Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions

A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.

Generation of input spectrum for electrolysis stack degradation test applied to wind power PEM hydrogen production

Hydrogen production by proton exchange membrane electrolysis has good fluctuation adaptability,making it suitable for hydrogen production by electrolysis in fluctuating power sources such as wind power.However,current research on the durability of proton exchange membrane electrolyzers is insufficient.Studying the typical operating conditions of wind power electrolysis for hydrogen production can provide boundary conditions for performance and degradation tests of electrolysis stacks.In this study,the operating condition spectrum of an electrolysis stack degradation test cycle was proposed.Based on the rate of change of the wind farm output power and the time-averaged peak-valley difference,a fluctuation output power sample set was formed.The characteristic quantities that played an important role in the degradation of the electrolysis stack were selected.Dimensionality reduction of the operating data was performed using principal component analysis.Clustering analysis of the data segments was completed using an improved Gaussian mixture clustering algorithm.Taking the annual output power data of wind farms in Northwest China with a sampling rate of 1 min as an example,the cyclic operating condition spectrum of the proton-exchange membrane electrolysis stack degradation test was constructed.After preliminary simulation analysis,the typical operating condition proposed in this paper effectively reflects the impact of the original curve on the performance degradation of the electrolysis stack.This study provides a method for evaluating the degradation characteristics and system efficiency of an electrolysis stack due to fluctuations in renewable energy.

Consistency of Water Production Function Models of Two Crops

On basis of test information, the research performed analysis on water production function models of two crops, which indicated that water model of crops in whole growth stage and water model of crops indifferent growth stages have consistency as well as differences, providing references for optimization of irrigation water. Meanwhile, the research analyzed the deficiency of optimization on irrigation water for crops just by Jensen model.

Produced-water treatment: Application and research of combined fiber coalescence technique in offshore oilfield

When the process of extraction of oil from an offshore oilfield enters the advanced stages,the water content in the extracted fluid can be above 90%.The water quality is complex with many types of pollutants and highly emulsified water.Therefore,a key consideration in the production process of offshore oilfields is the efficient and economical treatment of the oil-containing produced water to make it suitable for discharge and recover oil pollutants.In this study,we developed a hydrophilic and hydrophobic combined fiber coalescence separator with composite fiber shapes using fiber induction and X/Uweaving.The separator is designed based on experimental observations of the mechanism of structure coalescence in the physical oil removal method.A pilot test was performed on an oil exploration platform in the Bohai Sea.At the designed flow rate,the separator reduced the total concentration of petroleum in the produced water from 2000 to 3000 mg/L to below 60 mg/L,with an average oil removal efficiency of 98.24%.Furthermore,it effectively reduced the number of organic compounds present in the water from 120 to 17 and removed 70% of the SS.The test results show that the proposed device can be used fr produced-water treatment on offshore platforms.

Responses of water productivity to irrigation and N supply for hybrid maize seed production in an arid region of Northwest China

Water and nitrogen（N） are generally two of the most important factors in determining the crop productivity. Proper water and N managements are prerequisites for agriculture sustainable development in arid areas. Field experiments were conducted to study the responses of water productivity for crop yield（WP_（Y-ET）） and final biomass（WP_（B-ET）） of film-mulched hybrid maize seed production to different irrigation and N treatments in the Hexi Corridor, Northwest China during April to September in 2013 and also during April to September in 2014. Three irrigation levels（70%–65%, 60%–55%, and 50%–45% of the field capacity） combined with three N rates（500, 400, and 300 kg N/hm^2） were tested in 2013. The N treatments were adjusted to 500, 300, and 100 kg N/hm^2 in 2014. Results showed that the responses of WP_（Y-ET） and WP_（B-ET） to different irrigation amounts were different. WP_（Y-ET） was significantly reduced by lowering irrigation amounts while WP_（B-ET） stayed relatively insensitive to irrigation amounts. However, WP_（Y-ET） and WP_（B-ET） behaved consistently when subjected to different N treatments. There was a slight effect of reducing N input from 500 to 300 kg/hm^2 on the WP_（Y-ET） and WP_（B-ET）, however, when reducing N input to 100 kg/hm^2, the values of WP_（Y-ET） and WP_（B-ET） were significantly reduced. Water is the primary factor and N is the secondary factor in determining both yield（Y） and final biomass（B）. Partial factor productivity from applied N（PFP_N） was the maximum under the higher irrigation level and in lower N rate（100–300 kg N/hm^2） in both years（2013 and 2014）. Lowering the irrigation amount significantly reduced evapotranspiration（ET）, but ET did not vary with different N rates（100–500 kg N/hm^2）. Both Y and B had robust linear relationships with ET, but the correlation between B and ET（R^2=0.8588） was much better than that between Y and ET（R^2=0.6062）. When ET increased, WP_（Y-ET） linearly increased and WP_（B-ET） decreased. Taking the indices of Y, B, WP_（Y-ET）, WP_（B-ET） and PFP_N into account, a higher irrigation level（70%–65% of the field capacity） and a lower N rate（100–300 kg N/hm^2） are recommended to be a proper irrigation and N application strategy for plastic film-mulched hybrid maize seed production in arid Northwest China.

Technology and Practice of Stabiliing Oil Production and Controlling Water Cut in Kalamkas Oilfield in Central Asia

In this paper, by in-depth geological research of Kalamkas Oilfield in Central Asia, the geological body has been re-ascertained; combined with fine study of reservoir engineering, based on the understanding of the distribution of remaining oil horizontal wells have been given full play to stabilizing oil production and controlling water cut, reducing the producing pressure drop, improving well productivity and other advantages, and the development and deployment has been optimized; horizontal wells have been applied to solve problems such as old well casing damages, shutting down wells, low-productivity and low- efficiency wells, and high water cut wells to improve the utilization rate of old wells; through separate layer system improved injection production pattern, adjustment wells have been optimized and deployed, and part measures wells have been preferably selected to tap the residual oil improve the degree of reserves control realize the stabilization of oil production and control of water cut in an old oilfield, and further improve the development effects.

Characterization of Water Production and Its Implication to Forest Management

Nowadays, forests are being managed for multiple uses. The basic requirement of multiple use forestry is to identify and quantify forest values and to determine management objectives. The priorities of management objectives, however, must be decided. In this study, a model predicting water production for multi-objective forest management was developed. The model was based on data from permanent sample plots. The data were gathered from 132 sample plots. Approximately 80% of the observations were used for model development and 20% for validation. The model was designed for even-aged forests, as well as for forests with mixed and pure species composition. The explicatory variable in the model was number of trees. All parameter estimates were found highly significant （P 〈 0.001） in predicting water production. The model fit and validation tests were fairly good. The water production model presented in this study was considered to have an appropriate level of reliability. planning, but, it should be limited to the conditions for which the data It can be used in the overall multi-objective forest management were gathered.

The Industrial Production of Water Dedicated to Absorption of Gases

The paper presents a flow plasma reactor permitting modification of the properties of water/aqueous solutions by stochastic resonance amplification of vibrations of selected chemical species in water with electromagnetic noise generated during a plasma discharge. The main parameters characterizing the quality for super-pure water, tap water and water from the intake in Besko (Poland) before and after the process in the plasma reactor were presented for comparison. In addition, the 17O NMR (the full width at half maximum) and electrospray ionization mass spectrometry (ESI MS) methods were used to determine differences in physicochemical parameters between the untreated and plasma-treated water. It has been established that the water subjected to plasma treatment shows much different gas absorption properties than the untreated water samples, as a function of temperature and pressure, in this paper we report exemplary data for CO2, oxygen and acetylene. The improved gas absorption properties of the plasma-treated water make it attractive for the use in industrial processes. It is worth pointing to a great capacity of the new reactor (4000 l/h), and low energy consumption (20 MJ/h) for the treatment of the above mentioned volume flow rate of water.

Effect of water fluctuation on agricultural production in the Huang-Huai-Hai Plain, China

The biggest load of water resources for agricultural economy in the Huang-Huai Plainwill only arcount for 67.1 % of the forecasted irrigated area in 2010. The irrigated area and thequantity of water diverting from the Huanghe River was 2.2 million hm2 and 10.8 billion m3respectively in the lowe reaches of the river in the 1990s. The annual amount of yield increase forgrain is 6.3 billion kg calculated by converting and the annual benefit of yield-increase is 4.4 billionRMB yuan in the irrigated area of the region. The daily economic losses of industry and agricultureby absence of flow in the area in the 1990s is 44. 1 million RMB yuan. The annual water quantity willbe increased by 9.9 billion m3 after diverting water from the Huanghe River and 12.6 billion m3 afterdiverting water from the Changjiang River respectively in the plain in 2010.

Photothermal-photocatalytic thin-layer flow system for synergistic treatment of wastewater

The integration of the photocatalytic effect into solar steam is highly desirable for addressing freshwater shortages and water pollution.Here,a ternary film structure for the adsorption and photothermal and photocatalytic treatment of wastewater was designed by combining the technique of self-assembled carbon nano paper with a nitrogen composite titanium dioxide(N-TiO_(2))deposited on the surface of carbon nanotubes(CNT)using polyvinylidene fluoride(PVDF)as a substrate.The photogeneration of reactive oxygen species can be promoted by rapid oxygen diffusion at the three-phase interface,whereas the interfacial photothermal effect promotes subsequent free radical reactions for the degradation of rhodamine B(93%).The freshwater evaporation rate is 1.35 kg·m^(-2)·h^(-1)and the solar-to-water evaporation efficiency is 94%.Importantly,the N-TiO_(2)/CNT/PVDF(N-TCP)film not only effectively resists mechanical damage from the environment and maintains structural integrity,but can also be made into a large film for outdoor experiments in a large solar energy conversion device to collect fresh water from polluted water and degrade organic dyes in source water simultaneously,opening the way for applications in energy conversion and storage.

Optimized Operation of a Solar-Driven Thermoelectric Dehumidification System for Fresh Water Production

The work presents a parametric analysis of the performance of a solar-driven thermoelectric system to dehumidify air and produce fresh water. The system is combined with a solar distiller humidifying ambient air to enhance distillate output to meet the specified fresh water needs for a residential application. The presented system is a totally renewable energy-based system taking advantage of the clean solar energy. A model is developed to simulate the air dehumidification process using TEC （thermoelectrically cooled） channels. An optimization problem for setting system operational parameters is formulated to meet the fresh water requirement of 10 liters per day for a typical residential application in the Lebanese coastal humid climate. Using five TEC channels of length of 1.2 m and area of 0.07 - 0.05 m^2 integrated with 1.2 m^2 solar distiller is capable of meeting the water demand, where the air mass flow rate introduced to each TEC channel is optimally set at 0.0155 kg/s. The optimal electrical current input to the TEC modules from the photovoltaic solar panels varied depending on the month and is set at 2.2 A in June, 2.1 A in July and 2.0 A in August, September and October per each TEC module.

Influential Factors of Water Productivity of Maize in Oasis of Arid Areas——A Case Study of Linze County

[Objective] The aim was to research influential factors of water productivity of maize in oasis in arid areas. [Method] In middle reach of Heihe River in Linze County of Zhangye City, maize, a major crop in irrigated area in the oasis, was studied and nine influential factors were chosen through grey relation analysis. [Result] According to grey relation analysis, top five factors influencing water produc- tivity of maize during 1995-2009 were as follows： applied quantity of chemical fertil- izers〉labour input〉seeds〉mulch amount〉pesticide amount, which indicated that controllable factors, instead of uncontrollable ones, dominate in influence of water productivity of maize in oasis in arid areas. [Conclusion] With water resource limited, investment of controllable factors in high-efficient agricultural production should be the major strategy to improve water productivity of maize in oasis of arid areas.

Trade-offs and synergies between ecosystem services in Yutian County along the Keriya River Basin,Northwest China

The Keriya River Basin is located in an extremely arid climate zone on the southern edge of the Tarim Basin of Northwest China,exhibiting typical mountain-oasis-desert distribution characteristics.In recent decades,climate change and human activities have exerted significant impacts on the service functions of watershed ecosystems.However,the trade-offs and synergies between ecosystem services(ESs)have not been thoroughly examined.This study aims to reveal the spatiotemporal changes in ESs within the Keriya River Basin from 1995 to 2020 as well as the trade-offs and synergies between ESs.Leveraging the Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)and Revised Wind Erosion Equation(RWEQ)using land use/land cover(LULC),climate,vegetation,soil,and hydrological data,we quantified the spatiotemporal changes in the five principal ESs(carbon storage,water yield,food production,wind and sand prevention,and habitat quality)of the watershed from 1995 to 2020.Spearman correlation coefficients were used to analyze the trade-offs and synergies between ES pairs.The findings reveal that water yield,carbon storage,and habitat quality exhibited relatively high levels in the upstream,while food production and wind and sand prevention dominated the midstream and downstream,respectively.Furthermore,carbon storage,food production,wind and sand prevention,and habitat quality demonstrated an increase at the watershed scale while water yield exhibited a decline from 1995 to 2020.Specifically,carbon storage,wind and sand prevention,and habitat quality presented an upward trend in the upstream but downward trend in the midstream and downstream.Food production in the midstream showed a continuously increasing trend during the study period.Trade-off relationships were identified between water yield and wind and sand prevention,water yield and carbon storage,food production and water yield,and habitat quality and wind and sand prevention.Prominent temporal and spatial synergistic relationships were observed between different ESs,notably between carbon storage and habitat quality,carbon storage and food production,food production and wind and sand prevention,and food production and habitat quality.Water resources emerged as a decisive factor for the sustainable development of the basin,thus highlighting the intricate trade-offs and synergies between water yield and the other four services,particularly the relationship with food production,which warrants further attention.This research is of great significance for the protection and sustainable development of river basins in arid areas.

Hydrate Prevention Strategies and the Associated Cost in the Gulf of Mexico

With the petroleum industry endeavoring to develop promising oil and gas in deeper water, gas hydrates prevention is a serious concern for oil and gas producing companies producing at conditions in the hydrate region. This paper details lessons learned from the successful field deployment of AA LDHI and proper implementation strategies used for 3 different practical fields as case studies in the Gulf of Mexico. From the 3 field experiences, the AA LDHI has been used to replace the conventional thermodynamic hydrate inhibitor due to its numerous benefits during steady state operations and transition operations where AA LDHI is injected prior to extended shut in and restart for fields producing at low water cut. However, the strategy to develop a cost effective chemical management of hydrates for fields producing at high water cut is by pumping methanol or diesel to push down the wellbore fluid below the mud line during planned and unplanned shut-ins to delay water production, it also secures the riser with non hydrate fluids. This illustrates how the AA LDHIs are used in conjunction with more conventional hydrate management approaches to reach an optimal cost effective field hydrate management solution. However, this shows that the key to overall success of hydrate prevention is a full integration of a good front end design, a comprehensive deployment and an effective down hole monitoring system.

Effect of irrigation regime on grain yield,water productivity,and methane emissions in dry direct-seeded rice grown in raised beds with wheat straw incorporation

Dry direct-seeded rice grown in raised beds is becoming an important practice in the wheat–rice rotation system in China.However,little information has been available on the effect of various irrigation regimes on grain yield,water productivity(WP),nitrogen use efficiency(NUE),and greenhouse gas emission in this practice.This study investigated the question using two rice cultivars in 2015 and 2016 grown in soil with wheat straw incorporated into it.Rice seeds were directly seeded into raised beds,which were maintained under aerobic conditions during the early seedling period.Three irrigation regimes:continuous flooding(CF),alternate wetting and drying(AWD),and furrow irrigation(FI),were applied from 4.5-leaf-stage to maturity.Compared with CF,both AWD and FI significantly increased grain yield,WP,and internal NUE,with greater increases under the FI regime.The two cultivars showed the same tendency in both years.Both AWD and FI markedly increased soil redox potential,root and shoot biomass,root oxidation activity,leaf photosynthetic NUE,and harvest index and markedly decreased global warming potential,owing to substantial reduction in seasonalThe results demonstrate that adoption of either AWD or FI could increase grain yield and resource-use efficiency and reduce environmental risks in dry direct-seeded rice grown on raised beds with wheat straw incorporation in the wheat–rice rotation system.

Effect of NPK Application on Yield,Nutrients and Water Utilization Under Sudangrass and Ryegrass Rotation Regime

Sudangrass and ryegrass rotation is a new type of cropping system in Jianghan Plain,which develops very fast in recent years.So,it is essential to work out the optimal nutrients and water management measures in this new system.The effect of NPK fertilizer on yield of forage grass,nutrients and water utilization under sudangrass and ryegrass rotation was studied through continuous pot experiments for three years.The results showed that NPK combination could significantly improve the yield of forage grasses.The total yields during the periods of 2005-2006,2006-2007 and 2007-2008 were 1 690.0,2 091.3 and 1 770.7 g/pot,respectively.The yields in PK treatment were 700.7,1 256.9 and 856.3% lower than those of NPK treatment,while the yields in NK treatment were 426.3,384.9 and 792.3% lower than those of NPK treatment,respectively.Similarly,the yields in NP treatment were 15.9,4.4 and 10.6% lower than those of NPK treatment,respectively.The NPK combination was found to improve the nutrients uptake,and the total N uptakes during the above periods were 10.0,14.8 and 10.6 times higher than that of PK treatment,respectively,and 3.7,1.8 and 5.1 times higher than those of NK treatment,respectively,but,were similar to NP treatment.The total P uptakes were 4.6,6.8 and 5.3 times higher than those of PK treatment,and were 2.4,2.3 and 2.9 times higher than those of NK treatment,respectively,but were similar to NP treatment.The total K uptakes were 5.2,8.4 and 4.9 times higher than that of PK treatment,3.9,2.3 and 3.9 times higher than those of NK treatment,and 80.9,57.4 and 200.5% higher than those of NP treatment,respectively.Water productivity for three years time periods were 16.5,16.1 and 16.2 kg m-3,and were 3.8,5.4 and 4.2 times higher than those of PK treatment,2.3,1.3 and 2.6 times higher than those of NK treatment,and were 16.4,8.8 and 22.4% higher than those of NP treatment,respectively.The soil pH was decreased and soil organic matter was increased in all treatments with increase in the time of sudangrass and ryegrass rotation system.The total soil N was increased in NP,NK and NPK treatments,while it was stable in PK treatment.The available P in NP,PK and NPK treatments was increased significantly,while it was stable in NK treatment.The slow releasing K and available K were increased significantly in NK and PK treatments,but decreased in NP and NPK treatments.The treatment with NPK combination was found to improve the yield of forage,nutrient uptake and soil fertility in sudangrass and ryegrass rotation system.

Influence of Seed Priming on Performance and Water Productivity of Direct Seeded Rice in Alternating Wetting and Drying

Direct seeded rice is promising alternative to traditional transplanting, but requires appropriate crop and water management to maintain yield performance and achieve high water productivity. Present study evaluated the effect of seed priming and irrigation on crop establishment, tillering, agronomic traits, paddy yield, grain quality and water productivity of direct seeded rice in alternate wetting and drying （DSR-AWD） in comparison with direct seeded rice at field capacity （DSR- FC）. Seed priming treatments were osmo-priming with KCI （2.2%）, CaCI2 （2.2%） and moringa leaf extracts （MLE, 3.3%） including hydro-priming as control. Among the treatments, seed osmo-primed with MLE emerged earlier and had higher final emergence, followed by osmo-priming with CaCI2. Tillering emergence rate and number of tillers per plant were the highest for seed priming with CaCI2 in DSR- AWD. Total productive and non-productive tillers, panicle length, biological and grain yields, harvest index were highest for seed priming with MLE or CaCI2 in DSR-AWD. Similarly, grain quality, estimated in terms of normal grains, abortive and chalky grains, was also the highest in DSR-AWD with MLE osmo-priming. Benefit cost ratio and water productivity was also the highest in DSR-AWD for seed priming with MLE. In conclusion, seed priming with MLE or CaCI2 can be successfully employed to improve the direct seeded rice performance when practiced with alternate wetting and drying irrigation.

Effect of Phosphorus and Irrigation Levels on Yield,Water Productivity,Phosphorus Use Efficiency and Income of Lowland Rice in Northwest Pakistan

With decreasing availability of water for agriculture and increasing demand for rice production, an optimum use of irrigation water and phosphorus may guarantee sustainable rice production. Field experiments were conducted in 2003 and 2004 to investigate the effect of phosphorus and irrigation levels on yield, water productivity （WP）, phosphorus use efficiency （PUE） and income of low land rice. The experiment was laid out in randomized complete block design with split plot arrangements replicated four times. Main plot consisted of five phosphorus levels, viz. 0 （P0）, 50 （P50）, 100 （P100）, 150 （P15o）, and 200 （P200） kg/hm2, while subplots contained of irrigation times, i.e. 8 （I8）, 10 （I10）, 12 （I12）, and 14 （I14） irrigation levels, each with a water depth of 7.5 cm. Mean values revealed that P150 in combination with I10 produced the highest paddy yield （9.8 t/hm2） and net benefit （1 231.8 US$/hm2） among all the treatments. Phosphorus enhanced WP when applied in appropriate combination with irrigation level. The highest mean WP [13.3 kg/（hm2-mm）] could be achieved at Plso with 18 and decreased with increase in irrigation level, while the highest mean PUE （20.1 kg/kg） could be achieved at P100 with I10 and diminished with higher P levels. The overall results indicate that P150 along with I10 was the best combination for sustainable rice cultivation in silty clay soil.

Effects of mulches on water use in a winter wheat/summer maize rotation system in Loess Plateau, China

Limited water resources often result in reduced crop yield and low water productivity（WP）. In northwestern China, crop production is generally dependent on precipitation. Therefore, a variety of agricultural rainwater harvesting（ARH） techniques have been used for conserving soil moisture, ameliorating soil environment, increasing crop yield, and improving water use efficiency. A two-year（2013–2015） field experiment was conducted under a typical sub-humid drought-prone climate in Yangling（108°24′E, 34°20′N; 521 m a.s.l.）, Shaanxi Province, China, to explore the effects of mulching（same for summer maize and winter wheat） on soil moisture, soil temperature, crop water consumption, and crop yield with a winter wheat/summer maize rotation. Crops were planted in a ridge-furrow pattern and the treatments consisted of a transparent film mulch over the ridges（M1）, a crop straw mulch in the furrows（M2）, a transparent film mulch over the ridges and a crop straw mulch in the furrows（M3）, a black film mulch over the ridges and a crop straw mulch in the furrows（M4）, and a control with no mulch（CK）. Results showed that M4 was the best treatment for improving soil water storage and content, and decreasing crop water consumption during the summer maize and winter wheat rotation. In both maize and wheat seasons, M1 had a higher soil temperature than M2 and CK, and M3 had a higher soil temperature than M4. In the maize seasons, M4 had the highest yield, WP, and precipitation productivity（PP）, with the average values for these parameters increasing by 30.9%, 39.0%, and 31.0%, respectively, compared to those in CK. In the wheat seasons, however, M3 had the highest yield, WP, and PP, with the average values for these parameters being 23.7%, 26.7%, and 23.8% higher, respectively, than those in CK. Annual yield（maize and wheat yields combined） and WP did not differ significantly between M3 and M4. These results suggested that M3 and M4 may thus be the optimal ARH practices for the production of winter wheat and summer maize, respectively, in arid and semi-arid areas.

Detection of Cyanide in Pollution-free Livestock Product Breeding Water by Ion Chromatography

In order to verify the accuracy of ion chromatography for cyanide detection,optimization conditions were studied,and comparison was made for the detection results of cyanide between titration and isonicotinic acid pyrazolone spectrophotometry. The results showed that ion chromatography has good linearity and reproducibility,with the recovery rate of 95%-105% and the limit of detection of 0. 001 mg/L. This method is simple,rapid,safe,selective,and suitable for the determination of cyanide in pollution-free livestock product breeding water.