The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in th...The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.展开更多
The Daxinganling area collided during the Late Paleozoic.The study area Hongwei-Xiongguan-Songheyi Dongshan area is located at the superimposed transition site of the Paleozoic paleo-Asian tectonic-metallogenic domain...The Daxinganling area collided during the Late Paleozoic.The study area Hongwei-Xiongguan-Songheyi Dongshan area is located at the superimposed transition site of the Paleozoic paleo-Asian tectonic-metallogenic domain and the Mesozoic-Cenozoic Pacific Ocean tectonic-mineralization area.It is a good ore-forming fluid channel and has very good ore metallogenic geological conditions.The comprehensive research and metallogenic prediction of the geological background and geochemical characteristics of this area are carried out.It is believed that this area has good prospecting potential,and the prospecting area is circled.Suggestions for further prospecting work in this area are put forward.展开更多
This article is a review and promotion of the study of solutions of differential equations in the “neighborhood of infinity” via a non traditional compactification. We define and compute critical points at infinity ...This article is a review and promotion of the study of solutions of differential equations in the “neighborhood of infinity” via a non traditional compactification. We define and compute critical points at infinity of polynomial autonomuos differential systems and develop an explicit formula for the leading asymptotic term of diverging solutions to critical points at infinity. Applications to problems of completeness and incompleteness (the existence and nonexistence respectively of global solutions) of dynamical systems are provided. In particular a quadratic competing species model and the Lorentz equations are being used as arenas where our technique is applied. The study is also relevant to the Painlevé property and to questions of integrability of dynamical systems.展开更多
Gene editing has recently emerged as a promising technology to engineer genetic modifications precisely in the genome to achieve long-term relief from corneal disorders.Recent advances in the molecular biology leading...Gene editing has recently emerged as a promising technology to engineer genetic modifications precisely in the genome to achieve long-term relief from corneal disorders.Recent advances in the molecular biology leading to the development of clustered regularly interspaced short palindromic repeats(CRISPRs) and CRISPR-associated systems,zinc finger nucleases and transcription activator like effector nucleases have ushered in a new era for high throughput in vitro and in vivo genome engineering.Genome editing can be successfully used to decipher complex molecular mechanisms underlying disease pathophysiology,develop innovative next generation gene therapy,stem cell-based regenerative therapy,and personalized medicine for corneal and other ocular diseases.In this review we describe latest developments in the field of genome editing,current challenges,and future prospects for the development of personalized genebased medicine for corneal diseases.The gene editing approach is expected to revolutionize current diagnostic and treatment practices for curing blindness.展开更多
The Fe-Pb-Zn-Cu polymetallic deposits in the Luziyuan area, are of a sedimentary-reformed type related with magmatic hydrothermalism. Previous researches have suggested that the mineralization is closely related to th...The Fe-Pb-Zn-Cu polymetallic deposits in the Luziyuan area, are of a sedimentary-reformed type related with magmatic hydrothermalism. Previous researches have suggested that the mineralization is closely related to the hidden granites, but little is known about these granites including their burial depth and scale, which has limited the establishment of prospecting models and the optimization of prospecting targets. Geophysical methods have a great exploration depth, and have played a unique role in the prediction of hidden granites. It is shown that granites have low density and high resistivity,展开更多
A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex cr...A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in orthorhombic with space group Pna21, a=0.799 96(16) nm, b=0.823 77(16) nm, c=2.415 3(5) nm, V=1.591 6(6) nm3, Z=4, R=0.030 3, wR=0.070 0. The Ca atom is eight-coordinated by six O atoms of four 2-OPA- ligands and two water molecules, and displays a dodecahedron coordination geometry. Each 2-OPA- ligand bridges two adjacent Ca atoms, forming a infinite chain along the a direction. The Ca...Ca distance is 0.4102 2(8)nm. A two-dimensional supramolecular framework is further constructed by the hydrogen bonds and the weak π-π interactions. The results of TG analysis show the chain structure of the title complex was stable under 297.5 ℃. CCDC: 251669.展开更多
The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted hi...The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.展开更多
In order to overcome the main drawbacks of coaxial, waveguide, and stripline couplers, the analysis and the design of a compact coaxial-to-microstrip directional coupler convenient for power and antenna control applic...In order to overcome the main drawbacks of coaxial, waveguide, and stripline couplers, the analysis and the design of a compact coaxial-to-microstrip directional coupler convenient for power and antenna control application, are presented using the method of moments (MoM) in two dimensions. This technique is adapted to study the complex configuration of the line’s system, which does not have a simple analytical solution. The modeling of this structure consists in analyzing the primary inductive and capacitive matrices ([L] and [C]). When these matrices are determined, it is possible to calculate the inductive and capacitive coupling coefficients (kL and kC) and estimate the resulting scattering parameters of the coupler using an adapted numerical model. The coupler can be integrated into a printed circuit board (PCB) and operates over 17 to 35 dB coupling coefficients and is always compensated. The compensation is achieved by the proper displacement of a tuning ground plane with respect to the edge of the PCB from 0.1 to 3.3 mm. As an application, we present the design of a compact coupler with 7.5 × 4.8 × 25.8 mm of size and having approximately 20 dB of coupling coefficient at 2 GHz and a minimum directivity of 23.3 dB in the frequency range [0.1 - 4] GHz. In order to check our numerical calculations by the MoM we made simulations in 3D by using CST MICROWAVE STUDIO software for the same geometrical and physical parameters of our designed coupler. The results obtained by the two numerical models (MoM and CST) show a good agreement of the frequency responses of the coaxial-to-microstrip directional coupler. The studied structure represents a great improvement for high power measurement systems, since it has broad-band, good directivity, and can be easily designed and fabricated.展开更多
The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density ...The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density functional theory at B3LYP/6-31G* level. The electronic spectrums of the complex and ligand were calculated by ZINDO/S-CIS method. It is indicated from the calculation that: (1) The coordination effect of bridging ligand is bigger than that of chelating one, and the bridging ligands also translate more charge to Zn than the chelating one. (2) The calculated results about electronic spectrums are similarly to experimental measurement, and farther explain that absorption band at λ=267 nm of complex is assigned to two n → π* transitions :one arising from the bridging ligands and the another mainly arising from the chelating ligands;but absorption band at λ=236 nm of complex is assigned to π → π* transition which the electron mainly translates from the bridging ligands to the chelating ligands. (3) By consideration of delocalization and polar effects in coordination, the charge transfer from ligand to metal decreases the π-π and p-π conjugation effects in the chromophore group NCS2 and to increase the energy needed for the π → π* and n → π* transitions, and results in the absorption bands shifting towards the short wavelength direction.展开更多
This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technol...This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.展开更多
Recently, a number of large molybdenum (-copper) deposits have been discovered successively in the Laba area, Shangri-La county, northwestern Yunnan province. The investigation confirmed that there is a superlarge por...Recently, a number of large molybdenum (-copper) deposits have been discovered successively in the Laba area, Shangri-La county, northwestern Yunnan province. The investigation confirmed that there is a superlarge porphyry-skarn hydrothermal vein type molybdenum-polymetallic- metallogenic system with the total prediction reservoir of more than 150 mt molybdenum. The porphyry intrusions contributed to the mineralization closely, the superficial little vein molybdenum (-copper, lead, silver) ore-bodies are usually located in faults and fractures, and the deep porphyry type ore-bodies occurred in the granodiorite porphyries, the skarn type ore-bodies occurred in the contact zone intrused into Triassic limestone or Permian basalts. Laba ore block is a new exploration area with great prospecting potential. In order to reduce the target area and guide the further exploration work, the magnetic method measurement about 3.3 square kilometres was carried out in the ore field. This paper presents an application of analyzing the horizontal and vertical derivative, using Fast Fourier Transform (FFT) filter (FFT high-pass, low-pass, cosine roll-off, suscepbility), calculated spectra frequency energy to predict the depth and intensity of the apparent remanence magnetization of source (Hilbert). The calculated results and magnetic anomalous show that the remanence anomaly is caused by the intrusions into the Triassic limestone and Permian basalts with small anomalies, and the depth of located source is not great. We have identified a number of positions to the three drilled well, the drilled result specify interpretation with very high accuracy. The magnetic method is helpful to identify porphyry mineralization, and judge the shape and depth of the concealed ore-bearing intrusive bodies under the similar geological condition.展开更多
This paper is based on the analysis and research on the silver-lead-zinc polymetallic ore in New Ballyhoo Banner in southern Manzhouli of Inner Mongolia.Because metal mineralization brings rock formations,the geophysi...This paper is based on the analysis and research on the silver-lead-zinc polymetallic ore in New Ballyhoo Banner in southern Manzhouli of Inner Mongolia.Because metal mineralization brings rock formations,the geophysical features such as low resistivity,high polarization rate and uneven distribution of magnetization,the comprehensive geophysical methods are adopted including high-precision magnetic measurement,high-power induced polarization,IP field middle gradient and controlled source audio-frequency magnetotellurics.In the survey work of multi-metal ore deposits,from surface sweeping to single point measurement,and from single point to section going deeper layer by layer,the resolution of measurement is continuously improved,and various geophysical methods support and complement each other,so explorers can successfully predict the direction,scale and volume of the metallogenic belts in conjunction with geochemical exploration,geological survey and drilling.It has provided a strong basis for completing the exploration task of predicting the reserve volume of ore bodies.The research conclusions of this exploration case have thus a high reference value in the same type of exploration work.展开更多
An increasing number of tunnels are being constructed with tunnel-boring machines (TBMs) due to the increased efficiency and shorter completion time resulting from their use. However, when a TBM encoun- ters adverse...An increasing number of tunnels are being constructed with tunnel-boring machines (TBMs) due to the increased efficiency and shorter completion time resulting from their use. However, when a TBM encoun- ters adverse geological conditions in the course of tunnel construction (e.g., karst caves, faults, or frac- tured zones), disasters such as water and mud inrush, collapse, or machine blockage may result, and may severely imperil construction safety. Therefore, the advance detection of adverse geology and water-bearing conditions in front of the tunnel face is of great importance. This paper uses the TBM tun- neling of the water conveyance project from Songhua River as a case study in order to propose a compre- hensive forward geological prospecting technical system that is suitable for TBM tunnel construction under complicated geological conditions. By combining geological analysis with forward geological prospecting using a three-dimensional (3D) induced polarization method and a 3D seismic method, a comprehensive forward geological prospecting technical system can accurately forecast water inrush geo-hazards or faults in front of the TBM tunnel face. In this way, disasters such as water and mud inrush, collapse, or machine blockage can be avoided. This prospecting technical system also has reference value for carrying out the forward prospecting of adverse geology for potential TBM tunneling and for ensuring that a TBM can work efficiently.展开更多
基金funded by the project titled Prospect Survey and Exploration Demonstration of Hardrock Mineral Resources such as Uranium and Thorium(12120115014101)initiated by the Tianjin Center of China Geological Survey.The data and achievements cited in this paper are mainly from relevant scientific research,geological survey,and mineral exploration projects undertaken by the No.302 Brigade of Hunan Nuclear Industry Geology Bureau in recent years.
文摘The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.
文摘The Daxinganling area collided during the Late Paleozoic.The study area Hongwei-Xiongguan-Songheyi Dongshan area is located at the superimposed transition site of the Paleozoic paleo-Asian tectonic-metallogenic domain and the Mesozoic-Cenozoic Pacific Ocean tectonic-mineralization area.It is a good ore-forming fluid channel and has very good ore metallogenic geological conditions.The comprehensive research and metallogenic prediction of the geological background and geochemical characteristics of this area are carried out.It is believed that this area has good prospecting potential,and the prospecting area is circled.Suggestions for further prospecting work in this area are put forward.
文摘This article is a review and promotion of the study of solutions of differential equations in the “neighborhood of infinity” via a non traditional compactification. We define and compute critical points at infinity of polynomial autonomuos differential systems and develop an explicit formula for the leading asymptotic term of diverging solutions to critical points at infinity. Applications to problems of completeness and incompleteness (the existence and nonexistence respectively of global solutions) of dynamical systems are provided. In particular a quadratic competing species model and the Lorentz equations are being used as arenas where our technique is applied. The study is also relevant to the Painlevé property and to questions of integrability of dynamical systems.
文摘Gene editing has recently emerged as a promising technology to engineer genetic modifications precisely in the genome to achieve long-term relief from corneal disorders.Recent advances in the molecular biology leading to the development of clustered regularly interspaced short palindromic repeats(CRISPRs) and CRISPR-associated systems,zinc finger nucleases and transcription activator like effector nucleases have ushered in a new era for high throughput in vitro and in vivo genome engineering.Genome editing can be successfully used to decipher complex molecular mechanisms underlying disease pathophysiology,develop innovative next generation gene therapy,stem cell-based regenerative therapy,and personalized medicine for corneal and other ocular diseases.In this review we describe latest developments in the field of genome editing,current challenges,and future prospects for the development of personalized genebased medicine for corneal diseases.The gene editing approach is expected to revolutionize current diagnostic and treatment practices for curing blindness.
文摘The Fe-Pb-Zn-Cu polymetallic deposits in the Luziyuan area, are of a sedimentary-reformed type related with magmatic hydrothermalism. Previous researches have suggested that the mineralization is closely related to the hidden granites, but little is known about these granites including their burial depth and scale, which has limited the establishment of prospecting models and the optimization of prospecting targets. Geophysical methods have a great exploration depth, and have played a unique role in the prediction of hidden granites. It is shown that granites have low density and high resistivity,
文摘A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in orthorhombic with space group Pna21, a=0.799 96(16) nm, b=0.823 77(16) nm, c=2.415 3(5) nm, V=1.591 6(6) nm3, Z=4, R=0.030 3, wR=0.070 0. The Ca atom is eight-coordinated by six O atoms of four 2-OPA- ligands and two water molecules, and displays a dodecahedron coordination geometry. Each 2-OPA- ligand bridges two adjacent Ca atoms, forming a infinite chain along the a direction. The Ca...Ca distance is 0.4102 2(8)nm. A two-dimensional supramolecular framework is further constructed by the hydrogen bonds and the weak π-π interactions. The results of TG analysis show the chain structure of the title complex was stable under 297.5 ℃. CCDC: 251669.
基金This work is financially supported by the Special Fund for Foreign Mineral Resources Risk Exploration(201210B01600234).
文摘The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.
文摘In order to overcome the main drawbacks of coaxial, waveguide, and stripline couplers, the analysis and the design of a compact coaxial-to-microstrip directional coupler convenient for power and antenna control application, are presented using the method of moments (MoM) in two dimensions. This technique is adapted to study the complex configuration of the line’s system, which does not have a simple analytical solution. The modeling of this structure consists in analyzing the primary inductive and capacitive matrices ([L] and [C]). When these matrices are determined, it is possible to calculate the inductive and capacitive coupling coefficients (kL and kC) and estimate the resulting scattering parameters of the coupler using an adapted numerical model. The coupler can be integrated into a printed circuit board (PCB) and operates over 17 to 35 dB coupling coefficients and is always compensated. The compensation is achieved by the proper displacement of a tuning ground plane with respect to the edge of the PCB from 0.1 to 3.3 mm. As an application, we present the design of a compact coupler with 7.5 × 4.8 × 25.8 mm of size and having approximately 20 dB of coupling coefficient at 2 GHz and a minimum directivity of 23.3 dB in the frequency range [0.1 - 4] GHz. In order to check our numerical calculations by the MoM we made simulations in 3D by using CST MICROWAVE STUDIO software for the same geometrical and physical parameters of our designed coupler. The results obtained by the two numerical models (MoM and CST) show a good agreement of the frequency responses of the coaxial-to-microstrip directional coupler. The studied structure represents a great improvement for high power measurement systems, since it has broad-band, good directivity, and can be easily designed and fabricated.
文摘The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density functional theory at B3LYP/6-31G* level. The electronic spectrums of the complex and ligand were calculated by ZINDO/S-CIS method. It is indicated from the calculation that: (1) The coordination effect of bridging ligand is bigger than that of chelating one, and the bridging ligands also translate more charge to Zn than the chelating one. (2) The calculated results about electronic spectrums are similarly to experimental measurement, and farther explain that absorption band at λ=267 nm of complex is assigned to two n → π* transitions :one arising from the bridging ligands and the another mainly arising from the chelating ligands;but absorption band at λ=236 nm of complex is assigned to π → π* transition which the electron mainly translates from the bridging ligands to the chelating ligands. (3) By consideration of delocalization and polar effects in coordination, the charge transfer from ligand to metal decreases the π-π and p-π conjugation effects in the chromophore group NCS2 and to increase the energy needed for the π → π* and n → π* transitions, and results in the absorption bands shifting towards the short wavelength direction.
文摘This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.
文摘Recently, a number of large molybdenum (-copper) deposits have been discovered successively in the Laba area, Shangri-La county, northwestern Yunnan province. The investigation confirmed that there is a superlarge porphyry-skarn hydrothermal vein type molybdenum-polymetallic- metallogenic system with the total prediction reservoir of more than 150 mt molybdenum. The porphyry intrusions contributed to the mineralization closely, the superficial little vein molybdenum (-copper, lead, silver) ore-bodies are usually located in faults and fractures, and the deep porphyry type ore-bodies occurred in the granodiorite porphyries, the skarn type ore-bodies occurred in the contact zone intrused into Triassic limestone or Permian basalts. Laba ore block is a new exploration area with great prospecting potential. In order to reduce the target area and guide the further exploration work, the magnetic method measurement about 3.3 square kilometres was carried out in the ore field. This paper presents an application of analyzing the horizontal and vertical derivative, using Fast Fourier Transform (FFT) filter (FFT high-pass, low-pass, cosine roll-off, suscepbility), calculated spectra frequency energy to predict the depth and intensity of the apparent remanence magnetization of source (Hilbert). The calculated results and magnetic anomalous show that the remanence anomaly is caused by the intrusions into the Triassic limestone and Permian basalts with small anomalies, and the depth of located source is not great. We have identified a number of positions to the three drilled well, the drilled result specify interpretation with very high accuracy. The magnetic method is helpful to identify porphyry mineralization, and judge the shape and depth of the concealed ore-bearing intrusive bodies under the similar geological condition.
基金supported by Investigation and Evaluation of Groundwater Resources and Environmental Problems in Hetao Plain (Geological Survey Program, Grant No.1212010913010)
文摘This paper is based on the analysis and research on the silver-lead-zinc polymetallic ore in New Ballyhoo Banner in southern Manzhouli of Inner Mongolia.Because metal mineralization brings rock formations,the geophysical features such as low resistivity,high polarization rate and uneven distribution of magnetization,the comprehensive geophysical methods are adopted including high-precision magnetic measurement,high-power induced polarization,IP field middle gradient and controlled source audio-frequency magnetotellurics.In the survey work of multi-metal ore deposits,from surface sweeping to single point measurement,and from single point to section going deeper layer by layer,the resolution of measurement is continuously improved,and various geophysical methods support and complement each other,so explorers can successfully predict the direction,scale and volume of the metallogenic belts in conjunction with geochemical exploration,geological survey and drilling.It has provided a strong basis for completing the exploration task of predicting the reserve volume of ore bodies.The research conclusions of this exploration case have thus a high reference value in the same type of exploration work.
文摘An increasing number of tunnels are being constructed with tunnel-boring machines (TBMs) due to the increased efficiency and shorter completion time resulting from their use. However, when a TBM encoun- ters adverse geological conditions in the course of tunnel construction (e.g., karst caves, faults, or frac- tured zones), disasters such as water and mud inrush, collapse, or machine blockage may result, and may severely imperil construction safety. Therefore, the advance detection of adverse geology and water-bearing conditions in front of the tunnel face is of great importance. This paper uses the TBM tun- neling of the water conveyance project from Songhua River as a case study in order to propose a compre- hensive forward geological prospecting technical system that is suitable for TBM tunnel construction under complicated geological conditions. By combining geological analysis with forward geological prospecting using a three-dimensional (3D) induced polarization method and a 3D seismic method, a comprehensive forward geological prospecting technical system can accurately forecast water inrush geo-hazards or faults in front of the TBM tunnel face. In this way, disasters such as water and mud inrush, collapse, or machine blockage can be avoided. This prospecting technical system also has reference value for carrying out the forward prospecting of adverse geology for potential TBM tunneling and for ensuring that a TBM can work efficiently.