Dust deposition on the surface of photovoltaic (PV) cells poses a significant challenge to their efficiency, especially in arid regions characterized by desert and semi-desert conditions. Despite the pronounced impact...Dust deposition on the surface of photovoltaic (PV) cells poses a significant challenge to their efficiency, especially in arid regions characterized by desert and semi-desert conditions. Despite the pronounced impact of dust accumulation, these regions offer optimal solar radiation and minimal cloud cover, making them ideal candidates for widespread PV cell deployment. Various surface cleaning methods exist, each employing distinct approaches. Choosing an appropriate cleaning method requires a comprehensive understanding of the mechanisms involved in both dust deposition on module surfaces and dust adhesion to PV cell surfaces. The mechanisms governing dust deposition and adhesion are complex and multifaceted, influenced by factors such as the nature and properties of the dust particles, environmental climatic conditions, characteristics of protective coatings, and the specific location of the PV installation. These factors exhibit regional variations, necessitating the implementation of diverse cleaning approaches tailored to the unique conditions of each location. The first part of this article explores the factors influencing dust deposition on PV cell surfaces, delving into the intricate interplay of environmental variables and particle characteristics. Subsequently, the second part addresses various cleaning methods, offering an analysis of their respective advantages and disadvantages. By comprehensively examining the factors influencing dust accumulation and evaluating the effectiveness of different cleaning strategies, this article aims to contribute valuable insights to the ongoing efforts to optimize the performance and longevity of photovoltaic systems in diverse geographical contexts.展开更多
Fused deposition modelling(FDM), a widely used rapid prototyping process, is a promising technique in manufacturing engineering. In this work, a method for characterizing elastic constants of FDM-fabricated materials ...Fused deposition modelling(FDM), a widely used rapid prototyping process, is a promising technique in manufacturing engineering. In this work, a method for characterizing elastic constants of FDM-fabricated materials is proposed. First of all, according to the manufacturing process of FDM, orthotropic constitutive model is used to describe the mechanical behavior. Then the virtual fields method(VFM) is applied to characterize all the mechanical parameters(Q, Q, Q, Q) using the full-field strain,which is measured by digital image correlation(DIC). Since the principal axis of the FDM-fabricated structure is sometimes unknown due to the complexity of the manufacturing process, a disk in diametrical compression is used as the load configuration so that the loading angle can be changed conveniently. To verify the feasibility of the proposed method, finite element method(FEM) simulation is conducted to obtain the strain field of the disk. The simulation results show that higher accuracy can be achieved when the loading angle is close to 30?. Finally, a disk fabricated by FDM was used for the experiment. By rotating the disk, several tests with different loading angles were conducted. To determine the position of the principal axis in each test, two groups of parameters(Q, Q, Q, Q) are calculated by two different groups of virtual fields. Then the corresponding loading angle can be determined by minimizing the deviation between two groups of the parameters. After that, the four constants(Q, Q, Q, Q) were determined from the test with an angle of 27?.展开更多
An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced long...An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced longitudinal pressure gradient.But accumulation of pollutants such as N_2 and O_2 will decrease the adsorption ability of the NEG,leading to a reduction of NEG lifetime.Therefore,an NEG thin film coated with a layer of Pd,which has high diffusion rate and absorption ability for H_2,can extend the service life of NEG and improve the pumping rate of H_2 as well.In this paper,with argon as discharge gas,a magnetron sputtering method is adopted to prepare TiZrV-Pd films in a long straight pipe.By SEM measurement,deposition rates of TiZrV-Pd films are analyzed under different deposition parameters,such as magnetic field strength,gas flow rate,discharge current,discharge voltage and working pressure.By comparing the experimental results with the simulation results based on Sigmund's theory,the Pd deposition rate C can be estimated by the sputtered depth.展开更多
Introduction The East Kunlun Orogenic Belt is located in the northeastern part of the Qinghai–Tibet Plateau(Li et al.,2007),stretching from the East Kunlun to the Elashan area in an east–west direction(Guo et al.,20...Introduction The East Kunlun Orogenic Belt is located in the northeastern part of the Qinghai–Tibet Plateau(Li et al.,2007),stretching from the East Kunlun to the Elashan area in an east–west direction(Guo et al.,2018).It is an important part of the Central Orogenic Belt(Xiong et al.,2023).It is considered one of the important gold mineralization regions in the Tethys tectonic domain(Norbu et al.,2023)and an essential potential base for mineral resources in China.Wulonggou and Gouli gold mines have been discovered successively,earning the reputation of the"Golden Belt of Qinghai Province"(Feng et al.,2004;He et al.,2023).展开更多
The vapor deposition chemical reaction processes, which are of extremely extensive applications, can be classified as a mathematical model by the following governing nonlinear partial differential equations containing...The vapor deposition chemical reaction processes, which are of extremely extensive applications, can be classified as a mathematical model by the following governing nonlinear partial differential equations containing velocity vector, temperature field, pressure field, and gas mass field. The mixed finite element (MFE) method is employed to study the system of equations for the vapor deposition chemical reaction processes. The semidiscrete and fully discrete MFE formulations are derived. And the existence and convergence (error estimate) of the semidiscrete and fully discrete MFE solutions are demonstrated. By employing MFE method to treat the system of equations for the vapor deposition chemical reaction processes, the numerical solutions of the velocity vector, the temperature field, the pressure field, and the gas mass field can be found out simultaneously. Thus, these researches are not only of important theoretical means, but also of extremely extensive applied vistas.展开更多
The urgent need to develop customized functional products only possible by 3D printing had realized when faced with the unavailability of medical devices like surgical instruments during the coronavirus-19 disease and...The urgent need to develop customized functional products only possible by 3D printing had realized when faced with the unavailability of medical devices like surgical instruments during the coronavirus-19 disease and the ondemand necessity to perform surgery during space missions.Biopolymers have recently been the most appropriate option for fabricating surgical instruments via 3D printing in terms of cheaper and faster processing.Among all 3D printing techniques,fused deposition modelling(FDM)is a low-cost and more rapid printing technique.This article proposes the fabrication of surgical instruments,namely,forceps and hemostat using the fused deposition modeling(FDM)process.Excellent mechanical properties are the only indicator to judge the quality of the functional parts.The mechanical properties of FDM-processed parts depend on various process parameters.These parameters are layer height,infill pattern,top/bottom pattern,number of top/bottom layers,infill density,flow,number of shells,printing temperature,build plate temperature,printing speed,and fan speed.Tensile strength and modulus of elasticity are chosen as evaluation indexes to ascertain the mechanical properties of polylactic acid(PLA)parts printed by FDM.The experiments have performed through Taguchi’s L27orthogonal array(OA).Variance analysis(ANOVA)ascertains the significance of the process parameters and their percent contributions to the evaluation indexes.Finally,as a multiobjective optimization technique,grey relational analysis(GRA)obtains an optimal set of FDM process parameters to fabricate the best parts with comprehensive mechanical properties.Scanning electron microscopy(SEM)examines the types of defects and strong bonding between rasters.The proposed research ensures the successful fabrication of functional surgical tools with substantial ultimate tensile strength(42.6 MPa)and modulus of elasticity(3274 MPa).展开更多
As a direct wide bandgap semiconductor,CsPbCl_(3)has great potential applications in the eld of near-ultraviolet photodetectors,lasers and higher-order multiphoton uores-cent detectors.In this work,we synthesized CsPb...As a direct wide bandgap semiconductor,CsPbCl_(3)has great potential applications in the eld of near-ultraviolet photodetectors,lasers and higher-order multiphoton uores-cent detectors.In this work,we synthesized CsPbCl_(3)micro/nanocrystals by vapor depo-sition method with CsCl and PbCl_(2)powders as the source materials.It was con rmed that the formation of CsPbCl_(3)perovskite through the chemical reaction of CsCl with PbCl_(2)occurred in the quartz boat before the source evaporation,not in vapor or on sub-strate surface.The evaporated CsPbCl_(3)can form micro/nanocrystals on substrate surfaces under appropriate conditions.Various morphologies including irregular polyhedrons,rods and pyramids could be observed at lower temperature,while stable and uniform CsPbCl_(3)single crystal microplatelets were controllably synthesized at 450℃.Prolonging the growth time could modulate the size and density of the microcrystals,but could not change the morphology.Substrate types made little di erence to the morphology of CsPbCl_(3)crystals.The photoluminescence spectra indicated that the crystallinity and morphology of CsPbCl_(3)micro/nanocrystals have signi cant e ects on their optical properties.The work is expected to be helpful to the development of optoelectronic devices based on individual CsPbCl_(3)microcrystal.展开更多
Thin films of three types of fullerene derivatives were prepared through the electrospray deposition (ESD) method. The optimized conditions for the fabrication of the thin films were investigated for different types o...Thin films of three types of fullerene derivatives were prepared through the electrospray deposition (ESD) method. The optimized conditions for the fabrication of the thin films were investigated for different types of fullerene derivatives: [6,6]-phenyl-C61-butyric acid methyl ester, [6,6]-phenyl-C71-butyric acid methyl ester, and indene-C60-monoadduct. The spray diameter during the ESD process was observed as a function of the supply rate achieved by changing the applied voltage. In all cases, the spray diameter increased with increasing applied voltage, reaching the maximum diameter (Dmax) in the voltage range 4 to 6 kV. It was clear that Dmax was influenced by the dipole moments of the fullerene derivatives (as calculated by density functional theory methods). Scanning electron microscopy observation of the?fabricated thin films showed that imbricated structures were formed through the stacking of the fullerene-derivative sheets. Atomic force microscopy images revealed that the density of the imbricated structure was dependent on the spray diameter during the ESD process, and the root-mean-square roughness of the film surface decreased with increasing applied voltage. These findings suggest that the ESD method will be effective for the preparation of fullerene-derivative thin films for the production of organic devices.展开更多
Textured Bi and MnBi/Bi thin films are prepared by the pulsed laser deposition method. The highly c-axis textured MnBi films are obtained by annealing the bilayer consisting of textured Bi and Mn films. The eoerciviti...Textured Bi and MnBi/Bi thin films are prepared by the pulsed laser deposition method. The highly c-axis textured MnBi films are obtained by annealing the bilayer consisting of textured Bi and Mn films. The eoercivities of the MnBi/Bi film are 1.5 T and 2.35 T at room temperature and at 373K, respectively, showing a positive temperature coefficient. Microstructural investigations show that the textured MnBi film results from the orientated growth induced by the textured Bi under-layer.展开更多
A sequential deposition method is developed, where the hybrid organic-inorganic halide perovskite (CH3NH3Pb (I1-xBrx)3 ) is synthesized using precursor solutions containing CH3NH3I and PbBr2 with different mole ra...A sequential deposition method is developed, where the hybrid organic-inorganic halide perovskite (CH3NH3Pb (I1-xBrx)3 ) is synthesized using precursor solutions containing CH3NH3I and PbBr2 with different mole ratios and reaction times. The perovskite achieved here is quite stable in the atmosphere for a relatively long time without noticeable degradation, and the perovskite nanowires are proved to be single crystalline structure, based on transmission electron microscopy.Furthermore, strong red photoluminescence from perovskite is observed in the wavelength range from 746nm to 770nm with the increase of the reaction time, on account of the exchanges between I- ions and Br- ions in the perovskite crystal. Lastly, the influences of concentration and reaction time of the precursor solutions are discussed, which are important for evolution of hybrid perovskite from nanocuboid to nanowire and nanosheet.展开更多
Thin film deposition is one of the most important processes in IC manufacturing. In this paper, several typical models and numerical simulation methods for thin film deposition and atomic layer deposition are introduc...Thin film deposition is one of the most important processes in IC manufacturing. In this paper, several typical models and numerical simulation methods for thin film deposition and atomic layer deposition are introduced. Several modeling methods based on the characteristics of atomic layer deposition are introduced, it includes geometric method, cellular automata and multiscale simulation. The principle of each model and simulation method is explained, and their advantages and disadvantages are analyzed. Finally, the development direction of thin film deposition and atomic layer deposition modeling is prospected, and some modeling ideas are also provided.展开更多
Mn3O4was prepared with the chemical bath deposition(CBD) method. A Mn SO4 solution was obtained by the leaching and purifying of low-grade rhodochrosite ore(LGRO), which was used as raw material. The prepa ration proc...Mn3O4was prepared with the chemical bath deposition(CBD) method. A Mn SO4 solution was obtained by the leaching and purifying of low-grade rhodochrosite ore(LGRO), which was used as raw material. The prepa ration procedures were studied and promoted. The result showed that the Mn3O4 with the highest purity and highes specific surface area could be obtained under the following processes. An Mn SO4 solution of 1.0 mol/L was added into a beaker under a flow rate of 30 m L/h. The p H of the reaction solution was adjusted to 10 using NH3 H2 O a80 °C. Then the solids were washed and dried at 200 °C fo2.5 h. The total Mn content(TMC) of Mn3O4 was 72.0 %The ionic distributions was formulated as [Mn2?[Mn2??0.3024Mn30.2937Mn4?h0.37860.0254]2O4. The average crys tallite size of Mn3O4 with a tetragonal hausmannite struc ture was found to be about 35 nm by X-ray diffraction(XRD) analysis. The BET specific surface area of the Mn3O4 measured was 32 m2/g.展开更多
Deposition parameters that have great influences on hot filament chemical vapor deposition (HFCVD) diamond films growth on inner hole surfaces of WC?Co substrates mainly include the substrate temperature (t), carbon c...Deposition parameters that have great influences on hot filament chemical vapor deposition (HFCVD) diamond films growth on inner hole surfaces of WC?Co substrates mainly include the substrate temperature (t), carbon content (φ), total pressure (p) and total mass flow (F). Taguchi method was used for the experimental design in order to study the combined effects of the four parameters on the properties of as-deposited diamond films. A new figure-of-merit (FOM) was defined to assess their comprehensive performance. It is clarified thatt,φandp all have significant and complicated effects on the performance of the diamond film and the FOM, which also present some differences as compared with the previous studies on CVD diamond films growth on plane or external surfaces. Aiming to deposit HFCVD diamond films with the best comprehensive performance, the key deposition parameters were finally optimized as:t=830 °C,φ=4.5%,p=4000 Pa,F=800 mL/min.展开更多
Against the background of the sand-flow foundation treatment engineering of Guangzhou Zhoutouzui variable cross-section immersed tunnel, a kind of sand deposit-detecting method was devised on the basis of full-scale m...Against the background of the sand-flow foundation treatment engineering of Guangzhou Zhoutouzui variable cross-section immersed tunnel, a kind of sand deposit-detecting method was devised on the basis of full-scale model test of sand-flow method. The real-time data of sand-deposit height and radius were obtained by the self-developed sand-deposit detectors. The test results show that the detecting method is simple and has high precision. In the use of sand-flow method, the sand-carrying capability of fluid is limited, and sand particles are all transported to the sand-deposit periphery through crater, gap and chutes after the sand deposit formed. The diffusion range of the particles outside the sand-deposit does not exceed 2.0 m. Severe sorting of sand particles is not observed because of the unique oblique-layered depositing process. The temporal and spatial distributions of gap and chutes directly affect the sand-deposit expansion, and the expansion trend of the average sand-deposit radius accords with quadratic time-history curve.展开更多
Outwash deposit is a unique type of geological materials, and its features such as heterogeneity, discontinuity and nonlinearity determine the complexity of mechanical characteristics and failure mechanism. In this wo...Outwash deposit is a unique type of geological materials, and its features such as heterogeneity, discontinuity and nonlinearity determine the complexity of mechanical characteristics and failure mechanism. In this work, random meso-structure of outwash deposits was constructed by the technique of computer random simulation based on characteristics of its meso-structure in the statistical sense and some simplifications, and a series of large direct shear tests on numerical samples of outwash deposits with stone contents of 15%, 30%, 45% and 60% were conducted using the discrete element method to further investigate its mechanical characteristics and failure mechanism under external load. The results show that the deformation characteristics and shear strength of outwash deposits are to some extent improved with the increase of stone content, and the shear stress–shear displacement curves of outwash deposits show great differences at the post-peak stage due to the random spatial distribution and content of stones. From the mesoscopic view, normal directions of contacts between "soil" and "stone" particles undergo apparent deflection as the shear displacement continues during the shearing process, accompanying redistribution of the magnitude of contact forces during the shearing process. For outwash deposits, the shear zone formed after shear failure is an irregular stripe due to the movements of stones near the shear zone, and it expands gradually with the increase of stone content. In addition, there is an approximately linear relation between the mean increment of internal friction angle and the stone content lying between 30% and 60%, and a concave nonlinear relation between the mean increment of cohesion and stone content, which are in good agreement with the existing research results.展开更多
The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or...The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or low-pressure chemical vapor infiltration(LPCVI).In the field of ceramic matrix composites(CMCs),methyltrichlorosilane(CH3 SiCl3,MTS)is the most widely used source gas system for SiC,because stoichiometric SiC deposit can be facilitated at 900°C–1300°C.However,the reliability and accuracy of existing numerical models for these processing conditions are rarely reported.In this study,a comprehensive transport model was coupled with gas-phase and surface kinetics.The resulting gas-phase kinetics was confirmed via the measured concentration of gaseous species.The relationship between deposition rate and 24 gaseous species has been effectively evaluated by combining the special superiority of the novel extreme machine learning method and the conventional sticking coefficient method.Surface kinetics were then proposed and shown to reproduce the experimental results.The proposed simulation strategy can be used for different material systems.展开更多
La-doped and undoped xBiIn03-(1 - x)PbTi03 (BI-PT) thin films are deposited on (101)SrRuO3/(lOO)Pt/(lO0) MgO substrates by the rf-magnetron sputtering method. The structures of the films are characterized by...La-doped and undoped xBiIn03-(1 - x)PbTi03 (BI-PT) thin films are deposited on (101)SrRuO3/(lOO)Pt/(lO0) MgO substrates by the rf-magnetron sputtering method. The structures of the films are characterized by XRD and SEM, and the results indicate that the thin films are grown with mainly (100) oriented and columnar structures. The ferroelectricity and piezoelectricity of the BI-PT films are also measured, and the measured results illustrate that both performances are effectively improved by the La-doping with suitable concentrations. These results will open up wide potential applications of the films in electronic devices.展开更多
The effectiveness of optimizing electrical conductivity of carbon fiber/carbon nanotube (CNT)/epoxy hybrid composites via Taguchi method was demonstrated. CNTs were induced on carbon fabric by electrophoretic deposi...The effectiveness of optimizing electrical conductivity of carbon fiber/carbon nanotube (CNT)/epoxy hybrid composites via Taguchi method was demonstrated. CNTs were induced on carbon fabric by electrophoretic deposition (EPD) technique. The essential deposition parameters were identified as l) the deposition time, 2) the deposition voltage, 3) the mass fraction of CNTs in suspension, and 4) the distance between the electrodes. An experimental design was then performed to establish the appropriate levels for each factor. An orthogonal array of L9 (34) was designed to conduct the experiments. Electrical conductivity results were collected as the response. The relative influences of design parameters on the response were discussed. Using the model, signal to noise (S/N) ratio and response characteristics for the optimized deposition parameter combination were predicted. The results show clearly that the optimum condition of electrophoretic deposition (EPD) process improves the electrical conductivity of carbon/epoxy hybrid composites.展开更多
Nanoparticle transport and deposition in bends with circular cross-section are solved for different Reynolds numbers and Schmidt numbers. The perturbation method is used in solving the equations. The results show that...Nanoparticle transport and deposition in bends with circular cross-section are solved for different Reynolds numbers and Schmidt numbers. The perturbation method is used in solving the equations. The results show that the particle transport patterns are similar and independent of the particle size and other parameters when suspended nanoparticles flow in a straight tube. At the outside edge, particle deposition is the most intensive, while deposition at the inside edge is the weakest. In the upper and lower parts of the tube, depositions are approximately the same for different Schmidt numbers. Curvatures of tube, Reynolds number, and Schmidt number have second-order, forth-order, and first-order effects on the relative deposition efficiency, respectively.展开更多
Magnetic field was introduced in laser melting deposition to reduce the pores in workpieces.Finite 3-D model of the coil-deposition layer-substrate was established.Simulation results show that the electromagnetic forc...Magnetic field was introduced in laser melting deposition to reduce the pores in workpieces.Finite 3-D model of the coil-deposition layer-substrate was established.Simulation results show that the electromagnetic force in deposition layer mainly concentrates in the projection area of the coil.Axial electromagnetic force shows repulsion in one cycle.The experimental results indicate that the magnetic field is beneficial for grain refinement,microhardness increasement and decline of quantities and average sizes of pores.展开更多
文摘Dust deposition on the surface of photovoltaic (PV) cells poses a significant challenge to their efficiency, especially in arid regions characterized by desert and semi-desert conditions. Despite the pronounced impact of dust accumulation, these regions offer optimal solar radiation and minimal cloud cover, making them ideal candidates for widespread PV cell deployment. Various surface cleaning methods exist, each employing distinct approaches. Choosing an appropriate cleaning method requires a comprehensive understanding of the mechanisms involved in both dust deposition on module surfaces and dust adhesion to PV cell surfaces. The mechanisms governing dust deposition and adhesion are complex and multifaceted, influenced by factors such as the nature and properties of the dust particles, environmental climatic conditions, characteristics of protective coatings, and the specific location of the PV installation. These factors exhibit regional variations, necessitating the implementation of diverse cleaning approaches tailored to the unique conditions of each location. The first part of this article explores the factors influencing dust deposition on PV cell surfaces, delving into the intricate interplay of environmental variables and particle characteristics. Subsequently, the second part addresses various cleaning methods, offering an analysis of their respective advantages and disadvantages. By comprehensively examining the factors influencing dust accumulation and evaluating the effectiveness of different cleaning strategies, this article aims to contribute valuable insights to the ongoing efforts to optimize the performance and longevity of photovoltaic systems in diverse geographical contexts.
基金the financial support from the National Natural Science Foundation of China (Grants 11672153, 11232008, and 11227801)
文摘Fused deposition modelling(FDM), a widely used rapid prototyping process, is a promising technique in manufacturing engineering. In this work, a method for characterizing elastic constants of FDM-fabricated materials is proposed. First of all, according to the manufacturing process of FDM, orthotropic constitutive model is used to describe the mechanical behavior. Then the virtual fields method(VFM) is applied to characterize all the mechanical parameters(Q, Q, Q, Q) using the full-field strain,which is measured by digital image correlation(DIC). Since the principal axis of the FDM-fabricated structure is sometimes unknown due to the complexity of the manufacturing process, a disk in diametrical compression is used as the load configuration so that the loading angle can be changed conveniently. To verify the feasibility of the proposed method, finite element method(FEM) simulation is conducted to obtain the strain field of the disk. The simulation results show that higher accuracy can be achieved when the loading angle is close to 30?. Finally, a disk fabricated by FDM was used for the experiment. By rotating the disk, several tests with different loading angles were conducted. To determine the position of the principal axis in each test, two groups of parameters(Q, Q, Q, Q) are calculated by two different groups of virtual fields. Then the corresponding loading angle can be determined by minimizing the deviation between two groups of the parameters. After that, the four constants(Q, Q, Q, Q) were determined from the test with an angle of 27?.
基金supported by the National Natural Science Funds of China(No.11205155)Fundamental Research Funds for the Central Universities(WK2310000041)
文摘An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced longitudinal pressure gradient.But accumulation of pollutants such as N_2 and O_2 will decrease the adsorption ability of the NEG,leading to a reduction of NEG lifetime.Therefore,an NEG thin film coated with a layer of Pd,which has high diffusion rate and absorption ability for H_2,can extend the service life of NEG and improve the pumping rate of H_2 as well.In this paper,with argon as discharge gas,a magnetron sputtering method is adopted to prepare TiZrV-Pd films in a long straight pipe.By SEM measurement,deposition rates of TiZrV-Pd films are analyzed under different deposition parameters,such as magnetic field strength,gas flow rate,discharge current,discharge voltage and working pressure.By comparing the experimental results with the simulation results based on Sigmund's theory,the Pd deposition rate C can be estimated by the sputtered depth.
基金supported by Qinghai Provincial Association for Science and Technology Youth Science and Technology Talent Support Project(Grant No.2023QHSKXRCTJ47)Exploration Foundation of Qinghai Province(Grant No.2023085029ky004)。
文摘Introduction The East Kunlun Orogenic Belt is located in the northeastern part of the Qinghai–Tibet Plateau(Li et al.,2007),stretching from the East Kunlun to the Elashan area in an east–west direction(Guo et al.,2018).It is an important part of the Central Orogenic Belt(Xiong et al.,2023).It is considered one of the important gold mineralization regions in the Tethys tectonic domain(Norbu et al.,2023)and an essential potential base for mineral resources in China.Wulonggou and Gouli gold mines have been discovered successively,earning the reputation of the"Golden Belt of Qinghai Province"(Feng et al.,2004;He et al.,2023).
基金Project supported by the National Natural Science Foundation of China (Nos.10471100 and 40437017)the Science and Technology Foundation of Beijing Jiaotong University
文摘The vapor deposition chemical reaction processes, which are of extremely extensive applications, can be classified as a mathematical model by the following governing nonlinear partial differential equations containing velocity vector, temperature field, pressure field, and gas mass field. The mixed finite element (MFE) method is employed to study the system of equations for the vapor deposition chemical reaction processes. The semidiscrete and fully discrete MFE formulations are derived. And the existence and convergence (error estimate) of the semidiscrete and fully discrete MFE solutions are demonstrated. By employing MFE method to treat the system of equations for the vapor deposition chemical reaction processes, the numerical solutions of the velocity vector, the temperature field, the pressure field, and the gas mass field can be found out simultaneously. Thus, these researches are not only of important theoretical means, but also of extremely extensive applied vistas.
文摘The urgent need to develop customized functional products only possible by 3D printing had realized when faced with the unavailability of medical devices like surgical instruments during the coronavirus-19 disease and the ondemand necessity to perform surgery during space missions.Biopolymers have recently been the most appropriate option for fabricating surgical instruments via 3D printing in terms of cheaper and faster processing.Among all 3D printing techniques,fused deposition modelling(FDM)is a low-cost and more rapid printing technique.This article proposes the fabrication of surgical instruments,namely,forceps and hemostat using the fused deposition modeling(FDM)process.Excellent mechanical properties are the only indicator to judge the quality of the functional parts.The mechanical properties of FDM-processed parts depend on various process parameters.These parameters are layer height,infill pattern,top/bottom pattern,number of top/bottom layers,infill density,flow,number of shells,printing temperature,build plate temperature,printing speed,and fan speed.Tensile strength and modulus of elasticity are chosen as evaluation indexes to ascertain the mechanical properties of polylactic acid(PLA)parts printed by FDM.The experiments have performed through Taguchi’s L27orthogonal array(OA).Variance analysis(ANOVA)ascertains the significance of the process parameters and their percent contributions to the evaluation indexes.Finally,as a multiobjective optimization technique,grey relational analysis(GRA)obtains an optimal set of FDM process parameters to fabricate the best parts with comprehensive mechanical properties.Scanning electron microscopy(SEM)examines the types of defects and strong bonding between rasters.The proposed research ensures the successful fabrication of functional surgical tools with substantial ultimate tensile strength(42.6 MPa)and modulus of elasticity(3274 MPa).
基金supported by the National Natu-ral Science Foundation of China(No.11575187)the National Key Research and Development Program(No.2016YFB0700205).
文摘As a direct wide bandgap semiconductor,CsPbCl_(3)has great potential applications in the eld of near-ultraviolet photodetectors,lasers and higher-order multiphoton uores-cent detectors.In this work,we synthesized CsPbCl_(3)micro/nanocrystals by vapor depo-sition method with CsCl and PbCl_(2)powders as the source materials.It was con rmed that the formation of CsPbCl_(3)perovskite through the chemical reaction of CsCl with PbCl_(2)occurred in the quartz boat before the source evaporation,not in vapor or on sub-strate surface.The evaporated CsPbCl_(3)can form micro/nanocrystals on substrate surfaces under appropriate conditions.Various morphologies including irregular polyhedrons,rods and pyramids could be observed at lower temperature,while stable and uniform CsPbCl_(3)single crystal microplatelets were controllably synthesized at 450℃.Prolonging the growth time could modulate the size and density of the microcrystals,but could not change the morphology.Substrate types made little di erence to the morphology of CsPbCl_(3)crystals.The photoluminescence spectra indicated that the crystallinity and morphology of CsPbCl_(3)micro/nanocrystals have signi cant e ects on their optical properties.The work is expected to be helpful to the development of optoelectronic devices based on individual CsPbCl_(3)microcrystal.
文摘Thin films of three types of fullerene derivatives were prepared through the electrospray deposition (ESD) method. The optimized conditions for the fabrication of the thin films were investigated for different types of fullerene derivatives: [6,6]-phenyl-C61-butyric acid methyl ester, [6,6]-phenyl-C71-butyric acid methyl ester, and indene-C60-monoadduct. The spray diameter during the ESD process was observed as a function of the supply rate achieved by changing the applied voltage. In all cases, the spray diameter increased with increasing applied voltage, reaching the maximum diameter (Dmax) in the voltage range 4 to 6 kV. It was clear that Dmax was influenced by the dipole moments of the fullerene derivatives (as calculated by density functional theory methods). Scanning electron microscopy observation of the?fabricated thin films showed that imbricated structures were formed through the stacking of the fullerene-derivative sheets. Atomic force microscopy images revealed that the density of the imbricated structure was dependent on the spray diameter during the ESD process, and the root-mean-square roughness of the film surface decreased with increasing applied voltage. These findings suggest that the ESD method will be effective for the preparation of fullerene-derivative thin films for the production of organic devices.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51171001,51371009 and 50971003the Foundation of Key Laboratory of Neutron Physics of CAEP under Grant No 2014BB02
文摘Textured Bi and MnBi/Bi thin films are prepared by the pulsed laser deposition method. The highly c-axis textured MnBi films are obtained by annealing the bilayer consisting of textured Bi and Mn films. The eoercivities of the MnBi/Bi film are 1.5 T and 2.35 T at room temperature and at 373K, respectively, showing a positive temperature coefficient. Microstructural investigations show that the textured MnBi film results from the orientated growth induced by the textured Bi under-layer.
文摘A sequential deposition method is developed, where the hybrid organic-inorganic halide perovskite (CH3NH3Pb (I1-xBrx)3 ) is synthesized using precursor solutions containing CH3NH3I and PbBr2 with different mole ratios and reaction times. The perovskite achieved here is quite stable in the atmosphere for a relatively long time without noticeable degradation, and the perovskite nanowires are proved to be single crystalline structure, based on transmission electron microscopy.Furthermore, strong red photoluminescence from perovskite is observed in the wavelength range from 746nm to 770nm with the increase of the reaction time, on account of the exchanges between I- ions and Br- ions in the perovskite crystal. Lastly, the influences of concentration and reaction time of the precursor solutions are discussed, which are important for evolution of hybrid perovskite from nanocuboid to nanowire and nanosheet.
基金Beijing Natural Fund 4182021the National Natural Science Foundation of China 61874002+1 种基金the School of Information Science and Technology of North China University of Technology (NCUT) for financial supportthe Key Laboratory of Microelectronics Devices and Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences for advising.
文摘Thin film deposition is one of the most important processes in IC manufacturing. In this paper, several typical models and numerical simulation methods for thin film deposition and atomic layer deposition are introduced. Several modeling methods based on the characteristics of atomic layer deposition are introduced, it includes geometric method, cellular automata and multiscale simulation. The principle of each model and simulation method is explained, and their advantages and disadvantages are analyzed. Finally, the development direction of thin film deposition and atomic layer deposition modeling is prospected, and some modeling ideas are also provided.
基金supported jointly by the Bureau of Land Resources and Housing Management of Chongqing (Scientific & Technologic Program in 2011)
文摘Mn3O4was prepared with the chemical bath deposition(CBD) method. A Mn SO4 solution was obtained by the leaching and purifying of low-grade rhodochrosite ore(LGRO), which was used as raw material. The prepa ration procedures were studied and promoted. The result showed that the Mn3O4 with the highest purity and highes specific surface area could be obtained under the following processes. An Mn SO4 solution of 1.0 mol/L was added into a beaker under a flow rate of 30 m L/h. The p H of the reaction solution was adjusted to 10 using NH3 H2 O a80 °C. Then the solids were washed and dried at 200 °C fo2.5 h. The total Mn content(TMC) of Mn3O4 was 72.0 %The ionic distributions was formulated as [Mn2?[Mn2??0.3024Mn30.2937Mn4?h0.37860.0254]2O4. The average crys tallite size of Mn3O4 with a tetragonal hausmannite struc ture was found to be about 35 nm by X-ray diffraction(XRD) analysis. The BET specific surface area of the Mn3O4 measured was 32 m2/g.
基金Projects(51275302,51005154)supported by the National Natural Science Foundation of China
文摘Deposition parameters that have great influences on hot filament chemical vapor deposition (HFCVD) diamond films growth on inner hole surfaces of WC?Co substrates mainly include the substrate temperature (t), carbon content (φ), total pressure (p) and total mass flow (F). Taguchi method was used for the experimental design in order to study the combined effects of the four parameters on the properties of as-deposited diamond films. A new figure-of-merit (FOM) was defined to assess their comprehensive performance. It is clarified thatt,φandp all have significant and complicated effects on the performance of the diamond film and the FOM, which also present some differences as compared with the previous studies on CVD diamond films growth on plane or external surfaces. Aiming to deposit HFCVD diamond films with the best comprehensive performance, the key deposition parameters were finally optimized as:t=830 °C,φ=4.5%,p=4000 Pa,F=800 mL/min.
基金Project(51108190) supported by the National Natural Science Foundation of ChinaProject(2012ZC27) supported by the Independence Research Subject from State Key Laboratory of Subtropical Building Science,ChinaProject(GTCC 2008-253) supported by the Research Subject from Guangzhou City,China
文摘Against the background of the sand-flow foundation treatment engineering of Guangzhou Zhoutouzui variable cross-section immersed tunnel, a kind of sand deposit-detecting method was devised on the basis of full-scale model test of sand-flow method. The real-time data of sand-deposit height and radius were obtained by the self-developed sand-deposit detectors. The test results show that the detecting method is simple and has high precision. In the use of sand-flow method, the sand-carrying capability of fluid is limited, and sand particles are all transported to the sand-deposit periphery through crater, gap and chutes after the sand deposit formed. The diffusion range of the particles outside the sand-deposit does not exceed 2.0 m. Severe sorting of sand particles is not observed because of the unique oblique-layered depositing process. The temporal and spatial distributions of gap and chutes directly affect the sand-deposit expansion, and the expansion trend of the average sand-deposit radius accords with quadratic time-history curve.
基金Project(2011CB013504) supported by the National Basic Research Program(973 Program)of ChinaProject(2013BAB06B01) supported by the National Science&Technology Pillar Program during the Twelfth Five-year Plan Period+2 种基金Projects(11772118,51479049,51709282) supported by the National Natural Science Foundation of ChinaProject(2017M620838) supported by the Postdoctoral Science Foundation of ChinaProject(487237) supported by the Natural Sciences and Engineering Research Council of Canada
文摘Outwash deposit is a unique type of geological materials, and its features such as heterogeneity, discontinuity and nonlinearity determine the complexity of mechanical characteristics and failure mechanism. In this work, random meso-structure of outwash deposits was constructed by the technique of computer random simulation based on characteristics of its meso-structure in the statistical sense and some simplifications, and a series of large direct shear tests on numerical samples of outwash deposits with stone contents of 15%, 30%, 45% and 60% were conducted using the discrete element method to further investigate its mechanical characteristics and failure mechanism under external load. The results show that the deformation characteristics and shear strength of outwash deposits are to some extent improved with the increase of stone content, and the shear stress–shear displacement curves of outwash deposits show great differences at the post-peak stage due to the random spatial distribution and content of stones. From the mesoscopic view, normal directions of contacts between "soil" and "stone" particles undergo apparent deflection as the shear displacement continues during the shearing process, accompanying redistribution of the magnitude of contact forces during the shearing process. For outwash deposits, the shear zone formed after shear failure is an irregular stripe due to the movements of stones near the shear zone, and it expands gradually with the increase of stone content. In addition, there is an approximately linear relation between the mean increment of internal friction angle and the stone content lying between 30% and 60%, and a concave nonlinear relation between the mean increment of cohesion and stone content, which are in good agreement with the existing research results.
基金the National Key R&D Program of China(Grants No.2017YFB0703200)National Natural Science Foundation of China(Grants Nos.51702100,51972268)China Postdoctoral Science Foundation(Grants No.2018M643075)for financial support。
文摘The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or low-pressure chemical vapor infiltration(LPCVI).In the field of ceramic matrix composites(CMCs),methyltrichlorosilane(CH3 SiCl3,MTS)is the most widely used source gas system for SiC,because stoichiometric SiC deposit can be facilitated at 900°C–1300°C.However,the reliability and accuracy of existing numerical models for these processing conditions are rarely reported.In this study,a comprehensive transport model was coupled with gas-phase and surface kinetics.The resulting gas-phase kinetics was confirmed via the measured concentration of gaseous species.The relationship between deposition rate and 24 gaseous species has been effectively evaluated by combining the special superiority of the novel extreme machine learning method and the conventional sticking coefficient method.Surface kinetics were then proposed and shown to reproduce the experimental results.The proposed simulation strategy can be used for different material systems.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174142 and 11304160he National Basic Research Program of China under Grant No 2012CB921504the Special Fund for Public Interest of China under Grant No201510068
文摘La-doped and undoped xBiIn03-(1 - x)PbTi03 (BI-PT) thin films are deposited on (101)SrRuO3/(lOO)Pt/(lO0) MgO substrates by the rf-magnetron sputtering method. The structures of the films are characterized by XRD and SEM, and the results indicate that the thin films are grown with mainly (100) oriented and columnar structures. The ferroelectricity and piezoelectricity of the BI-PT films are also measured, and the measured results illustrate that both performances are effectively improved by the La-doping with suitable concentrations. These results will open up wide potential applications of the films in electronic devices.
基金Project supported by the Second Stage of Brain Korea 21 Projects and the National Research Foundation of Korea (2011-0030804) Funded by the Korea Government (MEST)
文摘The effectiveness of optimizing electrical conductivity of carbon fiber/carbon nanotube (CNT)/epoxy hybrid composites via Taguchi method was demonstrated. CNTs were induced on carbon fabric by electrophoretic deposition (EPD) technique. The essential deposition parameters were identified as l) the deposition time, 2) the deposition voltage, 3) the mass fraction of CNTs in suspension, and 4) the distance between the electrodes. An experimental design was then performed to establish the appropriate levels for each factor. An orthogonal array of L9 (34) was designed to conduct the experiments. Electrical conductivity results were collected as the response. The relative influences of design parameters on the response were discussed. Using the model, signal to noise (S/N) ratio and response characteristics for the optimized deposition parameter combination were predicted. The results show clearly that the optimum condition of electrophoretic deposition (EPD) process improves the electrical conductivity of carbon/epoxy hybrid composites.
基金supported by the National Natural Science Foundation of China (No. 10632070)
文摘Nanoparticle transport and deposition in bends with circular cross-section are solved for different Reynolds numbers and Schmidt numbers. The perturbation method is used in solving the equations. The results show that the particle transport patterns are similar and independent of the particle size and other parameters when suspended nanoparticles flow in a straight tube. At the outside edge, particle deposition is the most intensive, while deposition at the inside edge is the weakest. In the upper and lower parts of the tube, depositions are approximately the same for different Schmidt numbers. Curvatures of tube, Reynolds number, and Schmidt number have second-order, forth-order, and first-order effects on the relative deposition efficiency, respectively.
基金supported by the National Science Foundation of China(No.51475238)the Jiangsu Science and Technology Support Program(No.BE2014009-1)the Jiangsu Provincial Key Research and Development Plan (Nos.BE201561,BE201603-3)
文摘Magnetic field was introduced in laser melting deposition to reduce the pores in workpieces.Finite 3-D model of the coil-deposition layer-substrate was established.Simulation results show that the electromagnetic force in deposition layer mainly concentrates in the projection area of the coil.Axial electromagnetic force shows repulsion in one cycle.The experimental results indicate that the magnetic field is beneficial for grain refinement,microhardness increasement and decline of quantities and average sizes of pores.