A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysi...A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysis and FFIR. Surface properties of these surfactants were investigated. Due to the lipophilicity of adamantane, the critical micelle concentration （CMC） and C2o values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.展开更多
Reducing the emission of agrochemicals hazardous to the environment and human health is one of the key targets of the UN’s Sustainable Development Goal 12.Herein,we report a kind of quaternary ammonium pesticides wit...Reducing the emission of agrochemicals hazardous to the environment and human health is one of the key targets of the UN’s Sustainable Development Goal 12.Herein,we report a kind of quaternary ammonium pesticides with an acid-cleavable silaketal linkage on their backbones that enables control of hydrolysis.These pesticides possess outstanding bactericidal and insecticidal properties but become harmless to humans and other organisms after hydrolysis.Depending on the conditions of use,the hydrolytic process can be controlled over the time range of 10 min to 3 months.Both laboratory simulations and agricultural field demonstrations confirm that these pesticides can effectively protect crops from bacterial diseases and pests.At the sametime,single-dose intragastric administration using diisopropylsilyloxy bisquaternary ammonium salt 9(ISBQAS-9)in mice demonstrates its safety for multiple organs.Owing to the advantages of controllable degradability,environmental friendliness,and the low financial cost of these pesticides,this welldesigned strategy holds great promise for the generation of environmentally harmless pesticides and the development of green agriculture.展开更多
基金support by the Major Program of Guangdong University of Technology (No.405095220)
文摘A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysis and FFIR. Surface properties of these surfactants were investigated. Due to the lipophilicity of adamantane, the critical micelle concentration （CMC） and C2o values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.
基金the National Natural Science Foundation of China(grant nos.21825503 and 22335008).
文摘Reducing the emission of agrochemicals hazardous to the environment and human health is one of the key targets of the UN’s Sustainable Development Goal 12.Herein,we report a kind of quaternary ammonium pesticides with an acid-cleavable silaketal linkage on their backbones that enables control of hydrolysis.These pesticides possess outstanding bactericidal and insecticidal properties but become harmless to humans and other organisms after hydrolysis.Depending on the conditions of use,the hydrolytic process can be controlled over the time range of 10 min to 3 months.Both laboratory simulations and agricultural field demonstrations confirm that these pesticides can effectively protect crops from bacterial diseases and pests.At the sametime,single-dose intragastric administration using diisopropylsilyloxy bisquaternary ammonium salt 9(ISBQAS-9)in mice demonstrates its safety for multiple organs.Owing to the advantages of controllable degradability,environmental friendliness,and the low financial cost of these pesticides,this welldesigned strategy holds great promise for the generation of environmentally harmless pesticides and the development of green agriculture.
