders who use very inefficient equipment and thus have low oil extraction rates. Small-scale processing by smallholders dates back to the early 1980s and has witnessed a lot of changes as a result of new actors in the sector, changing technologies and to an extent, government policies. This paper attempts a review of the origins and evolution of small-scale palm oil processing using intermediate technology, highlighting its importance to both the farmer and the national economy. An attempt is made to look into the future of this activity, with proposals for its consolidation.

Processes for the Clarification of the Crude Oil of Baobab Seeds Extracted by Pressing on Activated Carbon Elaborated from the Capsules of the Fruit (Adansonia digitata L.)

The baobab, Adansonia digitata L. plays an important role in the economy of local populations. The oil from the seeds of the baobab fruit is nowadays highly prized because of its numerous cosmetic and therapeutic applications and its composition of unsaturated fatty acids, sterols and tocopherols. However, unlike refined oils, locally extracted baobab oil has not undergone purification operations to ensure its quality. Only a filtration on special cloths is carried out after decantation. Indeed, the oil obtained after pressing is cloudy because of the presence of various impurities. It therefore requires treatment operations to make it more attractive and of higher quality. Therefore, in order to provide innovative solutions to local companies to improve the quality of vegetable oils, a study of clarification (treatment) of crude oil is necessary. An experimental device has been developed in the laboratory. It includes a glass column and a filter bed of dune sand and activated carbon. This study has shown the efficiency of the experimental device. Indeed, the activated carbon, thanks to its adsorbing power, has allowed a significant decrease in turbidity at the 5% threshold, from 14.61 NTU for the raw oil to 0.08 NTU for the oil filtered on 3% carbon and 0.033 NTU for the oil filtered on 5% carbon. That is to say an abatement higher than 95%. This decrease in turbidity could be correlated with the decrease in brown index from 187.39a for the initial crude oil to 128.53d for the oil treated with 3% activated carbon versus 187.59a for the oil filtered on cloths. The lowest brown index was observed with the filtration using 5% activated carbon (35.99b). Thus, for the yellowness index, only the filtration on 5% charcoal allowed to obtain a significant decrease in yellowness. The yellowing index of the oil with 5% was 44.67b against 79.04a for the oil filtered with 3% activated carbon, 86.33a for the crude oil and 86.46a for the oil filtered on cloths. Finally, the oil sample treated with 5% activated carbon had the clearest clarity than the other samples with a clarity (L) equal to 97.98c against 95.63d for the oil treated with 3% carbon and 94.99b for the oil filtered on filter cloths. According to the results obtained, the experimental device made it possible to obtain a clearer baobab oil with a low brown index, thus improving the sensory quality of the oil.

The Effect of Reaction Temperature, Catalyst Concentration and Alcohol Ratio in the Production of Biodiesel from Raw and Purified Castor Oil

In this study, a homogeneous alkaline catalyst was used in the production of biodiesel from raw and refined castor oil feedstock. The effect of potassium hydroxide (KOH) as a catalyst between the two feedstocks, raw and refined castor oil was compared. The transesterification technique was utilized in this study, aiming to investigate the effect of different parameters, which include the reaction temperature, methanol-to-oil mole ratio, and catalyst concentration at a constant period of 90 minutes. The result revealed the performance of the KOH catalyst on raw castor oil yielded 98.49% FAME, which was higher than the refined castor oil which yielded 97.9% FAME. The optimal conditions obtained from refined castor oil were applied to raw castor oil because of the same properties. The fuel quality of castor oil and produced biodiesel were tested for physicochemical properties.

Production sharing contract: An analysis based on an oil price stochastic process

Assuming that oil price follows the stochastic processes of Geometric Brownian Motion （GBM） or the Mean-Reverting Process （MRP）, this paper takes the net present value （NPV） as an economic index and models the PSC in 11 different scenarios by changing the value of each contract element （i.e. royalty, cost oil, profit oil as well as income tax）. Then the NPVs are shown in probability density graphs to investigate the effect of different elements on contract economics. The results show that under oil price uncertainty the influence of profit oil and income tax on NPV are more significant than those of royalty and cost oil, while a tax holiday could improve the contractor＇s financial status remarkably. Results also show that MRP is more appropriate for cases with low future oil price volatility, and GBM is best for high future oil price volatility.

Consumer acceptability and sensory profiling of sesame oils obtained from different processes

This study aimed to investigate the effect of oil processing technologies on the sensory qualities of sesame oils and to identify drivers of liking.Using a check-all-that-apply(CATA)question and a hedonic scale,150 consumers evaluated the acceptability and sensory characteristics of 5 sesame oil samples including an aqueous extracted oil(S1),a cold-pressed oil(S2),two batches of screw-pressed oils(S3 and S5)and one crude sesame oil(S4).Solid-phase microextraction-gas chromatography-olfactometry-mass spectrometry(SPME-GC-O-MS)was used to identify odour-active compounds.The results showed that roasting,extraction techniques and filtration process influenced sensory perception and the acceptability of sesame oils.Consumers liked roasted sesame oils more than the cold-pressed sesame oil and liked the aqueous extracted sesame oil the most.Sensory attributes"sweet smell","mellow","roasted","nutty","persistent","high-intense flavour"and"cooked sesame seed flavour"were drivers of liking,while"green","raw sesame seed","rancid","woody"and"fishy"were drivers of disliking."Burnt"flavour was liked by some while disliked by others.Pyrazines contributed to roasted flavour;2-acetylpyrrole,acetophenone and furfural contributed to nutty flavour;2-pentyl-furan,5-methyl-2-furancarboxaldehyde,and 2-phenyl-2-butenal contributed to sweet odour in the roasted sesame seeds.Nonanal,hexanal,1-hexanol and ocimene were responsible for the"green"flavour perceived in the cold-pressed oil.This study provides valuable information for sesame manufacturers on how to improve the sensory qualities of sesame oils through process manipulation to meet the needs of diverse consumers.

Targeted Catalytic Cracking to Olefins(TCO):Reaction Mechanism,Production Scheme,and Process Perspectives

Light olefins are important organic building blocks in the chemicals industry.The main low-carbon olefin production methods,such as catalytic cracking and steam cracking,have considerable room for improvement in their utilization of hydrocarbons.This review provides a thorough overview of recent studies on catalytic cracking,steam cracking,and the conversion of crude oil processes.To maximize the production of light olefins and reduce carbon emissions,the perceived benefits of various technologies are examined.Taking olefin generation and conversion as a link to expand upstream and downstream processes,a targeted catalytic cracking to olefins(TCO)process is proposed to meet current demands for the transformation of oil refining into chemical production.The main innovations of this process include a multiple feedstock supply,the development of medium-sized catalysts,and a diameter-transformed fluidizedbed reactor with different feeding schemes.In combination with other chemical processes,TCO is expected to play a critical role in enabling petroleum refining and chemical processes to achieve low carbon dioxide emissions.

Source and accumulation process of Jurassic biodegraded oil in the Eastern Junggar Basin,NW China

Biodegradation usually obscures or even radically alters the original characteristics of oil biomarkers.The mixing of oil from multiple sources makes each source difficult to trace.Identifying the source of biodegraded oil from multiple sources has always been a hard nut to crack.Rising to this challenge,in this study-we carried out a comprehensive investigation of biodegradation impacts,oil-source correlation,and oil charging history to trace the source and reveal the mixing process of biodegraded oil in the Toutunhe Formation(J_(2)t)in the eastern Junggar Basin,NW China.The oil of this area was biodegraded to different extent,consequently,many commonly used biomarker parameters(e.g.Pr/Ph,Pr/n C_(17))became less powerful for oil-source correlation.To address this problem,the resistance of many biomarkers to biodegradation was analyzed,and those of high bio resistance were selected to generate a more reliable oil-source correlation.The results revealed that biodegraded oil was a mixture of oil sourced from Lucaogou Formation(P_(2)l)and Xiaoquangou Formation(T_(2-3)xq).Core sample observation,microscopic fluorescent analysis and fluid inclusion analysis were combined to analyze comprehensively oil charging history.The analysis of accumulation process exhibited that the existing oil in J_(2)t was a mixture originated from the P_(2)l and T_(2-3)xq source rocks in two separate charging stages when it underwent a complicated process of charging,biodegradation,recharging and mixing.

Study of the Process of Extraction and Refining of Pequi (<i>Caryocar brasiliense</i>Camb.) Oil

Pequi fruit is a characteristic of Central Brazil with high oil content. This study evaluated the extraction of oil from the fruit portions by chemical and physical methods and determined an optimal condition for neutralization and degumming of oil extracted by solvent pequi pulp. The solvent extraction of oil was better than the mechanical pressing method. The oil extracted by solvent of the pulp pequi had a higher yield compared to other portions of the fruit. The peels and impurities material of fruit has a negligible amount of oil. The oil extracted from the pulp has better commercial characteristics in relation to the oil obtained from almonds. The operating parameters (temperature and time) studied at the stage of degumming the crude oil were significant at the 5% significance. The Increase in temperature decreases the values of acidity and iodine of the degummed oil.

Modeling and Simulation of High Power Ultrasonic Process in Preparation of Stable Oil-in-Water Emulsion

The aims of this research are to study application of high power ultrasound in preparation of stable oil-in-water emulsion. The effect of pH, ionic strength, pectin, Guar gum, lecithin, egg yolk, and xanthan gum as well as the time of sonication, temperature and viscosity of oil-water mixture on the specific surface area and size of droplets, and creaming index of the emulsion samples was investigated. The experimental data were analyzed with Taguchi method and optimum conditions were determined. In addition, an adaptive neuro-fuzzy inference system (ANFIS) was employed to modeling and categorizes the properties of the resulted emulsion. The results showed that increasing sonication time narrowed the range of droplets size distribution. Pectin and xanthan enhanced the stability of emulsion, although they had different impacts on the emulsion stability when used individually or together. Guar gum improved the viscosity of the continuous phase. Emulsions stabilized by egg yolk were found to be stable to droplet flocculation at pH 3 and at relatively low salt concentrations.

Heavy Oil Processing and Utilizing in Liaohe Oilfields

Liaohe Oilfields,the third la-,rgest petroleum bases of China 1S located n Liaoning Province.The output of crude oil and natural gas has been increased rapidly,since 1970.due to making a great effort 1n exploration and development.

Air Quality Impacts of Smallholder Oil Palm Processing in Nigeria

Air emissions during palm oil processing by smallholders are issues of public health concern demanding urgent intervention by environmentalist. In this study, six smallholder oil palm processing mills were studied inElele,Nigeria. Air emission parameters (NO2, NH3, CO, H2S, SO2, VOC), noise and meteorology (wind speed, temperature, relative humidity and pressure) were determined at three distances (10 ft,25 ftand50 ft) in both wind ward and lee ward directions from the mills covering boiling and digestion activities. The emissions from biomass were found to be significantly higher than that from fossil diesel, while noise was higher during digestion. The health implications of air emissions were discussed. The study concluded by directing attentions of regulatory agencies to monitor the activities of smallholder oil palm processing to ensure the environmental sustainability of their operations. In summary, evidence during boiling activity revealed that: · H2S ranged from - 2.400 ppm at10 ft, - 2.067 ppm at25 ftand - 0.833 ppm at50 ftfrom the mills in the wind ward direction, and - 1.167 ppm at10 ft, - 0.567 ppm at25 ftand - 0.367 ppm at50ftdistance from the mills in lee ward direction and was significantly lower during digestion. · SPM ranged from 1634 - 7853 μg/m3 at10 ft, 657 - 1110 μg/m3 at25 ftand 81 - 854 μg/m3 at50 ftfrom the mills in the wind ward direction, and 46 - 236 μg/m3 at10 ft, 44 - 120 μg/m3 at25 ftand 30 - 58 μg/m3 at50 ftfrom the mills in lee ward direction. SPM was significantly lower during digestion. · VOC ranged from 67 - 13.933 ppm at10 ft, 1.033 - 13.133 ppm at25ftand 0.500 -

Exergetic Efficiencies Evaluation of Flows and Operations on the Mechanical Extraction Process of <i>Jatropha curcas</i>Oil

Jatropha curcas oil is one of the most promising renewable energy sources for rural areas due to its ease of production, which can be used as an alternative to diesel and fuel oil. The development of sustainable energy has been the issue of the discussion about biofuel production given the considerable consumption amount of fossil fuel during the transformation process. And any production process that consumes a lot of energy records a significant destruction of useful energy, which leads to thermodynamic inefficiencies of the process. Besides, the focus on environmental safety is gradually shifting towards energy efficiency in industrial processing. Exergetic analysis is an effective tool for measuring the performance of a production process since exergy is a quantity that measures energy quality. This study assesses the scale of resource degradation in Jatropha oil mechanical extraction processes and finds improving possible pretreatments options for more efficient production. Data from experiments combined with existing databases have permitted to establish the exergy flow balance at each stage of production. The process exergetic yield varies from 29.85% to 35.41% according to the chosen pretreatment process. Mass exergy accounts for 67% of incoming flows and, for outgoing flows, more than 60% is associated with the mass exergy generated by the process waste. The uncertainties analysis on the results was used to validate model results, and to visualize the minimum values for the most unfavorable cases and the maximum values when all the parameters are at their optimum values.

Source,Process and End Treatment Technology of Volatile Organic Compounds in Oil Storage

Oil storage is a source of volatile organic compounds( VOCs). Volatile organic compounds can cause different damages to the environment,animals and plants. Therefore, it is important to control the discharge of VOCs in oil storage. In this paper,the control technology of sources of VOCs pollution in oil storage was analyzed from the source,process and end treatment,and measures for the prevention and control of VOCs pollution in oil storage were proposed.

Optimization of Sesame Oil Extraction Process Conditions

In this study, the optimum operating conditions for sesame oil extraction were studied. N-hexane was used as a solvent. Different variables were investigated;sesame seeds particle sizes, ratio of solvent to seeds mass, contact time, stirring effect, roasting impact and extraction temperatures. Results obtained showed that higher rates of extraction were obtained when roasting sesame seed to 15℃. The ratio of solvent to seeds found to be 6:1 gave higher extraction. Moreover, stirring speed was tested and had been optimized to 600 rpm. Finally, the extraction under heating was studied and results showed that increasing operating temperature to more than 40℃ did not increase extraction efficiency.

准噶尔盆地重点领域油气勘探研究进展及潜力方向

准噶尔盆地胜利探区主要位于盆地周缘超剥带、复杂山前带和深洼区,油气成藏条件复杂,勘探难度大。为明确胜利探区重点领域的潜力方向,指导下步油气勘探部署层次优选,基于胜利探区准西缘超剥带领域、准中地区上组合深层领域、准中地区下组合超深层领域、准北缘及准东南山前带领域沉积、储层、油源对比、输导体系、成藏模式、油气富集控制因素等勘探研究进展系统总结,对各重点领域下步的潜力方向进行了分析。结果表明:准西缘超剥带领域的哈山地区侏罗系—白垩系、车排子地区新近系沙湾组、车排子地区石炭系及准中地区上组合深层领域的永进-征沙村地区侏罗系齐古组、莫西庄地区侏罗系三工河组及东道海子凹陷成6井区侏罗系八道湾组是下步主要的增储上产阵地;准中地区下组合超深层领域的沙湾凹陷征10井区二叠系上乌尔禾组—三叠系克拉玛依组、盆1井西凹陷庄深1井区二叠系风城组—夏子街组是下步重要的接替阵地;准北缘哈山山前带及准东南博格达山南、北山前带准原地系统是下步需要持续探索的有利阵地;石北凹陷及石钱滩凹陷石炭系深层非常规页岩气领域是今后需要积极准备的后备阵地。“十四五”—“十五五”期间,胜利探区应以“立足全区、决胜深层、常非并重、统筹推进”勘探思路为指导,持续、有序地推进盆地各重点领域的勘探。

Processing and Utilization of Naphthenic Base Heavy Crude Oil(continued)

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Processing and Utilization of Naphthenic Base Heavy Crude Oil

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Connotation and strategic role of in-situ conversion processing of shale oil underground in the onshore China

In-situ conversion processing (ICP) of shale oil underground at the depth ranging from 300 m to 3 000 m is a physical and chemical process caused by using horizontal drilling and electric heating technology, which converts heavy oil, bitumen and various organic matter into light oil and gas in a large scale, which can be called"underground refinery". ICP has several advantages as in CO2capture, recoverable resource potential and the quality of hydrocarbon output. Based on the geothermal evolution mechanism of organic materials established by Tissot et al., this study reveals that in the nonmarine organic-rich shale sequence, the amount of liquid hydrocarbon maintaining in the shale is as high as 25%in the liquid hydrocarbon window stage (R o less than 1.0%), and the unconverted organic materials (low mature-immature organic materials) in the shale interval can reach 40%to 100%. The conditions of organic-rich shale suitable for underground in-situ conversion of shale oil should be satisfied in the following aspects, TOC higher than 6%, R o ranging between 0.5%and 1%, concentrated thickness of organic-rich shale greater than 15 meters, burial depth less than 3 000 m, covering area bigger than 50 km2, good sealing condition in both up-and down-contacting sequences and water content smaller than 5%, etc. The shale oil resource in China’s onshore region is huge. It is estimated with this paper that the technical recoverable resource reaches 70-90 billion tons of oil and 60-65 trillion cubic meters of gas. The ICP of shale oil underground is believed to be a fairway to find big oil in the source kitchen in the near future. And it is also believed to be a milestone to keep China long-term stability of oil and gas sufficient supply by putting ICP of shale oil underground into real practice in the future.

Research on the Correlation Between Oil Menitoring and Vibration Monitoring in Information Collecting and Processing Monitoring

Oil monitoring and vibration monitoring are two principal techniques for mechanical fault diagnosis and condition monitoring at present. They monitor the mechanical condition by different approaches, nevertheless, oil and vibration monitoring are related in information collecting and processing. In the same mechanical system, the information obtained from the same information source can be described with the same expression form. The expressions are constituted of a structure matrix, a relative matrix and a system matrix. For oil and vibration monitoring, the information source is correlation and the collection is independent and complementary. And oil monitoring and vibration monitoring have the same process method when they yield their information. This research has provided a reasonable and useful approach to combine oil monitoring and vibration monitoring.