Temperature dependence of microscopic properties in diblock copolymer films:A dissipative particle dynamics simulation

Temperature dependence of microscopic properties in diblock copolymer films has been investigated by dissipative particle dynamics simulations. Results show the relation between mean-square bond length （MSBL） and system temperature can be described as a quadratic curve. The root-mean-square radius of gyration （RMSGR） and end-end distance （RMSED） increase gradually as the temperature rises and composition fraction changes from 0.1 to 0.5, in which the effect of the former is primary. Especially, the relation between RMSGR and temperature is nearly linear in the confinement-introduced direction. Density distribution of each component in the films can be controlled and adjusted effectively by its interaction with other components and boundaries. Moreover, the changes of system temperature and composition fraction can both affect the density distributions to a certain extent.

Retrieval of inherent optical properties of the Yellow Sea and East China Sea using a quasi-analytical algorithm

We tested and modified the quasi-analytical algorithm (QAA) using 57 groups of field data collected in the spring of 2003 in the Yellow Sea and East China Sea. The QAA performs well in deriving total absorption coefficients of typical coastal waters. The average percentage difference (APD) is in a range of 13.9%–38.5% for the total absorption coefficient (13.9% at 440 nm), and differences in particle backscattering coefficient bbp(λ) are less than 50% (in the case of the updated QAA). To obtain improved results, we modified the QAA by adjusting the empirical relationships. The modified algorithm is then applied to the field data to test its performance. The APDs were 44.7%–46.6% for bbp(λ) and 9.9%–32.8% (9.9% at 555 nm) for the total absorption coefficient. This indicates that the modified QAA derives better results. We also used the modified model to derive phytoplankton pigment absorption (aph) and detritus and CDOM absorption (adg) coefficients. The APDs for aph and adg at 440 nm are 37.1% and 19.8%. In this paper, we discuss error sources using the measured dataset. More independent field data can improve this algorithm and derive better results.

Effects of spherical quasi-crystal on microstructure and mechanical properties of ZA155 high zinc magnesium alloy

Effects of spherical quasi-crystal contained in Mg-Zn-Y-Mn master alloy on the microstructure and as-cast mechanical properties of ZA155 high zinc magnesium alloy have been investigated by means of optical microscopy,XRD,SEM,EDS,tensile test,impact test and hardness test.Experimental results show that the addition of spherical quasi-crystal contained in the Mg-Zn-Y-Mn master alloy into the ZA155 high zinc magnesium alloy resulted in grain refinement of the matrix,changing the morphologies of φ-Al2Mg5Zn2 phase and τ-Mg32(Al,Zn)49 phase from continuous net-like structures to discontinuous strip-like structure and blocky one,respectively.In the present research,the best comprehensive mechanical properties of reinforced ZA155 high zinc magnesium alloy has been obtained when 5.0wt% spherical quasi-crystal was introduced from the Mg-Zn-Y-Mn master alloy into the target alloy system.In such case,the room-temperature tensile strength reached 207 MPa,about 23% higher than that of the base alloy;the impact toughness peaked at 5.5 J/cm2,about 40% higher than that of the base alloy;and the elevated-temperature tensile strength reached 203 MPa,indicating improved heat resistance.

Carbon materials with quasi-graphene layers:The dielectric,percolation properties and the electronic transport mechanism

We investigate the dielectric properties of multi-walled carbon nanotubes（MWCNTs） and graphite filling in SiO2 with the filling concentration of 2-20 wt.% in the frequency range of 10 ^2-10^ 7 Hz.MWCNTs and graphite have general electrical properties and percolation phenomena owing to their quasi-structure made up of graphene layers.Both permittivity ε and conductivity σ exhibit jumps around the percolation threshold.Variations of dielectric properties of the composites are in agreement with the percolation theory.All the percolation phenomena are determined by hopping and migrating electrons,which are attributed to the special electronic transport mechanism of the fillers in the composites.However,the twin-percolation phenomenon exists when the concentration of MWCNTs is between 5-10 wt.% and 15-20 wt.% in the MWCNTs/SiO2 composites,while in the graphite/SiO2 composites,there is only one percolation phenomenon in the graphite concentration of 10-15 wt.%.The unique twin-percolation phenomenon of MWCNTs/SiO2 is described and attributed to the electronic transfer mechanism,especially the network effect of MWCNTs in the composites.The network formation plays an essential role in determining the second percolation threshold of MWCNTs/SiO2.

A Class of Complex Quasi-Orlicz Spaces and Their Analytic RN Property

Let X be a complex quasi Banach space and Φ:[0,∞)→[0,∞) an increasing convex function with Φ(0)=0 , lim t→∞Φ(t)=∞ and Φ∈Δ 2 . Then L * Φ(X) is a quasi Banach space with continuous quasi norm and L * Φ(X) has the ARNP if and only if X does.

Effect of Improving the Slip Properties of the Organic Materials on the Inorganic Filler in Heat Dissipated Pad

The heat dissipated pad is made of composite mixing silicon or epoxy resin with thermal conductive inorganic fillers. The heat-dissipation material improves performance as the amount of thermal conductivity filler increases. However, the optimum recipe should be determined by considering the price and pad formability. In this study, high performance thermal pad is made of silicon resin mixed with Al2O3 as a thermally conductive filler. Since Al2O3 is low cost, it can use much filler. Al2O3 has improved slip-ability with organic coating on it to increase the viscosity of the slurry. The same process and the same recipe, could maximize the amount of the filler. As a result, the thermal conductivity is lower by 10%. But the viscosity is reduced by 60%, too. So form-ability is getting priority.

Study on Thermodynamic Properties of Lithium by First-principles and Quasi-harmonic Debye Model

In this paper, the lattice parameter and bulk modulus of lithium(Li) at different pressures and temperatures are calculated by using the density functional theory method within the generalized gradient approximation(GGA).Through the quasi-harmonic Debye model, the thermodynamic properties of Li are predicted. The dependences of the normalized primitive cell volume V/V0 on pressure P, the variation of the thermal expansion coefficient α with pressure P and temperature T, as well as the dependences of the heat capacity Cv on pressure P and temperature T are obtained systematically in the ranges of 0~100 GPa and 0~2 000 K.

Mechanical and hydraulic properties of fault rocks under multi‑stage cyclic loading and unloading

The rock mass in fault zones is frequently subjected to cyclic loading and unloading during deep resource exploitation and tunnel excavation.Research on the mechanical and hydraulic characteristics of fault rock during the cyclic loading and unloading is of great signifcance for revealing the formation mechanism of water-conducting pathways in fault and preventing water inrush disasters.In this study,the mechanical and seepage tests of fault rock under the multi-stage cyclic loading and unloading of axial compression were carried out by using the fuid–solid coupling triaxial experimental device.The hysteresis loop of the stress–strain curve,peak strain rate,secant Young's modulus,and permeability of fault rock were obtained,and the evolution law of the dissipated energy of fault rock with the cyclic number of load and unloading was discussed.The experimental results show that with an increase in the cyclic number of loading and unloading,several changes occur.The hysteresis loop of the stress–strain curve of the fault rock shifts towards higher levels of strain.Additionally,both the peak strain rate and the secant Young's modulus of the fault rock increase,resulting in an increase in the secant Young's modulus of the fault rock mass.However,the growth rate of the secant Young's modulus gradually slows down with the increase of cyclic number of loading and unloading.The permeability evolution of fault rock under the multi-stage cyclic loading and unloading of axial compression can be divided into three stages:steady increase stage,cyclic decrease stage,and rapid increase stage.Besides,the calculation model of dissipated energy of fault rock considering the efective stress was established.The calculation results show that the relationship between the dissipated energy of fault rock and the cyclic number of loading and unloading conforms to an exponential function.

Experimental Investigation on Compressive Properties of Fiber Recycled Aggregate Concrete

This paper presents an experimental study to explore the compressive properties of fiber recycled aggregate concrete.A total of 75 specimens with the replacement rate of recycled coarse aggregate and fiber type were conducted under a uniaxial compressive test.The failure modes,stress-strain whole curves,peak stress,peak strain,and energy dissipation capacity were systematically observed and revealed.Test results indicate that steel fiber has the best modification effect on energy dissipation capacity and the toughness index of recycled concrete,corresponding to the enhancement of 81.75% and 22.90% on average.The addition of polyvinyl alcohol fiber can effectively improve the compressive strength and energy dissipation capacity of recycled aggregate concrete by 28.49% and 29.43% on average,respectively.The compressive strength and energy dissipation capacity of recycled aggregate concrete is increased by an average of 16.5% and 24.4% by incorporating carbon fiber.The energy dissipation capacity of recycled aggregate concrete is increased by an average of 13.5% with the incorporation of polypropylene fiber.However,the addition of carbon fiber results in a slight reduction of toughness by 16.97%,and the effect of polyvinyl alcohol fiber on the energy dissipation capacity is limited.Besides,with the increase in replacement rate,the compressive strength and the energy dissipation capacity of recycled coarse aggregate concrete with fiber decreased,and toughness first decreased and then increased.Finally,based on the analysis of test data,a segment-based stress-strain model of fiber recycled aggregate concrete was proposed,which shows good agreement with the test results.

Private Rights Absorbed in Quasi-public Goods: A Probe into the Relationship of Intellectual Property Rights and Standardization

Standards are a double edge sword and have come to be the main technical tariff and a window for market access to international trade. Standards are closely related to intellectual property, especially patents. The essence of intellectual property in standardization lies in the fact that standards are a kind of quasi-public good, while patents are essentially private property. The absorption of patents into standards creates an opportunity for a patent holder to take advantage by making a profit. To prevent the abuse of patents in standards by the patent holder, SDOs (Standards Development Organizations) have to adjust the disclosure policies of the standards in patents.

The Properties of k-quasi-＊-A（n） Operator

An operator T is called k-quasi-*-A(n) operator, if T^(*k)|T^(1+n)|^(2/(1+n))T^k ≥T^(*k)|T~* |~2T^k , k ∈ Z, which is a generalization of quasi-*-A(n) operator. In this paper we prove some properties of k-quasi-*-A(n) operator, such as, if T is a k-quasi-*-A(n) operator and N(T )■N(T~* ), then its point spectrum and joint point spectrum are identical. Using these results, we also prove that if T is a k-quasi-*-A(n) operator and N(T )■N(T ), then the spectral mapping theorem holds for the Weyl spectrum and for the essential approximate point spectrum.

预制孔洞煤样冲击力学特性及能量耗散试验研究

为研究冲击载荷下预制孔洞煤样力学特性及能量耗散规律,制备含轴向孔洞的直径50 mm,高50 mm圆柱体煤样,利用分离式霍普金森压杆(SHPB)装置,开展8个孔洞尺寸和3个冲击气压水平的加载试验研究,借助平面场应变测量技术(VIC-2D)和高速摄像机,分析了冲击加载过程中试件动态应力、动态应变、裂纹演化、破坏失效及能量耗散特性。结果表明:①在试验涉及的孔洞直径范围内,冲击载荷下完整与孔洞煤样动态应力-应变过程均呈现微裂隙压密阶段、弹性阶段、塑性阶段和破坏阶段。同一冲击气压下,随孔径增大,煤样动态抗压强度、动态峰值应变均降低;孔径由0增大至8 mm时,煤样动态抗压强度和峰值应变下降出现快-慢分区特征。与完整煤样以拉伸裂纹破坏为主不同,孔洞煤样主要以拉伸裂纹-剪切裂纹复合破坏为主,且随着孔径增加,试件内部裂纹扩展能力变弱。②揭示了冲击载荷下孔洞煤样的能量耗散规律:孔洞煤样透射能、吸收能与孔径呈负相关,反射能与孔径呈正相关,这主要由孔洞改变试件过波面积造成。随孔径增大,煤样过波面积降低,其吸收能和透射能随之降低,与冲击载荷下孔洞煤样破碎度与孔径负相关结论相一致。研究成果有利于明晰冲击地压巷道钻孔卸压机理,为冲击地压防治提供理论支持。

采用大直径灌浆套筒连接的预制桥墩抗震性能研究

为探究墩台处采用大直径灌浆套筒连接的预制装配式桥墩抗震性能,进行拟静力试验及有限元分析。设计、制作2个采用大直径灌浆套筒(主筋直径40 mm)连接的预制装配式桥墩(预制桥墩)及1个现浇桥墩开展拟静力试验,对2类试件的试验现象、破坏形态、滞回曲线和承载能力进行对比分析,并采用有限元法对预制桥墩混凝土、套筒及连接钢筋的受力性能进行研究。试验结果表明:在水平循环荷载作用下,预制桥墩与现浇桥墩一致表现为弯剪破坏,但墩底区域破坏形式不同,现浇桥墩主要表现为柱脚混凝土大面积压碎,而预制桥墩的破坏现象更为严重,集中表现为套筒四周混凝土成块压碎剥落;相较于现浇桥墩,预制桥墩的承载能力平均值偏小5.2%,位移延性系数平均值偏小2.7%,预制桥墩力学性能与现浇桥墩相当。有限元分析结果表明:预制桥墩会在套筒顶部和桥墩底部出现2个塑性区,且预制桥墩中大直径灌浆套筒的受力状态以轴向受力为主,按照轴向受力进行套筒设计可满足其在桥墩结构中的受力要求;预制桥墩在墩底混凝土破坏后,其主筋和灌浆料仍保持可靠粘结,采用大直径灌浆套筒连接的预制桥墩抗震性能良好。

中空波纹夹层钢管混凝土柱抗震性能拟静力试验研究

为了研究中空波纹夹层钢管混凝土柱的抗震性能,以轴压比、空心率、长细比和截面形式为试验参数,开展了中空波纹夹层钢管混凝土柱的拟静力试验,分析了试件的破坏模式、承载能力、延性与耗能能力、刚度退化和强度退化等性能指标.结果表明:中空波纹夹层钢管混凝土柱的水平承载力较高,滞回曲线饱满,无明显捏缩现象,延性和耗能能力良好,同级循环荷载作用下性能稳定;试件的破坏模式为延性破坏,具体表现为柱底钢管鼓曲变形、混凝土压溃、局部缺陷处管壁撕裂;空心率较小的试件承载力较高,耗能能力较强;当长细比由20增至30时,试件位移延性系数降低了47.49%,承载力也明显下降;随着轴压比的增大,试件耗能能力逐渐降低.

正交胶合木新型抗剪及抗拉连接耗能特性试验

连接节点是保证木结构抗震性能的重要因素,节点的耗能能力是衡量其是否适用于抗震区的重要指标。提出了适用于正交胶合木(cross laminated timber,CLT)结构的新型耗能抗剪连接节点和新型耗能抗拉连接节点,为研究该类连接节点的破坏模式及力学性能,开展了15组低周往复加载试验。试验结果表明,新型耗能连接节点试件延性系数(D)均大于9.0,满足欧洲规范Eurocode 8中对高延性节点D>6的要求,属于高延性范围;新型耗能连接节点工作阶段强度退化系数均低于20%,具备工程适用性;新型耗能连接节点工作阶段等效黏滞阻尼系数为12%~22%,普通商用连接节点等效黏滞阻尼系数为2.5%~15.8%,两类新型耗能连接节点具有较好的耗能能力。

BFRP复材的体育器械连接部用胶技术与粘接性能分析

为扩大BFRP在体育器械生产加工领域的应用范围,实现BFRP与传统铝合金材料之间的有效连接,研究提出了一项基于胶粘剂的基板材料连接方案。采用Araldite 2015高韧性胶粘剂和回天7130高模量脆性胶粘剂对BFRP和5052-H32铝合金2种基板材料进行胶粘连接处理,通过准静态加载试验的方式来测试该方案的应用效果。结果表明,具有高模量脆性的回天7130胶粘剂能够显著提升基板试件接头的力学性能,充分发挥5052-H32铝合金基板的初始刚度优势以及BFRP基板的峰值荷载优势,有助于BFRP基板在结构更加复杂的体育器械中广泛应用,推动体育器械朝向小型化、轻量化的方向发展。

梯形消能墩组合式台阶消能工水力特性

为了提高溢洪道的消能效果,降低台阶面负压,该研究提出了消能墩与台阶组合的消能工布置形式,在台阶凸角处布置梯形消能墩。通过模型试验与数值模拟的方法,研究单排布置与单排交错布置下组合式台阶消能工的流态、流速、压强和消能率,并与传统台阶消能工的水力特性对比。结果表明,组合式台阶消能工与传统台阶消能工水流流态基本相同,在凸角布置消能墩产生雍水作用,水流更为平缓;在靠近台阶水面位置,组合式台阶消能工水流流速相较于传统台阶消能工降低54%,并且各体型台阶消能工断面流速遵循底层小、表层大的规律;组合式台阶消能工的台阶水平面与竖直面在靠近凸角附近存在负压,且相较于传统台阶消能工在竖直面上负压范围缩小60%~70%;相对临界水深由0.714增大到1.486时,组合式台阶消能工较传统消能工消能率下降幅度小,且在相对水深较大的情况下消能率仍可达到70%以上,具有更好的消能特性,可为台阶溢洪道的相关工程提供参考依据。

改性氮化硼/水性聚氨酯导热复合材料的制备与表征

以氮化硼为原料,用γ-氨丙基三乙氧基硅烷对其进行氨基化改性,利用水解产生的硅羟基和氮化硼烯表面的含氧官能团进行缩合反应后,得到改性导热填料。将其与水性聚氨酯乳液原位聚合,制备改性氮化硼/水性聚氨酯复合乳液,室温干燥成膜后得到胶膜样品。分析了填料含量对复合胶膜结构、机械性能、导热性能和热稳定性等性能的影响,并分析其作为热界面材料的散热效果。结果表明:改性后的胶膜拉伸强度、断裂伸长率、导热性能和热稳定性都能得到明显的提升。当填料质量分数为15%时,复合胶膜较纯胶膜热源温度降低了2.2℃,界面间传热效率得到提高。

SiC基GaN上多晶金刚石散热膜生长及其影响

通过微波等离子体化学气相沉积(MPCVD)法,在SiC基GaN高电子迁移率晶体管(HEMT)异质结构材料上生长多晶金刚石散热膜,采用光学显微镜(OM)、拉曼光谱、非接触霍尔测试系统、X射线衍射(XRD)和扫描电子显微镜(SEM)对生长样品进行表征,研究了生长温度、多晶金刚石散热膜厚度对GaN HEMT异质结构材料性能的影响。测试结果表明,当多晶金刚石生长温度为625℃,散热膜厚度为20μm时,GaN材料载流子迁移率降低9.8%,载流子浓度上升5.3%,(002)衍射峰半高宽增加40%。生长温度越高,金刚石散热膜的生长速率越快。当金刚石散热膜厚度相差不大时,生长温度越高,GaN所受拉应力越大,材料电特性衰退越明显。多晶金刚石高温生长过程中,金刚石引入的应力未对GaN结构产生破坏作用,GaN材料中没有出现孔洞等缺陷。