Spray Atomized and Codeposited Al-Li Based Metal-matrix Composites Processing and Properties

In spray atomization and codeposition, a molten stream of metal is disintegrated into a fine dispersion of droplets by high velocity gas jets. The resulting semi-solidified droplets are directed towards a substrate where they impact and collect as rapidly solidified splats. Relatively high rates of solidification are achieved as a result of the thinness of the splats and the rapid heat extraction during flight and upon impacting with the substrate. The processing method uses codeposition of the metallic semi-solidified droplets (metallic matrix) with the injected reinforcement ceramic particles. In the present paper, the microstructures, mechanical properties, interfacial properties, thermal stability and aging behaviour of spray atomized and codeposited Al-Li-X MMC's (injected X=SiC, Al2O3) are reported and correlated to the processing conditions.

Effect of Rolling Process on Comprehensive Properties of Corrosion Resistant Steel for Bottom Plate of Cargo Oil Tanks

A new kind of corrosion resistant steelfor cargo oiltanks（COT）was developed.The influences of finalrolling temperature,cooling rate,and finalcooling temperature on microstructure were investigated.The proper rolling process parameters were obtained through multi-pass thermalsimulation test.The finalrolling temperature is about 820 ℃,the finalcooling temperature is about 600 ℃,and the cooling rate should be controlled between 10 ℃/s and 20 ℃/s.Based on the above analysis of the results,three groups of rolling samples by thermo mechanicalcontrolprocess are prepared.The tensile strength,yield strength,and toughness of the corrosion resistant steelare measured,which meet the requirements of DH36 steel,it can instruct the actualrolling production.The corrosion behaviour is also researched by weight loss and electrochemicalimpedance spectroscopic method,and it is found that the steelhas good corrosion resistance performance,the best one is No.3 steel,the corrosion rate of which is about 1/4 of the accepted criterion.

Effect of M/P and Borax on the Hydration Properties of Magnesium Potassium Phosphate Cement Blended with Large Volume of Fly Ash

The effect of the borax content and magnesia to phosphate ratio（M/P） on the hydration properties of the magnesium potassium phosphate cement（MKPC） with large volume of fly ash was investigated, and a five-hydration-stage for MKPCs was proposed. The results show that MKPC sets rapidly with less than 8% of borax, which is unfavorable to the application of MKPC on construction. Adding more than 8%（including 8%） of borax results in a secondary hydration peak for MKPC, in which the process of hydration can be divided into five stages, namely, pre-induction period, induction period, acceleration period, deceleration period and stable period. M/P ratios could not change the multi-step reactive stages but higher M/P ratios could accelerate the hydration. Borax tends to impact the formation of Mg-containing hydrated products.

Effect of Different Aging Processes on the Microstructure and Mechanical Properties of a Novel Al–Cu–Li Alloy

The effects of different aging processes on the microstructure and mechanical properties of a novel Al-Cu-Li alloy have been investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. It is found that the tensile properties of a novel Al-Cu-Li alloy are sensitive to aging processes, which correspond to different microstructures. σ（Al_5Cu_6Mg_2） and T_1（Al_2CuLi） phases are the major precipitates for the alloy in T6 aging condition（165 ℃/60 h）. After duplex aging condition（150 ℃/24 h ＋ 180 ℃/12 h）, σ, θ＇（Al_2Cu） and T_1 phases are detected. Only the T_1 phases can be found in the T8 state alloy（6% pre-strain＋135 ℃/60 h）. The failure modes of alloy in T6 and duplex aging conditions are dimple-intergranular fracture, while typical quasi-cleavage fracture in T8 condition.

Photocatalytic properties of hierarchical BiOXs obtained via an ethanol-assisted solvothermal process

In this study, bismuth oxyhalide（Bi OXs（X_Cl, Br, I）） semiconductors were prepared by a simple solvothermal method, with ethanol serving as solvent and a series of tetrabutylammonium halide surfactants as halogen sources. Under identical synthetic conditions, Bi OBr was more readily constructed into regular flower-like hierarchical architectures. The photocatalytic properties of the materials were studied by monitoring the degradation of rhodamine B（Rh B）,with visible light absorption, and colorless salicylic acid（SA）. It was found that both Rh B and SA were rapidly degraded on the surface of Bi OBr. Bi OCl was rather active for the degradation of Rh B,but ineffective toward the degradation of SA. However, neither Rh B nor SA could be degraded effectively in the case of Bi OI. Further experiments such as UV–visible spectroscopy and detection of U OH and O2 Uradicals suggest that the electronic structure of the Bi OX photocatalysts is responsible for the difference in their activities.

Prediction and experimental measurement of the electromagnetic thrust generated by a microwave thruster system

A microwave thruster system that can convert microwave power directly to thrust without a gas propellant is devel-oped. In the system, a cylindrical tapered resonance cavity and a magnetron microwave source are used respectively as the thruster cavity and the energy source to generate the electromagnetic wave. The wave is radiated into and then reflected from the cavity to form a pure standing wave with non-uniform electromagnetic pressure distribution. Consequently, a net electromagnetic thrust exerted on the axis of the thruster cavity appears, which is demonstrated through theoretical calcula- tion based on the electromagnetic theory. The net electromagnetic thrust is also experimentally measured in the range from 70 mN to 720 mN when the microwave output power is from 80 W to 2500 W.

Properties of 3Cr2W8V Die Steel With Striations Processed by Laser

The striations on the surface of 3Cr2W8V die steel were processed by laser. The microstructure, hardness, wear resistance and thermal fatigue behavior of the specimens processed by laser were measured. The appearance and mechanism of thermal fatigue crack propagation in the zone processed by laser were observed and discussed. The results show that the wear resistance and thermal fatigue resistance of materials processed by laser are all better than those of the unprocessed material. The processed zone by laser plays a role in baffling wearing process and crack propagation. The pile-nail effect of processed zone is the main factor for improving the wear resistance and thermal fatigue resistance of material.

Effect of friction stir processed microstructure on tensile properties of an Al-Zn-Mg-Sc alloy upon subsequent aging heat treatment

An as-cast Al-Zn-Mg-Sc alloy was friction stir processed varying tool related parameters, yielding microstructures with different grain sizes （0.68, 1.8 and 5.5 μm）. Significant increases in room temperature ductility were obtained in these materials with reasonable enhancement in strength. It is demonstrated that the type of microstructure produced by friction stir processing （FSP） has a significant influence on the choice of post-FSP heat treatment design for achieving improved tensile properties. It is also found that the ultrafine grained FSP material could not achieve the desired high strength during the post-FSP heat treatment without grain coarsening, whereas the micro-grained FSP materials could reach such strength levels （〉560 MPa） under conventional age hardening heat treatment conditions.

Effects of processing parameters on fatigue properties of LY2 Al alloy subjected to laser shock processing

We address the effects of processing parameters on residual stresses and fatigue properties of LY2 Al alloy by laser shock processing （LSP）. Results show that compressive residual stresses are generated near the surface of samples due to LSP. The maximum compressive residual stress at the surface by two LSP impacts on one side is higher than that by one LSP impact. The maximum value of tensile residual stress is found at the mid-plane of samples subjected to two-sided LSP. Compared with fatigue lives of samples treated by single-sided LSP, lives of those treated by two-sided LSP are lower. However, these are higher than untreated ones.

Dimension Properties of Sample Paths of Self-Similar Processes

The Hansdorff dimensions of the image and the graph of random fields are given under general conditions.The results can be used to a wider class of self-similar random fields and processes,including Brownian motion,Brownian sheet,fractional Brownian motion,processes with stable or(α,β)-fractional stable components.

Cost-effective integrated strategy for the fabrication of hard-magnet barium hexaferrite powders from low-grade barite ore

Ultrafine barium hexaferrite（BaFe12O19） powders were synthesized from the metallurgical extracts of low-grade Egyptian barite ore via a co-precipitation route. Hydrometallurgical treatment of barite ore was systematically studied to achieve the maximum dissolution efficiency of Fe（～99.7%） under the optimum conditions. The hexaferrite precursors were obtained by the co-precipitation of BaS produced by the reduction of barite ore with carbon at 1273 K and then dissolved in diluted HCl and FeCl3 solution at pH 10 using NaOH as a base; the product was then annealed at 1273 K in an open atmosphere. The effect of Fe^3＋/Ba^2＋ molar ratio and the addition of hydrogen peroxide（H2O2） on the phase structure, crystallite size, morphology, and magnetic properties were investigated by X-ray diffraction, scanning electron microscopy, and vibrating sample magnetometry. Single-phase BaFe（12）O（19） powder was obtained at an Fe^3＋/Ba^2＋ molar ratio of 8.00. The formed powders exhibited a hexagonal platelet-like structure. Good maximum magnetization（48.3 A×m^2×kg^–1） was achieved in the material prepared at an Fe^3＋/Ba^2＋ molar ratio of 8.0 in the presence of 5% H2O2 as an oxidizer and at 1273 K because of the formation of a uniform, hexagonal-shaped structure.

Microstructure and Performance Analysis of Organic Coating under High Temperature and High CO_2 Partial Pressure

To evaluate the property of the organic coatings in oil and gas plants, the aging process was studied in high temperature and high CO_2 partial pressure environment. Correlations were developed between the macroscopic properties and microstructure of the organic coatings. The surface appearance, mechanical properties, and permeability of the organic coatings were measured. Furthermore, the crystal structure of the organic coatings was investigated through synchrotron radiation grazing incidence X-ray diffraction（GIXRD） on the BL14B1 beam line in Shanghai Synchrotron Radiation Facility. Combined with the Fourier transform infrared spectroscopy, the molecular structure of the organic coatings was investigated. The experimental results indicate that the thickness variation and weight loss of the organic coatings increase with the immersion time, and the penetration resistance of the coating obviously decreases as the temperature rises. Moreover, the degradation of the organic coatings with immersion time in high temperature and high CO_2 partial pressure environment is caused by the amorphization of the organic coatings as the groups and bonds of the organic coatings were not damaged.

Synthesis and Characterization of Cubic Zinc Titanate Doped with Lithium

Cubic （Zn,Li）TiO3 powders were synthesized through a modified sol-gel route including the Pechini process via a three-step heat treatment.The as-synthesized （Zn,Li）TiO3 could be stable up to 1000 °C.The dielectric constant and dielectric loss tangent of all the synthesized （Zn,Li）TiO3 samples at different measurement frequencies showed the similar tendency.At the same frequency,the dielectric constant and the dielectric loss tangent of （Zn,Li）TiO3 samples decreased and increased,respectively,with the lithium doping content increase.The as-prepared （Zn,Li）TiO3 showed improved microwave dielectric properties,and its maximum value of quality factor could reach 34000 GHz.

Optical properties and dynamic process in metal ions doped on CdSe quantum dots sensitized solar cells

In recent years, the nanostructure for solar cells have attracted considerable attention from scientists as a result of a promising candidate for low cost devices. In this work, quantum dots sensitized solar cells with effective performance based on a co-sensitized Cd S∕Cd Se：Mn2＋（or Cu2＋） nanocrystal, which was made by successive ionic layer absorption and reaction, are discussed. The optical, physical, chemical, and photovoltaic properties of quantum dots sensitized solar cells were sensitized to Mn2＋and Cu2＋dopants. Therefore, the short current（JSC）of the quantum dot sensitized solar cells is boosted dramatically from 12.351 mA∕cm2 for pure Cd Se nanoparticles to 18.990 mA∕cm2 for Mn2＋ions and 19.915 mA∕cm2 for Cu2＋ions. Actually, metal dopant extended the band gap of pure Cd Se nanoparticles, reduced recombination, enhanced the efficiency of devices, and improved the charge transfer and collection. In addition, Mn2＋and Cu2＋dopants rose to the level of the conduction band of pure Cd Se nanoparticles, which leads to the reduction of the charge recombination, enhances the lightharvesting efficiency, and improves the charge diffusion and collection. The results also were confirmed by the obtained experimental data of photoluminescence decay and electrochemical impedance spectroscopy.

Electrical and dielectric characterization of Au/ZnO/n-Si device depending frequency and voltage

Au/Zn O/n-type Si device is obtained using atomic layer deposition（ALD） for Zn O layer, and some main electrical parameters are investigated, such as surface/interface state（Nss）, barrier height（Φb）, series resistance（Rs）, donor concentration（Nd）, and dielectric characterization depending on frequency or voltage. These parameters are acquired by use of impedance spectroscopy measurements at frequencies ranging from 10 k Hz to 1 MHz and the direct current（DC） bias voltages in a range from-2 V to ＋2 V at room temperature are used. The main electrical parameters and dielectric parameters,such as dielectric constant（ε＂）, dielectric loss（ε＂）, loss tangent（tan δ）, the real and imaginary parts of electric modulus（M and M）, and alternating current（AC） electrical conductivity（σ） are affected by changing voltage and frequency. The characterizations show that some main electrical parameters usually decrease with increasing frequency because charge carriers at surface states have not enough time to fallow an external AC signal at high frequencies, and all dielectric parameters strongly depend on the voltage and frequency especially in the depletion and accumulation regions. Consequently, it can be concluded that interfacial polarization and interface charges can easily follow AC signal at low frequencies.

Collaborative optimization design of process parameter and structural topology for laser additive manufacturing

High-resolution laser additive manufacturing(LAM)significantly releases design free-dom,promoting the development of topology optimization(TO)and advancing structural design methods.In order to fully take advantage of voxelated forming methods and establish the quantitative relationship between the mechanical properties of printing components and multiple process factors(laser-and process-parameters),the concurrent optimization design method based on LAM should cover the process-performance relationship.This study proposes a novel artificial intelligence-facilitated TO method for LAM to concurrently design microscale material property and macroscale structural topology of 3D components by adopting heuristic and gradient-based algorithms.The process–structure–property relationship of selective laser sintering is established by the back propagation neural network,and it is integrated into the TO algorithm for providing a systematic design scheme of structural topology and process parameter.Compared with the classical optimization method,numerical examples show that this method is able to improve the mechanical performance of the macrostructure significantly.In addition,the collaborative design method is able to be widely applied for complex functional part design and optimization,as well as case studies on artificial intelligence-facilitated product evaluation.

Optimal design of hot rolling process for C-Mn steel by combining industrial data-driven model and multi-objective optimization algorithm

A successful mechanical property data-driven prediction model is the core of the optimal design of hot rolling process for hot-rolled strips. However, the original industrial data, usually unbalanced, are inevitably mixed with fluctuant and abnormal values. Models established on the basis of the data without data processing can cause misleading results, which cannot be used for the optimal design of hot rolling process. Thus, a method of industrial data processing of C-Mn steel was proposed based on the data analysis. The Bayesian neural network was employed to establish the reliable mechanical property prediction models for the optimal design of hot rolling process. By using the multi-objective optimization algorithm and considering the individual requirements of costumers and the constraints of the equipment, the optimal design of hot rolling process was successfully applied to the rolling process design for Q345B steel with 0.017% Nb and 0.046% Ti content removed. The optimal process design results were in good agreement with the industrial trials results, which verify the effectiveness of the optimal design of hot rolling process.

Friction-stir welding and processing of Ti-6Al-4V titanium alloy:A review

In this work, the current understanding and development of fliction-stir welding and processing of Ti- 6Al-4V alloy are briefly reviewed. The critical issues of these processes are addressed, including welding tool materials and design, tool wea,, processing temperature, material flow, processing window and residual stresses. A particular emphasis is given to microstructural aspects and microstructure-properties relationship. Potential engineering applications are highlighted.

Comparative Study on Processing Property Between CWW CO_2 Gas Shielded Welding and SAW

Cable welding wire（CWW）CO2gas shielded welding is an innovative process arc welding with high efficiency,high quality and low consumption,in which cable wire is used as consumable electrode.CWW CO2gas shielded welding and submerged arc welding（SAW）are used for contrast studies on processing property of high strength steel A36used in ship structure.The results show that the shapes of weld seam,using CWW CO2gas shielded welding and SAW,are good and no weld defect such as air hole,flaw,slag inclusion,incomplete fusion,lack of penetration and so on are found in the weld seam.Because the rotating of arc during CWW CO2gas shielded welding process has a strong stirring effect on molten pool,the grain in the heat affected zone（HAZ）of the joints,using CWW CO2 gas shielded welding,is small.Tensile failure positions of joints by CWW CO2gas shielded welding and SAW are all in the base metal,but tensile strength of CWW CO2gas shielded welding joint is higher than that of SAW joint by an average of 2.3%.The average impact energy of HAZ,using CWW CO2gas shielded welding and SAW,is almost equal,but the average impact energy of the weld seam using CWW CO2gas shielded welding is increased by 6%,and the average impact energy of the fusion line is increased by 7%.The 180°bending tests for the joints of CWW CO2 gas shielded welding and SAW are all qualified,and the joints hardness is all less than HV 355,but hardness of CWW CO2gas shielded welding wire welding joint near the fusion line is obviously lower.It can be concluded that the properties of CWW CO2gas shielded welding are better than those of the SAW joint,and CWW CO2gas shielded welding is suitable for welding high strength steel A36used in ship structure.

MgO-based adsorbents for CO2 adsorption:Influence of structural and textural properties on the CO_2 adsorption performance

A series of MgO-based adsorbents were prepared through solution–combustion synthesis and ball-milling process.The prepared MgO-based powders were characterized using X-ray diffraction,scanning electron microscopy,N_2 physisorption measurements,and employed as potential adsorbents for CO_2 adsorption.The influence of structural and textural properties of these adsorbents over the CO_2 adsorption behaviour was also investigated.The results showed that MgO-based products prepared by solution–combustion and ball-milling processes,were highly porous,fluffy,nanocrystalline structures in nature,which are unique physico-chemical properties that significantly contribute to enhance their CO_2 adsorption.It was found that the MgO synthesized by solution combustion process,using a molar ratio of urea to magnesium nitrate（2：1）,and treated by ball-milling during 2.5 hr（MgO-BM2.5h）,exhibited the maximum CO_2 adsorption capacity of 1.611 mmol/g at 25℃ and 1 atm,mainly via chemisorption.The CO_2 adsorption behaviour on the MgO-based adsorbents was correlated to their improved specific surface area,total pore volume,pore size distribution and crystallinity.The reusability of synthesized MgO-BM2.5h was confirmed by five consecutive CO_2adsorption–desorption times,without any significant loss of performance,that supports the potential of MgO-based adsorbent.The results confirmed that the special features of MgO prepared by solution–combustion and treated by ball-milling during 2.5 hr are favorable to be used as effective MgO-based adsorbent in post-combustion CO_2 capture technologies.