The thiourea leaching of gold from the calcine of gold-bearing arsenical pyrite concentrate of Kangjiawan mine was studied.The effects of the leaching time,the concentrations of thiourea,hydrochloric acid and initial ...The thiourea leaching of gold from the calcine of gold-bearing arsenical pyrite concentrate of Kangjiawan mine was studied.The effects of the leaching time,the concentrations of thiourea,hydrochloric acid and initial ferric ion on the leaching recovery of gold were investigated,and a regressive model has been established,which showed that the concentrations of thiourea and hydrochloric acid were the most important factors,leaching time the second,and concentration of the initial ferric ion the least・Under the optimal conditions,that is,temperature 50℃,the ratio of liquid to solid 4:1,thiourea 12g/L,hydrochloric acid 1 mol/L,and initial ferric ion 1 g/L,the leaching recoveries of gold and silver were more than 81%and 73%,respectively.The increase of silver recovery and the reduction of thiourea consumption could be attained when sodium sulphite was added.展开更多
The xenoliths in host rocks of hydrothermal gold deposits can generally provide much geochemical information of the deep rocks, which may have an implication for the sources of ore-forming materials. Geochronology and...The xenoliths in host rocks of hydrothermal gold deposits can generally provide much geochemical information of the deep rocks, which may have an implication for the sources of ore-forming materials. Geochronology and geochemical characteristics are reported for a granite xenolith, which is enclosed by the lamprophyre in the Zhenyuan gold deposit(Yunnan Province, SW China). This granite xenolith mainly consists of K-feldspar, quartz, and plagioclase with trace amounts of magnetite, titanite, apatite, zircon, and sulfides. Zircons from the granite xenolith yield a weighted average U-Pb age of 281.1 ± 1.3 Ma(MSWD = 2.1), which could represent the crystallization age of this granite xenolith. The Ti-in-zircon geothermometer and the Mn concentration in apatite calculate that this granite xenolith formed at 685 ± 43℃ with the logf_(O2) values ranging from NNO + 3.7 to NNO + 6.4. The zircons in the granite xenolith have a restricted range of positive ε_(Hf)(t) values ranging from +9.4 to +10.8, and the corresponding Hf TDM2 model ages range from 588 to 678 Ma. The zircon U-Pb age and the Hf isotopic compositions indicate this granite xenolith within the lamprophyre is mainly derived from partial melting of juvenile crustal rocks before the completed closure of the Ailaoshan Ocean. The pyrites in the granite xenolith have higher Bi concentrations, and lower As, Sb, and Tl concentrations than the gold-bearing pyrites of the ores in the Zhenyuan gold deposit. The low Au concentrations of the pyrites together with the ore-forming age of the Zhenyuan gold deposit(Oligocene) indicate the granite xenolith may have limited contribution to the gold mineralization of the Zhenyuan gold deposit.展开更多
文摘The thiourea leaching of gold from the calcine of gold-bearing arsenical pyrite concentrate of Kangjiawan mine was studied.The effects of the leaching time,the concentrations of thiourea,hydrochloric acid and initial ferric ion on the leaching recovery of gold were investigated,and a regressive model has been established,which showed that the concentrations of thiourea and hydrochloric acid were the most important factors,leaching time the second,and concentration of the initial ferric ion the least・Under the optimal conditions,that is,temperature 50℃,the ratio of liquid to solid 4:1,thiourea 12g/L,hydrochloric acid 1 mol/L,and initial ferric ion 1 g/L,the leaching recoveries of gold and silver were more than 81%and 73%,respectively.The increase of silver recovery and the reduction of thiourea consumption could be attained when sodium sulphite was added.
基金supported by the National Natural Science Foundation of China (Grant Nos. 91962105, 41802113)the Fundamental Research Funds for the Central Universities (Grant No.2019B08214)a grant from Jiangsu Provincial “Double Innovation Doctors” Program (Grant No.(2020) 30462)。
文摘The xenoliths in host rocks of hydrothermal gold deposits can generally provide much geochemical information of the deep rocks, which may have an implication for the sources of ore-forming materials. Geochronology and geochemical characteristics are reported for a granite xenolith, which is enclosed by the lamprophyre in the Zhenyuan gold deposit(Yunnan Province, SW China). This granite xenolith mainly consists of K-feldspar, quartz, and plagioclase with trace amounts of magnetite, titanite, apatite, zircon, and sulfides. Zircons from the granite xenolith yield a weighted average U-Pb age of 281.1 ± 1.3 Ma(MSWD = 2.1), which could represent the crystallization age of this granite xenolith. The Ti-in-zircon geothermometer and the Mn concentration in apatite calculate that this granite xenolith formed at 685 ± 43℃ with the logf_(O2) values ranging from NNO + 3.7 to NNO + 6.4. The zircons in the granite xenolith have a restricted range of positive ε_(Hf)(t) values ranging from +9.4 to +10.8, and the corresponding Hf TDM2 model ages range from 588 to 678 Ma. The zircon U-Pb age and the Hf isotopic compositions indicate this granite xenolith within the lamprophyre is mainly derived from partial melting of juvenile crustal rocks before the completed closure of the Ailaoshan Ocean. The pyrites in the granite xenolith have higher Bi concentrations, and lower As, Sb, and Tl concentrations than the gold-bearing pyrites of the ores in the Zhenyuan gold deposit. The low Au concentrations of the pyrites together with the ore-forming age of the Zhenyuan gold deposit(Oligocene) indicate the granite xenolith may have limited contribution to the gold mineralization of the Zhenyuan gold deposit.
